Articles | Volume 18, issue 2
https://doi.org/10.5194/acp-18-833-2018
https://doi.org/10.5194/acp-18-833-2018
Research article
 | 
23 Jan 2018
Research article |  | 23 Jan 2018

Vertical distributions of N2O isotopocules in the equatorial stratosphere

Sakae Toyoda, Naohiro Yoshida, Shinji Morimoto, Shuji Aoki, Takakiyo Nakazawa, Satoshi Sugawara, Shigeyuki Ishidoya, Mitsuo Uematsu, Yoichi Inai, Fumio Hasebe, Chusaku Ikeda, Hideyuki Honda, and Kentaro Ishijima

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Revised manuscript not accepted
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Subject: Isotopes | Research Activity: Field Measurements | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Akiyoshi, H., Zhou, L. B., Yamashita, Y., Sakamoto, K., Yoshiki, M., Nagashima, T., Takahashi, M., Kurokawa, J., Takigawa, M., and Imamura, T.: A CCM simulation of the breakup of the Antarctic polar vortex in the years 1980–2004 under the CCMVal scenarios, J. Geophys. Res., 114, D03103, https://doi.org/10.1029/2007JD009261, 2009. 
Boering, K. A., Wofsy, S. C., Daube, B. C., Schneider, H. R., Loewenstein, M., Podolske, J. R., and Conway, T. J.: Stratospheric mean ages and transport rates from observations of carbon dioxide and nitrous oxide, Science, 274, 1340–1343, 1996. 
Coplen, T. B.: Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results, Rapid Commun. Mass Sp., 25, 2538–2560, https://doi.org/10.1002/rcm.5129, 2011. 
Engel, A., Möbius, T., Bönisch, H., Schmidt, U., Heinz, R., Levin, I., Atlas, E., Aoki, S., Nakazawa, T., Sugawara, S., Moore, F., Hurst, D., Elkins, J., Schauffler, S., Andrews, A., and Boering, K.: Age of stratospheric air unchanged within uncertainties over the past 30 years, Nat. Geosci., 2, 28–31, https://doi.org/10.1038/ngeo388, 2009. 
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Short summary
By analysis of whole air samples collected by balloon-borne compact cryogenic samplers, we found that apparent isotope effect for stratospheric N2O between 25 and 30 km over the Equator is larger than that observed in other latitudes and that it is almost equal to the effect predicted by laboratory simulation experiments. These results suggest that equatorial middle stratosphere can be treated as an isolated region when we consider the decomposition of N2O by photochemical processes.
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