Articles | Volume 21, issue 9
https://doi.org/10.5194/acp-21-6755-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-6755-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Aerosols from anthropogenic and biogenic sources and their interactions – modeling aerosol formation, optical properties, and impacts over the central Amazon basin
Janaína P. Nascimento
CORRESPONDING AUTHOR
Postgraduate Program in Climate and Environment (CLIAMB), National Institute for Amazonian Research and Amazonas State University, Manaus, AM, Brazil
Megan M. Bela
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
Bruno B. Meller
Institute of Physics, University of São Paulo, São Paulo, SP, Brazil
Alessandro L. Banducci
Department of Physics, Colorado State University, Fort Collins, CO, USA
Luciana V. Rizzo
Department of Environmental Sciences, Institute of Environmental, Chemical and Pharmaceutical Sciences, Federal University of São Paulo, São Paulo, SP, Brazil
Angel Liduvino Vara-Vela
Center for Weather Forecasting and Climate Studies, National Institute for Space Research, Cachoeira Paulista, São Paulo, SP, Brazil
Henrique M. J. Barbosa
Institute of Physics, University of São Paulo, São Paulo, SP, Brazil
Helber Gomes
Institute of Atmospheric Sciences, Federal University of Alagoas, Maceió, AL, Brazil
Department of Meteorology, Federal University of Campina Grande, Campina Grande, PB, Brazil
Sameh A. A. Rafee
Department of Atmospheric Sciences, Institute of Astronomy, Geophysics and Atmospheric Sciences, University of São Paulo, São Paulo, SP, Brazil
Marco A. Franco
Institute of Physics, University of São Paulo, São Paulo, SP, Brazil
Samara Carbone
Agrarian Sciences Institute, Federal University of Uberlândia, Uberlândia, MG, Brazil
Institute of Physics, University of São Paulo, São Paulo, SP, Brazil
Glauber G. Cirino
Department of Meteorology, Geosciences Institute, Federal University of Pará, Pará, PA, Brazil
Rodrigo A. F. Souza
Postgraduate Program in Climate and Environment (CLIAMB), National Institute for Amazonian Research and Amazonas State University, Manaus, AM, Brazil
Stuart A. McKeen
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
NOAA Earth System Research Laboratory, Boulder, CO, USA
Paulo Artaxo
Institute of Physics, University of São Paulo, São Paulo, SP, Brazil
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Composite analysis of gas concentration before and after rainfall, during the day and night, gives insight into the complex relationship between trace gas variability and precipitation. The analysis helps us to understand the sources and sinks of trace gases within a forest ecosystem. It elucidates processes that are not discernible under undisturbed conditions and contributes to a deeper understanding of the trace gas life cycle and its intricate interactions with cloud dynamics in the Amazon.
Marco A. Franco, Rafael Valiati, Bruna A. Holanda, Bruno B. Meller, Leslie A. Kremper, Luciana V. Rizzo, Samara Carbone, Fernando G. Morais, Janaína P. Nascimento, Meinrat O. Andreae, Micael A. Cecchini, Luiz A. T. Machado, Milena Ponczek, Ulrich Pöschl, David Walter, Christopher Pöhlker, and Paulo Artaxo
Atmos. Chem. Phys., 24, 8751–8770, https://doi.org/10.5194/acp-24-8751-2024, https://doi.org/10.5194/acp-24-8751-2024, 2024
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The Amazon wet-season atmosphere was studied at the Amazon Tall Tower Observatory site, revealing vertical variations (between 60 and 325 m) in natural aerosols. Daytime mixing contrasted with nighttime stratification, with distinct rain-induced changes in aerosol populations. Notably, optical property recovery at higher levels was faster, while near-canopy aerosols showed higher scattering efficiency. These findings enhance our understanding of aerosol impacts on climate dynamics.
Leandro Alex Moreira Viscardi, Giuseppe Torri, David K. Adams, and Henrique de Melo Jorge Barbosa
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We evaluate the environmental conditions that control how clouds grow from fair weather cumulus into severe thunderstorms during the Amazonian wet season. Days with rain clouds begin with more moisture in the air and have strong convergence in the afternoon, while precipitation intensity increases with large-scale vertical velocity, moisture, and low-level wind. These results contribute to understanding how clouds form over the rainforest.
Gabriela R. Unfer, Luiz A. T. Machado, Paulo Artaxo, Marco A. Franco, Leslie A. Kremper, Mira L. Pöhlker, Ulrich Pöschl, and Christopher Pöhlker
Atmos. Chem. Phys., 24, 3869–3882, https://doi.org/10.5194/acp-24-3869-2024, https://doi.org/10.5194/acp-24-3869-2024, 2024
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Simone Rodrigues, Glauber Cirino, Demerval Moreira, Andrea Pozzer, Rafael Palácios, Sung-Ching Lee, Breno Imbiriba, José Nogueira, Maria Isabel Vitorino, and George Vourlitis
Biogeosciences, 21, 843–868, https://doi.org/10.5194/bg-21-843-2024, https://doi.org/10.5194/bg-21-843-2024, 2024
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The radiative effects of atmospheric particles are still unknown for a wide variety of species and types of vegetation present in Amazonian biomes. We examined the effects of aerosols on solar radiation and their impacts on photosynthesis in an area of semideciduous forest in the southern Amazon Basin. Under highly smoky-sky conditions, our results show substantial photosynthetic interruption (20–70 %), attributed specifically to the decrease in solar radiation and leaf canopy temperature.
Natalie M. Mahowald, Longlei Li, Julius Vira, Marje Prank, Douglas S. Hamilton, Hitoshi Matsui, Ron L. Miller, Louis Lu, Ezgi Akyuz, Daphne Meidan, Peter Hess, Heikki Lihavainen, Christine Wiedinmyer, Jenny Hand, Maria Grazia Alaimo, Célia Alves, Andres Alastuey, Paulo Artaxo, Africa Barreto, Francisco Barraza, Silvia Becagli, Giulia Calzolai, Shankarararman Chellam, Ying Chen, Patrick Chuang, David D. Cohen, Cristina Colombi, Evangelia Diapouli, Gaetano Dongarra, Konstantinos Eleftheriadis, Corinne Galy-Lacaux, Cassandra Gaston, Dario Gomez, Yenny González Ramos, Hannele Hakola, Roy M. Harrison, Chris Heyes, Barak Herut, Philip Hopke, Christoph Hüglin, Maria Kanakidou, Zsofia Kertesz, Zbiginiw Klimont, Katriina Kyllönen, Fabrice Lambert, Xiaohong Liu, Remi Losno, Franco Lucarelli, Willy Maenhaut, Beatrice Marticorena, Randall V. Martin, Nikolaos Mihalopoulos, Yasser Morera-Gomez, Adina Paytan, Joseph Prospero, Sergio Rodríguez, Patricia Smichowski, Daniela Varrica, Brenna Walsh, Crystal Weagle, and Xi Zhao
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-1, https://doi.org/10.5194/essd-2024-1, 2024
Preprint withdrawn
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Aerosol particles can interact with incoming solar radiation and outgoing long wave radiation, change cloud properties, affect photochemistry, impact surface air quality, and when deposited impact surface albedo of snow and ice, and modulate carbon dioxide uptake by the land and ocean. Here we present a new compilation of aerosol observations including composition, a methodology for comparing the datasets to model output, and show the implications of these results using one model.
Xurong Wang, Qiaoqiao Wang, Maria Prass, Christopher Pöhlker, Daniel Moran-Zuloaga, Paulo Artaxo, Jianwei Gu, Ning Yang, Xiajie Yang, Jiangchuan Tao, Juan Hong, Nan Ma, Yafang Cheng, Hang Su, and Meinrat O. Andreae
Atmos. Chem. Phys., 23, 9993–10014, https://doi.org/10.5194/acp-23-9993-2023, https://doi.org/10.5194/acp-23-9993-2023, 2023
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In this work, with an optimized particle mass size distribution, we captured observed aerosol optical depth (AOD) and coarse aerosol concentrations over source and/or receptor regions well, demonstrating good performance in simulating export of African dust toward the Amazon Basin. In addition to factors controlling the transatlantic transport of African dust, the study investigated the impact of African dust over the Amazon Basin, including the nutrient inputs associated with dust deposition.
Juan Vicente Pallotta, Silvânia Alves de Carvalho, Fabio Juliano da Silva Lopes, Alexandre Cacheffo, Eduardo Landulfo, and Henrique Melo Jorge Barbosa
Geosci. Instrum. Method. Data Syst., 12, 171–185, https://doi.org/10.5194/gi-12-171-2023, https://doi.org/10.5194/gi-12-171-2023, 2023
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Lidar networks coordinate efforts of different groups, providing guidelines to homogenize retrievals from different instruments. We describe an ongoing effort to develop the Lidar Processing Pipeline (LPP) collaboratively, a collection of tools developed in C/C++ to handle all the steps of a typical lidar analysis. Analysis of simulations and real lidar data showcases the LPP’s features. From this exercise, we draw a roadmap to guide future development, accommodating the needs of our community.
Eliane Gomes Alves, Raoni Aquino Santana, Cléo Quaresma Dias-Júnior, Santiago Botía, Tyeen Taylor, Ana Maria Yáñez-Serrano, Jürgen Kesselmeier, Efstratios Bourtsoukidis, Jonathan Williams, Pedro Ivo Lembo Silveira de Assis, Giordane Martins, Rodrigo de Souza, Sérgio Duvoisin Júnior, Alex Guenther, Dasa Gu, Anywhere Tsokankunku, Matthias Sörgel, Bruce Nelson, Davieliton Pinto, Shujiro Komiya, Diogo Martins Rosa, Bettina Weber, Cybelli Barbosa, Michelle Robin, Kenneth J. Feeley, Alvaro Duque, Viviana Londoño Lemos, Maria Paula Contreras, Alvaro Idarraga, Norberto López, Chad Husby, Brett Jestrow, and Iván Mauricio Cely Toro
Atmos. Chem. Phys., 23, 8149–8168, https://doi.org/10.5194/acp-23-8149-2023, https://doi.org/10.5194/acp-23-8149-2023, 2023
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Isoprene is emitted mainly by plants and can influence atmospheric chemistry and air quality. But, there are uncertainties in model emission estimates and follow-up atmospheric processes. In our study, with long-term observational datasets of isoprene and biological and environmental factors from central Amazonia, we show that isoprene emission estimates could be improved when biological processes were mechanistically incorporated into the model.
Qiaozhi Zha, Wei Huang, Diego Aliaga, Otso Peräkylä, Liine Heikkinen, Alkuin Maximilian Koenig, Cheng Wu, Joonas Enroth, Yvette Gramlich, Jing Cai, Samara Carbone, Armin Hansel, Tuukka Petäjä, Markku Kulmala, Douglas Worsnop, Victoria Sinclair, Radovan Krejci, Marcos Andrade, Claudia Mohr, and Federico Bianchi
Atmos. Chem. Phys., 23, 4559–4576, https://doi.org/10.5194/acp-23-4559-2023, https://doi.org/10.5194/acp-23-4559-2023, 2023
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We investigate the chemical composition of atmospheric cluster ions from January to May 2018 at the high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes. With state-of-the-art mass spectrometers and air mass history analysis, the measured cluster ions exhibited distinct diurnal and seasonal patterns, some of which contributed to new particle formation. Our study will improve the understanding of atmospheric ions and their role in high-altitude new particle formation.
Elion Daniel Hack, Theotonio Pauliquevis, Henrique Melo Jorge Barbosa, Marcia Akemi Yamasoe, Dimitri Klebe, and Alexandre Lima Correia
Atmos. Meas. Tech., 16, 1263–1278, https://doi.org/10.5194/amt-16-1263-2023, https://doi.org/10.5194/amt-16-1263-2023, 2023
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Water vapor is a key factor when seeking to understand fast-changing processes when clouds and storms form and develop. We show here how images from a calibrated infrared camera can be used to derive how much water vapor there is in the atmosphere at a given time. Comparing our results to an established technique, for a case of stable atmospheric conditions, we found an agreement within 2.8 %. Water vapor sky maps can be retrieved every few minutes, day or night, under partly cloudy skies.
Wiebke Scholz, Jiali Shen, Diego Aliaga, Cheng Wu, Samara Carbone, Isabel Moreno, Qiaozhi Zha, Wei Huang, Liine Heikkinen, Jean Luc Jaffrezo, Gaelle Uzu, Eva Partoll, Markus Leiminger, Fernando Velarde, Paolo Laj, Patrick Ginot, Paolo Artaxo, Alfred Wiedensohler, Markku Kulmala, Claudia Mohr, Marcos Andrade, Victoria Sinclair, Federico Bianchi, and Armin Hansel
Atmos. Chem. Phys., 23, 895–920, https://doi.org/10.5194/acp-23-895-2023, https://doi.org/10.5194/acp-23-895-2023, 2023
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Dimethyl sulfide (DMS), emitted from the ocean, is the most abundant biogenic sulfur emission into the atmosphere. OH radicals, among others, can oxidize DMS to sulfuric and methanesulfonic acid, which are relevant for aerosol formation. We quantified DMS and nearly all DMS oxidation products with novel mass spectrometric instruments for gas and particle phase at the high mountain station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes in free tropospheric air after long-range transport.
Yunfan Liu, Hang Su, Siwen Wang, Chao Wei, Wei Tao, Mira L. Pöhlker, Christopher Pöhlker, Bruna A. Holanda, Ovid O. Krüger, Thorsten Hoffmann, Manfred Wendisch, Paulo Artaxo, Ulrich Pöschl, Meinrat O. Andreae, and Yafang Cheng
Atmos. Chem. Phys., 23, 251–272, https://doi.org/10.5194/acp-23-251-2023, https://doi.org/10.5194/acp-23-251-2023, 2023
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The origins of the abundant cloud condensation nuclei (CCN) in the upper troposphere (UT) of the Amazon remain unclear. With model developments of new secondary organic aerosol schemes and constrained by observation, we show that strong aerosol nucleation and condensation in the UT is triggered by biogenic organics, and organic condensation is key for UT CCN production. This UT CCN-producing mechanism may prevail over broader vegetation canopies and deserves emphasis in aerosol–climate feedback.
Micael Amore Cecchini, Marco de Bruine, Jordi Vilà-Guerau de Arellano, and Paulo Artaxo
Atmos. Chem. Phys., 22, 11867–11888, https://doi.org/10.5194/acp-22-11867-2022, https://doi.org/10.5194/acp-22-11867-2022, 2022
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Shallow clouds (vertical extent up to 3 km height) are ubiquitous throughout the Amazon and are responsible for redistributing the solar heat and moisture vertically and horizontally. They are a key component of the water cycle because they can grow past the shallow phase to contribute significantly to the precipitation formation. However, they need favourable environmental conditions to grow. In this study, we analyse how changing wind patterns affect the development of such shallow clouds.
Deanna C. Myers, Saewung Kim, Steven Sjostedt, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 22, 10061–10076, https://doi.org/10.5194/acp-22-10061-2022, https://doi.org/10.5194/acp-22-10061-2022, 2022
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We present the first measurements of gas-phase sulfuric acid from the Amazon basin and evaluate the efficacy of existing sulfuric acid parameterizations in this understudied region. Sulfuric acid is produced during the daytime and nighttime, though current proxies underestimate nighttime production. These results illustrate the need for better parameterizations of sulfuric acid and its precursors that are informed by measurements across a broad range of locations.
Li Zhang, Raffaele Montuoro, Stuart A. McKeen, Barry Baker, Partha S. Bhattacharjee, Georg A. Grell, Judy Henderson, Li Pan, Gregory J. Frost, Jeff McQueen, Rick Saylor, Haiqin Li, Ravan Ahmadov, Jun Wang, Ivanka Stajner, Shobha Kondragunta, Xiaoyang Zhang, and Fangjun Li
Geosci. Model Dev., 15, 5337–5369, https://doi.org/10.5194/gmd-15-5337-2022, https://doi.org/10.5194/gmd-15-5337-2022, 2022
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The NOAA’s air quality predictions contribute to protecting lives and health in the US, which requires sustainable development and improvement of forecast systems. GEFS-Aerosols v1 has been developed in a collaboration between the NOAA research laboratories for operational forecast since September 2020 in the NCEP. The predictions demonstrate substantial improvements for both composition and variability of aerosol distributions over those from the former operational system.
Marco A. Franco, Florian Ditas, Leslie A. Kremper, Luiz A. T. Machado, Meinrat O. Andreae, Alessandro Araújo, Henrique M. J. Barbosa, Joel F. de Brito, Samara Carbone, Bruna A. Holanda, Fernando G. Morais, Janaína P. Nascimento, Mira L. Pöhlker, Luciana V. Rizzo, Marta Sá, Jorge Saturno, David Walter, Stefan Wolff, Ulrich Pöschl, Paulo Artaxo, and Christopher Pöhlker
Atmos. Chem. Phys., 22, 3469–3492, https://doi.org/10.5194/acp-22-3469-2022, https://doi.org/10.5194/acp-22-3469-2022, 2022
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In Central Amazonia, new particle formation in the planetary boundary layer is rare. Instead, there is the appearance of sub-50 nm aerosols with diameters larger than about 20 nm that eventually grow to cloud condensation nuclei size range. Here, 254 growth events were characterized which have higher predominance in the wet season. About 70 % of them showed direct relation to convective downdrafts, while 30 % occurred partly under clear-sky conditions, evidencing still unknown particle sources.
Li Zhang, Georg A. Grell, Stuart A. McKeen, Ravan Ahmadov, Karl D. Froyd, and Daniel Murphy
Geosci. Model Dev., 15, 467–491, https://doi.org/10.5194/gmd-15-467-2022, https://doi.org/10.5194/gmd-15-467-2022, 2022
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Applying the chemistry package from WRF-Chem into the Flow-following finite-volume Icosahedra Model, we essentially make it possible to explore the importance of different levels of complexity in gas and aerosol chemistry, as well as in physics parameterizations, for the interaction processes in global modeling systems. The model performance validated by the Atmospheric Tomography Mission aircraft measurements in summer 2016 shows good performance in capturing the aerosol and gas-phase tracers.
Luiz A. T. Machado, Marco A. Franco, Leslie A. Kremper, Florian Ditas, Meinrat O. Andreae, Paulo Artaxo, Micael A. Cecchini, Bruna A. Holanda, Mira L. Pöhlker, Ivan Saraiva, Stefan Wolff, Ulrich Pöschl, and Christopher Pöhlker
Atmos. Chem. Phys., 21, 18065–18086, https://doi.org/10.5194/acp-21-18065-2021, https://doi.org/10.5194/acp-21-18065-2021, 2021
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Several studies evaluate aerosol–cloud interactions, but only a few attempted to describe how clouds modify aerosol properties. This study evaluates the effect of weather events on the particle size distribution at the ATTO, combining remote sensing and in situ data. Ultrafine, Aitken and accumulation particles modes have different behaviors for the diurnal cycle and for rainfall events. This study opens up new scientific questions that need to be pursued in detail in new field campaigns.
Diego Aliaga, Victoria A. Sinclair, Marcos Andrade, Paulo Artaxo, Samara Carbone, Evgeny Kadantsev, Paolo Laj, Alfred Wiedensohler, Radovan Krejci, and Federico Bianchi
Atmos. Chem. Phys., 21, 16453–16477, https://doi.org/10.5194/acp-21-16453-2021, https://doi.org/10.5194/acp-21-16453-2021, 2021
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We investigate the origin of air masses sampled at Mount Chacaltaya, Bolivia. Three-quarters of the measured air has not been influenced by the surface in the previous 4 d. However, it is rare that, at any given time, the sampled air has not been influenced at all by the surface, and often the sampled air has multiple origins. The influence of the surface is more prevalent during day than night. Furthermore, during the 6-month study, one-third of the air masses originated from Amazonia.
Maria Prass, Meinrat O. Andreae, Alessandro C. de Araùjo, Paulo Artaxo, Florian Ditas, Wolfgang Elbert, Jan-David Förster, Marco Aurélio Franco, Isabella Hrabe de Angelis, Jürgen Kesselmeier, Thomas Klimach, Leslie Ann Kremper, Eckhard Thines, David Walter, Jens Weber, Bettina Weber, Bernhard M. Fuchs, Ulrich Pöschl, and Christopher Pöhlker
Biogeosciences, 18, 4873–4887, https://doi.org/10.5194/bg-18-4873-2021, https://doi.org/10.5194/bg-18-4873-2021, 2021
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Bioaerosols in the atmosphere over the Amazon rain forest were analyzed by molecular biological staining and microscopy. Eukaryotic, bacterial, and archaeal aerosols were quantified in time series and altitude profiles which exhibited clear differences in number concentrations and vertical distributions. Our results provide insights into the sources and dispersion of different Amazonian bioaerosol types as a basis for a better understanding of biosphere–atmosphere interactions.
James Weber, Scott Archer-Nicholls, Nathan Luke Abraham, Youngsub M. Shin, Thomas J. Bannan, Carl J. Percival, Asan Bacak, Paulo Artaxo, Michael Jenkin, M. Anwar H. Khan, Dudley E. Shallcross, Rebecca H. Schwantes, Jonathan Williams, and Alex T. Archibald
Geosci. Model Dev., 14, 5239–5268, https://doi.org/10.5194/gmd-14-5239-2021, https://doi.org/10.5194/gmd-14-5239-2021, 2021
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The new mechanism CRI-Strat 2 features state-of-the-art isoprene chemistry not previously available in UKCA and improves UKCA's ability to reproduce observed concentrations of isoprene, monoterpenes, and OH in tropical regions. The enhanced ability to model isoprene, the most widely emitted non-methane volatile organic compound (VOC), will allow understanding of how isoprene and other biogenic VOCs affect atmospheric composition and, through biosphere–atmosphere feedbacks, climate change.
Djacinto Monteiro dos Santos, Luciana Varanda Rizzo, Samara Carbone, Patrick Schlag, and Paulo Artaxo
Atmos. Chem. Phys., 21, 8761–8773, https://doi.org/10.5194/acp-21-8761-2021, https://doi.org/10.5194/acp-21-8761-2021, 2021
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The metropolitan area of São Paulo (MASP), with very extensive biofuel use, has unique atmospheric chemistry among world megacities. In this study, we examine the complex relationships between aerosol chemical composition and particle size distribution. Our findings provide a better understanding of the dynamics of the physicochemical properties of submicron particles and highlight the key role of secondary organic aerosol formation in the pollution levels in São Paulo.
Robbie Ramsay, Chiara F. Di Marco, Mathew R. Heal, Matthias Sörgel, Paulo Artaxo, Meinrat O. Andreae, and Eiko Nemitz
Biogeosciences, 18, 2809–2825, https://doi.org/10.5194/bg-18-2809-2021, https://doi.org/10.5194/bg-18-2809-2021, 2021
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The exchange of the gas ammonia between the atmosphere and the surface is an important biogeochemical process, but little is known of this exchange for certain ecosystems, such as the Amazon rainforest. This study took measurements of ammonia exchange over an Amazon rainforest site and subsequently modelled the observed deposition and emission patterns. We observed emissions of ammonia from the rainforest, which can be simulated accurately by using a canopy resistance modelling approach.
Guilherme F. Camarinha-Neto, Julia C. P. Cohen, Cléo Q. Dias-Júnior, Matthias Sörgel, José Henrique Cattanio, Alessandro Araújo, Stefan Wolff, Paulo A. F. Kuhn, Rodrigo A. F. Souza, Luciana V. Rizzo, and Paulo Artaxo
Atmos. Chem. Phys., 21, 339–356, https://doi.org/10.5194/acp-21-339-2021, https://doi.org/10.5194/acp-21-339-2021, 2021
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It was observed that friagem phenomena (incursion of cold waves from the high latitudes of the Southern Hemisphere to the Amazon region), very common in the dry season of the Amazon region, produced significant changes in microclimate and atmospheric chemistry. Moreover, the effects of the friagem change the surface O3 and CO2 mixing ratios and therefore interfere deeply in the microclimatic conditions and the chemical composition of the atmosphere above the rainforest.
Jann Schrod, Erik S. Thomson, Daniel Weber, Jens Kossmann, Christopher Pöhlker, Jorge Saturno, Florian Ditas, Paulo Artaxo, Valérie Clouard, Jean-Marie Saurel, Martin Ebert, Joachim Curtius, and Heinz G. Bingemer
Atmos. Chem. Phys., 20, 15983–16006, https://doi.org/10.5194/acp-20-15983-2020, https://doi.org/10.5194/acp-20-15983-2020, 2020
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Long-term ice-nucleating particle (INP) data are presented from four semi-pristine sites located in the Amazon, the Caribbean, Germany and the Arctic. Average INP concentrations did not differ by orders of magnitude between the sites. For all sites short-term variability dominated the time series, which lacked clear trends and seasonalities. Common drivers to explain the INP levels and their variations could not be identified, illustrating the complex nature of heterogeneous ice nucleation.
Robbie Ramsay, Chiara F. Di Marco, Matthias Sörgel, Mathew R. Heal, Samara Carbone, Paulo Artaxo, Alessandro C. de Araùjo, Marta Sá, Christopher Pöhlker, Jost Lavric, Meinrat O. Andreae, and Eiko Nemitz
Atmos. Chem. Phys., 20, 15551–15584, https://doi.org/10.5194/acp-20-15551-2020, https://doi.org/10.5194/acp-20-15551-2020, 2020
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The Amazon rainforest is a unique
laboratoryto study the processes which govern the exchange of gases and aerosols to and from the atmosphere. This study investigated these processes by measuring the atmospheric concentrations of trace gases and particles at the Amazon Tall Tower Observatory. We found that the long-range transport of pollutants can affect the atmospheric composition above the Amazon rainforest and that the gases ammonia and nitrous acid can be emitted from the rainforest.
Lixia Liu, Yafang Cheng, Siwen Wang, Chao Wei, Mira L. Pöhlker, Christopher Pöhlker, Paulo Artaxo, Manish Shrivastava, Meinrat O. Andreae, Ulrich Pöschl, and Hang Su
Atmos. Chem. Phys., 20, 13283–13301, https://doi.org/10.5194/acp-20-13283-2020, https://doi.org/10.5194/acp-20-13283-2020, 2020
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This modeling paper reveals how aerosol–cloud interactions (ACIs) and aerosol–radiation interactions (ARIs) induced by biomass burning (BB) aerosols act oppositely on radiation, cloud, and precipitation in the Amazon during the dry season. The varying relative significance of ACIs and ARIs with BB aerosol concentration leads to a nonlinear dependence of the total climate response on BB aerosol loading and features the growing importance of ARIs at high aerosol loading.
Kouji Adachi, Naga Oshima, Zhaoheng Gong, Suzane de Sá, Adam P. Bateman, Scot T. Martin, Joel F. de Brito, Paulo Artaxo, Glauber G. Cirino, Arthur J. Sedlacek III, and Peter R. Buseck
Atmos. Chem. Phys., 20, 11923–11939, https://doi.org/10.5194/acp-20-11923-2020, https://doi.org/10.5194/acp-20-11923-2020, 2020
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Occurrences, size distributions, and number fractions of individual aerosol particles from the Amazon basin during the GoAmazon2014/5 campaign were analyzed using transmission electron microscopy. Aerosol particles from natural sources (e.g., mineral dust, primary biological aerosols, and sea salts) during the wet season originated from the Amazon forest and long-range transports (the Saharan desert and the Atlantic Ocean). They commonly mix at an individual particle scale during transport.
Anin Puthukkudy, J. Vanderlei Martins, Lorraine A. Remer, Xiaoguang Xu, Oleg Dubovik, Pavel Litvinov, Brent McBride, Sharon Burton, and Henrique M. J. Barbosa
Atmos. Meas. Tech., 13, 5207–5236, https://doi.org/10.5194/amt-13-5207-2020, https://doi.org/10.5194/amt-13-5207-2020, 2020
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In this work, we report the demonstration and validation of the aerosol properties retrieved using AirHARP and GRASP for data from the NASA ACEPOL campaign 2017. These results serve as a proxy for the scale and detail of aerosol retrievals that are anticipated from future space mission data, as HARP CubeSat (mission begins 2020) and HARP2 (aboard the NASA PACE mission with the launch in 2023) are near duplicates of AirHARP and are expected to provide the same level of aerosol characterization.
Kirk Knobelspiesse, Henrique M. J. Barbosa, Christine Bradley, Carol Bruegge, Brian Cairns, Gao Chen, Jacek Chowdhary, Anthony Cook, Antonio Di Noia, Bastiaan van Diedenhoven, David J. Diner, Richard Ferrare, Guangliang Fu, Meng Gao, Michael Garay, Johnathan Hair, David Harper, Gerard van Harten, Otto Hasekamp, Mark Helmlinger, Chris Hostetler, Olga Kalashnikova, Andrew Kupchock, Karla Longo De Freitas, Hal Maring, J. Vanderlei Martins, Brent McBride, Matthew McGill, Ken Norlin, Anin Puthukkudy, Brian Rheingans, Jeroen Rietjens, Felix C. Seidel, Arlindo da Silva, Martijn Smit, Snorre Stamnes, Qian Tan, Sebastian Val, Andrzej Wasilewski, Feng Xu, Xiaoguang Xu, and John Yorks
Earth Syst. Sci. Data, 12, 2183–2208, https://doi.org/10.5194/essd-12-2183-2020, https://doi.org/10.5194/essd-12-2183-2020, 2020
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The Aerosol Characterization from Polarimeter and Lidar (ACEPOL) field campaign is a resource for the next generation of spaceborne multi-angle polarimeter (MAP) and lidar missions. Conducted in the fall of 2017 from the Armstrong Flight Research Center in Palmdale, California, four MAP instruments and two lidars were flown on the high-altitude ER-2 aircraft over a variety of scene types and ground assets. Data are freely available to the public and useful for algorithm development and testing.
Cited articles
Abdul-Razzak, H. and Ghan, S. J.: A parameterization of aerosol activation: 2. multiple aerosol types, J. Geophys. Res., 105, 6837–6844,
https://doi.org/10.1029/1999JD901161, 2000. a
Abou Rafee, S. A., Martins, L. D., Kawashima, A. B., Almeida, D. S., Morais, M. V. B., Souza, R. V. A., Oliveira, M. B. L., Souza, R. A. F., Medeiros, A. S. S., Urbina, V., Freitas, E. D., Martin, S. T., and Martins, J. A.: Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model, Atmos. Chem. Phys., 17, 7977–7995, https://doi.org/10.5194/acp-17-7977-2017, 2017. a, b, c, d, e, f, g
Ahmadov, R., McKeen, S., Robinson, A., Bahreini, R., Middlebrook, A., De Gouw, J., Meagher, J., Hsie, E.-Y., Edgerton, Shaw, S., and Trainer, M.: A
volatility basis set model for summertime secondary organic aerosols over the
eastern United States in 2006, J. Geophys. Res., 117, D06301,
https://doi.org/10.1029/2011JD016831, 2012. a, b, c, d
Albuquerque, T. T. A., Andrade, M. F., and Ynoue, R. Y.: Characterization of
atmospheric aerosols in the city of São Paulo, Brazil: comparisons
between polluted and unpolluted periods, Environ. Monit. Assess., 184,
969–984, 2012. a
Alves, E. G., Jardine, K., Tota, J., Jardine, A., Yãnez-Serrano, A. M., Karl, T., Tavares, J., Nelson, B., Gu, D., Stavrakou, T., Martin, S., Artaxo, P., Manzi, A., and Guenther, A.: Seasonality of isoprenoid emissions from a primary rainforest in central Amazonia, Atmos. Chem. Phys., 16, 3903–3925, https://doi.org/10.5194/acp-16-3903-2016, 2016. a
Alves, E. G., Tóta, J., Turnipseed, A., Guenther, A. B., Vega Bustillos, J. O. W., Santana, R. A., Cirino, G. G., Tavares, J. V., Lopes, A. P., Nelson, B. W., de Souza, R. A., Gu, D., Stavrakou, T., Adams, D. K., Wu, J., Saleska, S., and Manzi, A. O.: Leaf phenology as one important driver of seasonal changes in isoprene emissions in central Amazonia, Biogeosciences, 15, 4019–4032, https://doi.org/10.5194/bg-15-4019-2018, 2018. a
Andreae, M. O., Artaxo, P., Beck, V., Bela, M., Freitas, S., Gerbig, C., Longo, K., Munger, J. W., Wiedemann, K. T., and Wofsy, S. C.: Carbon monoxide and related trace gases and aerosols over the Amazon Basin during the wet and dry seasons, Atmos. Chem. Phys., 12, 6041–6065, https://doi.org/10.5194/acp-12-6041-2012, 2012. a
Andreae, M. O., Acevedo, O. C., Araùjo, A., Artaxo, P., Barbosa, C. G. G., Barbosa, H. M. J., Brito, J., Carbone, S., Chi, X., Cintra, B. B. L., da Silva, N. F., Dias, N. L., Dias-Júnior, C. Q., Ditas, F., Ditz, R., Godoi, A. F. L., Godoi, R. H. M., Heimann, M., Hoffmann, T., Kesselmeier, J., Könemann, T., Krüger, M. L., Lavric, J. V., Manzi, A. O., Lopes, A. P., Martins, D. L., Mikhailov, E. F., Moran-Zuloaga, D., Nelson, B. W., Nölscher, A. C., Santos Nogueira, D., Piedade, M. T. F., Pöhlker, C., Pöschl, U., Quesada, C. A., Rizzo, L. V., Ro, C.-U., Ruckteschler, N., Sá, L. D. A., de Oliveira Sá, M., Sales, C. B., dos Santos, R. M. N., Saturno, J., Schöngart, J., Sörgel, M., de Souza, C. M., de Souza, R. A. F., Su, H., Targhetta, N., Tóta, J., Trebs, I., Trumbore, S., van Eijck, A., Walter, D., Wang, Z., Weber, B., Williams, J., Winderlich, J., Wittmann, F., Wolff, S., and Yáñez-Serrano, A. M.: The Amazon Tall Tower Observatory (ATTO): overview of pilot measurements on ecosystem ecology, meteorology, trace gases, and aerosols, Atmos. Chem. Phys., 15, 10723–10776, https://doi.org/10.5194/acp-15-10723-2015, 2015. a, b, c
ARM: Atmospheric Radiation Measurement (ARM) user facility, updated hourly. Aerosol Intensive Properties (AIP1OGREN), 2014-01-31–2014-03-31, ARM Mobile Facility (MAO) Manacapuru, Amazonas, Brazil; AMF1 (M1), compiled by Flynn, C., ARM Data Center, https://doi.org/10.5439/1027280, 2013. a
ARM: Atmospheric Radiation Measurement (ARM) user facility, updated hourly. Aethalometer (AOSAETH), 2014-01-31–2014-04-30, ARM Mobile Facility (MAO) Manacapuru, Amazonas, Brazil; MAOS (S1), compiled by: Sedlacek, A., Andrews, E., and Salwen, C., ARM Data Center, https://doi.org/10.5439/1095580, 2014. a
Artaxo, P., Maenhaut, W., Storms, H., and Van Grieken, R.: Aerosol
characteristics and sources for the Amazon Basin during the wet season, J.
Geophys. Res.-Atmos., 95, 16971–16985,
https://doi.org/10.1029/JD095iD10p16971, 1990. a
Artaxo, P., Yamasoe, M., Martins, J., Kocinas, S., Car-Vallo, S., and Maenhaut, W.: Case study of atmospheric measurements in Brazil : aerosol emissions from Amazon Basin fires, in: Environmental Sciences Research Report, edited by: Crutzen, P. J. and Goldammer, J., Wiley, 13, 139–158, 1993. a
Artaxo, P., Gerab, F., Yamasoe, M. A., and Martins, J. V.: Fine mode aerosol
composition at three long-term atmospheric monitoring sites in the Amazon
Basin, J. Geophys. Res.-Atmos., 99, 22857–22868,
https://doi.org/10.1029/94JD01023, 1994. a
Artaxo, P., Martins, J. V., Yamasoe, M. A., Procópio, A. S., Pauliquevis,
T. M., Andreae, M. O., Guyon, P., Gatti, L. V., and Leal, A. M. C.: Physical
and chemical properties of aerosols in the wet and dry seasons in
Rondônia, Amazonia, J. Geophys. Res., 107, 8081,
https://doi.org/10.1029/2001JD000666, 2002. a
Artaxo, P., Rizzo, L. V., Brito, J. F., Barbosa, H. M., Arana, A., Sena, E. T., Cirino, G. G., Bastos, W., Martin, S. T., and Andreae, M. O.: Atmospheric aerosols in Amazonia and land use change: from natural biogenic to biomass burning conditions, Faraday Discuss., 165, 203–235,
https://doi.org/10.1039/C3FD00052D, 2013. a, b, c
Artaxo, P., Hansson, H.-C., Andreae, M. O., Bäck, J., Alves, E. G., Barbosa,
H. M. J., Bender, F., Bourtsoukidis, E., Carbone, S., Chi, J., Decesari, S.,
Després, V. R., Ditas, F., Ezhova, E., Fuzzi, S., Hasselquist, N. J.,
Heintzenberg, J., Holanda, B. A., Guenther, A., Hakola, H., Heikkinen, L.,
Kerminen, V.-M., Kontkanen, J., Krejci, R., Kulmala, M., Lavric, J.,
de Leeuw, G., Lehtipalo, K., Machado, L. A. T., McFiggans, G., Franco, M.
A. M., Mohr, C., Morgan, W., Nilsson, M. B., Peichl, M., Petäjä, T., Praß,
M., Pöhlker, C., Pöhlker, M. L., Pöschl, U., Randow, C. V., Riipinen, I.,
Rinne, J., Rizzo, L. V., Rosenfeld, D., Dias, M. A. F. S., Sogacheva, L.,
Stier, P., Swietlicki, E., Sörgel, M., Tunved, P., Virkkula, A., Wang, J.,
Weber, B., Yáñez-Serrano, A. M., Zieger, P., Mikhailov, E., Smith, J., and
Kesselmeier, J.: Tropical and Boreal Forest – Atmosphere Interactions: A
Review, Tellus B, in review, 2020. a, b
Backman, J., Rizzo, L. V., Hakala, J., Nieminen, T., Manninen, H. E., Morais, F., Aalto, P. P., Siivola, E., Carbone, S., Hillamo, R., Artaxo, P., Virkkula, A., Petäjä, T., and Kulmala, M.: On the diurnal cycle of urban aerosols, black carbon and the occurrence of new particle formation events in springtime São Paulo, Brazil, Atmos. Chem. Phys., 12, 11733–11751, https://doi.org/10.5194/acp-12-11733-2012, 2012. a
Bela, M. M., Barth, M. C., Toon, O. B., Fried, A., Homeyer, C. R., Morrison,
H., Cummings, K. A., Li, Y., Pickering, K. E., Allen, D. J., Yang, Q.,
Wennberg, P. O., Crounse, J. D., St. Clair, J. M., Teng, A. P., O’Sullivan,
D., Huey, L. G., Chen, D., Liu, X., Blake, D. R., Blake, N. J., Apel, E. C.,
Hornbrook, R. S., Flocke, F., Campos, T., and Diskin, G.: Wet scavenging of
soluble gases in DC3 deep convective storms using WRF-Chem simulations and
aircraft observations, J. Geophys. Res.-Atmos., 121, 4233–4257,
https://doi.org/10.1002/2015JD024623, 2016. a
Ben-Ami, Y., Koren, I., Rudich, Y., Artaxo, P., Martin, S. T., and Andreae, M. O.: Transport of North African dust from the Bodélé depression to the Amazon Basin: a case study, Atmos. Chem. Phys., 10, 7533–7544, https://doi.org/10.5194/acp-10-7533-2010, 2010. a
Bezdek, J. C., Ehrlich, R., and Full, W.: FCM: The fuzzy c-means clustering
algorithm, Comput. Geosci., 10, 191–203,
https://doi.org/10.1016/0098-3004(84)90020-7, 1984. a
Boucher, O.: Atmospheric Aerosols: Properties and Climate Impacts, Springer,
2013. a
Boucher, O.: Atmospheric Aerosols: Properties and Climate Impacts, Springer
Netherlands, https://doi.org/10.1007/978-94-017-9649-1, 2015. a, b
Brito, J., Rizzo, L. V., Herckes, P., Vasconcellos, P. C., Caumo, S. E. S., Fornaro, A., Ynoue, R. Y., Artaxo, P., and Andrade, M. F.: Physical–chemical characterisation of the particulate matter inside two road tunnels in the São Paulo Metropolitan Area, Atmos. Chem. Phys., 13, 12199–12213, https://doi.org/10.5194/acp-13-12199-2013, 2013. a
Brito, J., Rizzo, L. V., Morgan, W. T., Coe, H., Johnson, B., Haywood, J., Longo, K., Freitas, S., Andreae, M. O., and Artaxo, P.: Ground-based aerosol characterization during the South American Biomass Burning Analysis (SAMBBA) field experiment, Atmos. Chem. Phys., 14, 12069–12083, https://doi.org/10.5194/acp-14-12069-2014, 2014. a
Cappa, C. D., Kolesar, K. R., Zhang, X., Atkinson, D. B., Pekour, M. S., Zaveri, R. A., Zelenyuk, A., and Zhang, Q.: Understanding the optical properties of ambient sub- and supermicron particulate matter: results from the CARES 2010 field study in northern California, Atmos. Chem. Phys., 16, 6511–6535, https://doi.org/10.5194/acp-16-6511-2016, 2016. a
Carneiro, R. G. and Fisch, G.: Observational analysis of the daily cycle of the planetary boundary layer in the central Amazon during a non-El Niño year and El Niño year (GoAmazon project 2014/5), Atmos. Chem. Phys., 20, 5547–5558, https://doi.org/10.5194/acp-20-5547-2020, 2020. a
Cazorla, A., Bahadur, R., Suski, K. J., Cahill, J. F., Chand, D., Schmid, B., Ramanathan, V., and Prather, K. A.: Relating aerosol absorption due to soot, organic carbon, and dust to emission sources determined from in-situ chemical measurements, Atmos. Chem. Phys., 13, 9337–9350, https://doi.org/10.5194/acp-13-9337-2013, 2013. a, b
Chen, Q., Farmer, D. K., Rizzo, L. V., Pauliquevis, T., Kuwata, M., Karl, T. G., Guenther, A., Allan, J. D., Coe, H., Andreae, M. O., Pöschl, U., Jimenez, J. L., Artaxo, P., and Martin, S. T.: Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08), Atmos. Chem. Phys., 15, 3687–3701, https://doi.org/10.5194/acp-15-3687-2015, 2015. a
Cirino, G., Brito, J., Barbosa, H. M. J., Rizzo, L. V., Tunved, P., de Sá, S. S., Jimenez, J. L., Palm, B. B., Carbone, S., Lavric, J., Souza, R. A. F.,
Wolff, S., Walter, D., Tota, J., Oliveira, M. B. L., Martin, S. T., and
Artaxo, P.: Observations of Manaus urban plume evolution and interaction with
biogenic emissions in GoAmazon 2014/5, Atmos. Environ., 191, 513–524,
https://doi.org/10.1016/j.atmosenv.2018.08.031, 2018. a, b, c, d, e, f
Cirino, G. G., Souza, R. A. F., Adams, D. K., and Artaxo, P.: The effect of atmospheric aerosol particles and clouds on net ecosystem exchange in the Amazon, Atmos. Chem. Phys., 14, 6523–6543, https://doi.org/10.5194/acp-14-6523-2014, 2014. a
Cosgrove, B. A., Lohmann, D., Kenneth, M. E., Houser, P. R., Wood, E. F.,
Schaake, J. C., Robock, A., Marshall, C., Sheffield, J., Duan, Q., Lifeng,
L., Higgins, W. R., Pinker, R. T., Tarpley, D. J., and Meng, J.: Real-time and
retrospective forcing in the North American Land Data Assimilation System
(NLDAS) project, J. Geophys. Res.-Atmos., 108, 8842, https://doi.org/10.1029/2002JD003118,
2003. a
de Sá, S. S., Palm, B. B., Campuzano-Jost, P., Day, D. A., Hu, W., Isaacman-VanWertz, G., Yee, L. D., Brito, J., Carbone, S., Ribeiro, I. O., Cirino, G. G., Liu, Y., Thalman, R., Sedlacek, A., Funk, A., Schumacher, C., Shilling, J. E., Schneider, J., Artaxo, P., Goldstein, A. H., Souza, R. A. F., Wang, J., McKinney, K. A., Barbosa, H., Alexander, M. L., Jimenez, J. L., and Martin, S. T.: Urban influence on the concentration and composition of submicron particulate matter in central Amazonia, Atmos. Chem. Phys., 18, 12185–12206, https://doi.org/10.5194/acp-18-12185-2018, 2018. a, b, c, d, e, f, g, h
de Sá, S. S., Rizzo, L. V., Palm, B. B., Campuzano-Jost, P., Day, D. A., Yee, L. D., Wernis, R., Isaacman-VanWertz, G., Brito, J., Carbone, S., Liu, Y. J., Sedlacek, A., Springston, S., Goldstein, A. H., Barbosa, H. M. J., Alexander, M. L., Artaxo, P., Jimenez, J. L., and Martin, S. T.: Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season, Atmos. Chem. Phys., 19, 7973–8001, https://doi.org/10.5194/acp-19-7973-2019, 2019. a
de Souza, D. O. and dos Santos Alvalá, R. C.: Observational evidence of the urban heat island of Manaus City, Brazil, Meteorol. Appl., 21,
186–193, 2014. a
dos Santos, M. J., Silva Dias, M. A. F., and Freitas, E. D.: Influence of local circulations on wind, moisture, and precipitation close to Manaus City,
Amazon Region, Brazil, J. Geophys. Res.-Atmos., 119, 13233–13249,
https://doi.org/10.1002/2014JD021969, 2014. a, b
Draxler, R. R.: Demonstration of a global modeling methodology to determine the
relative importance of local and long-distance sources, Atmos. Environ., 41,
776–789, https://doi.org/10.1016/j.atmosenv.2006.08.052, 2007. a
Drinovec, L., Močnik, G., Zotter, P., Prévôt, A. S. H., Ruckstuhl, C., Coz, E., Rupakheti, M., Sciare, J., Müller, T., Wiedensohler, A., and Hansen, A. D. A.: The ”dual-spot” Aethalometer: an improved measurement of aerosol black carbon with real-time loading compensation, Atmos. Meas. Tech., 8, 1965–1979, https://doi.org/10.5194/amt-8-1965-2015, 2015. a
Dubovik, O. and King, M. D.: A flexible inversion algorithm for retrieval of
aerosol optical properties from Sun and sky radiance measurements, J.
Geophys. Res.-Atmos., 105, 20673–20696, 2000. a
Easter, R. C., Ghan, S. J., Zhang, Y., Saylor, R. D., Chapman, E. G.,
Laulainen, N. S., Abdul-Razzak, H., Leung, L. R., Bian, X., and Zaveri,
R. A.: MIRAGE: Model description and evaluation of aerosols and trace gases,
J. Geophys. Res.-Atmos., 109, D20210, https://doi.org/10.1029/2004JD004571, 2004. a
Fast, J. D., Gustafson, W. I., Easter, R. C., Zaveri, R. A., Barnard, J. C.,
Chapman, E. G., Grell, G. A., and Peckham, S. E.: Evolution of ozone,
particulates, and aerosol direct radiative forcing in the vicinity of Houston
using a fully coupled meteorology-chemistry-aerosol model, J. Geophys.
Res.-Atmos., 111, D21305, https://doi.org/10.1029/2005JD006721, 2006. a, b
Forkel, R., Werhahn, J., Hansen, A. B., McKeen, S., Peckham, S., Grell, G., and Suppan, P.: Effect of aerosol-radiation feedback on regional air quality – A
case study with WRF/Chem, Atmos. Environ., 53, 202–211,
https://doi.org/10.1016/j.atmosenv.2011.10.009, 2012. a, b
Fraund, M., Pham, D. Q., Bonanno, D., Harder, T., Wang, B., Brito, J.,
de Sá, S. S., Carbone, S., China, S., Artaxo, P., Martin, S., Pöhlker,
C., Andreae, M., Laskin, A., Gilles, M., and Moffet, R.: Elemental mixing
state of aerosol particles collected in Central Amazonia during
GoAmazon2014/15, Atmosphere, 8, 173, https://doi.org/10.3390/atmos8090173, 2017. a
Graham, B., Guyon, P., Maenhaut, W., Taylor, P. E., Ebert, M., Matthias-Maser,
S., Mayol-Bracero, O. L., Godoi, R. H. M., Artaxo, P., Meixner, F. X.,
Lima Moura, M. A., Eça D’Almeida Rocha, C. H., Van Grieken, R., Glovsky,
M. M., Flagan, R. C., and Andreae, M. O.: Composition and diurnal variability
of the natural Amazonian aerosol, J. Geophys. Res.-Atmos., 108, 4765,
https://doi.org/10.1029/2003JD004049, 2003a. a
Graham, B., Guyon, P., Taylor, P. E., Artaxo, P., Maenhaut, W., Glovsky, M. M., Flagan, R. C., and Andreae, M. O.: Organic compounds present in the natural Amazonian aerosol: Characterization by gas chromatography–mass spectrometry,
J. Geophys. Res.-Atmos., 108, 4766, https://doi.org/10.1029/2003JD003990,
2003b. a
Grell, G. A., Peckham, S. E., Schmitz, R., McKeen, S., Frost, G., Skamarock,
W. C., and Eder, B.: Fully coupled “online” chemistry within the WRF
model, Atmos. Environ., 39, 6957–6975, https://doi.org/10.1016/j.atmosenv.2005.04.027,
2005. a, b
Grell, G. A. and Freitas, S. R.: A scale and aerosol aware stochastic convective parameterization for weather and air quality modeling, Atmos. Chem. Phys., 14, 5233–5250, https://doi.org/10.5194/acp-14-5233-2014, 2014. a, b
Gu, D., Guenther, A. B., Shilling, J. E., Yu, H., Huang, M., Zhao, C., Yang,
Q., Martin, S. T., Artaxo, P., Kim, S., Seco, R., Stavrakou, T., Longo,
K. M., Tóta, J., de Souza, R. A. F., Vega, O., Liu, Y., Shrivastava, M.,
Alves, E. G., Santos, F. C., Leng, G., and Hu, Z.: Airborne observations
reveal elevational gradient in tropical forest isoprene emissions, Nat.
Commun., 8, 1–7, https://doi.org/10.1038/ncomms15541, 2017. a
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181–3210, https://doi.org/10.5194/acp-6-3181-2006, 2006. a, b
Haywood, J. and Boucher, O.: Estimates of the direct and indirect radiative
forcing due to tropospheric aerosols: A review, Rev. Geophys., 38,
513–543, https://doi.org/10.1029/1999RG000078, 2000. a
He, X., Li, C. C., Lau, A. K. H., Deng, Z. Z., Mao, J. T., Wang, M. H., and Liu, X. Y.: An intensive study of aerosol optical properties in Beijing urban area, Atmos. Chem. Phys., 9, 8903–8915, https://doi.org/10.5194/acp-9-8903-2009, 2009. a
Holanda, B. A., Pöhlker, M. L., Walter, D., Saturno, J., Sörgel, M., Ditas, J., Ditas, F., Schulz, C., Franco, M. A., Wang, Q., Donth, T., Artaxo, P., Barbosa, H. M. J., Borrmann, S., Braga, R., Brito, J., Cheng, Y., Dollner, M., Kaiser, J. W., Klimach, T., Knote, C., Krüger, O. O., Fütterer, D., Lavrič, J. V., Ma, N., Machado, L. A. T., Ming, J., Morais, F. G., Paulsen, H., Sauer, D., Schlager, H., Schneider, J., Su, H., Weinzierl, B., Walser, A., Wendisch, M., Ziereis, H., Zöger, M., Pöschl, U., Andreae, M. O., and Pöhlker, C.: Influx of African biomass burning aerosol during the Amazonian dry season through layered transatlantic transport of black carbon-rich smoke, Atmos. Chem. Phys., 20, 4757–4785, https://doi.org/10.5194/acp-20-4757-2020, 2020. a
Hong, S.-Y., Noh, Y., and Dudhia, J.: A new vertical diffusion package with an explicit treatment of entrainment processes, Mon. Weather Rev., 134,
2318–2341, https://doi.org/10.1175/MWR3199.1, 2006. a, b
Iacono, M. J., Delamere, J. S., Mlawer, E. J., Shephard, M. W., Clough, S. A., and Collins, W. D.: Radiative forcing by long-lived greenhouse gases:
Calculations with the AER radiative transfer models, J. Geophys. Res.-Atmos.,
113, D13103, https://doi.org/10.1029/2008JD009944, 2008. a, b
Jiménez, P. A., Dudhia, J., González-Rouco, J. F., Navarro, J.,
Montávez, J. P., and García-Bustamante, E.: A revised scheme for the
WRF surface layer formulation, Mon. Weather Rev., 140, 898–918,
https://doi.org/10.1175/MWR-D-11-00056.1, 2012. a, b
Korras-Carraca, M. B., Hatzianastassiou, N., Matsoukas, C., Gkikas, A., and Papadimas, C. D.: The regime of aerosol asymmetry parameter over Europe, the Mediterranean and the Middle East based on MODIS satellite data: evaluation against surface AERONET measurements, Atmos. Chem. Phys., 15, 13113–13132, https://doi.org/10.5194/acp-15-13113-2015, 2015. a, b, c
Kroll, J. H. and Seinfeld, J. H.: Chemistry of secondary organic aerosol:
Formation and evolution of low-volatility organics in the atmosphere, ,
Atmos. Environ., 42, 3593–3624, 2008. a
Kuhn, U., Ganzeveld, L., Thielmann, A., Dindorf, T., Schebeske, G., Welling, M., Sciare, J., Roberts, G., Meixner, F. X., Kesselmeier, J., Lelieveld, J., Kolle, O., Ciccioli, P., Lloyd, J., Trentmann, J., Artaxo, P., and Andreae, M. O.: Impact of Manaus City on the Amazon Green Ocean atmosphere: ozone production, precursor sensitivity and aerosol load, Atmos. Chem. Phys., 10, 9251–9282, https://doi.org/10.5194/acp-10-9251-2010, 2010. a, b
Lim, S., Lee, M., Kim, S.-W., Yoon, S.-C., Lee, G., and Lee, Y. J.: Absorption and scattering properties of organic carbon versus sulfate dominant aerosols at Gosan climate observatory in Northeast Asia, Atmos. Chem. Phys., 14, 7781–7793, https://doi.org/10.5194/acp-14-7781-2014, 2014. a
Lu, L., Denning, A. S., da Silva-Dias, M. A., da Silva-Dias, P., Longo, M.,
Freitas, S. R., and Saatchi, S.: Mesoscale circulations and atmospheric CO2
variations in the Tapajós Region, Pará, Brazil, J. Geophys.
Res.-Atmos., 110, 1–17, https://doi.org/10.1029/2004JD005757, 2005. a
Madronich, S.: Photodissociation in the atmosphere: 1. Actinic flux and the
effects of ground reflections and clouds, J. Geophys. Res.-Atmos., 92,
9740–9752, https://doi.org/10.1029/JD092iD08p09740, 1987. a
Marengo, J. A., Nobre, C. A., and Culf, A. D.: Climatic impacts of
“friagens” in forested and deforested areas of the Amazon basin, J. Appl. Meteorol., 36, 1553–1566,
https://doi.org/10.1175/1520-0450(1997)036<1553:CIOFIF>2.0.CO;2, 1997. a
Marinho, R. R., Filizola Junior, N. P., and Cremon, É. H.: Analysis of
Suspended Sediment in the Anavilhanas Archipelago, Rio Negro, Amazon Basin,
Water, 12, 1073, https://doi.org/10.3390/w12041073, 2020. a
Martin, S. T., Artaxo, P., Machado, L. A. T., Manzi, A. O., Souza, R. A. F., Schumacher, C., Wang, J., Andreae, M. O., Barbosa, H. M. J., Fan, J., Fisch, G., Goldstein, A. H., Guenther, A., Jimenez, J. L., Pöschl, U., Silva Dias, M. A., Smith, J. N., and Wendisch, M.: Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5), Atmos. Chem. Phys., 16, 4785–4797, https://doi.org/10.5194/acp-16-4785-2016, 2016. a, b, c, d, e, f
Martin, S. T., Andreae, M. O., Althausen, D., Artaxo, P., Baars, H., Borrmann, S., Chen, Q., Farmer, D. K., Guenther, A., Gunthe, S. S., Jimenez, J. L., Karl, T., Longo, K., Manzi, A., Müller, T., Pauliquevis, T., Petters, M. D., Prenni, A. J., Pöschl, U., Rizzo, L. V., Schneider, J., Smith, J. N., Swietlicki, E., Tota, J., Wang, J., Wiedensohler, A., and Zorn, S. R.: An overview of the Amazonian Aerosol Characterization Experiment 2008 (AMAZE-08), Atmos. Chem. Phys., 10, 11415–11438, https://doi.org/10.5194/acp-10-11415-2010, 2010. a
Martin, S. T., Artaxo, P., Machado, L., Manzi, A. O., Souza, R., Schumacher,
C., Wang, J., Biscaro, T., Brito, J., Calheiros, A., Jardine, K., Medeiros, A., Portela, B., Sá, S. S. d., Adachi, K., Aiken, A. C., Albrecht, R., Alexander, L., Andreae, M. O., Barbosa, H. M. J., Buseck, P., Chand, D., Comstock, J. M., Day, D. A., Dubey, M., Fan, J., Fast, J., Fisch, G., Fortner, E., Giangrande, S., Gilles, M., Goldstein, A. H., Guenther, A., Hubbe, J., Jensen, M., Jimenez, J. L., Keutsch, F. N., Kim, S., Kuang, C., Laskin, A., McKinney, K., Mei, F., Miller, M., Nascimento, R., Pauliquevis, T., Pekour, M., Peres, J., Petäjä, T., Pöhlker, C., Pöschl, U., Rizzo, L., Schmid, B., Shilling, J. E., Dias, M. A. S., Smith, J. N., Tomlinson, J. M., Tóta, J., and Wendisch, M.: The Green Ocean
Amazon experiment (GoAmazon2014/5) observes pollution affecting gases,
aerosols, clouds, and rainfall over the rain forest, B. Am.
Meteorol. Soc., 98, 981–997, https://doi.org/10.1175/BAMS-D-15-00221.1, 2017. a, b, c
Martins, L. D., Andrade, M. F., Freitas, E. D., Pretto, A., Gatti, L. V.,
Albuquerque, É. L., Tomaz, E., Guardani, M. L., Martins, M. H., and
Junior, O. M.: Emission factors for gas-powered vehicles traveling through
road tunnels in São Paulo, Brazil, Environ. Sci. Technol.,
40, 6722–6729, 2006. a
Medeiros, A. S. S., Calderaro, G., Guimarães, P. C., Magalhaes, M. R., Morais, M. V. B., Rafee, S. A. A., Ribeiro, I. O., Andreoli, R. V., Martins, J. A., Martins, L. D., Martin, S. T., and Souza, R. A. F.: Power plant fuel switching and air quality in a tropical, forested environment, Atmos. Chem. Phys., 17, 8987–8998, https://doi.org/10.5194/acp-17-8987-2017, 2017. a, b, c, d
Mie, G.: Beiträge zur Optik trüber Medien, speziell kolloidaler
Metallösungen, Ann. Phys., 330, 377–445, 1908. a
Miranda, R. M. and Andrade, M. F.: Physicochemical characteristics of
atmospheric aerosol during winter in the São Paulo Metropolitan area in
Brazil, Atmos. Environ, 39, 6188–6193, 2005. a
Moran-Zuloaga, D., Ditas, F., Walter, D., Saturno, J., Brito, J., Carbone, S., Chi, X., Hrabě de Angelis, I., Baars, H., Godoi, R. H. M., Heese, B., Holanda, B. A., Lavrič, J. V., Martin, S. T., Ming, J., Pöhlker, M. L., Ruckteschler, N., Su, H., Wang, Y., Wang, Q., Wang, Z., Weber, B., Wolff, S., Artaxo, P., Pöschl, U., Andreae, M. O., and Pöhlker, C.: Long-term study on coarse mode aerosols in the Amazon rain forest with the frequent intrusion of Saharan dust plumes, Atmos. Chem. Phys., 18, 10055–10088, https://doi.org/10.5194/acp-18-10055-2018, 2018. a, b
Morrison, H., Thompson, G., and Tatarskii, V.: Impact of cloud microphysics on the development of trailing stratiform precipitation in a simulated squall
line: Comparison of one-and two-moment schemes, Mon. Weather Rev., 137,
991–1007, https://doi.org/10.1175/2008MWR2556.1, 2009. a, b
Müller, T., Henzing, J. S., de Leeuw, G., Wiedensohler, A., Alastuey, A., Angelov, H., Bizjak, M., Collaud Coen, M., Engström, J. E., Gruening, C., Hillamo, R., Hoffer, A., Imre, K., Ivanow, P., Jennings, G., Sun, J. Y., Kalivitis, N., Karlsson, H., Komppula, M., Laj, P., Li, S.-M., Lunder, C., Marinoni, A., Martins dos Santos, S., Moerman, M., Nowak, A., Ogren, J. A., Petzold, A., Pichon, J. M., Rodriquez, S., Sharma, S., Sheridan, P. J., Teinilä, K., Tuch, T., Viana, M., Virkkula, A., Weingartner, E., Wilhelm, R., and Wang, Y. Q.: Characterization and intercomparison of aerosol absorption photometers: result of two intercomparison workshops, Atmos. Meas. Tech., 4, 245–268, https://doi.org/10.5194/amt-4-245-2011, 2011. a
Murphy, B. N. and Pandis, S. N.: Simulating the formation of semivolatile
primary and secondary organic aerosol in a regional chemical transport model,
Environ. Sci. Technol., 43, 4722–4728, https://doi.org/10.1021/es803168a,
2009. a
Nobre, C. A., Obregón, G. O., , J. A., Fu, R., and Poveda, G.:
Characteristics of Amazonian climate: Main features, Amazonia and Global
Change, edited by: Keller, M., Bustamante, M., Gash, J., Silva Dias, P.,
Geophys. Mon. Ser, 186, 149–162, https://doi.org/10.1029/2002JD002911, 2009. a
Palacios, R. d. S., Romera, K. S., Curado, L. F., Banga, N. M., Rothmund,
L. D., Sallo, F. d. S., Morais, D., Santos, A. C., Moraes, T. J., Morais,
F. G., Santos, A. C., Moraes, T. J., Morais, F. G., Landufo, E., Franco, M, A. d. M., Kuhnen, I. A., Marques, J, B., Nogueira, J. d. S., Valle Junior, L, C., and Rodrigues, T.: Long term analysis of optical and radiative properties of
aerosols in the Amazon Basin, Aerosol Air Qual. Res.,
https://doi.org/10.4209/aaqr.2019.04.0189, 2020. a, b
Palm, B. B., de Sá, S. S., Day, D. A., Campuzano-Jost, P., Hu, W., Seco, R., Sjostedt, S. J., Park, J.-H., Guenther, A. B., Kim, S., Brito, J., Wurm, F., Artaxo, P., Thalman, R., Wang, J., Yee, L. D., Wernis, R., Isaacman-VanWertz, G., Goldstein, A. H., Liu, Y., Springston, S. R., Souza, R., Newburn, M. K., Alexander, M. L., Martin, S. T., and Jimenez, J. L.: Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia, Atmos. Chem. Phys., 18, 467–493, https://doi.org/10.5194/acp-18-467-2018, 2018. a
Papiez, M. R., Potosnak, M. J., Goliff, W. S., Guenther, A. B., Matsunaga,
S. N., and Stockwell, W. R.: The impacts of reactive terpene emissions from
plants on air quality in Las Vegas, Nevada, Atmos. Environ, 43, 4109–4123,
https://doi.org/10.1016/j.atmosenv.2009.05.048, 2009. a
Pereira Oliveira, A. and Fitzjarrald, D. R.: The Amazon river breeze and the
local boundary layer: I. Observations, Bound.-Lay. Meteorol., 63,
141–162, https://doi.org/10.1007/BF00705380, 1993. a
Pöhlker, C., Walter, D., Paulsen, H., Könemann, T., Rodríguez-Caballero, E., Moran-Zuloaga, D., Brito, J., Carbone, S., Degrendele, C., Després, V. R., Ditas, F., Holanda, B. A., Kaiser, J. W., Lammel, G., Lavrič, J. V., Ming, J., Pickersgill, D., Pöhlker, M. L., Praß, M., Löbs, N., Saturno, J., Sörgel, M., Wang, Q., Weber, B., Wolff, S., Artaxo, P., Pöschl, U., and Andreae, M. O.: Land cover and its transformation in the backward trajectory footprint region of the Amazon Tall Tower Observatory, Atmos. Chem. Phys., 19, 8425–8470, https://doi.org/10.5194/acp-19-8425-2019, 2019. a, b
Pöhlker, M. L., Ditas, F., Saturno, J., Klimach, T., Hrabě de Angelis, I., Araùjo, A. C., Brito, J., Carbone, S., Cheng, Y., Chi, X., Ditz, R., Gunthe, S. S., Holanda, B. A., Kandler, K., Kesselmeier, J., Könemann, T., Krüger, O. O., Lavrič, J. V., Martin, S. T., Mikhailov, E., Moran-Zuloaga, D., Rizzo, L. V., Rose, D., Su, H., Thalman, R., Walter, D., Wang, J., Wolff, S., Barbosa, H. M. J., Artaxo, P., Andreae, M. O., Pöschl, U., and Pöhlker, C.: Long-term observations of cloud condensation nuclei over the Amazon rain forest – Part 2: Variability and characteristics of biomass burning, long-range transport, and pristine rain forest aerosols, Atmos. Chem. Phys., 18, 10289–10331, https://doi.org/10.5194/acp-18-10289-2018, 2018. a, b
Ramachandran, S. and Rajesh, T.: Black carbon aerosol mass concentrations over Ahmedabad, an urban location in western India: comparison with urban sites in Asia, Europe, Canada, and the United States, J. Geophys. Res.-Atmos., 112, D06211, https://doi.org/10.1029/2006JD007488, 2007. a
Rap, A., Spracklen, D. V., Mercado, L., Reddington, C. L., Haywood, J. M., Ellis, R. J., Phillips, O. L., Artaxo, P., Bonal, D., C., R., and
Butt, N.: Fires
increase Amazon forest productivity through increases in diffuse radiation,
Geophys. Res. Lett., 42, 4654–4662, https://doi.org/10.1002/2015GL063719,
2015. a
Rizzo, L. V., Correia, A. L., Artaxo, P., Procópio, A. S., and Andreae, M. O.: Spectral dependence of aerosol light absorption over the Amazon Basin, Atmos. Chem. Phys., 11, 8899–8912, https://doi.org/10.5194/acp-11-8899-2011, 2011. a, b
Rizzo, L. V., Artaxo, P., Müller, T., Wiedensohler, A., Paixão, M., Cirino, G. G., Arana, A., Swietlicki, E., Roldin, P., Fors, E. O., Wiedemann, K. T., Leal, L. S. M., and Kulmala, M.: Long term measurements of aerosol optical properties at a primary forest site in Amazonia, Atmos. Chem. Phys., 13, 2391–2413, https://doi.org/10.5194/acp-13-2391-2013, 2013. a, b, c, d, e
Rizzolo, J. A., Barbosa, C. G. G., Borillo, G. C., Godoi, A. F. L., Souza, R. A. F., Andreoli, R. V., Manzi, A. O., Sá, M. O., Alves, E. G., Pöhlker, C., Angelis, I. H., Ditas, F., Saturno, J., Moran-Zuloaga, D., Rizzo, L. V., Rosário, N. E., Pauliquevis, T., Santos, R. M. N., Yamamoto, C. I., Andreae, M. O., Artaxo, P., Taylor, P. E., and Godoi, R. H. M.: Soluble iron nutrients in Saharan dust over the central Amazon rainforest, Atmos. Chem. Phys., 17, 2673–2687, https://doi.org/10.5194/acp-17-2673-2017, 2017. a
Romano, S., Perrone, M. R., Pavese, G., Esposito, F., and Calvello, M.: Optical properties of PM2.5 particles: Results from a monitoring campaign in southeastern Italy, Atmos. Environ, 203, 35–47,
https://doi.org/10.1016/j.atmosenv.2019.01.037, 2019. a, b, c
Russell, P. B., Bergstrom, R. W., Shinozuka, Y., Clarke, A. D., DeCarlo, P. F., Jimenez, J. L., Livingston, J. M., Redemann, J., Dubovik, O., and Strawa, A.: Absorption Angstrom Exponent in AERONET and related data as an indicator of aerosol composition, Atmos. Chem. Phys., 10, 1155–1169, https://doi.org/10.5194/acp-10-1155-2010, 2010. a
Sánchez-Ccoyllo, O. R., Ynoue, R. Y., Martins, L. D., Astolfo, R., Miranda, R. M., Freitas, E. D., Borges, A. S., Fornaro, A., Freitas, H., Moreira, A., and Andrade, M. F.: Vehicular particulate matter emissions in road tunnels in Sao Paulo,
Brazil, Environ. Monitor. Assess., 149, 241–249,
https://doi.org/10.1007/s10661- 008-0198-5, 2009. a
Saturno, J., Holanda, B. A., Pöhlker, C., Ditas, F., Wang, Q., Moran-Zuloaga, D., Brito, J., Carbone, S., Cheng, Y., Chi, X., Ditas, J., Hoffmann, T., Hrabe de Angelis, I., Könemann, T., Lavrič, J. V., Ma, N., Ming, J., Paulsen, H., Pöhlker, M. L., Rizzo, L. V., Schlag, P., Su, H., Walter, D., Wolff, S., Zhang, Y., Artaxo, P., Pöschl, U., and Andreae, M. O.: Black and brown carbon over central Amazonia: long-term aerosol measurements at the ATTO site, Atmos. Chem. Phys., 18, 12817–12843, https://doi.org/10.5194/acp-18-12817-2018, 2018. a
Sátyro, Z. C., Farias, C., Candido, L. A., and Veiga, J. A.: The relative
and joint effect of rivers and urban area on a squall line in the Central
Amazonia, Sci. Total Enviro., 755, 142178, https://doi.org/10.1016/j.scitotenv.2020.142178, 2021. a
Schultz, M. G., Schroder, S., Lyapina, O., Cooper, O. R., Galbally, I., Petropavlovskikh, I., von Schneidemesser, E., Tanimoto, H., Elshorbany, Y., Naja, M., Seguel, R. J., Dauert, U., Eckhardt, P., Feigenspan, S., Fiebig, M., Hjellbrekke, A.-G., Hong, Y.-D., Kjeld, P. C., Koide, H., Lear, G., Tarasick, D., Ueno, M., Wallasch, M., Baumgardner, D., Chuang, M.-T., Gillett, R., Lee, M., Molloy, S., Moolla, R., Wang, T., Sharps, K., Adame, J. A., Ancellet, G., Apadula, F., Artaxo, P., Barlasina, M. E., Bogucka, M., Bonasoni, P., Chang, L., Colomb, A., CuevasAgullo, E., Cupeiro, M., Degorska, A., Ding, A., Fröhlich, M., Frolova, M., Gadhavi, H., Gheusi, F., Gilge, S., Gonzalez, M. Y., Gros, V., Hamad, S. H., Helmig, D., Henriques, D., Hermansen, O., Holla, R., Hueber, J., Im, U., Jaffe, D. A., Komala, N., Kubistin, D., Lam, K.-S., Laurila, T., Lee, H., Levy, I., Mazzoleni, C., Mazzoleni, L. R., McClure-Begley, A., Mohamad, M., Murovec, M., Navarro-Comas, M., Nicodim, F., Parrish, D., Read, K. A., Reid, N., Ries, L., Saxena, P., Schwab, J. J., Scorgie, Y., Senik, I., Simmonds, P., Sinha, V., Skorokhod, A. I., Spain, G., Spangl, W., Spoor, R., Springston, S. R., Steer, K., Steinbacher, M., Suharguniyawan, E., Torre, P., Trickl, T., Lin, W., Weller, R., Xu, X., Xue, L., and Ma, Z.: Tropospheric Ozone Assessment Report: Database and metrics
data of global surface ozone observations, Elementa, 5, 58, https://doi.org/10.1525/elementa.244, 2017. a
Seinfeld, J. H. and Pandis, S. N.: Atmospheric Chemistry and Physics: from air pollution to
climate change, 3rd edn., John Wiley & Sons, 2016. a
Shilling, J. E., Pekour, M. S., Fortner, E. C., Artaxo, P., de Sá, S., Hubbe, J. M., Longo, K. M., Machado, L. A. T., Martin, S. T., Springston, S. R., Tomlinson, J., and Wang, J.: Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5, Atmos. Chem. Phys., 18, 10773–10797, https://doi.org/10.5194/acp-18-10773-2018, 2018. a, b, c, d, e, f, g, h
Shrivastava, M., Andreae, M. O., Artaxo, P., Barbosa, H. M. J., Berg, L. K., Brito, J., Ching, J., Easter, R. C., Fan, J. W., Fast, J. D., Feng, Z., Fuentes, J. D., Glasius, M., Goldstein, A. H., Alves, E. G., Gomes, H., Gu, D., Guenther, A., Jathar, S. H., Kim, S., Liu, Y., Lou, S. J., Martin, S. T., McNeill, V. F., Medeiros, A., de Sa, S. S., Shilling, J. E., Springston, S. R., Souza, R. A. F., Thornton, J. A., Isaacman-VanWertz, G., Yee, L. D., Ynoue, R., Zaveri, R. A., Zelenyuk, A., and Zhao, C.: Urban
pollution greatly enhances formation of natural aerosols over the Amazon
rainforest, Nat. Commun., 10, 1046, https://doi.org/10.1038/s41467-019-08909-4,
2019. a, b, c, d, e, f, g, h, i, j, k
Silva Dias, M. A. F., Silva Dias, P. L., Longo, M., Fitzjarrald, D. R., and
Denning, A. S.: River breeze circulation in eastern Amazonia: observations
and modelling results, Theor. Appl. Climatol., 78, 111–121,
https://doi.org/10.1007/s00704-004-0047-6, 2004. a
Stein, A. F., Isakov, V., Godowitch, J., and Draxler, R. R.: A hybrid modeling
approach to resolve pollutant concentrations in an urban area, Atmos.
Environ., 41, 9410–9426, https://doi.org/10.1016/j.atmosenv.2007.09.004, 2007.
a
Tewari, M., Chen, F., Wang, W., Dudhia, J., LeMone, M., Mitchell, K., Ek, M.,
Gayno, G., Wegiel, J., and Cuenca, R.: Implementation and verification of the
unified NOAH land surface model in the WRF model, in: 20th conference on
weather analysis and forecasting/16th conference on numerical weather
prediction,American Meteorological Society
Seattle, WA, 1115, 2165–2170, 2004. a, b
Thalman, R., de Sá, S. S., Palm, B. B., Barbosa, H. M. J., Pöhlker, M. L., Alexander, M. L., Brito, J., Carbone, S., Castillo, P., Day, D. A., Kuang, C., Manzi, A., Ng, N. L., Sedlacek III, A. J., Souza, R., Springston, S., Watson, T., Pöhlker, C., Pöschl, U., Andreae, M. O., Artaxo, P., Jimenez, J. L., Martin, S. T., and Wang, J.: CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions, Atmos. Chem. Phys., 17, 11779–11801, https://doi.org/10.5194/acp-17-11779-2017, 2017. a, b, c
Trebs, I., Mayol-Bracero, O. L., Pauliquevis, T., Kuhn, U., Sander, R.,
Ganzeveld, L., Meixner, F. X., Kesselmeier, J., Artaxo, P., and Andreae,
M. O.: Impact of the Manaus urban plume on trace gas mixing ratios near the
surface in the Amazon Basin: Implications for the NO-NO2-O3 photostationary state and peroxy radical levels, J. Geophys. Res.-Atmos., 117, D05307, https://doi.org/10.1029/2011JD016386, 2012. a
Vara-Vela, A., de Fátima Andrade, M., Zhang, Y., Kumar, P., Ynoue, R. Y.,
Souto-Oliveira, C. E., da Silva Lopes, F. J., and Landulfo, E.: Modeling of
Atmospheric Aerosol Properties in the São Paulo Metropolitan Area: Impact
of Biomass Burning, J. Geophys. Res.-Atmos., 123, 9935–9956,
https://doi.org/10.1029/2018JD028768, 2018. a
Yáñez-Serrano, A. M., Bourtsoukidis, E., Alves, E. G., Bauwens, M., Stavrakou, T., Llusià, J., Filella, I., Guenther, A., Williams, J., Artaxo, P., Sindelarova, K., Doubalova, J., Kesselmeier, J., and Peñuelas, J.: Amazonian biogenic volatile organic compounds under
global change, Glob. Change Biol., 26, 4722–4751, https://doi.org/10.1111/gcb.15185, 2020. a
Ynoue, R. Y. and Andrade, M. F.: Size-resolved mass balance of aerosol
particles over the São Paulo metropolitan area of Brazil, Aerosol Sci. Tech., 38, 52–62, 2004. a
Zhang, Y., Wen, X.-Y., and Jang, C.: Simulating
chemistry–aerosol–cloud–radiation–climate feedbacks over the continental
US using the online-coupled Weather Research Forecasting Model with chemistry
(WRF/Chem), Atmos. Environ, 44, 3568–3582, 2010. a
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