Articles | Volume 11, issue 4
https://doi.org/10.5194/acp-11-1549-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-11-1549-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Feb 2011
Research article |
| 17 Feb 2011
Spatial variability of POPs in European background air
A. K. Halse
Norwegian Institute for Air Research (NILU), P.O. Box 100, 2027 Kjeller, Norway
M. Schlabach
Norwegian Institute for Air Research (NILU), P.O. Box 100, 2027 Kjeller, Norway
S. Eckhardt
Norwegian Institute for Air Research (NILU), P.O. Box 100, 2027 Kjeller, Norway
A. Sweetman
Department of Environmental Science, Institute of Environmental and Natural Sciences, Lancaster University, Lancaster, LA1 4YQ, UK
K. C. Jones
Department of Environmental Science, Institute of Environmental and Natural Sciences, Lancaster University, Lancaster, LA1 4YQ, UK
K. Breivik
Norwegian Institute for Air Research (NILU), P.O. Box 100, 2027 Kjeller, Norway
University of Oslo, Department of Chemistry, P.O. Box 1033, 0315 Oslo, Norway
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Automated compound speciation, cluster analysis, and quantification of organic vapors and aerosols using comprehensive two-dimensional gas chromatography and mass spectrometry
Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints
Bridging gas and aerosol properties between the northeastern US and Bermuda: analysis of eight transit flights
The behaviour of charged particles (ions) during new particle formation events in urban Leipzig, Germany
Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China
Measurement report: Characteristics of airborne black-carbon-containing particles during the 2021 summer COVID-19 lockdown in a typical Yangtze River Delta city, China
Aerosol optical properties within the atmospheric boundary layer predicted from ground-based observations compared to Raman lidar retrievals during RITA-2021
Hygroscopic growth and activation changed submicron aerosol composition and properties in the North China Plain
Measurement report: Formation of tropospheric brown carbon in a lifting air mass
Vertical variability of aerosol properties and trace gases over a remote marine region: a case study over Bermuda
Differences in aerosol and cloud properties along the central California coast when winds change from northerly to southerly
International airport emissions and their impact on local air quality: chemical speciation of ambient aerosols at Madrid–Barajas Airport during the AVIATOR campaign
The local ship speed reduction effect on black carbon emissions measured at a remote marine station
High-altitude aerosol chemical characterization and source identification: insights from the CALISHTO campaign
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – a short-term case study in Beijing
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Impact of cloud processes on secondary organic aerosols at a forested mountain site in southeastern China
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic in Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean
The water-insoluble organic carbon in PM2.5 of typical Chinese urban areas: light-absorbing properties, potential sources, radiative forcing effects, and a possible light-absorbing continuum
Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Atmospheric evolution of environmentally persistent free radicals in rural North China Plain: insights into water solubility and effects on PM2.5 oxidative potential
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
A Multi-site Passive Approach for Studying the Emissions and Evolution of Smoke from Prescribed Fires
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Two distinct ship emission profiles for organic-sulfate source apportionment of PM in sulfur emission control areas
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Primary and secondary emissions from a modern fleet of city buses
Enhanced daytime secondary aerosol formation driven by gas-particle partitioning in downwind urban plumes
Dominant Influence of Biomass Combustion and Cross-Border Transport on Nitrogen-Containing Organic Compound Levels in the Southeastern Tibetan Plateau
Impact assessment of terrestrial and marine air-mass on the constituents and intermixing of bioaerosols over coastal atmosphere
Assessing the influence of long-range transport of aerosols on the PM2.5 chemical composition and concentration in the Aburrá Valley
Measurement report: Characteristics of nitrogen-containing organics in PM2.5 in Ürümqi, northwestern China – differential impacts of combustion of fresh and aged biomass materials
Measurement report: Bio-physicochemistry of tropical clouds at Maïdo (Réunion, Indian Ocean): overview of results from the BIO-MAÏDO campaign
Impacts of elevated anthropogenic emissions on physicochemical characteristics of BC-containing particles over the Tibetan Plateau
Chemical properties and single-particle mixing state of soot aerosol in Houston during the TRACER campaign
Measurement report: Evaluation of the TOF-ACSM-CV for PM1.0 and PM2.5 measurements during the RITA-2021 field campaign
Sea salt reactivity over the northwest Atlantic: an in-depth look using the airborne ACTIVATE dataset
Measurement report: Atmospheric ice nuclei in the Changbai Mountains (2623 m a.s.l.) in northeastern Asia
Morphological and optical properties of carbonaceous aerosol particles from ship emissions and biomass burning during a summer cruise measurement in the South China Sea
Tropical tropospheric aerosol sources and chemical composition observed at high altitude in the Bolivian Andes
Chemical composition, sources and formation mechanism of urban PM2.5 in Southwest China: a case study at the beginning of 2023
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
Atmos. Chem. Phys., 24, 10655–10666, https://doi.org/10.5194/acp-24-10655-2024, https://doi.org/10.5194/acp-24-10655-2024, 2024
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This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Yu Xu, Tang Liu, Yi-Jia Ma, Qi-Bin Sun, Hong-Wei Xiao, Hao Xiao, Hua-Yun Xiao, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, https://doi.org/10.5194/acp-24-10531-2024, 2024
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This study investigates the characteristics of aminiums and ammonium in PM2.5 on clean and polluted winter days in 11 Chinese cities, highlighting the possibility of the competitive uptake of ammonia versus amines on acidic aerosols or the displacement of aminiums by ammonia under high-ammonia conditions. The overall results deepen the understanding of the spatiotemporal differences in aminium characteristics and formation in China.
Cassidy Soloff, Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Francesca Gallo, Johnathan W. Hair, Miguel Ricardo A. Hilario, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 10385–10408, https://doi.org/10.5194/acp-24-10385-2024, https://doi.org/10.5194/acp-24-10385-2024, 2024
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Using aircraft measurements over the northwestern Atlantic between the US East Coast and Bermuda and trajectory modeling of continental outflow, we identify trace gas and particle properties that exhibit gradients with offshore distance and quantify these changes with high-resolution measurements of concentrations and particle chemistry, size, and scattering properties. This work furthers our understanding of the complex interactions between continental and marine environments.
Alex Rowell, James Brean, David C. S. Beddows, Zongbo Shi, Avinash Kumar, Matti Rissanen, Miikka Dal Maso, Peter Mettke, Kay Weinhold, Maik Merkel, and Roy M. Harrison
Atmos. Chem. Phys., 24, 10349–10361, https://doi.org/10.5194/acp-24-10349-2024, https://doi.org/10.5194/acp-24-10349-2024, 2024
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Ions enhance the formation and growth rates of new particles, affecting the Earth's radiation budget. Despite these effects, there is little published data exploring the sources of ions in the urban environment and their role in new particle formation (NPF). Here we show that natural ion sources dominate in urban environments, while traffic is a secondary source. Ions contribute up to 12.7 % of the formation rate of particles, indicating that they are important for forming urban PM.
Yuan Cheng, Xu-bing Cao, Sheng-qiang Zhu, Zhi-qing Zhang, Jiu-meng Liu, Hong-liang Zhang, Qiang Zhang, and Ke-bin He
Atmos. Chem. Phys., 24, 9869–9883, https://doi.org/10.5194/acp-24-9869-2024, https://doi.org/10.5194/acp-24-9869-2024, 2024
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The agreement between observational and modeling results is essential for the development of efficient air pollution control strategies. Here we constrained the modeling results of carbonaceous aerosols by field observation in Northeast China, a historically overlooked but recently targeted region of national clean-air actions. Our study suggested that the simulation of agricultural fire emissions and secondary organic aerosols remains challenging.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
Atmos. Chem. Phys., 24, 9733–9748, https://doi.org/10.5194/acp-24-9733-2024, https://doi.org/10.5194/acp-24-9733-2024, 2024
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Short-term strict emission control can improve air quality, but its effectiveness needs assessment. During the 2021 summer COVID-19 lockdown in Yangzhou, we found that PM2.5 levels did not decrease despite reduced primary emissions. Aged black-carbon particles increased substantially due to higher O3 levels and transported pollutants. High humidity and low wind also played key roles. The results highlight the importance of a regionally balanced control strategy for future air quality management.
Xinya Liu, Diego Alves Gouveia, Bas Henzing, Arnoud Apituley, Arjan Hensen, Danielle van Dinther, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 9597–9614, https://doi.org/10.5194/acp-24-9597-2024, https://doi.org/10.5194/acp-24-9597-2024, 2024
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The vertical distribution of aerosol optical properties is important for their effect on climate. This is usually measured by lidar, which has limitations, most notably the assumption of a lidar ratio. Our study shows that routine surface-level aerosol measurements are able to predict this lidar ratio reasonably well within the lower layers of the atmosphere and thus provide a relatively simple and cost-effective method to improve lidar measurements.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
Atmos. Chem. Phys., 24, 9387–9399, https://doi.org/10.5194/acp-24-9387-2024, https://doi.org/10.5194/acp-24-9387-2024, 2024
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We deployed an advanced aerosol–fog sampling system at a rural site in the North China Plain to investigate impacts of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient relative humidity (RH) conditions and that RH levels significantly impact aerosol sampling through the aerosol swelling effect.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 9263–9275, https://doi.org/10.5194/acp-24-9263-2024, https://doi.org/10.5194/acp-24-9263-2024, 2024
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Brown carbon (BrC) is prevalent in the troposphere and can efficiently absorb solar and terrestrial radiation. Our observations show that the enhanced light absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Johnathan W. Hair, Miguel Ricardo A. Hilario, Chris A. Hostetler, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Cassidy Soloff, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9197–9218, https://doi.org/10.5194/acp-24-9197-2024, https://doi.org/10.5194/acp-24-9197-2024, 2024
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This study uses airborne data to examine vertical profiles of trace gases, aerosol particles, and meteorological variables over a remote marine area (Bermuda). Results show distinct differences based on both air mass source region (North America, Ocean, Caribbean/North Africa) and altitude for a given air mass type. This work highlights the sensitivity of remote marine areas to long-range transport and the importance of considering the vertical dependence of trace gas and aerosol properties.
Kira Zeider, Grace Betito, Anthony Bucholtz, Peng Xian, Annette Walker, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9059–9083, https://doi.org/10.5194/acp-24-9059-2024, https://doi.org/10.5194/acp-24-9059-2024, 2024
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The predominant wind direction along the California coast (northerly) reverses several times during the summer (to southerly). The effects of these wind reversals on aerosol and cloud characteristics are not well understood. Using data from multiple datasets we found that southerly flow periods had enhanced signatures of anthropogenic emissions due to shipping and continental sources, and clouds had more but smaller droplets.
Saleh Alzahrani, Doğuşhan Kılıç, Michael Flynn, Paul I. Williams, and James Allan
Atmos. Chem. Phys., 24, 9045–9058, https://doi.org/10.5194/acp-24-9045-2024, https://doi.org/10.5194/acp-24-9045-2024, 2024
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This paper investigates emissions from aviation activities at an international airport to evaluate their impact on local air quality. The study provides detailed insights into the chemical composition of aerosols and key pollutants in the airport environment. Source apportionment analysis using positive matrix factorisation (PMF) identified three significant sources: less oxidised oxygenated organic aerosol, alkane organic aerosol, and more oxidised oxygenated organic aerosol.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
Atmos. Chem. Phys., 24, 8927–8941, https://doi.org/10.5194/acp-24-8927-2024, https://doi.org/10.5194/acp-24-8927-2024, 2024
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Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams per kilogram of fuel. Ships with an exhaust gas cleaning system (EGCS) were found to have median BC emissions per fuel consumed 5 times lower than ships without an EGCS. However, this might be because of non-EGCS ships running at low engine loads rather than the EGCS itself. A local speed restriction would increase BC emissions of ships.
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 24, 8911–8926, https://doi.org/10.5194/acp-24-8911-2024, https://doi.org/10.5194/acp-24-8911-2024, 2024
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Characterization of PM1 and positive matrix factorization (PMF) source apportionment of organic and inorganic fractions were conducted at the high-altitude station (HAC)2. Cloud presence reduced PM1, affecting sulfate more than organics. Free-troposphere (FT) conditions showed more black carbon (eBC) than planetary boundary layer (PBL) conditions.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
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Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROSs) play an active role in the atmosphere. Despite control measures having effectively reduced their emissions, reductions were less than in PM2.5. Emission control measures performed well in achieving Parade Blue, but reducing the impact of the atmosphere on human health remains challenging. Thus, there is a need to reassess emission control measures to better address the challenges posed by EPFRs and ROSs.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 24, 8507–8518, https://doi.org/10.5194/acp-24-8507-2024, https://doi.org/10.5194/acp-24-8507-2024, 2024
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The water solubility of secondary organic aerosols (SOAs) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOAs with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyan Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
Atmos. Chem. Phys., 24, 8473–8488, https://doi.org/10.5194/acp-24-8473-2024, https://doi.org/10.5194/acp-24-8473-2024, 2024
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We investigated aerosol composition and sources and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more oxidized SOA; however, cloud evaporation leads to the production of less oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
Atmos. Chem. Phys., 24, 8397–8411, https://doi.org/10.5194/acp-24-8397-2024, https://doi.org/10.5194/acp-24-8397-2024, 2024
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Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Maya Abou-Ghanem, Daniel M. Murphy, Gregory P. Schill, Michael J. Lawler, and Karl D. Froyd
Atmos. Chem. Phys., 24, 8263–8275, https://doi.org/10.5194/acp-24-8263-2024, https://doi.org/10.5194/acp-24-8263-2024, 2024
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Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
Atmos. Chem. Phys., 24, 8049–8066, https://doi.org/10.5194/acp-24-8049-2024, https://doi.org/10.5194/acp-24-8049-2024, 2024
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To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate in Barbados and compared them to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable, except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions in sulfur dioxide (SO2) in the US and Europe; then it increased in the 2000s, likely due to anthropogenic emissions from Africa.
Jiao Xue, Tian Zhang, Keyhong Park, Jinpei Yan, Young Jun Yoon, Jiyeon Park, and Bingbing Wang
Atmos. Chem. Phys., 24, 7731–7754, https://doi.org/10.5194/acp-24-7731-2024, https://doi.org/10.5194/acp-24-7731-2024, 2024
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Ice formation by particles is an important way of making mixed-phase and ice clouds. We found that particles collected in the marine atmosphere exhibit diverse ice nucleation abilities and mixing states. Sea salt mixed-sulfate particles were enriched in ice-nucleating particles. Selective aging on sea salt particles made particle populations more externally mixed. Characterizations of particles and their mixing state are needed for a better understanding of aerosol–cloud interactions.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 24, 7755–7772, https://doi.org/10.5194/acp-24-7755-2024, https://doi.org/10.5194/acp-24-7755-2024, 2024
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In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %) were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibiting the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O'Dowd
Atmos. Chem. Phys., 24, 7687–7698, https://doi.org/10.5194/acp-24-7687-2024, https://doi.org/10.5194/acp-24-7687-2024, 2024
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The chemical composition of atmospheric particles has shown significant changes in recent years. We investigated the potential effects of changes in inorganics on aerosol water uptake and, thus, secondary organic aerosol formation in wintertime haze based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, northwestern China. We highlight the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
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Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
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The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
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The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Xu Yang, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi He, and Haijie Tong
EGUsphere, https://doi.org/10.5194/egusphere-2024-1622, https://doi.org/10.5194/egusphere-2024-1622, 2024
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A study in rural North China Plain revealed Environmental persistent free radicals (EPFRs) in atmospheric particulate matter (PM), with a notable water-soluble fraction likely from atmospheric oxidation during transport. Significant positive correlations between EPFRs and the water-soluble oxidative potential of PM2.5 were found, primarily attributable to the water-soluble fractions of EPFRs. These findings emphasize understanding EPFRs’ atmospheric evolution for climate and health impacts.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
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We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Rime El Asmar, Zongrun Li, David J. Tanner, Yongtao Hu, Susan O’Neill, L. Gregory Huey, M. Talat Odman, and Rodney J. Weber
EGUsphere, https://doi.org/10.5194/egusphere-2024-1485, https://doi.org/10.5194/egusphere-2024-1485, 2024
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Prescribed burning is an important method for managing ecosystems and preventing wildfires, however, smoke from prescribed fires can have a significant impact on air quality. Here, using a network of fixed sites and sampling throughout an extended prescribed burning period in two different years, we characterize the emissions and evolution up to 8 hours of PM2.5 mass, BC, and BrC in smoke from burning of forested lands in the southeastern US.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Kirsten N. Fossum, Chunshui Lin, Niall O'Sullivan, Lu Lei, Stig Hellebust, Darius Ceburnis, Aqeel Afzal, Anja Tremper, David Green, Srishti Jain, Steigvilė Byčenkienė, Colin O'Dowd, John Wenger, and Jurgita Ovadnevaite
EGUsphere, https://doi.org/10.5194/egusphere-2024-1262, https://doi.org/10.5194/egusphere-2024-1262, 2024
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The chemical composition and sources of submicron aerosol in the Dublin Port area were investigated over a month-long campaign. Two distinct types of ship emissions were identified and characterized: sulfate-rich plumes from use of heavy fuel oil with scrubbers and organic-rich plumes from use of low sulfur fuels. The latter were more frequent, emitting double the particle number, and having atypical V/Ni ratio for ship emission.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Liyuan Zhou, Qianyun Liu, Christian M. Salvador, Michael Le Breton, Mattias Hallquist, Jian Zhen Yu, Chak K. Chan, and Åsa M. Hallquist
EGUsphere, https://doi.org/10.5194/egusphere-2024-494, https://doi.org/10.5194/egusphere-2024-494, 2024
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Our research on city bus emissions reveals that alternative fuels (compressed natural gas and biofuels) reduce fresh particle emissions compared to diesel. However, all fuels lead to secondary air pollution. Aiming at guiding better environmental policies, we studied 76 buses using advanced emission measurement techniques. This work sheds light on the complex effects of bus fuels on urban air quality, emphasizing the need for comprehensive evaluations of future transportation technologies.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
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This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
Meng Wang, Qiyuan Wang, Steven Sai Hang Ho, Jie Tian, Yong Zhang, Shun-cheng Lee, and Junji Cao
EGUsphere, https://doi.org/10.5194/egusphere-2024-1130, https://doi.org/10.5194/egusphere-2024-1130, 2024
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This study explores nitrogen-containing organic compounds (NOCs) in PM2.5 particles on the Southeastern Tibetan Plateau. We discovered that biomass burning and transboundary transport are the primary sources of NOCs in the high-altitude area. Understanding these aerosol sources informs how they contribute to regional and potentially global climate changes. Our findings could help shape effective environmental policies to enhance air quality and address climate impacts in this sensitive region.
Qun He, Zhaowen Wang, Houfeng Liu, Pengju Xu, Rongbao Duan, Caihong Xu, Jianmin Chen, and Min Wei
EGUsphere, https://doi.org/10.5194/egusphere-2024-841, https://doi.org/10.5194/egusphere-2024-841, 2024
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Coastal environments provide an ideal setting for investigating the intermixing processes of terrestrial and marine aerosols. Terrestrial air mass constituted a larger proportion during severe air pollution, harboring more animal and human pathogens. A relative shift towards marine air-mass with respect to pollution elimination, where saprophytic bacteria and fungi were predominant. Mixed air-mass reveals the intermixing processes of terrestrial and marine sources.
Maria P. Velásquez-García, K. Santiago Hernández, James A. Vergara-Correa, Richard J. Pope, Miriam Gómez-Marín, and Angela M. Rendón
EGUsphere, https://doi.org/10.5194/egusphere-2024-695, https://doi.org/10.5194/egusphere-2024-695, 2024
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For the Aburrá Valley, Colombia, local emissions dominate aerosol concentrations, which degrade air quality (AQ) and impact human health. However, this can be exacerbated by the influx of external emissions from sources such as regional fires, Saharan dust, and volcanic degassing. While substantially increasing city-wide aerosols, these external sources can also degrade the aerosol chemical composition (i.e. their toxicity) and impact AQ, which we investigate in this study.
Yi-Jia Ma, Yu Xu, Ting Yang, Hong-Wei Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 24, 4331–4346, https://doi.org/10.5194/acp-24-4331-2024, https://doi.org/10.5194/acp-24-4331-2024, 2024
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This study provides field-based evidence about the differential impacts of combustion of fresh and aged biomass materials on aerosol nitrogen-containing organic compounds (NOCs) in different seasons in Ürümqi, bridging the linkages between the observations and previous laboratory studies showing the formation mechanisms of NOCs.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Jinbo Wang, Jiaping Wang, Yuxuan Zhang, Tengyu Liu, Xuguang Chi, Xin Huang, Dafeng Ge, Shiyi Lai, Caijun Zhu, Lei Wang, Qiaozhi Zha, Ximeng Qi, Wei Nie, Congbin Fu, and Aijun Ding
EGUsphere, https://doi.org/10.5194/egusphere-2024-879, https://doi.org/10.5194/egusphere-2024-879, 2024
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In this study, we found large spatial discrepancies in the physical and chemical properties of black carbon over the Tibetan Plateau (TP). Elevated anthropogenic emissions from low-altitude regions can significantly change the mass concentration, mixing state and chemical composition of black carbon -containing aerosol in TP region, further altering its light absorption ability. Our study emphasizes the vulnerability of remote plateau regions to intense anthropogenic influences.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
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The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Xinya Liu, Bas Henzing, Arjan Hensen, Jan Mulder, Peng Yao, Danielle van Dinther, Jerry van Bronckhorst, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 3405–3420, https://doi.org/10.5194/acp-24-3405-2024, https://doi.org/10.5194/acp-24-3405-2024, 2024
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We evaluated the time-of-flight aerosol chemical speciation monitor (TOF-ACSM) following the implementation of the PM2.5 aerodynamic lens and a capture vaporizer (CV). The results showed that it significantly improved the accuracy and precision of ACSM in the field observations. The paper elucidates the measurement outcomes of various instruments and provides an analysis of their biases. This comprehensive evaluation is expected to benefit the ACSM community and other aerosol field measurements.
Eva-Lou Edwards, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Claire E. Robinson, Michael A. Shook, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 3349–3378, https://doi.org/10.5194/acp-24-3349-2024, https://doi.org/10.5194/acp-24-3349-2024, 2024
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We investigate Cl− depletion in sea salt particles over the northwest Atlantic from December 2021 to June 2022 using an airborne dataset. Losses of Cl− are greatest in May and least in December–February and March. Inorganic acidic species can account for all depletion observed for December–February, March, and June near Bermuda but none in May. Quantifying Cl− depletion as a percentage captures seasonal trends in depletion but fails to convey the effects it may have on atmospheric oxidation.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Cuizhi Sun, Yongyun Zhang, Baoling Liang, Min Gao, Xi Sun, Fei Li, Xue Ni, Qibin Sun, Hengjia Ou, Dexian Chen, Shengzhen Zhou, and Jun Zhao
Atmos. Chem. Phys., 24, 3043–3063, https://doi.org/10.5194/acp-24-3043-2024, https://doi.org/10.5194/acp-24-3043-2024, 2024
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In a May–June 2021 expedition in the South China Sea, we analyzed black and brown carbon in marine aerosols, key to light absorption and climate impact. Using advanced in situ and microscope techniques, we observed particle size, structure, and tar balls mixed with various elements. Results showed biomass burning and fossil fuels majorly influence light absorption, especially during significant burning events. This research aids the understanding of carbonaceous aerosols' role in marine climate.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Cited articles
Aas, W. and Breivik, K.: Heavy metals and POPs measurements, 2006 Co-operative programme for monitoring and evaluation of long range transmission of air pollutants in Europe (EMEP), NILU, Kjeller, 2008.
Aas, W. and Breivik, K.: Heavy metals and POP measurements 2007, Co-operative programm for monitoring and evaluation of long-range transmissions of air pollutants in Europe, NILU, KjellerO-95038/O-99050, 3-117, 2009.
Bailey, R. E.: Global hexachlorobenzene emissions, Chemosphere, 43, 167–182, 2001.
Barber, J. L., Sweetman, A. J., van Wijk, D., and Jones, K. C.: Hexachlorobenzene in the global environment: Emissions, levels, distribution, trends and processes, Sci. Total Environ., 349, 1–44, https://doi.org/10.1016/j.sciotenv.2005.03.014, 2005.
Bartkow, M. E., Jones, K. C., Kennedy, K. E., Holling, N., Hawker, D. W., and Müller, J. F.: Evaluation of performance reference compounds in polyethylene-based passive air samplers, Environ. Pollut., 144, 365–370, https://doi.org/10.1016/j.envpol.2005.12.043, 2006a.
Bartkow, M. E., Kennedy, K. E., Huckins, J. N., Holling, N., Komarova, T., and Müller, J. F.: Photodegradation of polyaromatic hydrocarbons in passive air samplers: Field testing different deployment chambers, Environ. Pollut., 144, 371–376, https://doi.org/10.1016/j.envpol.2005.12.050, 2006b.
Becker, S.: Trends and behaviour of semi-volatile organic compounds in the Artic Atmosphere, Ph.D., Environmental Science Department, Lancaster University, Lancaster, UK, 2008.
Beyer, A., Mackay, D., Matthies, M., Wania, F., and Webster, E.: Assessing long-range transport potential of persistent organic pollutants, Environ. Sci. Technol., 34, 699–703, 2000.
Bidleman, T. F., Jantunen, L. M. M., Helm, P. A., Brorstrom-Lunden, E., and Juntto, S.: Chlordane enantiomers and temporal trends of chlordane isomers in arctic air, Environ. Sci. Technol., 36, 539–544, https://doi.org/10.1021/es011142b, 2002.
Breivik, K. and Wania, F.: Mass budgets, pathways, and equilibrium states of two hexachlorocyclohexanes in the Baltic Sea environment, Environ. Sci. Technol., 36, 1024–1032, https://doi.org/10.1021/es001972+, 2002.
Breivik, K., Pacyna, J. M., and Munch, J.: Use of alpha-, beta- and gamma-hexachlorocyclohexane in Europe, 1970–1996, Sci. Total. Environ., 239, 151–163, 1999.
Breivik, K., Sweetman, A., Pacyna, J. M., and Jones, K. C.: Towards a global historical emission inventory for selected PCB congeners – A mass balance approach-3. An update, Sci. Total Environ., 377, 296–307, https://doi.org/10.1016/j.scitotenv.2007.02.026, 2007.
Chaemfa, C., Barber, J. L., Gocht, T., Harner, T., Holoubek, I., Klanova, J., and Jones, K. C.: Field calibration of polyurethane foam (PUF) disk passive air samplers for PCBs and OC pesticides, Environ. Pollut., 156, 1290–1297, https://doi.org/10.1016/j.envpol.2008.03.016, 2008.
Chaemfa, C., Barber, J. L., Kim, K. S., Harner, T., and Jones, K. C.: Further studies on the uptake of persistent organic pollutants (POPs) by polyurethane foam disk passive air samplers, Atmos. Environ., 43, 3843–3849, https://doi.org/10.1016/j.atmosenv.2009.05.020, 2009a.
Chaemfa, C., Wild, E., Davison, B., Barber, J. L., and Jones, K. C.: A study of aerosol entrapment and the influence of wind speed, chamber design and foam density on polyurethane foam passive air samplers used for persistent organic pollutants, J. Environ. Monit., 11, 1135–1139, https://doi.org/10.1039/b823016a, 2009b.
Dearth, M. A. and Hites, R. A.: Highly chlorinated dimethanofluorenes in technical chlordane and in human adipose-tissue, J. Am. Soc. Mass. Spectr., 1, 99–103, 1990.
Eckhardt, S., Breivik, K., Li, Y. F., Man$ø$, S., and Stohl, A.: Source regions of some persistent organic pollutants measured in the atmosphere at Birkenes, Norway, Atmos. Chem. Phys., 9, 6597–6610, https://doi.org/10.5194/acp-9-6597-2009, 2009.
Gillespie, M. J., Lythgo, C. M., Plumb, A. D., and Wilkins, J. P. G.: A survey comparing the chemical composition of dicofol formulations sold in the UK before and after the introduction of the EC prohibition directive 79/117/EEC, Pestic. Sci., 42, 305–314, 1994.
Gouin, T., Harner, T., Blanchard, P., and Mackay, D.: Passive and active air samplers as complementary methods for investigating persistent organic pollutants in the Great Lakes basin, Environ. Sci. Technol., 39, 9115–9122, https://doi.org/10.1021/ES051387f, 2005a.
Gouin, T., Harner, T., Daly, G. L., Wania, F., Mackay, D., and Jones, K. C.: Variability of concentrations of polybrominated diphenyl ethers and polychlorinated biphenyls in air: implications for monitoring, modeling and control, Atmos. Environ., 39, 151–166, https://doi.org/10.1016/j.atmosenv.2004.09.022, 2005b.
Gouin, T., Wania, F., Ruepert, C., and Castillo, L. E.: Field testing passive air samplers for current use pesticides in a tropical environment, Environ. Sci. Technol., 42, 6625–6630, https://doi.org/10.1021/es8008425, 2008.
Halsall, C. J., Coleman, P. J., Davis, B. J., Burnett, V., Waterhouse, K. S., Hardingjones, P., and Jones, K. C.: Polycyclic aromatic-hydrocarbons in UK urban air, Environ. Sci. Technol., 28, 2380–2386, 1994.
Harju, M., Haglund, P., and Naikwadi, K., P: Gas-chromatographic properties of the 209 PCB congeners on non-polar, chiral and liquid-crystal columns, Organohalogen compounds, 35, 111–114, 1998.
Harner, T. and Bidleman, T. F: Measurement of octanol-air partition coefficients for polychlorinated biphenyls, J. Chem. Eng. Data, 41, 895–899, 1996.
Harner, T., Shoeib, M., Diamond, M., Stern, G., and Rosenberg, B.: Using passive air samplers to assess urban – Rural trends for persistent organic pollutants. 1. Polychlorinated biphenyls and organochlorine pesticides, Environ. Sci. Technol., 38, 4474–4483, https://doi.org/10.1021/es040302r, 2004.
Harner, T., Bartkow, M., Holoubek, I., Klanova, J., Wania, F., Gioia, R., Moeckel, C., Sweetman, A. J., and Jones, K. C.: Passive air sampling for persistent organic pollutants: Introductory remarks to the special issue, Environ. Pollut., 144, 361–364, https://doi.org/10.1016/j.envpol.2005.12.044, 2006a.
Harner, T., Pozo, K., Gouin, T., Macdonald, A. M., Hung, H., Cainey, J., and Peters, A.: Global pilot study for persistent organic pollutants (POPs) using PUF disk passive air samplers, Environ. Pollut., 144, 445–452, https://doi.org/10.1016/j.envpol.2005.12.053, 2006b.
Harner, T., Shoeib, M., Diamond, M., Ikonomou, M., and Stern, G.: Passive sampler derived air concentrations of PBDEs along an urban-rural transect: Spatial and temporal trends, Chemosphere, 64, 262–267, https://doi.org/10.1016/j.chemosphere.2005.12.018, 2006c.
Hayward, S. J., Gouin, T., and Wania, F.: Comparison of Four Active and Passive Sampling Techniques for Pesticides in Air, Environ. Sci. Technol., 44, 3410–3416, https://doi.org/10.1021/es902512h, 2010.
Huckins, J. N., Petty, J. D., Lebo, J. A., Almeida, F. V., Booij, K., Alvarez, D. A., Clark, R. C., and Mogensen, B. B.: Development of the permeability/performance reference compound approach for in situ calibration of semipermeable membrane devices, Environ. Sci. Technol., 36, 85–91, https://doi.org/10.1021/es010991w, 2002.
Hung, H., Kallenborn, R., Breivik, K., Su, Y., Brorström-Lundén, E., Olafsdottir, K., Thorlacius, J. M., Leppänen, S., Bossi, R., Skov, H., Manø, S., Patton, G. W., Stern, G., Sverko, E., and Fellin, P.: Atmospheric monitoring of organic pollutants in the Arctic under the Arctic Monitoring and Assessment Programme (AMAP): 1993–2006, Sci. Total Environ., in press, Corrected Proof, https://doi.org/10.1016, 2010.
Jaward, F. M., Farrar, N. J., Harner, T., Sweetman, A. J., and Jones, K. C.: Passive air sampling of PCBs, PBDEs, and organochlorine pesticides across Europe, Environ. Sci. Technol., 38, 34–41, https://doi.org/10.1021/es034705n, 2004a.
Jaward, F. M., Farrar, N. J., Harner, T., Sweetman, A. J., and Jones, K. C.: Passive air sampling of polycyclic aromatic hydrocarbons and polychlorinated naphthalenes across Europe, Environ. Toxicol. Chem., 23, 1355–1364, 2004b.
Jaward, T. M., Zhang, G., Nam, J. J., Sweetman, A. J., Obbard, J. P., Kobara, Y., and Jones, K. C.: Passive air sampling of polychlorinated biphenyls, organochlorine compounds, and polybrominated diphenyl ethers across Asia, Environ. Sci. Technol., 39, 8638–8645, https://doi.org/10.1021/es051382h, 2005.
Kennedy, K., Hawker, D. W., Bartkow, M. E., Carter, S., Ishikawa, Y., and Mueller, J. F.: The potential effect of differential ambient and deployment chamber temperatures on PRC derived sampling rates with polyurethane foam (PUF) passive air samplers, Environ. Pollut., 158, 142–147, https://doi.org/10.1016/j.envpol.2009.07.031, 2010.
Klanova, J., Eupr, P., Kohoutek, J., and Harner, T.: Assessing the influence of meteorological parameters on the performance of polyurethane foam-based passive air samplers, Environ. Sci. Technol., 42, 550–555, https://doi.org/10.1021/es072098o, 2008.
Li, N. Q., Wania, F., Lei, Y. D., and Daly, G. L.: A comprehensive and critical compilation, evaluation, and selection of physical-chemical property data for selected polychlorinated biphenyls, J. Phys. Chem. Ref. Data., 32, 1545–1590, https://doi.org/10.1063/1.1562632, 2003.
Li, Y. F.: Global technical hexachlorocyclohexane usage and its contamination consequences in the environment: from 1948 to 1997, Sci. Total. Environ., 232, 121–158, 1999.
Li, Y. F., McMillan, A., and Scholtz, M. T.: Global HCH usage with 1 degrees x1 degrees longitude/latitude resolution, Environ. Sci. Technol., 30, 3525–3533, 1996.
Li, Y. F., Macdonald, R. W., Jantunen, L. M. M., Harner, T., Bidleman, T. F., and Strachan, W. M. J.: The transport of beta-hexachlorocyclohexane to the western Arctic Ocean: a contrast to alpha-HCH, Sci. Total Environ., 291, 229–246, 2002.
Li, Y. F., Harner, T., Liu, L. Y., Zhang, Z., Ren, N. Q., Jia, H. L., Ma, J. M., and Sverko, E.: Polychlorinated Biphenyls in Global Air and Surface Soil: Distributions, Air-Soil Exchange, and Fractionation Effect, Environ. Sci. Technol., 44, 2784–2790, https://doi.org/10.1021/es901871e, 2010.
List of signatories and ratifications to the Stockholm Convention on POPs: http://www.pops.int/documents/signature/signstatus.htm, 2003.
Lohmann, R., Northcott, G. L., and Jones, K. C.: Assessing the contribution of diffuse domestic burning as a source of PCDD/Fs, PCBs, and PAHs to the UK atmosphere, Environ. Sci. Technol., 34, 2892–2899, https://doi.org/10.1021/es991183w, 2000.
Malanichev, A., Mantseva, E., Shatalov, V., Strukov, B., and Vulykh, N.: Numerical evaluation of the PCBs transport over the Northern Hemisphere, Environ. Pollut., 128, 279–289, https://doi.org/10.1016/j.envpol.2003.08.040, 2004.
Mari, M., Schuhmacher, M., Feliubadalo, J., and Domingo, J. L.: Air concentrations of PCDD/Fs, PCBs and PCNs using active and passive air samplers, Chemosphere, 70, 1637–1643, https://doi.org/10.1016/j.chemosphere.2007.07.076, 2008.
Meijer, S. N., Ockenden, W. A., Sweetman, A., Breivik, K., Grimalt, J. O., and Jones, K. C.: Global distribution and budget of PCBs and HCB in background surface soils: Implications or sources and environmental processes, Environ. Sci. Technol., 37, 667–672, https://doi.org/10.1021/es025809l, 2003.
Moeckel, C., Harner, T., Nizzetto, L., Strandberg, B., Lindroth, A., and Jones, K. C.: Use of Depuration Compounds in Passive Air Samplers: Results from Active Sampling-Supported Field Deployment, Potential Uses, and Recommendations, Environ. Sci. Technol., 43, 3227–3232, https://doi.org/10.1021/es802897x, 2009.
Motelay-Massei, A., Harner, T., Shoeib, M., Diamond, M., Stern, G., and Rosenberg, B.: Using passive air samplers to assess urban-rural trends for persistent organic pollutants and polycyclic aromatic hydrocarbons. 2. Seasonal trends for PAHs, PCBs, and organochlorine pesticides, Environ. Sci. Technol., 39, 5763–5773, https://doi.org/10.1021/es0504183, 2005.
Pacyna, J. M., Breivik, K., Munch, J., and Fudala, J.: European atmospheric emissions of selected persistent organic pollutants, 1970–1995, S119–S131, 2003.
Pozo, K., Harner, T., Shoeib, M., Urrutia, R., Barra, R., Parra, O., and Focardi, S.: Passive-sampler derived air concentrations of persistent organic pollutants on a north-south transect in Chile, Environ. Sci. Technol., 38, 6529–6537, https://doi.org/10.1021/es049065i, 2004.
Pozo, K., Harner, T., Wania, F., Muir, D. C. G., Jones, K. C., and Barrie, L. A.: Toward a global network for persistent organic pollutants in air: Results from the GAPS study, Environ. Sci. Technol., 40, 4867–4873, https://doi.org/10.1021/es060447t, 2006.
Pozo, K., Harner, T., Lee, S. C., Wania, F., Muir, D. C. G., and Jones, K. C.: Seasonally Resolved Concentrations of Persistent Organic Pollutants in the Global Atmosphere from the First Year of the GAPS Study, Environ. Sci. Technol., 43, 796–803, https://doi.org/10.1021/es802106a, 2009.
Qiu, X. H., Zhu, T., Yao, B., Hu, J. X., and Hu, S. W.: Contribution of dicofol to the current DDT pollution in China, Environ. Sci. Technol., 39, 4385–4390, https://doi.org/10.1021/es050342a, 2005.
Ruzickova, P., Klanova, J., Cupr, P., Lammel, G., and Holoubek, I.: An assessment of air-soil exchange of polychlorinated biphenyls and organochlorine pesticides across Central and Southern Europe, Environ. Sci. Technol., 42, 179–185, https://doi.org/10.1021/es071406f, 2008.
Santiago, E. C. and Cayetano, M. G.: Polycyclic aromatic hydrocarbons in ambient air in the Philippines derived from passive sampler with polyurethane foam disk, Atmos. Environ., 41, 4138–4147, https://doi.org/10.1016/j.atmosenv.2007.01.021, 2007.
Schuster, J. K., Gioia, R., Breivik, K., Steinnes, E., Scheringer, M., and Jones, K. C.: Trends in European Background Air Reflect Reductions in Primary Emissions of PCBs and PBDEs, Environ. Sci. Technol., 44, 6760–6766, https://doi.org/10.1021/es101009x, 2010.
Seibert, P. and Frank, A.: Source-receptor matrix calculation with a Lagrangian particle dispersion model in backward mode, Atmos. Chem. Phys., 4, 51–63, https://doi.org/10.5194/acp-4-51-2004, 2004.
Shoeib, M. and Harner, T.: Using measured octanol-air partition coefficients to explain environmental partitioning of organochlorine pesticides, 21, 984–990, 2002a.
Shoeib, M. and Harner, T.: Characterization and comparison of three passive air samplers for persistent organic pollutants, Environ. Sci. Technol., 36, 4142–4151, https://doi.org/10.1021/es020635t, 2002b.
Sovocool, G. W., Lewis, R. G., Harless, R. L., Wilson, N. K., and Zehr, R. D.: Analysis of technical chlordane by gas chromatography mass spectrometry., Anal. Chem., 49, 734–740, 1977.
Stohl, A., Hittenberger, M., and Wotawa, G.: Validation of the Lagrangian particle dispersion model FLEXPART against large-scale tracer experiment data, Atmos. Environ., 32, 4245–4264, 1998.
Stohl, A. and Thomson, D. J.: A density correction for Lagrangian particle dispersion models, Bound.-Lay. Meteorol., 90, 155–167, 1999.
Stohl, A., Forster, C., Eckhardt, S., Spichtinger, N., Huntrieser, H., Heland, J., Schlager, H., Wilhelm, S., Arnold, F., and Cooper, O.: A backward modeling study of intercontinental pollution transport using aircraft measurements, J. Geophys. Res.-Atmos., 108(18), 4370, https://doi.org/10.1029/2002jd002862, 2003.
Stohl, A., Forster, C., Frank, A., Seibert, P., and Wotawa, G.: Technical note: The Lagrangian particle dispersion model FLEXPART version 6.2, Atmos. Chem. Phys., 5, 2461–2474, https://doi.org/10.5194/acp-5-2461-2005, 2005.
Su, Y. S. and Hung, H. L.: Inter-laboratory comparison study on measuring semi-volatile organic chemicals in standards and air samples, Environ. Pollut., 158, 3365–3371, https://doi.org/10.1016/j.envpol.2010.07.041, 2010.
Tuduri, L., Harner, T., and Hung, H.: Polyurethane foam (PUF) disks passive air samplers: Wind effect on sampling rates, Environ. Pollut., 144, 377–383, https://doi.org/10.1016/j.envpol.2005.12.047, 2006.
Turgut, C., Gokbulut, C., and Cutright, T. J.: Contents and sources of DDT impurities in dicofol formulations in Turkey, Environ. Sci. Pollut. R., 16, 214–217, https://doi.org/10.1007/s11356-008-0083-3, 2009.
The 1998 Aarhus Protocol on persistant organic pollutants (POPs): United Nations Economics Commission for Europe: http://www.unece.org/env/lrtap/welcome.html, 1998.
Vallack, H. W., Bakker, D. J., Brandt, I., Brostrom-Lunden, E., Brouwer, A., Bull, K. R., Gough, C., Guardans, R., Holoubek, I., Jansson, B., Koch, R., Kuylenstierna, J., Lecloux, A., Mackay, D., McCutcheon, P., Mocarelli, P., and Taalman, R. D. F.: Controlling persistent organic pollutants – what next?, Environ. Toxicol. Pharmacol., 6, 143–175, 1998.
Wania, F. and Mackay, D.: Tracking the distribution of persistent organic pollutants, Environ. Sci. Technol., 30, A390–A396, 1996.
Wania, F. and Daly, G. L.: Estimating the contribution of degradation in air and deposition to the deep sea to the global loss of PCBs, Atmos. Environ., 36, 5581–5593, 2002.
Wilford, B. H., Harner, T., Zhu, J. P., Shoeib, M., and Jones, K. C.: Passive sampling survey of polybrominated diphenyl ether flame retardants in indoor and outdoor air in Ottawa, Canada: Implications for sources and exposure, Environ. Sci. Technol., 38, 5312–5318, https://doi.org/10.1021/es049260x, 2004.
Xiao, H., Li, N. Q., and Wania, F.: Compilation, evaluation, and selection of physical-chemical property data for alpha-, beta-, and gamma-hexachlorocyclohexane, J. Chem. Eng. Data, 49, 173–185, https://doi.org/10.1021/je034214i, 2004.
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