Articles | Volume 24, issue 3
https://doi.org/10.5194/acp-24-1627-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-1627-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Feb 2024
Research article |
| 06 Feb 2024
| 06 Feb 2024
Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study
Chen He
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
Hanxiong Che
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Zier Bao
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Yiliang Liu
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Qing Li
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Miao Hu
CNOOC Institute of Chemicals & Advanced Materials, Beijing 102200, China
Jiawei Zhou
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Shumin Zhang
Institute of Basic Medicine and Forensic Medicine, North Sichuan Medical College, Nanchong 637000, Sichuan, China
Xiaojiang Yao
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Quan Shi
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
Chunmao Chen
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
Yan Han
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Lingshuo Meng
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Xin Long
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
Fumo Yang
Department of Environmental Science and Engineering, College of Architecture and Environment, Sichuan University, Chengdu 610065, China
Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
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Qiyuan Wang, Li Li, Jiamao Zhou, Jianhuai Ye, Wenting Dai, Huikun Liu, Yong Zhang, Renjian Zhang, Jie Tian, Yang Chen, Yunfei Wu, Weikang Ran, and Junji Cao
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Action Plan for the Prevention and Control of Air Pollution.
Jingsha Xu, Shaojie Song, Roy M. Harrison, Congbo Song, Lianfang Wei, Qiang Zhang, Yele Sun, Lu Lei, Chao Zhang, Xiaohong Yao, Dihui Chen, Weijun Li, Miaomiao Wu, Hezhong Tian, Lining Luo, Shengrui Tong, Weiran Li, Junling Wang, Guoliang Shi, Yanqi Huangfu, Yingze Tian, Baozhu Ge, Shaoli Su, Chao Peng, Yang Chen, Fumo Yang, Aleksandra Mihajlidi-Zelić, Dragana Đorđević, Stefan J. Swift, Imogen Andrews, Jacqueline F. Hamilton, Ye Sun, Agung Kramawijaya, Jinxiu Han, Supattarachai Saksakulkrai, Clarissa Baldo, Siqi Hou, Feixue Zheng, Kaspar R. Daellenbach, Chao Yan, Yongchun Liu, Markku Kulmala, Pingqing Fu, and Zongbo Shi
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An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
Cited articles
Antony, R., Grannas, A. M., Willoughby, A. S., Sleighter, R. L., Thamban, M., and Hatcher, P. G.: Origin and sources of dissolved organic matter in snow on the East Antarctic ice sheet, Environ. Sci. Technol., 48, 6151–6159, https://doi.org/10.1021/es405246a, 2014.
Ao, M., Pham, G. H., Sunarso, J., Tade, M. O., and Liu, S.: Active centers of catalysts for higher alcohol synthesis from syngas: a review, ACS Catal., 8, 7025–7050, 2018.
Bandowe, B. A. M. and Meusel, H.: Nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) in the environment – A review, Sci. Total. Environ., 581–582, 237–257, https://doi.org/10.1016/j.scitotenv.2016.12.115, 2017.
Bianco, A., Deguillaume, L., Vaitilingom, M., Nicol, E., Baray, J. L., Chaumerliac, N., and Bridoux, M.: Molecular Characterization of Cloud Water Samples Collected at the Puy de Dome (France) by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Environ. Sci. Technol., 52, 10275–10285, https://doi.org/10.1021/acs.est.8b01964, 2018.
Brege, M., Paglione, M., Gilardoni, S., Decesari, S., Facchini, M. C., and Mazzoleni, L. R.: Molecular insights on aging and aqueous-phase processing from ambient biomass burning emissions-influenced Po Valley fog and aerosol, Atmos. Chem. Phys., 18, 13197–13214, https://doi.org/10.5194/acp-18-13197-2018, 2018.
Chen, Y.: Diurnal Evolution of Nucleophilic High-molecular-weight Organic Compounds in Ambient Aerosols, Zenodo [data set], https://doi.org/10.5281/zenodo.7830299, 2023.
Chen, Y., Cao, J., Zhao, J., Xu, H., Arimoto, R., Wang, G., Han, Y., Shen, Z., and Li, G.: N-alkanes and polycyclic aromatic hydrocarbons in total suspended particulates from the southeastern Tibetan Plateau: concentrations, seasonal variations, and sources, Sci. Total. Environ., 470–471, 9–18, https://doi.org/10.1016/j.scitotenv.2013.09.033, 2014.
Chen, Y., Tian, M., Huang, R.-J., Shi, G., Wang, H., Peng, C., Cao, J., Wang, Q., Zhang, S., Guo, D., Zhang, L., and Yang, F.: Characterization of urban amine-containing particles in southwestern China: seasonal variation, source, and processing, Atmos. Chem. Phys., 19, 3245–3255, https://doi.org/10.5194/acp-19-3245-2019, 2019.
Creamean, J. M., Lee, C., Hill, T. C., Ault, A. P., DeMott, P. J., White, A. B., Ralph, F. M., and Prather, K. A.: Chemical properties of insoluble precipitation residue particles, J. Aerosol Sci., 76, 13–27, https://doi.org/10.1016/j.jaerosci.2014.05.005, 2014.
Darer, A. I., Cole-Filipiak, N. C., O'Connor, A. E., and Elrod, M. J.: Formation and stability of atmospherically relevant isoprene-derived organosulfates and organonitrates, Environ. Sci. Technol., 45, 1895–1902, 2011.
Dinar, E., Anttila, T., and Rudich, Y.: CCN activity and hygroscopic growth of organic aerosols following reactive uptake of ammonia, Environ. Sci. Technol., 42, 793–799, 2008.
Ditto, J. C., Barnes, E. B., Khare, P., Takeuchi, M., Joo, T., Bui, A. A. T., Lee-Taylor, J., Eris, G., Chen, Y., Aumont, B., Jimenez, J. L., Ng, N. L., Griffin, R. J., and Gentner, D. R.: An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol, Communications Chemistry, 1, 75, https://doi.org/10.1038/s42004-018-0074-3, 2018.
Ditto, J. C., He, M., Hass-Mitchell, T. N., Moussa, S. G., Hayden, K., Li, S.-M., Liggio, J., Leithead, A., Lee, P., Wheeler, M. J., Wentzell, J. J. B., and Gentner, D. R.: Atmospheric evolution of emissions from a boreal forest fire: the formation of highly functionalized oxygen-, nitrogen-, and sulfur-containing organic compounds, Atmos. Chem. Phys., 21, 255–267, https://doi.org/10.5194/acp-21-255-2021, 2021.
Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069–11102, https://doi.org/10.5194/acp-11-11069-2011, 2011.
George, C., Ammann, M., D'Anna, B., Donaldson, D. J., and Nizkorodov, S. A.: Heterogeneous photochemistry in the atmosphere, Chem. Rev., 115, 4218–4258, https://doi.org/10.1021/cr500648z, 2015.
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009.
He, C., Fang, Z., Li, Y., Jiang, C., Zhao, S., Xu, C., Zhang, Y., and Shi, Q.: Ionization selectivity of electrospray and atmospheric pressure photoionization FT-ICR MS for petroleum refinery wastewater dissolved organic matter, Environ. Sci.-Proc. Imp., 23, 1466–1475, https://doi.org/10.1039/d1em00248a, 2021.
He, C., He, D., Chen, C., and Shi, Q.: Application of Fourier Transform Ion Cyclotron Resonance Mass Spectrometry in molecular characterization of dissolved organic matter, Sci. China Earth Sci., 65, 2219–2236, https://doi.org/10.1360/SSTe-2021-0390, 2022.
He, Q., Tomaz, S., Li, C., Zhu, M., Meidan, D., Riva, M., Laskin, A., Brown, S. S., George, C., Wang, X., and Rudich, Y.: Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds, Environ. Sci. Technol., 55, 2878–2889, https://doi.org/10.1021/acs.est.0c06838, 2021.
Hodshire, A. L., Akherati, A., Alvarado, M. J., Brown-Steiner, B., Jathar, S. H., Jimenez, J. L., Kreidenweis, S. M., Lonsdale, C. R., Onasch, T. B., Ortega, A. M., and Pierce, J. R.: Aging Effects on Biomass Burning Aerosol Mass and Composition: A Critical Review of Field and Laboratory Studies, Environ. Sci. Technol., 53, 10007–10022, https://doi.org/10.1021/acs.est.9b02588, 2019.
Huang, R. J., Zhang, Y., Bozzetti, C., Ho, K. F., Cao, J. J., Han, Y., Daellenbach, K. R., Slowik, J. G., Platt, S. M., Canonaco, F., Zotter, P., Wolf, R., Pieber, S. M., Bruns, E. A., Crippa, M., Ciarelli, G., Piazzalunga, A., Schwikowski, M., Abbaszade, G., Schnelle-Kreis, J., Zimmermann, R., An, Z., Szidat, S., Baltensperger, U., El Haddad, I., and Prevot, A. S.: High secondary aerosol contribution to particulate pollution during haze events in China, Nature, 514, 218–222, https://doi.org/10.1038/nature13774, 2014.
Jiang, B., Liang, Y., Xu, C., Zhang, J., Hu, M., and Shi, Q.: Polycyclic aromatic hydrocarbons (PAHs) in ambient aerosols from Beijing: characterization of low volatile PAHs by positive-ion atmospheric pressure photoionization (APPI) coupled with Fourier transform ion cyclotron resonance, Environ. Sci. Technol., 48, 4716–4723, https://doi.org/10.1021/es405295p, 2014.
Jimenez, J. L., Canagaratna, M. R., Donahue, N. M., Prevot, A. S., Zhang, Q., Kroll, J. H., DeCarlo, P. F., Allan, J. D., Coe, H., Ng, N. L., Aiken, A. C., Docherty, K. S., Ulbrich, I. M., Grieshop, A. P., Robinson, A. L., Duplissy, J., Smith, J. D., Wilson, K. R., Lanz, V. A., Hueglin, C., Sun, Y. L., Tian, J., Laaksonen, A., Raatikainen, T., Rautiainen, J., Vaattovaara, P., Ehn, M., Kulmala, M., Tomlinson, J. M., Collins, D. R., Cubison, M. J., Dunlea, E. J., Huffman, J. A., Onasch, T. B., Alfarra, M. R., Williams, P. I., Bower, K., Kondo, Y., Schneider, J., Drewnick, F., Borrmann, S., Weimer, S., Demerjian, K., Salcedo, D., Cottrell, L., Griffin, R., Takami, A., Miyoshi, T., Hatakeyama, S., Shimono, A., Sun, J. Y., Zhang, Y. M., Dzepina, K., Kimmel, J. R., Sueper, D., Jayne, J. T., Herndon, S. C., Trimborn, A. M., Williams, L. R., Wood, E. C., Middlebrook, A. M., Kolb, C. E., Baltensperger, U., and Worsnop, D. R.: Evolution of organic aerosols in the atmosphere, Science, 326, 1525–1529, https://doi.org/10.1126/science.1180353, 2009.
Kanawati, B., Herrmann, F., Joniec, S., Winterhalter, R., and Moortgat, G. K.: Mass spectrometric characterization of beta-caryophyllene ozonolysis products in the aerosol studied using an electrospray triple quadrupole and time-of-flight analyzer hybrid system and density functional theory, Rapid Commun. Mass Sp., 22, 165–186, https://doi.org/10.1002/rcm.3340, 2008.
Koch, B. P. and Dittmar, T.: From mass to structure: an aromaticity index for high-resolution mass data of natural organic matter, Rapid Commun. Mass Sp., 20, 926–932, https://doi.org/10.1002/rcm.2386, 2006.
Kroll, J. H., Donahue, N. M., Jimenez, J. L., Kessler, S. H., Canagaratna, M. R., Wilson, K. R., Altieri, K. E., Mazzoleni, L. R., Wozniak, A. S., Bluhm, H., Mysak, E. R., Smith, J. D., Kolb, C. E., and Worsnop, D. R.: Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol, Nat. Chem., 3, 133–139, https://doi.org/10.1038/nchem.948, 2011.
Kurek, M. R., Poulin, B. A., McKenna, A. M., and Spencer, R. G. M.: Deciphering Dissolved Organic Matter: Ionization, Dopant, and Fragmentation Insights via Fourier Transform-Ion Cyclotron Resonance Mass Spectrometry, Environ. Sci. Technol., 54, 16249–16259, https://doi.org/10.1021/acs.est.0c05206, 2020.
Laskin, J., Laskin, A., Nizkorodov, S. A., Roach, P., Eckert, P., Gilles, M. K., Wang, B., Lee, H. J., and Hu, Q.: Molecular selectivity of brown carbon chromophores, Environ. Sci. Technol., 48, 12047–12055, https://doi.org/10.1021/es503432r, 2014.
Li, H., Zhang, Q., Zhang, Q., Chen, C., Wang, L., Wei, Z., Zhou, S., Parworth, C., Zheng, B., Canonaco, F., Prévôt, A. S. H., Chen, P., Zhang, H., Wallington, T. J., and He, K.: Wintertime aerosol chemistry and haze evolution in an extremely polluted city of the North China Plain: significant contribution from coal and biomass combustion, Atmos. Chem. Phys., 17, 4751–4768, https://doi.org/10.5194/acp-17-4751-2017, 2017.
Li, K., Li, J., Liggio, J., Wang, W., Ge, M., Liu, Q., Guo, Y., Tong, S., Li, J., Peng, C., Jing, B., Wang, D., and Fu, P.: Enhanced Light Scattering of Secondary Organic Aerosols by Multiphase Reactions, Environ. Sci. Technol., 51, 1285–1292, https://doi.org/10.1021/acs.est.6b03229, 2017.
Li, X., Yu, F., Cao, J., Fu, P., Hua, X., Chen, Q., Li, J., Guan, D., Tripathee, L., Chen, Q., and Wang, Y.: Chromophoric dissolved organic carbon cycle and its molecular compositions and optical properties in precipitation in the Guanzhong basin, China, Sci. Total. Environ., 814, 152775, https://doi.org/10.1016/j.scitotenv.2021.152775, 2022.
Liggio, J. and Li, S.-M.: Organosulfate formation during the uptake of pinonaldehyde on acidic sulfate aerosols, Geophys. Res. Lett., 33, L13808-L13808, https://doi.org/10.1029/2006gl026079, 2006.
Lim, Y. B., Kim, H., Kim, J. Y., and Turpin, B. J.: Photochemical organonitrate formation in wet aerosols, Atmos. Chem. Phys., 16, 12631–12647, https://doi.org/10.5194/acp-16-12631-2016, 2016.
Lin, P., Rincon, A. G., Kalberer, M., and Yu, J. Z.: Elemental composition of HULIS in the Pearl River Delta Region, China: results inferred from positive and negative electrospray high resolution mass spectrometric data, Environ. Sci. Technol., 46, 7454–7462, https://doi.org/10.1021/es300285d, 2012.
Liu, Y., Liggio, J., Staebler, R., and Li, S.-M.: Reactive uptake of ammonia to secondary organic aerosols: kinetics of organonitrogen formation, Atmos. Chem. Phys., 15, 13569–13584, https://doi.org/10.5194/acp-15-13569-2015, 2015.
McGuire, M. L., Chang, R. Y.-W., Slowik, J. G., Jeong, C.-H., Healy, R. M., Lu, G., Mihele, C., Abbatt, J. P. D., Brook, J. R., and Evans, G. J.: Enhancing non-refractory aerosol apportionment from an urban industrial site through receptor modeling of complete high time-resolution aerosol mass spectra, Atmos. Chem. Phys., 14, 8017–8042, https://doi.org/10.5194/acp-14-8017-2014, 2014.
Pöschl, U.: Atmospheric Aerosols: Composition, Transformation, Climate and Health Effects, Angew. Chem. Int. Ed., 44, 7520–7540, https://doi.org/10.1002/anie.200501122, 2005.
Ray, D., Singh, S., Ghosh, S. K., and Raha, S.: Dynamic response of light absorption by PM2.5 bound water-soluble organic carbon to heterogeneous oxidation, Aerosol Sci. Technol., 53, 1404–1414, https://doi.org/10.1080/02786826.2019.1661350, 2019.
Rice, S., Maurer, D. L., Fennell, A., Dharmadhikari, M., and Koziel, J. A.: Evaluation of Volatile Metabolites Emitted In-Vivo from Cold-Hardy Grapes during Ripening Using SPME and GC-MS: A Proof-of-Concept, Molecules, 24, 536, https://doi.org/10.3390/molecules24030536, 2019.
Seidel, M., Beck, M., Riedel, T., Waska, H., Suryaputra, I. G. N. A., Schnetger, B., Niggemann, J., Simon, M., and Dittmar, T.: Biogeochemistry of dissolved organic matter in an anoxic intertidal creek bank, Geochim. Cosmochim. Ac., 140, 418–434, https://doi.org/10.1016/j.gca.2014.05.038, 2014.
Song, J., Li, M., Zou, C., Cao, T., Fan, X., Jiang, B., Yu, Z., Jia, W., and Peng, P.: Molecular Characterization of Nitrogen-Containing Compounds in Humic-like Substances Emitted from Biomass Burning and Coal Combustion, Environ. Sci. Technol., 56, 119–130, https://doi.org/10.1021/acs.est.1c04451, 2022.
Stenson, A. C., Marshall, A. G., and Cooper, W. T.: Exact masses and chemical formulas of individual Suwannee River fulvic acids from ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectra, Anal. Chem., 75, 1275–1284, https://doi.org/10.1021/ac026106p, 2003.
Tang, J., Li, J., Su, T., Han, Y., Mo, Y., Jiang, H., Cui, M., Jiang, B., Chen, Y., Tang, J., Song, J., Peng, P., and Zhang, G.: Molecular compositions and optical properties of dissolved brown carbon in biomass burning, coal combustion, and vehicle emission aerosols illuminated by excitation–emission matrix spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry analysis, Atmos. Chem. Phys., 20, 2513–2532, https://doi.org/10.5194/acp-20-2513-2020, 2020.
Tao, J., Zhang, L., Cao, J., and Zhang, R.: A review of current knowledge concerning PM2.5 chemical composition, aerosol optical properties and their relationships across China, Atmos. Chem. Phys., 17, 9485–9518, https://doi.org/10.5194/acp-17-9485-2017, 2017.
Wang, H., Qiao, B., Zhang, L., Yang, F., and Jiang, X.: Characteristics and sources of trace elements in PM2.5 in two megacities in Sichuan Basin of southwest China, Environ. Pollut., 242, 1577–1586, https://doi.org/10.1016/j.envpol.2018.07.125, 2018.
Wang, Y., Hu, M., Lin, P., Tan, T., Li, M., Xu, N., Zheng, J., Du, Z., Qin, Y., Wu, Y., Lu, S., Song, Y., Wu, Z., Guo, S., Zeng, L., Huang, X., and He, L.: Enhancement in Particulate Organic Nitrogen and Light Absorption of Humic-Like Substances over Tibetan Plateau Due to Long-Range Transported Biomass Burning Emissions, Environ. Sci. Technol., 53, 14222–14232, https://doi.org/10.1021/acs.est.9b06152, 2019.
Xie, Q., Su, S., Chen, S., Xu, Y., Cao, D., Chen, J., Ren, L., Yue, S., Zhao, W., Sun, Y., Wang, Z., Tong, H., Su, H., Cheng, Y., Kawamura, K., Jiang, G., Liu, C.-Q., and Fu, P.: Molecular characterization of firework-related urban aerosols using Fourier transform ion cyclotron resonance mass spectrometry, Atmos. Chem. Phys., 20, 6803–6820, https://doi.org/10.5194/acp-20-6803-2020, 2020.
Yu, L., Smith, J., Laskin, A., George, K. M., Anastasio, C., Laskin, J., Dillner, A. M., and Zhang, Q.: Molecular transformations of phenolic SOA during photochemical aging in the aqueous phase: competition among oligomerization, functionalization, and fragmentation, Atmos. Chem. Phys., 16, 4511–4527, https://doi.org/10.5194/acp-16-4511-2016, 2016.
Yun, Y., Liang, L., Wei, Y., Luo, Z., Yuan, F., Li, G., and Sang, N.: Exposure to Nitro-PAHs interfere with germination and early growth of Hordeum vulgare via oxidative stress, Ecotox. Environ. Safe., 180, 756–761, https://doi.org/10.1016/j.ecoenv.2019.05.032, 2019.
Zarzana, K. J., De Haan, D. O., Freedman, M. A., Hasenkopf, C. A., and Tolbert, M. A.: Optical Properties of the Products of α-Dicarbonyl and Amine Reactions in Simulated Cloud Droplets, Environ. Sci. Technol., 46, 4845–4851, https://doi.org/10.1021/es2040152, 2012.
Zhang, Q., Jimenez, J. L., Canagaratna, M. R., Allan, J. D., Coe, H., Ulbrich, I., Alfarra, M. R., Takami, A., Middlebrook, A. M., Sun, Y. L., Dzepina, K., Dunlea, E., Docherty, K., DeCarlo, P. F., Salcedo, D., Onasch, T., Jayne, J. T., Miyoshi, T., Shimono, A., Hatakeyama, S., Takegawa, N., Kondo, Y., Schneider, J., Drewnick, F., Borrmann, S., Weimer, S., Demerjian, K., Williams, P., Bower, K., Bahreini, R., Cottrell, L., Griffin, R. J., Rautiainen, J., Sun, J. Y., Zhang, Y. M., and Worsnop, D. R.: Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes, Geophys. Res. Lett., 34, L13801, https://doi.org/10.1029/2007gl029979, 2007.
Zhang, Q., Jimenez, J. L., Canagaratna, M. R., Ulbrich, I. M., Ng, N. L., Worsnop, D. R., and Sun, Y.: Understanding atmospheric organic aerosols via factor analysis of aerosol mass spectrometry: a review, Anal. Bioanal. Chem., 401, 3045–3067, https://doi.org/10.1007/s00216-011-5355-y, 2011.
Zhang, R., Wang, G., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang, W., Hu, M., and Wang, Y.: Formation of urban fine particulate matter, Chem. Rev., 115, 3803–3855, https://doi.org/10.1021/acs.chemrev.5b00067, 2015.
Zhang, Z., Zhao, W., Hu, W., Deng, J., Ren, L., Wu, L., Chen, S., Meng, J., Pavuluri, C. M., Sun, Y., Wang, Z., Kawamura, K., and Fu, P.: Molecular characterization and spatial distribution of dicarboxylic acids and related compounds in fresh snow in China, Environ. Pollut., 291, 118114, https://doi.org/10.1016/j.envpol.2021.118114, 2021.
Short summary
We examined the daily evolution of high molecular-weight organic compounds with a molecular weight of up to 1000 Da in order to comprehend their behaviors in the atmosphere under actual conditions. These compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and nighttime chemistry.
We examined the daily evolution of high molecular-weight organic compounds with a molecular...
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