Articles | Volume 26, issue 13
https://doi.org/10.5194/acp-26-9997-2026
https://doi.org/10.5194/acp-26-9997-2026
Research article
 | 
16 Jul 2026
Research article |  | 16 Jul 2026

Alkaline dust deposition to foliage surfaces likely enhances the dry deposition velocity of SO2: an investigation in the Alberta Oil-Sands Region using the GEM-MACH air-quality model

Stefan Miller, Paul A. Makar, Kenjiro Toyota, Colin Lee, Verica Savic-Jovcic, Sepehr Fathi, Mahtab Majdzadeh, and Katherine Hayden

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Cited articles

Adams, C. M. and Hutchinson, T. C.: A comparison of the ability of leaf surfaces of three species to neutralize acidic rain drops, New Phytol., 97, 463–478, https://doi.org/10.1111/j.1469-8137.1984.tb03612.x, 1984. 
Adams, C. M. and Hutchinson, T. C.: Comparative abilities of leaf surfaces to neutralize acidic raindrops. II. the influence of leaf wettability, leaf age and rain duration on changes in droplet pH and chemistry on leaf surfaces, New Phytol., 106, 437–456, https://doi.org/10.1111/j.1469-8137.1987.tb00151.x, 1987. 
Adema, E. H. and Heeres, P.: Dry deposition of sulphur dioxide and ammonia on wet surfaces and the surface oxidation kinetics of bisulphite, Atmos. Environ., 29, 1091–1103, https://doi.org/10.1016/1352-2310(95)00039-2, 1995. 
AEP (Alberta Environment and Parks): Development of Performance Specifications for Continuous Ambient Air Monitoring Analyzers, Government of Alberta, AEP, Alberta, Canada, https://open.alberta.ca/publications/9781460115442 (last access: 9 July 2026), 2014. 
Avila, A., Alarcón, M., and Queralt, I.: The chemical composition of dust transported in Red Rains – its contribution to the biogeochemical cycle of a Holm Oak Forest in Catalonia (Spain), Atmos. Environ., 32, 179–191, https://doi.org/10.1016/s1352-2310(97)00286-0, 1998. 
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This work identifies an important and hitherto unsuspected controlling factor influencing the rate of deposition of atmospheric gases to foliage surfaces. We show base cation-containing dust that settles on foliage can raise the pH of thin water films on leaves, significantly increasing sulphur dioxide dry deposition rates (often by more than 1 cm s-1), and lowering concentrations (by up to 60%), near sources of alkaline dust emissions, changing sulphur deposition fluxes' spatial distribution.
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