Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2639-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-2639-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Feb 2022
Research article |
| 25 Feb 2022
| 25 Feb 2022
The role of organic acids in new particle formation from methanesulfonic acid and methylamine
Rongjie Zhang
Key Laboratory of Industrial Ecology and Environmental Engineering
(Ministry of Education), School of Environmental Science and Technology,
Dalian University of Technology, Dalian 116024, China
Jiewen Shen
Key Laboratory of Industrial Ecology and Environmental Engineering
(Ministry of Education), School of Environmental Science and Technology,
Dalian University of Technology, Dalian 116024, China
Hong-Bin Xie
CORRESPONDING AUTHOR
Key Laboratory of Industrial Ecology and Environmental Engineering
(Ministry of Education), School of Environmental Science and Technology,
Dalian University of Technology, Dalian 116024, China
Jingwen Chen
Key Laboratory of Industrial Ecology and Environmental Engineering
(Ministry of Education), School of Environmental Science and Technology,
Dalian University of Technology, Dalian 116024, China
Jonas Elm
Department of Chemistry and iClimate, Aarhus University,
Langelandsgade 140, 8000 Aarhus C, Denmark
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Haide Wu, Yosef Knattrup, Andreas Buchgraitz Jensen, and Jonas Elm
Aerosol Research, 2, 303–314, https://doi.org/10.5194/ar-2-303-2024, https://doi.org/10.5194/ar-2-303-2024, 2024
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The exact point at which a given assembly of molecules represents an atmospheric molecular cluster or a particle remains ambiguous. Using quantum chemical methods, here we explore a cluster-to-particle transition point. Based on our results, we deduce a property-based criterion for defining freshly nucleated particles (FNPs) that act as a boundary between discrete cluster configurations and bulk particles.
Yosef Knattrup and Jonas Elm
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-37, https://doi.org/10.5194/ar-2024-37, 2024
Preprint under review for AR
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Using quantum chemical methods we studied the uptake of first generation oxidation products onto freshly nucleated particles (FNPs). We find that pinic acid can condense on these small FNPs at realistic atmospheric conditions, thereby contributing to the early particle growth. The mechanism involves two pinic acid molecules interacting with each other, showing that direct organic-organic interactions during co-condensation onto the particle contributes to the growth.
Galib Hasan, Haide Wu, Yosef Knattrup, and Jonas Elm
Aerosol Research Discuss., https://doi.org/10.5194/ar-2024-28, https://doi.org/10.5194/ar-2024-28, 2024
Preprint under review for AR
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Aerosol formation is an important process for our global climate. However, there are large uncertainties associated with the formation of new aerosol particles. We present quantum chemical calculations of large atmospheric molecular cluster composed of sulfuric acid (SA), ammonia (AM) and dimethyl amine (DMA). We find that mixed SA-AM-DMA clusters more efficiently for freshly nucleated particles compared to the pure SA-AM and SA-DMA systems.
Astrid Nørskov Pedersen, Yosef Knattrup, and Jonas Elm
Aerosol Research, 2, 123–134, https://doi.org/10.5194/ar-2-123-2024, https://doi.org/10.5194/ar-2-123-2024, 2024
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Aerosol formation is an important process for our global climate. While inorganic species have been shown to be important for aerosol formation, there remains a large gap in our knowledge about the exact involvement of organics. We present a new quantum chemical procedure for screening relevant organics that for the first time allows us to obtain direct molecular-level insight into the organics involved in aerosol formation.
Zhiqiang Zhang, Ying Li, Haiyan Ran, Junling An, Yu Qu, Wei Zhou, Weiqi Xu, Weiwei Hu, Hongbin Xie, Zifa Wang, Yele Sun, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 4809–4826, https://doi.org/10.5194/acp-24-4809-2024, https://doi.org/10.5194/acp-24-4809-2024, 2024
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Secondary organic aerosols (SOAs) can exist in liquid, semi-solid, or amorphous solid states, which are rarely accounted for in current chemical transport models. We predict the phase state of SOA particles over China and find that in northwestern China SOA particles are mostly highly viscous or glassy solid. Our results indicate that the particle phase state should be considered in SOA formation in chemical transport models for more accurate prediction of SOA mass concentrations.
Jonas Elm, Aladár Czitrovszky, Andreas Held, Annele Virtanen, Astrid Kiendler-Scharr, Benjamin J. Murray, Daniel McCluskey, Daniele Contini, David Broday, Eirini Goudeli, Hilkka Timonen, Joan Rosell-Llompart, Jose L. Castillo, Evangelia Diapouli, Mar Viana, Maria E. Messing, Markku Kulmala, Naděžda Zíková, and Sebastian H. Schmitt
Aerosol Research, 1, 13–16, https://doi.org/10.5194/ar-1-13-2023, https://doi.org/10.5194/ar-1-13-2023, 2023
Bernadette Rosati, Sini Isokääntä, Sigurd Christiansen, Mads Mørk Jensen, Shamjad P. Moosakutty, Robin Wollesen de Jonge, Andreas Massling, Marianne Glasius, Jonas Elm, Annele Virtanen, and Merete Bilde
Atmos. Chem. Phys., 22, 13449–13466, https://doi.org/10.5194/acp-22-13449-2022, https://doi.org/10.5194/acp-22-13449-2022, 2022
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Sulfate aerosols have a strong influence on climate. Due to the reduction in sulfur-based fossil fuels, natural sulfur emissions play an increasingly important role. Studies investigating the climate relevance of natural sulfur aerosols are scarce. We study the water uptake of such particles in the laboratory, demonstrating a high potential to take up water and form cloud droplets. During atmospheric transit, chemical processing affects the particles’ composition and thus their water uptake.
Jingwen Xue, Fangfang Ma, Jonas Elm, Jingwen Chen, and Hong-Bin Xie
Atmos. Chem. Phys., 22, 11543–11555, https://doi.org/10.5194/acp-22-11543-2022, https://doi.org/10.5194/acp-22-11543-2022, 2022
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·OH/·Cl initiated indole reactions mainly form organonitrates, alkoxy radicals and hydroperoxide products, showing a varying mechanism from previously reported amines reactions. This study reveals carcinogenic nitrosamines cannot be formed in indole oxidation reactions despite radicals formed from -NH- H abstraction. The results are important to understand the atmospheric impact of indole oxidation and extend current understanding on the atmospheric chemistry of organic nitrogen compounds.
Robin Wollesen de Jonge, Jonas Elm, Bernadette Rosati, Sigurd Christiansen, Noora Hyttinen, Dana Lüdemann, Merete Bilde, and Pontus Roldin
Atmos. Chem. Phys., 21, 9955–9976, https://doi.org/10.5194/acp-21-9955-2021, https://doi.org/10.5194/acp-21-9955-2021, 2021
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This study presents a detailed analysis of the OH-initiated oxidation of dimethyl sulfide (DMS) based on experiments performed in the Aarhus University Research on Aerosol (AURA) smog chamber and the gas- and particle-phase chemistry kinetic multilayer model (ADCHAM). We capture the formation, growth and chemical composition of aerosols in the chamber setup by an improved multiphase oxidation mechanism and utilize our results to reproduce the important role of DMS in the marine boundary layer.
Noora Hyttinen, Reyhaneh Heshmatnezhad, Jonas Elm, Theo Kurtén, and Nønne L. Prisle
Atmos. Chem. Phys., 20, 13131–13143, https://doi.org/10.5194/acp-20-13131-2020, https://doi.org/10.5194/acp-20-13131-2020, 2020
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We present aqueous solubilities and activity coefficients of mono- and dicarboxylic acids (C1–C6 and C2–C8, respectively) estimated using the COSMOtherm program. In addition, we have calculated effective equilibrium constants of dimerization and hydration of the same acids in the condensed phase. We were also able to improve the agreement between experimental and estimated properties of monocarboxylic acids in aqueous solutions by including clustering reactions in COSMOtherm calculations.
Kasper Kristensen, Louise N. Jensen, Lauriane L. J. Quéléver, Sigurd Christiansen, Bernadette Rosati, Jonas Elm, Ricky Teiwes, Henrik B. Pedersen, Marianne Glasius, Mikael Ehn, and Merete Bilde
Atmos. Chem. Phys., 20, 12549–12567, https://doi.org/10.5194/acp-20-12549-2020, https://doi.org/10.5194/acp-20-12549-2020, 2020
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Atmospheric particles are important in relation to human health and the global climate. As the global temperature changes, so may the atmospheric chemistry controlling the formation of particles from reactions of naturally emitted volatile organic compounds (VOCs). In the current work, we show how temperatures influence the formation and chemical composition of atmospheric particles from α-pinene: a biogenic VOC largely emitted in high-latitude environments such as the boreal forests.
Yibei Wan, Xiangpeng Huang, Bin Jiang, Binyu Kuang, Manfei Lin, Deming Xia, Yuhong Liao, Jingwen Chen, Jian Zhen Yu, and Huan Yu
Atmos. Chem. Phys., 20, 9821–9835, https://doi.org/10.5194/acp-20-9821-2020, https://doi.org/10.5194/acp-20-9821-2020, 2020
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Biogenic iodine emission from macroalgae and microalgae could initiate atmospheric new particle formation (NPF). But it is unknown if other species are needed to drive the growth of new iodine particles in the marine boundary layer. Unlike the deeper understanding of organic compounds driving continental NPF, little is known about the organics involved in coastal or open-ocean NPF. This article reveals a new group of important organic compounds involved in this process.
Noora Hyttinen, Jonas Elm, Jussi Malila, Silvia M. Calderón, and Nønne L. Prisle
Atmos. Chem. Phys., 20, 5679–5696, https://doi.org/10.5194/acp-20-5679-2020, https://doi.org/10.5194/acp-20-5679-2020, 2020
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Organosulfates have been identified in atmospheric secondary organic aerosol (SOA). The thermodynamic properties of SOA constituents, such as organosulfates, affect the stability and atmospheric impact of the SOA. Here we present estimated solubility, activity, pKa, saturation vapor pressure and Henry's law solubility values for several atmospherically relevant monoterpene- and isoprene-derived organosulfate compounds. These properties can be used, for example, in aerosol process modeling.
Yonghong Wang, Matthieu Riva, Hongbin Xie, Liine Heikkinen, Simon Schallhart, Qiaozhi Zha, Chao Yan, Xu-Cheng He, Otso Peräkylä, and Mikael Ehn
Atmos. Chem. Phys., 20, 5145–5155, https://doi.org/10.5194/acp-20-5145-2020, https://doi.org/10.5194/acp-20-5145-2020, 2020
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Chamber experiments were conducted with alpha-pinene and chlorine under low- and high-nitrogen-oxide (NOX) conditions. We estimated the HOM yields from chlorine-initiated oxidation of alpha-pinene under low-NOX conditions to be around 1.8 %, though with a uncertainty range (0.8 %–4 %) due to lack of suitable calibration methods. Our study clearly demonstrates that the chlorine-atom-initiated oxidation of alpha-pinene can produce low-volatility organic compounds.
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Rapid oxidation of phenolic compounds by O3 and HO●: effects of the air–water interface and mineral dust in tropospheric chemical processes
Modeling the contribution of leads to sea spray aerosol in the high Arctic
Importance of aerosol composition and aerosol vertical profiles in global spatial variation in the relationship between PM2.5 and aerosol optical depth
The co-benefits of a low-carbon future for PM2.5 and O3 air pollution in Europe
Assessing the effectiveness of SO2, NOx, and NH3 emission reductions in mitigating winter PM2.5 in Taiwan using CMAQ
Modelling of atmospheric concentrations of fungal spores: a 2-year simulation over France using CHIMERE
Cluster-dynamics-based parameterization for sulfuric acid–dimethylamine nucleation: comparison and selection through box and three-dimensional modeling
The surface tension and CCN activation of sea spray aerosol particles
Observed and CMIP6-model-simulated organic aerosol response to drought in the contiguous United States during summertime
Cooling radiative forcing effect enhancement of atmospheric amines and mineral particles caused by heterogeneous uptake and oxidation
Exploring the processes controlling secondary inorganic aerosol: Evaluating the global GEOS-Chem simulation using a suite of aircraft campaigns
Source-resolved atmospheric metal emissions, concentrations, and deposition fluxes into the East Asian seas
Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks, Alaska, the N. Hemisphere, and the Contiguous United States
Quantifying the impact of global nitrate aerosol on tropospheric composition fields and its production from lightning NOx
Land use change influence on atmospheric organic gases, aerosols, and radiative effects
Analysis of secondary inorganic aerosols over the greater Athens area using the EPISODE–CityChem source dispersion and photochemistry model
Global estimates of ambient reactive nitrogen components during 2000–2100 based on the multi-stage model
Quantifying the Impacts of Marine Aerosols over the Southeast Atlantic Ocean using a chemical transport model: Implications for aerosol-cloud interactions
The role of naphthalene and its derivatives in the formation of secondary organic aerosol in the Yangtze River Delta region, China
Unveiling the optimal regression model for source apportionment of the oxidative potential of PM10
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 2: Modeling chemical drivers and 3-D new particle formation occurrence
Technical note: Influence of different averaging metrics and temporal resolutions on the aerosol pH calculated by thermodynamic modeling
Dual roles of the inorganic aqueous phase on secondary organic aerosol growth from benzene and phenol
Global source apportionment of aerosols into major emission regions and sectors over 1850–2017
Modeling atmospheric brown carbon in the GISS ModelE Earth system model
Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere
Significant impact of urban tree biogenic emissions on air quality estimated by a bottom-up inventory and chemistry transport modeling
Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state
Modeling the drivers of fine PM pollution over Central Europe: impacts and contributions of emissions from different sources
Reaction of SO3 with H2SO4 and its implications for aerosol particle formation in the gas phase and at the air–water interface
Weakened aerosol–radiation interaction exacerbating ozone pollution in eastern China since China's clean air actions
Uncertainties from biomass burning aerosols in air quality models obscure public health impacts in Southeast Asia
Oxidative potential apportionment of atmospheric PM1: a new approach combining high-sensitive online analysers for chemical composition and offline OP measurement technique
Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon
An updated modeling framework to simulate Los Angeles air quality – Part 1: Model development, evaluation, and source apportionment
Frequent haze events associated with transport and stagnation over the corridor between the North China Plain and Yangtze River Delta
Evaluation of WRF-Chem-simulated meteorology and aerosols over northern India during the severe pollution episode of 2016
How well are aerosol–cloud interactions represented in climate models? – Part 1: Understanding the sulfate aerosol production from the 2014–15 Holuhraun eruption
pH regulates the formation of organosulfates and inorganic sulfate from organic peroxide reaction with dissolved SO2 in aquatic media
Technical note: Accurate, reliable, and high-resolution air quality predictions by improving the Copernicus Atmosphere Monitoring Service using a novel statistical post-processing method
Contribution of intermediate-volatility organic compounds from on-road transport to secondary organic aerosol levels in Europe
Development of an integrated model framework for multi-air-pollutant exposure assessments in high-density cities
CAMx–UNIPAR simulation of secondary organic aerosol mass formed from multiphase reactions of hydrocarbons under the Central Valley urban atmospheres of California
Impact of urbanization on fine particulate matter concentrations over central Europe
Measurement report: Assessing the impacts of emission uncertainty on aerosol optical properties and radiative forcing from biomass burning in peninsular Southeast Asia
The Emissions Model Intercomparison Project (Emissions-MIP): quantifying model sensitivity to emission characteristics
Dynamics-based estimates of decline trend with fine temporal variations in China's PM2.5 emissions
Effects of simulated secondary organic aerosol water on PM1 levels and composition over the US
Reactive organic carbon air emissions from mobile sources in the United States
Development and evaluation of processes affecting simulation of diel fine particulate matter variation in the GEOS-Chem model
Yanru Huo, Mingxue Li, Xueyu Wang, Jianfei Sun, Yuxin Zhou, Yuhui Ma, and Maoxia He
Atmos. Chem. Phys., 24, 12409–12423, https://doi.org/10.5194/acp-24-12409-2024, https://doi.org/10.5194/acp-24-12409-2024, 2024
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This work found that the air–water (A–W) interface and TiO2 clusters promote the oxidation of phenolic compounds (PhCs) to varying degrees compared with the gas phase and bulk water. Some byproducts are more harmful than their parent compounds. This work provides important evidence for the rapid oxidation observed in O3/HO• + PhC experiments at the A–W interface and in mineral dust.
Rémy Lapere, Louis Marelle, Pierre Rampal, Laurent Brodeau, Christian Melsheimer, Gunnar Spreen, and Jennie L. Thomas
Atmos. Chem. Phys., 24, 12107–12132, https://doi.org/10.5194/acp-24-12107-2024, https://doi.org/10.5194/acp-24-12107-2024, 2024
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Elongated open-water areas in sea ice, called leads, can release marine aerosols into the atmosphere. In the Arctic, this source of atmospheric particles could play an important role for climate. However, the amount, seasonality and spatial distribution of such emissions are all mostly unknown. Here, we propose a first parameterization for sea spray aerosols emitted through leads in sea ice and quantify their impact on aerosol populations in the high Arctic.
Haihui Zhu, Randall V. Martin, Aaron van Donkelaar, Melanie S. Hammer, Chi Li, Jun Meng, Christopher R. Oxford, Xuan Liu, Yanshun Li, Dandan Zhang, Inderjeet Singh, and Alexei Lyapustin
Atmos. Chem. Phys., 24, 11565–11584, https://doi.org/10.5194/acp-24-11565-2024, https://doi.org/10.5194/acp-24-11565-2024, 2024
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Ambient fine particulate matter (PM2.5) contributes to 4 million deaths globally each year. Satellite remote sensing of aerosol optical depth (AOD), coupled with a simulated PM2.5–AOD relationship (η), can provide global PM2.5 estimations. This study aims to understand the spatial patterns and driving factors of η to guide future measurement and modeling efforts. We quantified η globally and regionally and found that its spatial variation is strongly influenced by aerosol composition.
Connor J. Clayton, Daniel R. Marsh, Steven T. Turnock, Ailish M. Graham, Kirsty J. Pringle, Carly L. Reddington, Rajesh Kumar, and James B. McQuaid
Atmos. Chem. Phys., 24, 10717–10740, https://doi.org/10.5194/acp-24-10717-2024, https://doi.org/10.5194/acp-24-10717-2024, 2024
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We demonstrate that strong climate mitigation could improve air quality in Europe; however, less ambitious mitigation does not result in these co-benefits. We use a high-resolution atmospheric chemistry model. This allows us to demonstrate how this varies across European countries and analyse the underlying chemistry. This may help policy-facing researchers understand which sectors and regions need to be prioritised to achieve strong air quality co-benefits of climate mitigation.
Ping-Chieh Huang, Hui-Ming Hung, Hsin-Chih Lai, and Charles C.-K. Chou
Atmos. Chem. Phys., 24, 10759–10772, https://doi.org/10.5194/acp-24-10759-2024, https://doi.org/10.5194/acp-24-10759-2024, 2024
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Models were used to study ways to reduce particulate matter (PM) pollution in Taiwan during winter. After considering various factors, such as physical processes and chemical reactions, we found that reducing NOx or NH3 emissions is more effective at mitigating PM2.5 than reducing SO2 emissions. When considering both efficiency and cost, reducing NH3 emissions seems to be a more suitable policy for the studied environment in Taiwan.
Matthieu Vida, Gilles Foret, Guillaume Siour, Florian Couvidat, Olivier Favez, Gaelle Uzu, Arineh Cholakian, Sébastien Conil, Matthias Beekmann, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 24, 10601–10615, https://doi.org/10.5194/acp-24-10601-2024, https://doi.org/10.5194/acp-24-10601-2024, 2024
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We simulate 2 years of atmospheric fungal spores over France and use observations of polyols and primary biogenic factors from positive matrix factorisation. The representation of emissions taking into account a proxy for vegetation surface and specific humidity enables us to reproduce very accurately the seasonal cycle of fungal spores. Furthermore, we estimate that fungal spores can account for 20 % of PM10 and 40 % of the organic fraction of PM10 over vegetated areas in summer.
Jiewen Shen, Bin Zhao, Shuxiao Wang, An Ning, Yuyang Li, Runlong Cai, Da Gao, Biwu Chu, Yang Gao, Manish Shrivastava, Jingkun Jiang, Xiuhui Zhang, and Hong He
Atmos. Chem. Phys., 24, 10261–10278, https://doi.org/10.5194/acp-24-10261-2024, https://doi.org/10.5194/acp-24-10261-2024, 2024
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We extensively compare various cluster-dynamics-based parameterizations for sulfuric acid–dimethylamine nucleation and identify a newly developed parameterization derived from Atmospheric Cluster Dynamic Code (ACDC) simulations as being the most reliable one. This study offers a valuable reference for developing parameterizations of other nucleation systems and is meaningful for the accurate quantification of the environmental and climate impacts of new particle formation.
Judith Kleinheins, Nadia Shardt, Ulrike Lohmann, and Claudia Marcolli
EGUsphere, https://doi.org/10.5194/egusphere-2024-2838, https://doi.org/10.5194/egusphere-2024-2838, 2024
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We model the CCN activation of sea spray aerosol particles with classical Köhler theory and with a new model approach that takes surface tension lowering into account. We categorize organic compounds into weak, intermediate, and strong surfactants and we outline for which composition surface tension lowering is important. The results suggest that surface tension lowering allows sea spray aerosol particles in the Aitken mode to be a source of CCN in marine updrafts.
Wei Li and Yuxuan Wang
Atmos. Chem. Phys., 24, 9339–9353, https://doi.org/10.5194/acp-24-9339-2024, https://doi.org/10.5194/acp-24-9339-2024, 2024
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Droughts immensely increased organic aerosol (OA) in the contiguous United States in summer (1998–2019), notably in the Pacific Northwest (PNW) and Southeast (SEUS). The OA rise in the SEUS is driven by the enhanced formation of epoxydiol-derived secondary organic aerosol due to the increase in biogenic volatile organic compounds and sulfate, while in the PNW, it is caused by wildfires. A total of 10 climate models captured the OA increase in the PNW yet greatly underestimated it in the SEUS.
Weina Zhang, Jianhua Mai, Zhichao Fan, Yongpeng Ji, Yuemeng Ji, Guiying Li, Yanpeng Gao, and Taicheng An
Atmos. Chem. Phys., 24, 9019–9030, https://doi.org/10.5194/acp-24-9019-2024, https://doi.org/10.5194/acp-24-9019-2024, 2024
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This study reveals heterogeneous oxidation causes further radiative forcing effect (RFE) enhancement of amine–mineral mixed particles. Note that RFE increment is higher under clean conditions than that under polluted conditions, which is contributed to high-oxygen-content products. The enhanced RFE of amine–mineral particles caused by heterogenous oxidation is expected to alleviate warming effects.
Olivia G. Norman, Colette L. Heald, Pedro Campuzano-Jost, Hugh Coe, Marc N. Fiddler, Jaime R. Green, Jose L. Jimenez, Katharina Kaiser, Jin Liao, Ann M. Middlebrook, Benjamin A. Nault, John B. Nowak, Johannes Schneider, and André Welti
EGUsphere, https://doi.org/10.5194/egusphere-2024-2296, https://doi.org/10.5194/egusphere-2024-2296, 2024
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This study finds that one component of secondary inorganic aerosols, nitrate, is greatly overestimated by a global atmospheric chemistry model compared to observations from 11 flight campaigns. None of the loss and production pathways explored can explain the nitrate bias alone. The model’s inability to capture the variability in the observations remains and requires future investigation to avoid biases in policy-related studies (i.e., air quality, health, climate impacts of these aerosols).
Shenglan Jiang, Yan Zhang, Guangyuan Yu, Zimin Han, Junri Zhao, Tianle Zhang, and Mei Zheng
Atmos. Chem. Phys., 24, 8363–8381, https://doi.org/10.5194/acp-24-8363-2024, https://doi.org/10.5194/acp-24-8363-2024, 2024
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This study aims to provide gridded data on sea-wide concentrations, deposition fluxes, and soluble deposition fluxes with detailed source categories of metals using the modified CMAQ model. We developed a monthly emission inventory of six metals – Fe, Al, V, Ni, Zn, and Cu – from terrestrial anthropogenic, ship, and dust sources in East Asia in 2017. Our results reveal the contribution of each source to the emissions, concentrations, and deposition fluxes of metals in the East Asian seas.
Sara Louise Farrell, Havala O. T. Pye, Robert Gilliam, George Pouliot, Deanna Huff, Golam Sarwar, William Vizuete, Nicole Briggs, and Kathleen Fahey
EGUsphere, https://doi.org/10.5194/egusphere-2024-1550, https://doi.org/10.5194/egusphere-2024-1550, 2024
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In this work we implement heterogeneous sulfur chemistry into the Community Multiscale Air Quality (CMAQ) model. This new chemistry accounts for the formation of sulfate via aqueous oxidation of SO2 in aerosol liquid water and the formation of hydroxymethanesulfonate (HMS) – often confused by measurement techniques as sulfate. Model performance in predicting sulfur PM2.5 in Fairbanks, Alaska, and other places that experience dark and cold winters, is improved.
Ashok K. Luhar, Anthony C. Jones, and Jonathan M. Wilkinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1363, https://doi.org/10.5194/egusphere-2024-1363, 2024
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Nitrate aerosol is often omitted in global chemistry-climate models due to the chemical complexity of its formation process. Using a global model, we demonstrate that including nitrate aerosol significantly impacts tropospheric composition fields, such as ozone, and radiation. Additionally, lightning-generated oxides of nitrogen influence both nitrate aerosol mass concentrations and aerosol size distribution, which has important implications for radiative fluxes and indirect aerosol effects.
Ryan Vella, Matthew Forrest, Andrea Pozzer, Alexandra P. Tsimpidi, Thomas Hickler, Jos Lelieveld, and Holger Tost
EGUsphere, https://doi.org/10.5194/egusphere-2024-2014, https://doi.org/10.5194/egusphere-2024-2014, 2024
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This study examines how land cover changes influence biogenic volatile organic compound (BVOC) emissions and atmospheric states. Using a coupled chemistry-climate/vegetation model, we compare present-day land cover (deforested for crops and grazing) with natural vegetation, and an extreme reforestation scenario. We find that vegetation changes significantly impact global BVOC emissions and organic aerosols but have a relatively small effect on total aerosols, clouds, and radiative effects.
Stelios Myriokefalitakis, Matthias Karl, Kim A. Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos
Atmos. Chem. Phys., 24, 7815–7835, https://doi.org/10.5194/acp-24-7815-2024, https://doi.org/10.5194/acp-24-7815-2024, 2024
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A state-of-the-art thermodynamic model has been coupled with the city-scale chemistry transport model EPISODE–CityChem to investigate the equilibrium between the inorganic gas and aerosol phases over the greater Athens area, Greece. The simulations indicate that the formation of nitrates in an urban environment is significantly affected by local nitrogen oxide emissions, as well as ambient temperature, relative humidity, photochemical activity, and the presence of non-volatile cations.
Rui Li, Yining Gao, Lijia Zhang, Yubing Shen, Tianzhao Xu, Wenwen Sun, and Gehui Wang
Atmos. Chem. Phys., 24, 7623–7636, https://doi.org/10.5194/acp-24-7623-2024, https://doi.org/10.5194/acp-24-7623-2024, 2024
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A three-stage model was developed to obtain the global maps of reactive nitrogen components during 2000–2100. The results implied that cross-validation R2 values of four species showed satisfactory performance (R2 > 0.55). Most reactive nitrogen components, except NH3, in China showed increases during 2000–2013. In the future scenarios, SSP3-7.0 (traditional-energy scenario) and SSP1-2.6 (carbon neutrality scenario) showed the highest and lowest reactive nitrogen component concentrations.
Mashiat Hossain, Rebecca M. Garland, and Hannah M. Horowitz
EGUsphere, https://doi.org/10.5194/egusphere-2024-1948, https://doi.org/10.5194/egusphere-2024-1948, 2024
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Our research examines aerosol dynamics over the southeast Atlantic, a region with significant uncertainties in aerosol radiative forcings. Using the GEOS-Chem model, we find that at cloud altitudes, organic aerosols dominate during the biomass burning season, while sulfate aerosols, driven by marine emissions, prevail during peak primary production. These findings highlight the need for accurate representation of marine aerosols in models to improve climate predictions and reduce uncertainties.
Fei Ye, Jingyi Li, Yaqin Gao, Hongli Wang, Jingyu An, Cheng Huang, Song Guo, Keding Lu, Kangjia Gong, Haowen Zhang, Momei Qin, and Jianlin Hu
Atmos. Chem. Phys., 24, 7467–7479, https://doi.org/10.5194/acp-24-7467-2024, https://doi.org/10.5194/acp-24-7467-2024, 2024
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Naphthalene (Nap) and methylnaphthalene (MN) are key precursors of secondary organic aerosol (SOA), yet their sources and sinks are often inadequately represented in air quality models. In this study, we incorporated detailed emissions, gas-phase chemistry, and SOA parameterization of Nap and MN into CMAQ to address this issue. The findings revealed remarkably high SOA formation potentials for these compounds despite their low emissions in the Yangtze River Delta region during summer.
Vy Dinh Ngoc Thuy, Jean-Luc Jaffrezo, Ian Hough, Pamela A. Dominutti, Guillaume Salque Moreton, Grégory Gille, Florie Francony, Arabelle Patron-Anquez, Olivier Favez, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 7261–7282, https://doi.org/10.5194/acp-24-7261-2024, https://doi.org/10.5194/acp-24-7261-2024, 2024
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The capacity of particulate matter (PM) to generate reactive oxygen species in vivo is represented by oxidative potential (OP). This study focuses on finding the appropriate model to evaluate the oxidative character of PM sources in six sites using the PM sources and OP. Eight regression techniques are introduced to assess the OP of PM. The study highlights the importance of selecting a model according to the input data characteristics and establishes some recommendations for the procedure.
Ming Chu, Xing Wei, Shangfei Hai, Yang Gao, Huiwang Gao, Yujiao Zhu, Biwu Chu, Nan Ma, Juan Hong, Yele Sun, and Xiaohong Yao
Atmos. Chem. Phys., 24, 6769–6786, https://doi.org/10.5194/acp-24-6769-2024, https://doi.org/10.5194/acp-24-6769-2024, 2024
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We used a 20-bin WRF-Chem model to simulate NPF events in the NCP during a three-week observational period in the summer of 2019. The model was able to reproduce the observations during June 29–July 6, which was characterized by a high frequency of NPF occurrence.
Haoqi Wang, Xiao Tian, Wanting Zhao, Jiacheng Li, Haoyu Yu, Yinchang Feng, and Shaojie Song
Atmos. Chem. Phys., 24, 6583–6592, https://doi.org/10.5194/acp-24-6583-2024, https://doi.org/10.5194/acp-24-6583-2024, 2024
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pH is a key property of ambient aerosols, which affect many atmospheric processes. As aerosol pH is a non-conservative parameter, diverse averaging metrics and temporal resolutions may influence the pH values calculated by thermodynamic models. This technical note seeks to quantitatively evaluate the average pH using varied metrics and resolutions. The ultimate goal is to establish standardized reporting practices in future research endeavors.
Jiwon Choi, Myoseon Jang, and Spencer Blau
Atmos. Chem. Phys., 24, 6567–6582, https://doi.org/10.5194/acp-24-6567-2024, https://doi.org/10.5194/acp-24-6567-2024, 2024
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Persistent phenoxy radical (PPR), formed by phenol gas oxidation and its aqueous reaction, catalytically destroys O3 and retards secondary organic aerosol (SOA) growth. Explicit gas mechanisms including the formation of PPR and low-volatility products from the oxidation of phenol or benzene are applied to the UNIPAR model to predict SOA mass via multiphase reactions of precursors. Aqueous reactions of reactive organics increase SOA mass but retard SOA growth via heterogeneously formed PPR.
Yang Yang, Shaoxuan Mou, Hailong Wang, Pinya Wang, Baojie Li, and Hong Liao
Atmos. Chem. Phys., 24, 6509–6523, https://doi.org/10.5194/acp-24-6509-2024, https://doi.org/10.5194/acp-24-6509-2024, 2024
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The variations in anthropogenic aerosol concentrations and source contributions and their subsequent radiative impact in major emission regions during historical periods are quantified based on an aerosol-tagging system in E3SMv1. Due to the industrial development and implementation of economic policies, sources of anthropogenic aerosols show different variations, which has important implications for pollution prevention and control measures and decision-making for global collaboration.
Maegan A. DeLessio, Kostas Tsigaridis, Susanne E. Bauer, Jacek Chowdhary, and Gregory L. Schuster
Atmos. Chem. Phys., 24, 6275–6304, https://doi.org/10.5194/acp-24-6275-2024, https://doi.org/10.5194/acp-24-6275-2024, 2024
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This study presents the first explicit representation of brown carbon aerosols in the GISS ModelE Earth system model (ESM). Model sensitivity to a range of brown carbon parameters and model performance compared to AERONET and MODIS retrievals of total aerosol properties were assessed. A summary of best practices for incorporating brown carbon into ModelE is also included.
Chuanyang Shen, Xiaoyan Yang, Joel Thornton, John Shilling, Chenyang Bi, Gabriel Isaacman-VanWertz, and Haofei Zhang
Atmos. Chem. Phys., 24, 6153–6175, https://doi.org/10.5194/acp-24-6153-2024, https://doi.org/10.5194/acp-24-6153-2024, 2024
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In this work, a condensed multiphase isoprene oxidation mechanism was developed to simulate isoprene SOA formation from chamber and field studies. Our results show that the measured isoprene SOA mass concentrations can be reasonably reproduced. The simulation results indicate that multifunctional low-volatility products contribute significantly to total isoprene SOA. Our findings emphasize that the pathways to produce these low-volatility species should be considered in models.
Alice Maison, Lya Lugon, Soo-Jin Park, Alexia Baudic, Christopher Cantrell, Florian Couvidat, Barbara D'Anna, Claudia Di Biagio, Aline Gratien, Valérie Gros, Carmen Kalalian, Julien Kammer, Vincent Michoud, Jean-Eudes Petit, Marwa Shahin, Leila Simon, Myrto Valari, Jérémy Vigneron, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 24, 6011–6046, https://doi.org/10.5194/acp-24-6011-2024, https://doi.org/10.5194/acp-24-6011-2024, 2024
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This study presents the development of a bottom-up inventory of urban tree biogenic emissions. Emissions are computed for each tree based on their location and characteristics and are integrated in the regional air quality model WRF-CHIMERE. The impact of these biogenic emissions on air quality is quantified for June–July 2022. Over Paris city, urban trees increase the concentrations of particulate organic matter by 4.6 %, of PM2.5 by 0.6 %, and of ozone by 1.0 % on average over 2 months.
Tommaso Galeazzo, Bernard Aumont, Marie Camredon, Richard Valorso, Yong B. Lim, Paul J. Ziemann, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 5549–5565, https://doi.org/10.5194/acp-24-5549-2024, https://doi.org/10.5194/acp-24-5549-2024, 2024
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Secondary organic aerosol (SOA) derived from n-alkanes is a major component of anthropogenic particulate matter. We provide an analysis of n-alkane SOA by chemistry modeling, machine learning, and laboratory experiments, showing that n-alkane SOA adopts low-viscous semi-solid or liquid states. Our results indicate few kinetic limitations of mass accommodation in SOA formation, supporting the application of equilibrium partitioning for simulating n-alkane SOA in large-scale atmospheric models.
Lukáš Bartík, Peter Huszár, Jan Karlický, Ondřej Vlček, and Kryštof Eben
Atmos. Chem. Phys., 24, 4347–4387, https://doi.org/10.5194/acp-24-4347-2024, https://doi.org/10.5194/acp-24-4347-2024, 2024
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The presented study deals with the attribution of fine particulate matter (PM2.5) concentrations to anthropogenic emissions over Central Europe using regional-scale models. It calculates the present-day contributions of different emissions sectors to concentrations of PM2.5 and its secondary components. Moreover, the study investigates the effect of chemical nonlinearities by using multiple source attribution methods and secondary organic aerosol calculation methods.
Rui Wang, Yang Cheng, Shasha Chen, Rongrong Li, Yue Hu, Xiaokai Guo, Tianlei Zhang, Fengmin Song, and Hao Li
Atmos. Chem. Phys., 24, 4029–4046, https://doi.org/10.5194/acp-24-4029-2024, https://doi.org/10.5194/acp-24-4029-2024, 2024
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We used quantum chemical calculations, Born–Oppenheimer molecular dynamics simulations, and the ACDC kinetic model to characterize SO3–H2SO4 interaction in the gas phase and at the air–water interface and to study the effect of H2S2O7 on H2SO4–NH3-based clusters. The work expands our understanding of new pathways for the loss of SO3 in acidic polluted areas and helps reveal some missing sources of NPF in metropolitan industrial regions and understand the atmospheric organic–sulfur cycle better.
Hao Yang, Lei Chen, Hong Liao, Jia Zhu, Wenjie Wang, and Xin Li
Atmos. Chem. Phys., 24, 4001–4015, https://doi.org/10.5194/acp-24-4001-2024, https://doi.org/10.5194/acp-24-4001-2024, 2024
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The present study quantifies the response of aerosol–radiation interaction (ARI) to anthropogenic emission reduction from 2013 to 2017, with the main focus on the contribution to changed O3 concentrations over eastern China both in summer and winter using the WRF-Chem model. The weakened ARI due to decreased anthropogenic emission aggravates the summer (winter) O3 pollution by +0.81 ppb (+0.63 ppb), averaged over eastern China.
Margaret R. Marvin, Paul I. Palmer, Fei Yao, Mohd Talib Latif, and Md Firoz Khan
Atmos. Chem. Phys., 24, 3699–3715, https://doi.org/10.5194/acp-24-3699-2024, https://doi.org/10.5194/acp-24-3699-2024, 2024
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We use an atmospheric chemistry model to investigate aerosols emitted from fire activity across Southeast Asia. We find that the limited nature of measurements in this region leads to large uncertainties that significantly hinder the model representation of these aerosols and their impacts on air quality. As a result, the number of monthly attributable deaths is underestimated by as many as 4500, particularly in March at the peak of the mainland burning season.
Julie Camman, Benjamin Chazeau, Nicolas Marchand, Amandine Durand, Grégory Gille, Ludovic Lanzi, Jean-Luc Jaffrezo, Henri Wortham, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 3257–3278, https://doi.org/10.5194/acp-24-3257-2024, https://doi.org/10.5194/acp-24-3257-2024, 2024
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Fine particle (PM1) pollution is a major health issue in the city of Marseille, which is subject to numerous pollution sources. Sampling carried out during the summer enabled a fine characterization of the PM1 sources and their oxidative potential, a promising new metric as a proxy for health impact. PM1 came mainly from combustion sources, secondary ammonium sulfate, and organic nitrate, while the oxidative potential of PM1 came from these sources and from resuspended dust in the atmosphere.
Yuemeng Ji, Zhang Shi, Wenjian Li, Jiaxin Wang, Qiuju Shi, Yixin Li, Lei Gao, Ruize Ma, Weijun Lu, Lulu Xu, Yanpeng Gao, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 3079–3091, https://doi.org/10.5194/acp-24-3079-2024, https://doi.org/10.5194/acp-24-3079-2024, 2024
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The formation mechanisms for secondary brown carbon (SBrC) contributed by multifunctional reduced nitrogen compounds (RNCs) remain unclear. Hence, from combined laboratory experiments and quantum chemical calculations, we investigated the heterogeneous reactions of glyoxal (GL) with multifunctional RNCs, which are driven by four-step indirect nucleophilic addition reactions. Our results show a possible missing source for SBrC formation on urban, regional, and global scales.
Elyse A. Pennington, Yuan Wang, Benjamin C. Schulze, Karl M. Seltzer, Jiani Yang, Bin Zhao, Zhe Jiang, Hongru Shi, Melissa Venecek, Daniel Chau, Benjamin N. Murphy, Christopher M. Kenseth, Ryan X. Ward, Havala O. T. Pye, and John H. Seinfeld
Atmos. Chem. Phys., 24, 2345–2363, https://doi.org/10.5194/acp-24-2345-2024, https://doi.org/10.5194/acp-24-2345-2024, 2024
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To assess the air quality in Los Angeles (LA), we improved the CMAQ model by using dynamic traffic emissions and new secondary organic aerosol schemes to represent volatile chemical products. Source apportionment demonstrates that the urban areas of the LA Basin and vicinity are NOx-saturated, with the largest sensitivity of O3 to changes in volatile organic compounds in the urban core. The improvement and remaining issues shed light on the future direction of the model development.
Feifan Yan, Hang Su, Yafang Cheng, Rujin Huang, Hong Liao, Ting Yang, Yuanyuan Zhu, Shaoqing Zhang, Lifang Sheng, Wenbin Kou, Xinran Zeng, Shengnan Xiang, Xiaohong Yao, Huiwang Gao, and Yang Gao
Atmos. Chem. Phys., 24, 2365–2376, https://doi.org/10.5194/acp-24-2365-2024, https://doi.org/10.5194/acp-24-2365-2024, 2024
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PM2.5 pollution is a major air quality issue deteriorating human health, and previous studies mostly focus on regions like the North China Plain and Yangtze River Delta. However, the characteristics of PM2.5 concentrations between these two regions are studied less often. Focusing on the transport corridor region, we identify an interesting seesaw transport phenomenon with stagnant weather conditions, conducive to PM2.5 accumulation over this region, resulting in large health effects.
Prerita Agarwal, David S. Stevenson, and Mathew R. Heal
Atmos. Chem. Phys., 24, 2239–2266, https://doi.org/10.5194/acp-24-2239-2024, https://doi.org/10.5194/acp-24-2239-2024, 2024
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Air pollution levels across northern India are amongst some of the worst in the world, with episodic and hazardous haze events. Here, the ability of the WRF-Chem model to predict air quality over northern India is assessed against several datasets. Whilst surface wind speed and particle pollution peaks are over- and underestimated, respectively, meteorology and aerosol trends are adequately captured, and we conclude it is suitable for investigating severe particle pollution events.
George Jordan, Florent Malavelle, Ying Chen, Amy Peace, Eliza Duncan, Daniel G. Partridge, Paul Kim, Duncan Watson-Parris, Toshihiko Takemura, David Neubauer, Gunnar Myhre, Ragnhild Skeie, Anton Laakso, and James Haywood
Atmos. Chem. Phys., 24, 1939–1960, https://doi.org/10.5194/acp-24-1939-2024, https://doi.org/10.5194/acp-24-1939-2024, 2024
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The 2014–15 Holuhraun eruption caused a huge aerosol plume in an otherwise unpolluted region, providing a chance to study how aerosol alters cloud properties. This two-part study uses observations and models to quantify this relationship’s impact on the Earth’s energy budget. Part 1 suggests the models capture the observed spatial and chemical evolution of the plume, yet no model plume is exact. Understanding these differences is key for Part 2, where changes to cloud properties are explored.
Lin Du, Xiaofan Lv, Makroni Lily, Kun Li, and Narcisse Tsona Tchinda
Atmos. Chem. Phys., 24, 1841–1853, https://doi.org/10.5194/acp-24-1841-2024, https://doi.org/10.5194/acp-24-1841-2024, 2024
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This study explores the pH effect on the reaction of dissolved SO2 with selected organic peroxides. Results show that the formation of organic and/or inorganic sulfate from these peroxides strongly depends on their electronic structures, and these processes are likely to alter the chemical composition of dissolved organic matter in different ways. The rate constants of these reactions exhibit positive pH and temperature dependencies within pH 1–10 and 240–340 K ranges.
Angelo Riccio and Elena Chianese
Atmos. Chem. Phys., 24, 1673–1689, https://doi.org/10.5194/acp-24-1673-2024, https://doi.org/10.5194/acp-24-1673-2024, 2024
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Starting from the Copernicus Atmosphere Monitoring Service (CAMS), we provided a novel ensemble statistical post-processing approach to improve their air quality predictions. Our approach is able to provide reliable short-term forecasts of pollutant concentrations, which is a key challenge in supporting national authorities in their tasks related to EU Air Quality Directives, such as planning and reporting the state of air quality to the citizens.
Stella E. I. Manavi and Spyros N. Pandis
Atmos. Chem. Phys., 24, 891–909, https://doi.org/10.5194/acp-24-891-2024, https://doi.org/10.5194/acp-24-891-2024, 2024
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Organic vapors of intermediate volatility have often been neglected as sources of atmospheric organic aerosol. In this work we use a new approach for their simulation and quantify the contribution of these compounds emitted by transportation sources (gasoline and diesel vehicles) to particulate matter over Europe. The estimated secondary organic aerosol levels are on average 60 % higher than predicted by previous approaches. However, these estimates are probably lower limits.
Zhiyuan Li, Kin-Fai Ho, Harry Fung Lee, and Steve Hung Lam Yim
Atmos. Chem. Phys., 24, 649–661, https://doi.org/10.5194/acp-24-649-2024, https://doi.org/10.5194/acp-24-649-2024, 2024
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This study developed an integrated model framework for accurate multi-air-pollutant exposure assessments in high-density and high-rise cities. Following the proposed integrated model framework, we established multi-air-pollutant exposure models for four major PM10 chemical species as well as four criteria air pollutants with R2 values ranging from 0.73 to 0.93. The proposed framework serves as an important tool for combined exposure assessment in epidemiological studies.
Yujin Jo, Myoseon Jang, Sanghee Han, Azad Madhu, Bonyoung Koo, Yiqin Jia, Zechen Yu, Soontae Kim, and Jinsoo Park
Atmos. Chem. Phys., 24, 487–508, https://doi.org/10.5194/acp-24-487-2024, https://doi.org/10.5194/acp-24-487-2024, 2024
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The CAMx–UNIPAR model simulated the SOA budget formed via multiphase reactions of hydrocarbons and the impact of emissions and climate on SOA characteristics under California’s urban environments during winter 2018. SOA growth was dominated by daytime oxidation of long-chain alkanes and nighttime terpene oxidation with O3 and NO−3 radicals. The spatial distributions of anthropogenic SOA were affected by the northwesterly wind, whereas those of biogenic SOA were insensitive to wind directions.
Peter Huszar, Alvaro Patricio Prieto Perez, Lukáš Bartík, Jan Karlický, and Anahi Villalba-Pradas
Atmos. Chem. Phys., 24, 397–425, https://doi.org/10.5194/acp-24-397-2024, https://doi.org/10.5194/acp-24-397-2024, 2024
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Urbanization transforms rural land into artificial land, while due to human activities, it also introduces a great quantity of emissions. We quantify the impact of urbanization on the final particulate matter pollutant levels by looking not only at these emissions, but also at the way urban land cover influences meteorological conditions, how the removal of pollutants changes due to urban land cover, and how biogenic emissions from vegetation change due to less vegetation in urban areas.
Yinbao Jin, Yiming Liu, Xiao Lu, Xiaoyang Chen, Ao Shen, Haofan Wang, Yinping Cui, Yifei Xu, Siting Li, Jian Liu, Ming Zhang, Yingying Ma, and Qi Fan
Atmos. Chem. Phys., 24, 367–395, https://doi.org/10.5194/acp-24-367-2024, https://doi.org/10.5194/acp-24-367-2024, 2024
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This study aims to address these issues by evaluating eight independent biomass burning (BB) emission inventories (GFED, FINN1.5, FINN2.5 MOS, FINN2.5 MOSVIS, GFAS, FEER, QFED, and IS4FIRES) using the WRF-Chem model and analyzing their impact on aerosol optical properties (AOPs) and direct radiative forcing (DRF) during wildfire events in peninsular Southeast Asia (PSEA) that occurred in March 2019.
Hamza Ahsan, Hailong Wang, Jingbo Wu, Mingxuan Wu, Steven J. Smith, Susanne Bauer, Harrison Suchyta, Dirk Olivié, Gunnar Myhre, Hitoshi Matsui, Huisheng Bian, Jean-François Lamarque, Ken Carslaw, Larry Horowitz, Leighton Regayre, Mian Chin, Michael Schulz, Ragnhild Bieltvedt Skeie, Toshihiko Takemura, and Vaishali Naik
Atmos. Chem. Phys., 23, 14779–14799, https://doi.org/10.5194/acp-23-14779-2023, https://doi.org/10.5194/acp-23-14779-2023, 2023
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We examine the impact of the assumed effective height of SO2 injection, SO2 and BC emission seasonality, and the assumed fraction of SO2 emissions injected as SO4 on climate and chemistry model results. We find that the SO2 injection height has a large impact on surface SO2 concentrations and, in some models, radiative flux. These assumptions are a
hiddensource of inter-model variability and may be leading to bias in some climate model results.
Zhen Peng, Lili Lei, Zhe-Min Tan, Meigen Zhang, Aijun Ding, and Xingxia Kou
Atmos. Chem. Phys., 23, 14505–14520, https://doi.org/10.5194/acp-23-14505-2023, https://doi.org/10.5194/acp-23-14505-2023, 2023
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Annual PM2.5 emissions in China consistently decreased by about 3% to 5% from 2017 to 2020 with spatial variations and seasonal dependencies. High-temporal-resolution and dynamics-based PM2.5 emission estimates provide quantitative diurnal variations for each season. Significant reductions in PM2.5 emissions in the North China Plain and northeast of China in 2020 were caused by COVID-19.
Stylianos Kakavas, Spyros N. Pandis, and Athanasios Nenes
Atmos. Chem. Phys., 23, 13555–13564, https://doi.org/10.5194/acp-23-13555-2023, https://doi.org/10.5194/acp-23-13555-2023, 2023
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Water uptake from organic species in aerosol can affect the partitioning of semi-volatile inorganic compounds but are not considered in global and chemical transport models. We address this with a version of the PM-CAMx model that considers such organic water effects and use it to carry out 1-year aerosol simulations over the continental US. We show that such organic water impacts can increase dry PM1 levels by up to 2 μg m-3 when RH levels and PM1 concentrations are high.
Benjamin N. Murphy, Darrell Sonntag, Karl M. Seltzer, Havala O. T. Pye, Christine Allen, Evan Murray, Claudia Toro, Drew R. Gentner, Cheng Huang, Shantanu Jathar, Li Li, Andrew A. May, and Allen L. Robinson
Atmos. Chem. Phys., 23, 13469–13483, https://doi.org/10.5194/acp-23-13469-2023, https://doi.org/10.5194/acp-23-13469-2023, 2023
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We update methods for calculating organic particle and vapor emissions from mobile sources in the USA. Conventionally, particulate matter (PM) and volatile organic carbon (VOC) are speciated without consideration of primary semivolatile emissions. Our methods integrate state-of-the-science speciation profiles and correct for common artifacts when sampling emissions in a laboratory. We quantify impacts of the emission updates on ambient pollution with the Community Multiscale Air Quality model.
Yanshun Li, Randall V. Martin, Chi Li, Brian L. Boys, Aaron van Donkelaar, Jun Meng, and Jeffrey R. Pierce
Atmos. Chem. Phys., 23, 12525–12543, https://doi.org/10.5194/acp-23-12525-2023, https://doi.org/10.5194/acp-23-12525-2023, 2023
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We developed and evaluated processes affecting within-day (diel) variability in PM2.5 concentrations in a chemical transport model over the contiguous US. Diel variability in PM2.5 for the contiguous US is driven by early-morning accumulation into a shallow mixed layer, decreases from mid-morning through afternoon with mixed-layer growth, increases from mid-afternoon through evening as the mixed-layer collapses, and decreases overnight as emissions decrease.
Cited articles
Almeida, J., Schobesberger, S., Kuerten, A., Ortega, I. K.,
Kupiainen-Maatta, O., Praplan, A. P., Adamov, A., Amorim, A., Bianchi, F.,
Breitenlechner, M., David, A., Dommen, J., Donahue, N. M., Downard, A.,
Dunne, E., Duplissy, J., Ehrhart, S., Flagan, R. C., Franchin, A., Guida,
R., Hakala, J., Hansel, A., Heinritzi, M., Henschel, H., Jokinen, T.,
Junninen, H., Kajos, M., Kangasluoma, J., Keskinen, H., Kupc, A., Kurten,
T., Kvashin, A. N., Laaksonen, A., Lehtipalo, K., Leiminger, M., Leppa, J.,
Loukonen, V., Makhmutov, V., Mathot, S., McGrath, M. J., Nieminen, T.,
Olenius, T., Onnela, A., Petaja, T., Riccobono, F., Riipinen, I., Rissanen,
M., Rondo, L., Ruuskanen, T., Santos, F. D., Sarnela, N., Schallhart, S.,
Schnitzhofer, R., Seinfeld, J. H., Simon, M., Sipila, M., Stozhkov, Y.,
Stratmann, F., Tome, A., Troestl, J., Tsagkogeorgas, G., Vaattovaara, P.,
Viisanen, Y., Virtanen, A., Vrtala, A., Wagner, P. E., Weingartner, E., Wex,
H., Williamson, C., Wimmer, D., Ye, P., Yli-Juuti, T., Carslaw, K. S.,
Kulmala, M., Curtius, J., Baltensperger, U., Worsnop, D. R., Vehkamaki, H.,
and Kirkby, J.: Molecular understanding of sulphuric acid-amine particle
nucleation in the atmosphere, Nature, 502, 359–363,
https://doi.org/10.1038/nature12663, 2013.
An, P., Yuan, C.-Q., Liu, X.-H., Xiao, D.-B., and Luo, Z.-X.: Vibrational
spectroscopic identification of isoprene, pinenes and their mixture, Chin.
Chem. Lett., 27, 527–534, https://doi.org/10.1016/j.cclet.2016.01.036, 2016.
Arquero, K. D., Gerber, R. B., and Finlayson-Pitts, B. J.: The role of
oxalic acid in new particle formation from methanesulfonic Acid,
methylamine, and water, Environ. Sci. Technol., 51, 2124–2130,
https://doi.org/10.1021/acs.est.6b05056, 2017a.
Arquero, K. D., Xu, J., Gerber, R. B., and Finlayson-Pitts, B. J.: Particle
formation and growth from oxalic acid, methanesulfonic acid, trimethylamine
and water: a combined experimental and theoretical study, Phys. Chem. Chem.
Phys., 19, 28286–28301, https://doi.org/10.1039/c7cp04468b, 2017b.
Carlton, A. G., Turpin, B. J., Lim, H. J., Altieri, K. E., and Seitzinger,
S.: Link between isoprene and secondary organic aerosol (SOA): Pyruvic acid
oxidation yields low volatility organic acids in clouds, Geophys. Res.
Lett., 33, 4, https://doi.org/10.1029/2005gl025374, 2006.
Chan, M. N., Choi, M. Y., Ng, N. L., and Chan, C. K.: Hygroscopicity of
water-soluble organic compounds in atmospheric aerosols: Amino acids and
biomass burning derived organic species, Environ. Sci. Technol., 39,
1555–1562, https://doi.org/10.1021/es049584l, 2005.
Chebbi, A. and Carlier, P.: Carboxylic acids in the troposphere, occurrence,
sources, and sinks: A review, Atmos. Environ., 30, 4233–4249,
https://doi.org/10.1016/1352-2310(96)00102-1, 1996.
Chen, D., Li, D., Wang, C., Liu, F., and Wang, W.: Formation mechanism of
methanesulfonic acid and ammonia clusters: A kinetics simulation study,
Atmos. Environ., 222, 117161, https://doi.org/10.1016/j.atmosenv.2019.117161,
2020a.
Chen, D., Li, D., Wang, C., Luo, Y., Liu, F., and Wang, W.: Atmospheric
implications of hydration on the formation of methanesulfonic acid and
methylamine clusters: A theoretical study, Chemosphere, 244, 125538,
https://doi.org/10.1016/j.chemosphere.2019.125538, 2020b.
Chen, H. and Finlayson-Pitts, B. J.: New particle formation from
methanesulfonic acid and amines/ammonia as a function of temperature,
Environ. Sci. Technol., 51, 243–252, https://doi.org/10.1021/acs.est.6b04173,
2017.
Chen, H., Ezell, M. J., Arquero, K. D., Varner, M. E., Dawson, M. L.,
Gerber, R. B., and Finlayson-Pitts, B. J.: New particle formation and growth
from methanesulfonic acid, trimethylamine and water, Phys. Chem. Chem.
Phys., 17, 13699–13709, https://doi.org/10.1039/c5cp00838g, 2015.
Chen, H., Varner, M. E., Gerber, R. B., and Finlayson-Pitts, B. J.:
Reactions of methanesulfonic acid with amines and ammonia as a source of new
particles in air, J. Phys. Chem. B, 120, 1526–1536,
https://doi.org/10.1021/acs.jpcb.5b07433, 2016.
Cong, Z., Kawamura, K., Kang, S., and Fu, P.: Penetration of biomass-burning
emissions from South Asia through the Himalayas: new insights from
atmospheric organic acids, Sci. Rep., 5, 9580, https://doi.org/10.1038/srep09580,
2015.
Dawson, M. L., Varner, M. E., Perraud, V., Ezell, M. J., Gerber, R. B., and
Finlayson-Pitts, B. J.: Simplified mechanism for new particle formation from
methanesulfonic acid, amines, and water via experiments and ab initio
calculations, Proc. Natl. Acad. Sci. USA, 109, 18719–18724,
https://doi.org/10.1073/pnas.1211878109, 2012.
Elm, J.: Clusteromics II: Methanesulfonic Acid–Base Cluster Formation, ACS
Omega, 6, 17035–17044, https://doi.org/10.1021/acsomega.1c02115, 2021.
Elm, J. and Kristensen, K.: Basis set convergence of the binding energies of
strongly hydrogen-bonded atmospheric clusters, Phys. Chem. Chem. Phys., 19,
1122–1133, https://doi.org/10.1039/c6cp06851k, 2017.
Elm, J., Bilde, M., and Mikkelsen, K. V.: Assessment of binding energies of
atmospherically relevant clusters, Phys. Chem. Chem. Phys., 15, 16442–16445,
https://doi.org/10.1039/c3cp52616j, 2013.
Elm, J., Myllys, N., and Kurten, T.: What is required for highly oxidized
molecules to form clusters with sulfuric acid?, J. Phys. Chem. A, 121,
4578–4587, https://doi.org/10.1021/acs.jpca.7b03759, 2017.
Elm, J., Hyttinen, N., Lin, J. J., Kurten, T., and Prisle, N. L.: Strong
Even/Odd Pattern in the Computed Gas-Phase Stability of Dicarboxylic Acid
Dimers: Implications for Condensation Thermodynamics, J. Phys. Chem. A, 123,
9594–9599, https://doi.org/10.1021/acs.jpca.9b08020, 2019.
Elm, J., Kubecka, J., Besel, V., Jaaskelainen, M. J., Halonen, R., Kurten,
T., and Vehkamaki, H.: Modeling the formation and growth of atmospheric
molecular clusters: A review, J. Aerosol Sci., 149, 105621,
https://doi.org/10.1016/j.jaerosci.2020.105621, 2020.
Falkovich, A. H., Graber, E. R., Schkolnik, G., Rudich, Y., Maenhaut, W., and Artaxo, P.: Low molecular weight organic acids in aerosol particles from Rondônia, Brazil, during the biomass-burning, transition and wet periods, Atmos. Chem. Phys., 5, 781–797, https://doi.org/10.5194/acp-5-781-2005, 2005.
Fehsenfeld, F., Calvert, J., Fall, R., Goldan, P., Guenther, A. B., Hewitt,
C. N., Lamb, B., Liu, S., Trainer, M., Westberg, H., and Zimmerman, P.:
Emissions of volatile organic compounds from vegetation and the implications
for atmospheric chemistry, Glob. Biogeochem. Cycle, 6, 389–430,
https://doi.org/10.1029/92gb02125, 1992.
Franco, B., Blumenstock, T., Cho, C., Clarisse, L., Clerbaux, C., Coheur, P.
F., De Maziere, M., De Smedt, I., Dorn, H. P., Emmerichs, T., Fuchs, H.,
Gkatzelis, G., Griffith, D. W. T., Gromov, S., Hannigan, J. W., Hase, F.,
Hohaus, T., Jones, N., Kerkweg, A., Kiendler-Scharr, A., Lutsch, E., Mahieu,
E., Novelli, A., Ortega, I., Paton-Walsh, C., Pommier, M., Pozzer, A.,
Reimer, D., Rosanka, S., Sander, R., Schneider, M., Strong, K., Tillmann,
R., Van Roozendael, M., Vereecken, L., Vigouroux, C., Wahner, A., and
Taraborrelli, D.: Ubiquitous atmospheric production of organic acids
mediated by cloud droplets, Nature, 593, 233–237,
https://doi.org/10.1038/s41586-021-03462-x, 2021.
Friedman, B., Link, M. F., Fulgham, S. R., Brophy, P., Galang, A., Brune, W.
H., Jathar, S. H., and Farmer, D. K.: Primary and secondary sources of
gas-phase organic acids from diesel exhaust, Environ. Sci. Technol., 51,
10872–10880, https://doi.org/10.1021/acs.est.7b01169, 2017.
Glasoe, W. A., Volz, K., Panta, B., Freshour, N., Bachman, R., Hanson, D.
R., McMurry, P. H., and Jen, C.: Sulfuric acid nucleation: An experimental
study of the effect of seven bases, J. Geophys. Res.-Atmos., 120,
1933–1950, https://doi.org/10.1002/2014jd022730, 2015.
Heal, M. R., Kumar, P., and Harrison, R. M.: Particles, air quality, policy
and health, Chem. Soc. Rev., 41, 6606–6630,
https://doi.org/10.1039/c2cs35076a, 2012.
Ho, K. F., Cao, J. J., Lee, S. C., Kawamura, K., Zhang, R. J., Chow, J. C.,
and Watson, J. G.: Dicarboxylic acids, ketocarboxylic acids, and dicarbonyls
in the urban atmosphere of China, J. Geophys. Res.-Atmos., 112, D22S27,
https://doi.org/10.1029/2006jd008011, 2007.
Kavouras, I. G., Mihalopoulos, N., and Stephanou, E. G.: Formation of
atmospheric particles from organic acids produced by forests, Nature, 395,
683–686, https://doi.org/10.1038/27179, 1998.
Khwaja, H. A.: Atmospheric concentrations of carboxylic acids and related
compounds at a semiurban site, Atmos. Environ., 29, 127–139,
https://doi.org/10.1016/1352-2310(94)00211-3, 1995.
Kirkby, J., Curtius, J., Almeida, J., Dunne, E., Duplissy, J., Ehrhart, S.,
Franchin, A., Gagne, S., Ickes, L., Kuerten, A., Kupc, A., Metzger, A.,
Riccobono, F., Rondo, L., Schobesberger, S., Tsagkogeorgas, G., Wimmer, D.,
Amorim, A., Bianchi, F., Breitenlechner, M., David, A., Dommen, J., Downard,
A., Ehn, M., Flagan, R. C., Haider, S., Hansel, A., Hauser, D., Jud, W.,
Junninen, H., Kreissl, F., Kvashin, A., Laaksonen, A., Lehtipalo, K., Lima,
J., Lovejoy, E. R., Makhmutov, V., Mathot, S., Mikkila, J., Minginette, P.,
Mogo, S., Nieminen, T., Onnela, A., Pereira, P., Petaja, T., Schnitzhofer,
R., Seinfeld, J. H., Sipila, M., Stozhkov, Y., Stratmann, F., Tome, A.,
Vanhanen, J., Viisanen, Y., Vrtala, A., Wagner, P. E., Walther, H.,
Weingartner, E., Wex, H., Winkler, P. M., Carslaw, K. S., Worsnop, D. R.,
Baltensperger, U., and Kulmala, M.: Role of sulphuric acid, ammonia and
galactic cosmic rays in atmospheric aerosol nucleation, Nature, 476,
429–433, https://doi.org/10.1038/nature10343, 2011.
Kurtén, T., Loukonen, V., Vehkamäki, H., and Kulmala, M.: Amines are likely to enhance neutral and ion-induced sulfuric acid-water nucleation in the atmosphere more effectively than ammonia, Atmos. Chem. Phys., 8, 4095–4103, https://doi.org/10.5194/acp-8-4095-2008, 2008.
Lee, S.-H., Gordon, H., Yu, H., Lehtipalo, K., Haley, R., Li, Y., and Zhang,
R.: New particle formation in the atmosphere: from molecular clusters to
global climate, J. Geophys. Res.-Atmos., 124, 7098–7146,
https://doi.org/10.1029/2018jd029356, 2019.
Li, H., Kupiainen-Maatta, O., Zhang, H., Zhang, X., and Ge, M.: A
molecular-scale study on the role of lactic acid in new particle formation:
Influence of relative humidity and temperature, Atmos. Environ., 166,
479–487, https://doi.org/10.1016/j.atmosenv.2017.07.039, 2017.
Li, Y., Zhang, H., Zhang, Q., Xu, Y., and Nadykto, A. B.: Interactions of
sulfuric acid with common atmospheric bases and organic acids:
Thermodynamics and implications to new particle formation, J. Environ. Sci., 95, 130–140, https://doi.org/10.1016/j.jes.2020.03.033, 2020.
Lin, Y., Ji, Y., Li, Y., Secrest, J., Xu, W., Xu, F., Wang, Y., An, T., and Zhang, R.: Interaction between succinic acid and sulfuric acid–base clusters, Atmos. Chem. Phys., 19, 8003–8019, https://doi.org/10.5194/acp-19-8003-2019, 2019.
Liu, L., Kupiainen-Maatta, O., Zhang, H., Li, H., Zhong, J., Kurten, T.,
Vehkamaki, H., Zhang, S., Zhang, Y., Ge, M., Zhang, X., and Li, Z.:
Clustering mechanism of oxocarboxylic acids involving hydration reaction:
Implications for the atmospheric models, J. Chem. Phys., 148, 214303,
https://doi.org/10.1063/1.5030665, 2018.
Loukonen, V., Kurtén, T., Ortega, I. K., Vehkamäki, H., Pádua, A. A. H., Sellegri, K., and Kulmala, M.: Enhancing effect of dimethylamine in sulfuric acid nucleation in the presence of water – a computational study, Atmos. Chem. Phys., 10, 4961–4974, https://doi.org/10.5194/acp-10-4961-2010, 2010.
Ma, F., Xie, H.-B., Elm, J., Shen, J., Chen, J., and Vehkamaki, H.:
Piperazine enhancing sulfuric acid-based new particle formation:
implications for the atmospheric fate of piperazine, Environ. Sci. Technol.,
53, 8785–8795, https://doi.org/10.1021/acs.est.9b02117, 2019a.
Ma, X., Sun, Y., Huang, Z., Zhang, Q., and Wang, W.: A density functional
theory study of the molecular interactions between a series of amides and
sulfuric acid, Chemosphere, 214, 781–790,
https://doi.org/10.1016/j.chemosphere.2018.08.152, 2019b.
McGrath, M. J., Olenius, T., Ortega, I. K., Loukonen, V., Paasonen, P., Kurtén, T., Kulmala, M., and Vehkamäki, H.: Atmospheric Cluster Dynamics Code: a flexible method for solution of the birth-death equations, Atmos. Chem. Phys., 12, 2345–2355, https://doi.org/10.5194/acp-12-2345-2012, 2012.
Neese, F.: The ORCA program system, Wiley Interdiscip. Rev.-Comput. Mol.
Sci., 2, 73–78, https://doi.org/10.1002/wcms.81, 2012.
Nieminen, T., Manninen, H. E., Sihto, S. L., Yli-Juuti, T., Mauldin, I. R.
L., Petäjä, T., Riipinen, I., Kerminen, V. M., and Kulmala, M.:
Connection of Sulfuric Acid to Atmospheric Nucleation in Boreal Forest,
Environ. Sci. Technol., 43, 4715–4721, https://doi.org/10.1021/es803152j,
2009.
Nishino, N., Arquero, K. D., Dawson, M. L., and Finlayson-Pitts, B. J.:
Infrared studies of the reaction of methanesulfonic acid with trimethylamine
on surfaces, Environ. Sci. Technol., 48, 323–330,
https://doi.org/10.1021/es403845b, 2014.
Olenius, T., Kupiainen-Maatta, O., Ortega, I. K., Kurten, T., and Vehkamaki,
H.: Free energy barrier in the growth of sulfuric acid-ammonia and sulfuric
acid-dimethylamine clusters, J. Chem. Phys., 139, 084312,
https://doi.org/10.1063/1.4819024, 2013.
Olenius, T., Halonen, R., Kurten, T., Henschel, H., Kupiainen-Maata, O.,
Ortega, I. K., Jen, C. N., Vehkamaki, H., and Riipinen, I.: New particle
formation from sulfuric acid and amines: Comparison of monomethylamine,
dimethylamine, and trimethylamine, J. Geophys. Res.-Atmos., 122, 7103–7118,
https://doi.org/10.1002/2017jd026501, 2017.
Paulot, F., Crounse, J. D., Kjaergaard, H. G., Kroll, J. H., Seinfeld, J. H., and Wennberg, P. O.: Isoprene photooxidation: new insights into the production of acids and organic nitrates, Atmos. Chem. Phys., 9, 1479–1501, https://doi.org/10.5194/acp-9-1479-2009, 2009.
Perraud, V., Horne, J. R., Martinez, A. S., Kalinowski, J., Meinardi, S.,
Dawson, M. L., Wingen, L. M., Dabdub, D., Blake, D. R., Gerber, R. B., and
Finlayson-Pitts, B. J.: The future of airborne sulfur-containing particles
in the absence of fossil fuel sulfur dioxide emissions, Proc. Natl. Acad.
Sci. USA, 112, 13514–13519, https://doi.org/10.1073/pnas.1510743112, 2015.
Perraud, V., Xu, J., Gerber, R. B., and Finlayson-Pitts, B. J.: Integrated
experimental and theoretical approach to probe the synergistic effect of
ammonia in methanesulfonic acid reactions with small alkylamines, Environ.
Sci.-Processes Impacts, 22, 305–328, https://doi.org/10.1039/c9em00431a,
2020a.
Perraud, V., Li, X., Jiang, J., Finlayson-Pitts, B. J., and Smith, J. N.:
Size-resolved chemical composition of sub-20 nm particles from
methanesulfonic acid reactions with methylamine and ammonia, ACS Earth Space
Chem., 4, 1182–1194, https://doi.org/10.1021/acsearthspacechem.0c00120,
2020b.
Shen, J., Xie, H.-B., Elm, J., Ma, F., Chen, J., and Vehkamaki, H.:
Methanesulfonic Acid-driven New Particle Formation Enhanced by
Monoethanolamine: A Computational Study, Environ. Sci. Technol., 53,
14387–14397, https://doi.org/10.1021/acs.est.9b05306, 2019.
Shen, J., Elm, J., Xie, H.-B., Chen, J., Niu, J., and Vehkamaki, H.:
Structural effects of amines in enhancing methanesulfonic acid-driven new
particle formation, Environ. Sci. Technol., 54, 13498–13508,
https://doi.org/10.1021/acs.est.0c05358, 2020.
Sheng, X., Wang, B., Song, X., Ngwenya, C. A., Wang, Y., and Zhao, H.:
Atmospheric Initial Nucleation Containing Carboxylic Acids, J. Phys. Chem. A,
123, 3876–3886, https://doi.org/10.1021/acs.jpca.9b01104, 2019.
Shi, X., Zhao, X., Zhang, R., Xu, F., Cheng, J., Zhang, Q., and Wang, W.:
Theoretical study of the cis-pinonic acid and its atmospheric hydrolysate
participation in the atmospheric nucleation, Sci. Total Environ., 674,
234–241, https://doi.org/10.1016/j.scitotenv.2019.03.479, 2019.
Sipila, M., Berndt, T., Petaja, T., Brus, D., Vanhanen, J., Stratmann, F.,
Patokoski, J., Mauldin, R. L. III., Hyvarinen, A.-P., Lihavainen, H., and
Kulmala, M.: The role of sulfuric acid in atmospheric nucleation, Science,
327, 1243–1246, https://doi.org/10.1126/science.1180315, 2010.
Stahl, C., Cruz, M. T., Bañaga, P. A., Betito, G., Braun, R. A., Aghdam, M. A., Cambaliza, M. O., Lorenzo, G. R., MacDonald, A. B., Hilario, M. R. A., Pabroa, P. C., Yee, J. R., Simpas, J. B., and Sorooshian, A.: Sources and characteristics of size-resolved particulate organic acids and methanesulfonate in a coastal megacity: Manila, Philippines, Atmos. Chem. Phys., 20, 15907–15935, https://doi.org/10.5194/acp-20-15907-2020, 2020.
Veres, P. R., Roberts, J. M., Cochran, A. K., Gilman, J. B., Kuster, W. C.,
Holloway, J. S., Graus, M., Flynn, J., Lefer, B., Warneke, C., and de Gouw,
J.: Evidence of rapid production of organic acids in an urban air mass,
Geophys. Res. Lett., 38, 5, https://doi.org/10.1029/2011gl048420, 2011.
Wang, H., Zhao, X., Zuo, C., Ma, X., Xu, F., Sun, Y., and Zhang, Q.: A
molecular understanding of the interaction of typical aromatic acids with
common aerosol nucleation precursors and their atmospheric implications, RSC
Adv., 9, 36171–36181, https://doi.org/10.1039/c9ra07398a, 2019.
Wen, H., Huang, T., Wang, C.-Y., Peng, X.-Q., Jiang, S., Liu, Y.-R., and
Huang, W.: A study on the microscopic mechanism of methanesulfonic
acid-promoted binary nucleation of sulfuric acid and water, Atmos. Environ.,
191, 214–226, https://doi.org/10.1016/j.atmosenv.2018.07.050, 2018.
Xie, H.-B., Elm, J., Halonen, R., Myllys, N., Kurten, T., Kulmala, M., and
Vehkamaki, H.: Atmospheric fate of monoethanolamine: enhancing new particle
formation of sulfuric acid as an important removal process, Environ. Sci.
Technol., 51, 8422–8431, https://doi.org/10.1021/acs.est.7b02294, 2017.
Xu, C. X., Jiang, S., Liu, Y. R., Feng, Y. J., Wang, Z. H., Huang, T., Zhao,
Y., Li, J., and Huang, W.: Formation of atmospheric molecular clusters of
methanesulfonic acid-diethylamine complex and its atmospheric significance,
Atmos. Environ., 226, 9, https://doi.org/10.1016/j.atmosenv.2020.117404,
2020.
Xu, J., Finlayson-Pitts, B. J., and Gerber, R. B.: Proton transfer in mixed
clusters of methanesulfonic acid, methylamine, and oxalic acid: implications
for atmospheric particle formation, J. Phys. Chem. A, 121, 2377–2385,
https://doi.org/10.1021/acs.jpca.7b01223, 2017.
Yao, L., Garmash, O., Bianchi, F., Zheng, J., Yan, C., Kontkanen, J.,
Junninen, H., Mazon, S. B., Ehn, M., Paasonen, P., Sipila, M., Wang, M.,
Wang, X., Xiao, S., Chen, H., Lu, Y., Zhang, B., Wang, D., Fu, Q., Geng, F.,
Li, L., Wang, H., Qiao, L., Yang, X., Chen, J., Kerminen, V.-M., Petaja, T.,
Worsnop, D. R., Kulmala, M., and Wang, L.: Atmospheric new particle
formation from sulfuric acid and amines in a Chinese megacity, Science, 361,
278–281, https://doi.org/10.1126/science.aao4839, 2018.
Yin, R., Yan, C., Cai, R., Li, X., Shen, J., Lu, Y., Schobesberger, S., Fu,
Y., Deng, C., Wang, L., Liu, Y., Zheng, J., Xie, H., Bianchi, F., Worsnop,
D. R., Kulmala, M., and Jiang, J.: Acid-Base Clusters during Atmospheric New
Particle Formation in Urban Beijing, Environ. Sci. Technol., 55,
10994–11005, https://doi.org/10.1021/acs.est.1c02701, 2021.
Zhang, H., Kupiainen-Maatta, O., Zhang, X., Molinero, V., Zhang, Y., and Li,
Z.: The enhancement mechanism of glycolic acid on the formation of
atmospheric sulfuric acid-ammonia molecular clusters, J. Chem. Phys., 146, 184308, https://doi.org/10.1063/1.4982929, 2017.
Zhang, H., Li, H., Liu, L., Zhang, Y., Zhang, X., and Li, Z.: The potential
role of malonic acid in the atmospheric sulfuric acid – Ammonia clusters
formation, Chemosphere, 203, 26–33,
https://doi.org/10.1016/j.chemosphere.2018.03.154, 2018.
Zhang, R., Suh, I., Zhao, J., Zhang, D., Fortner, E. C., Tie, X. X.,
Molina, L. T., and Molina, M. J.: Atmospheric new particle formation
enhanced by organic acids, Science, 304, 1487–1490,
https://doi.org/10.1126/science.1095139, 2004.
Zhang, R., Khalizov, A., Wang, L., Hu, M., and Xu, W.: Nucleation and growth
of nanoparticles in the atmosphere, Chem. Rev., 112, 1957–2011,
https://doi.org/10.1021/cr2001756, 2012.
Zhang, R., Wang, G., Guo, S., Zarnora, M. L., Ying, Q., Lin, Y., Wang, W.,
Hu, M., and Wang, Y.: Formation of Urban Fine Particulate Matter, Chem.
Rev., 115, 3803–3855, https://doi.org/10.1021/acs.chemrev.5b00067, 2015.
Zhao, H., Jiang, X., and Du, L.: Contribution of methane sulfonic acid to
new particle formation in the atmosphere, Chemosphere, 174, 689–699,
https://doi.org/10.1016/j.chemosphere.2017.02.040, 2017.
Zuo, C., Zhao, X., Wang, H., Ma, X., Zheng, S., Xu, F., and Zhang, Q.: A
theoretical study of hydrogen-bonded molecular clusters of sulfuric acid and
organic acids with amides, J. Environ. Sci., 100, 328–339,
https://doi.org/10.1016/j.jes.2020.07.022, 2021.
Short summary
Formic acid is screened out as the species that can effectively catalyze the new particle formation (NPF) of the methanesulfonic acid (MSA)–methylamine system, indicating organic acids might be required to facilitate MSA-driven NPF in the atmosphere. The results are significant to comprehensively understand the MSA-driven NPF and expand current knowledge of the contribution of OAs to NPF.
Formic acid is screened out as the species that can effectively catalyze the new particle...
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