Articles | Volume 19, issue 16
https://doi.org/10.5194/acp-19-10557-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-10557-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Aug 2019
Research article |
| 21 Aug 2019
| 21 Aug 2019
NH3-promoted hydrolysis of NO2 induces explosive growth in HONO
Wanyun Xu
State Key Laboratory of Severe Weather, Key Laboratory for
Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy
of Meteorological Sciences, Beijing, 100081, China
Institute for Environmental and Climate Research, Jinan University,
Guangzhou, China
Chunsheng Zhao
Department of Atmospheric and Oceanic Sciences, School of Physics,
Peking University, Beijing, China
Jiangchuan Tao
Institute for Environmental and Climate Research, Jinan University,
Guangzhou, China
Gang Zhao
Department of Atmospheric and Oceanic Sciences, School of Physics,
Peking University, Beijing, China
Yuxuan Bian
State Key Laboratory of Severe Weather, Chinese Academy of
Meteorological Sciences, Beijing, 100081, China
Wen Yang
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing, 100081, China
Yingli Yu
Department of Atmospheric and Oceanic Sciences, School of Physics,
Peking University, Beijing, China
Chuanyang Shen
Department of Atmospheric and Oceanic Sciences, School of Physics,
Peking University, Beijing, China
Linlin Liang
State Key Laboratory of Severe Weather, Key Laboratory for
Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy
of Meteorological Sciences, Beijing, 100081, China
Gen Zhang
State Key Laboratory of Severe Weather, Key Laboratory for
Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy
of Meteorological Sciences, Beijing, 100081, China
Weili Lin
College of Life and Environmental Sciences, Minzu University of
China, Beijing, 100081, China
Xiaobin Xu
State Key Laboratory of Severe Weather, Key Laboratory for
Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy
of Meteorological Sciences, Beijing, 100081, China
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- Preparation and Characterization of Metastable trans-Dinitrogen Tetroxide J. Maurais et al. 10.1021/acs.jpca.2c01009
- Aqueous phase oxidation of bisulfite influenced by nitrate and its photolysis L. Chen et al. 10.1016/j.scitotenv.2021.147345
- Resolving the Formation Mechanism of HONO via Ammonia-Promoted Photosensitized Conversion of Monomeric NO2 on Urban Glass Surfaces J. Liu et al. 10.1021/jacs.3c02067
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Comprehensive study about the heterogeneous conversion of NH3on nanoscale TiO2particles: insight into the mechanism and atmospheric implications Q. Ma et al. 10.1039/D2EN00966H
- Measurement report: Chemical characteristics of PM<sub>2.5</sub> during typical biomass burning season at an agricultural site of the North China Plain L. Liang et al. 10.5194/acp-21-3181-2021
- Combined effects of high relative humidity and ultraviolet irradiation: Enhancing the production of gaseous NO2 from the photolysis of NH4NO3 S. Jin et al. 10.1016/j.scitotenv.2022.156480
- Exploring HONO formation and its role in driving secondary pollutants formation during winter in the North China Plain S. Zhang et al. 10.1016/j.jes.2022.09.034
- Multiphase chemistry experiment in Fogs and Aerosols in the North China Plain (McFAN): integrated analysis and intensive winter campaign 2018 G. Li et al. 10.1039/D0FD00099J
- Springtime HONO budget and its impact on the O3 production in Zibo, Shandong, China Z. Qin et al. 10.1016/j.apr.2023.101935
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- The observation of atmospheric HONO by wet-rotating-denuder ion chromatograph in a coastal city: Performance and influencing factors B. Hu et al. 10.1016/j.envpol.2024.124355
- Aerosol Promotes Peroxyacetyl Nitrate Formation During Winter in the North China Plain W. Xu et al. 10.1021/acs.est.0c08157
- Double High-Level Ozone and PM2.5 Co-Pollution Episodes in Shanghai, China: Pollution Characteristics and Significant Role of Daytime HONO K. Yang et al. 10.3390/atmos12050557
- Simulation Verification of Barrierless HONO Formation from the Oxidation Reaction System of NO, Cl, and Water in the Atmosphere X. Zhao et al. 10.1021/acs.est.1c01773
- Machine learning revealing key factors influencing HONO chemistry in Beijing during heating and non-heating periods W. Zhang et al. 10.1016/j.atmosres.2023.107130
- Fast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze J. Wang et al. 10.1038/s41467-020-16683-x
- First long-term surface ozone variations at an agricultural site in the North China Plain: Evolution under changing meteorology and emissions X. Zhang et al. 10.1016/j.scitotenv.2022.160520
- Abundant NH3 in China Enhances Atmospheric HONO Production by Promoting the Heterogeneous Reaction of SO2 with NO2 S. Ge et al. 10.1021/acs.est.9b04196
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- Characterization of Atmospheric PM2.5 Inorganic Aerosols Using the Semi-Continuous PPWD-PILS-IC System and the ISORROPIA-II T. Le et al. 10.3390/atmos11080820
- Budget of atmospheric nitrous acid (HONO) during the haze and clean periods in Shanghai: Importance of heterogeneous reactions J. Feng et al. 10.1016/j.scitotenv.2023.165717
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- Exploration of the atmospheric chemistry of nitrous acid in a coastal city of southeastern China: results from measurements across four seasons B. Hu et al. 10.5194/acp-22-371-2022
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- Atmospheric ammonia in the rural North China Plain during wintertime: Variations, sources, and implications for HONO heterogeneous formation P. Liu et al. 10.1016/j.scitotenv.2022.160768
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- Discrepancies in ozone levels and temporal variations between urban and rural North China Plain X. Zhang et al. 10.1525/elementa.2022.00019
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- The Impact of Agroecosystems on Nitrous Acid (HONO) Emissions during Spring and Autumn in the North China Plain J. Zeng et al. 10.3390/toxics12050331
Latest update: 20 Nov 2024
Short summary
The study of HONO, the primary source of OH radicals, is crucial for atmospheric photochemistry and heterogeneous chemistry. Heterogeneous NO2 conversion was shown to be one of the missing sources of HONO on the North China Plain, but the reaction path is still under debate. In this work, evidence was found that NH3 was the key factor that promoted the hydrolysis of NO2, leading to the explosive growth of HONO and nitrate, suggesting that NH3 emission control measures are urgently needed.
The study of HONO, the primary source of OH radicals, is crucial for atmospheric photochemistry...
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