Articles | Volume 15, issue 13
https://doi.org/10.5194/acp-15-7287-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-7287-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Jul 2015
Research article |
| 07 Jul 2015
800-year ice-core record of nitrogen deposition in Svalbard linked to ocean productivity and biogenic emissions
I. A. Wendl
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, Bern, Switzerland
Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland
A. Eichler
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, Bern, Switzerland
E. Isaksson
Norwegian Polar Institute, Framsenteret, 9296 Tromsø, Norway
T. Martma
Institute of Geology, Tallinn University of Technology, Tallinn, Estonia
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, Bern, Switzerland
Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland
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Shugui Hou, Wangbin Zhang, Hongxi Pang, Shuang-Ye Wu, Theo M. Jenk, Margit Schwikowski, and Yetang Wang
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Dimitri Osmont, Isabel A. Wendl, Loïc Schmidely, Michael Sigl, Carmen P. Vega, Elisabeth Isaksson, and Margit Schwikowski
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Shugui Hou, Theo M. Jenk, Wangbin Zhang, Chaomin Wang, Shuangye Wu, Yetang Wang, Hongxi Pang, and Margit Schwikowski
The Cryosphere, 12, 2341–2348, https://doi.org/10.5194/tc-12-2341-2018, https://doi.org/10.5194/tc-12-2341-2018, 2018
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We present multiple lines of evidence indicating that the Chongce ice cores drilled from the northwestern Tibetan Plateau reaches back only to the early Holocene. This result is at least, 1 order of magnitude younger than the nearby Guliya ice core (~30 km away from the Chongce ice core drilling site) but similar to other Tibetan ice cores. Thus it is necessary to explore multiple dating techniques to confirm the age ranges of the Tibetan ice cores.
Mackenzie M. Grieman, Murat Aydin, Elisabeth Isaksson, Margit Schwikowski, and Eric S. Saltzman
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The Cryosphere, 12, 1681–1697, https://doi.org/10.5194/tc-12-1681-2018, https://doi.org/10.5194/tc-12-1681-2018, 2018
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Barbara Stenni, Mark A. J. Curran, Nerilie J. Abram, Anais Orsi, Sentia Goursaud, Valerie Masson-Delmotte, Raphael Neukom, Hugues Goosse, Dmitry Divine, Tas van Ommen, Eric J. Steig, Daniel A. Dixon, Elizabeth R. Thomas, Nancy A. N. Bertler, Elisabeth Isaksson, Alexey Ekaykin, Martin Werner, and Massimo Frezzotti
Clim. Past, 13, 1609–1634, https://doi.org/10.5194/cp-13-1609-2017, https://doi.org/10.5194/cp-13-1609-2017, 2017
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Elizabeth R. Thomas, J. Melchior van Wessem, Jason Roberts, Elisabeth Isaksson, Elisabeth Schlosser, Tyler J. Fudge, Paul Vallelonga, Brooke Medley, Jan Lenaerts, Nancy Bertler, Michiel R. van den Broeke, Daniel A. Dixon, Massimo Frezzotti, Barbara Stenni, Mark Curran, and Alexey A. Ekaykin
Clim. Past, 13, 1491–1513, https://doi.org/10.5194/cp-13-1491-2017, https://doi.org/10.5194/cp-13-1491-2017, 2017
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Meri M. Ruppel, Joana Soares, Jean-Charles Gallet, Elisabeth Isaksson, Tõnu Martma, Jonas Svensson, Jack Kohler, Christina A. Pedersen, Sirkku Manninen, Atte Korhola, and Johan Ström
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Pascal Bohleber, Leo Sold, Douglas R. Hardy, Margit Schwikowski, Patrick Klenk, Andrea Fischer, Pascal Sirguey, Nicolas J. Cullen, Mariusz Potocki, Helene Hoffmann, and Paul Mayewski
The Cryosphere, 11, 469–482, https://doi.org/10.5194/tc-11-469-2017, https://doi.org/10.5194/tc-11-469-2017, 2017
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Our study is the first to use ground-penetrating radar (GPR) to investigate ice thickness and internal layering at Kilimanjaro’s largest ice body, the Northern Ice Field (NIF). For monitoring the ongoing ice loss, our ice thickness soundings allowed us to estimate the total ice volume remaining at NIF's southern portion. Englacial GPR reflections indicate undisturbed layers within NIF's center and provide a first link between age information obtained from ice coring and vertical wall sampling.
Rune Strand Ødegård, Atle Nesje, Ketil Isaksen, Liss Marie Andreassen, Trond Eiken, Margit Schwikowski, and Chiara Uglietti
The Cryosphere, 11, 17–32, https://doi.org/10.5194/tc-11-17-2017, https://doi.org/10.5194/tc-11-17-2017, 2017
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Despite numerous spectacular archaeological discoveries worldwide related to melting ice, governing processes related to ice patch development are still largely unexplored. We present new results from Jotunheimen in central southern Norway showing that the Juvfonne ice patch has existed continuously since ca. 7600 cal years BP. This is the oldest dating of ice in mainland Norway. Moss mats along the margin of Juvfonne in 2014 were covered by the expanding ice patch about 2000 years ago.
Chiara Uglietti, Alexander Zapf, Theo Manuel Jenk, Michael Sigl, Sönke Szidat, Gary Salazar, and Margit Schwikowski
The Cryosphere, 10, 3091–3105, https://doi.org/10.5194/tc-10-3091-2016, https://doi.org/10.5194/tc-10-3091-2016, 2016
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A meaningful interpretation of the climatic history contained in ice cores requires a precise chronology. For dating the older and deeper part of the glaciers, radiocarbon analysis can be used when organic matter such as plant or insect fragments are found in the ice. Since this happens rarely, a complementary dating tool, based on radiocarbon dating of the insoluble fraction of carbonaceous aerosols entrapped in the ice, allows for ice dating between 200 and more than 10 000 years.
Paolo Gabrielli, Carlo Barbante, Giuliano Bertagna, Michele Bertó, Daniel Binder, Alberto Carton, Luca Carturan, Federico Cazorzi, Giulio Cozzi, Giancarlo Dalla Fontana, Mary Davis, Fabrizio De Blasi, Roberto Dinale, Gianfranco Dragà, Giuliano Dreossi, Daniela Festi, Massimo Frezzotti, Jacopo Gabrieli, Stephan P. Galos, Patrick Ginot, Petra Heidenwolf, Theo M. Jenk, Natalie Kehrwald, Donald Kenny, Olivier Magand, Volkmar Mair, Vladimir Mikhalenko, Ping Nan Lin, Klaus Oeggl, Gianni Piffer, Mirko Rinaldi, Ulrich Schotterer, Margit Schwikowski, Roberto Seppi, Andrea Spolaor, Barbara Stenni, David Tonidandel, Chiara Uglietti, Victor Zagorodnov, Thomas Zanoner, and Piero Zennaro
The Cryosphere, 10, 2779–2797, https://doi.org/10.5194/tc-10-2779-2016, https://doi.org/10.5194/tc-10-2779-2016, 2016
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New ice cores were extracted from Alto dell'Ortles, the highest glacier of South Tyrol in the Italian Alps, to check whether prehistoric ice, which is coeval to the famous 5300-yr-old Tyrolean Iceman, is still preserved in this region. Dating of the ice cores confirms the hypothesis and indicates the drilling site has been glaciated since the end of the Northern Hemisphere Climatic Optimum (7000 yrs BP). We also infer that an unprecedented acceleration of the glacier flow has recently begun.
Carmen P. Vega, Elisabeth Schlosser, Dmitry V. Divine, Jack Kohler, Tõnu Martma, Anja Eichler, Margit Schwikowski, and Elisabeth Isaksson
The Cryosphere, 10, 2763–2777, https://doi.org/10.5194/tc-10-2763-2016, https://doi.org/10.5194/tc-10-2763-2016, 2016
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Surface mass balance and water stable isotopes from firn cores on three ice rises at Fimbul Ice Shelf are reported. The results suggest that the ice rises are suitable sites for the retrieval of longer firn and ice cores. The first deuterium excess data for the area suggests a possible role of seasonal moisture transport changes on the annual isotopic signal. Large-scale atmospheric circulation patterns most likely provide the dominant influence on water stable isotope ratios at the sites.
Carmen P. Vega, Veijo A. Pohjola, Emilie Beaudon, Björn Claremar, Ward J. J. van Pelt, Rickard Pettersson, Elisabeth Isaksson, Tõnu Martma, Margit Schwikowski, and Carl E. Bøggild
The Cryosphere, 10, 961–976, https://doi.org/10.5194/tc-10-961-2016, https://doi.org/10.5194/tc-10-961-2016, 2016
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To quantify post-depositional relocation of major ions by meltwater in snow and firn at Lomonosovfonna, Svalbard, consecutive ice cores drilled at this site were used to construct a synthetic core. The relocation length of most of the ions was on the order of 1 m between 2007 and 2010. Considering the ionic relocation lengths and annual melt percentages, we estimate that the atmospheric ionic signal remains preserved in recently drilled Lomonosovfonna ice cores at an annual or bi-annual resolution.
C. Müller-Tautges, A. Eichler, M. Schwikowski, G. B. Pezzatti, M. Conedera, and T. Hoffmann
Atmos. Chem. Phys., 16, 1029–1043, https://doi.org/10.5194/acp-16-1029-2016, https://doi.org/10.5194/acp-16-1029-2016, 2016
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The paper focuses on the determination and interpretation of historic records of organic compounds in an ice core from Grenzgletscher in the southern Swiss Alps, covering the time period from 1942 to 1993. The resulting long-term records of organic species were found to be influenced by the forest fire history in southern Switzerland, anthropogenic emissions, as well as changing mineral dust transport to the drilling site.
J. Gabbi, M. Huss, A. Bauder, F. Cao, and M. Schwikowski
The Cryosphere, 9, 1385–1400, https://doi.org/10.5194/tc-9-1385-2015, https://doi.org/10.5194/tc-9-1385-2015, 2015
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Light-absorbing impurities in snow and ice increase the absorption of solar radiation and thus enhance melting. We investigated the effect of Saharan dust and black carbon on the mass balance of an Alpine glacier over 1914-2014. Snow impurities increased melt by 15-19% depending on the location on the glacier. From the accumulation area towards the equilibrium line, the effect of impurities increased as more frequent years with negative mass balance led to a re-exposure of dust-enriched layers.
S. Kang, F. Wang, U. Morgenstern, Y. Zhang, B. Grigholm, S. Kaspari, M. Schwikowski, J. Ren, T. Yao, D. Qin, and P. A. Mayewski
The Cryosphere, 9, 1213–1222, https://doi.org/10.5194/tc-9-1213-2015, https://doi.org/10.5194/tc-9-1213-2015, 2015
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L. Sold, M. Huss, A. Eichler, M. Schwikowski, and M. Hoelzle
The Cryosphere, 9, 1075–1087, https://doi.org/10.5194/tc-9-1075-2015, https://doi.org/10.5194/tc-9-1075-2015, 2015
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This study presents a method for estimating annual accumulation rates on a temperate Alpine glacier based on the interpretation of internal reflection horizons in helicopter-borne ground-penetrating radar (GPR) data. In combination with a simple model for firn densification and refreezing of meltwater, GPR can be used not only to complement existing mass balance monitoring programmes but also to retrospectively extend newly initiated time series.
S. Altnau, E. Schlosser, E. Isaksson, and D. Divine
The Cryosphere, 9, 925–944, https://doi.org/10.5194/tc-9-925-2015, https://doi.org/10.5194/tc-9-925-2015, 2015
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The first comprehensive study of a set of 76 firn cores in Dronning Maud Land was carried out. The δ18O of both the plateau and the ice shelf cores exhibit a slight positive trend over the second half of the 20th century. The SMB has a negative trend in the ice shelf cores, but increases on the plateau. Comparison with meteorological data revealed that for the ice shelf regions, atmospheric dynamic effects are more important, while on the plateau, thermodynamic effects predominate.
Y.-L. Zhang, R.-J. Huang, I. El Haddad, K.-F. Ho, J.-J. Cao, Y. Han, P. Zotter, C. Bozzetti, K. R. Daellenbach, F. Canonaco, J. G. Slowik, G. Salazar, M. Schwikowski, J. Schnelle-Kreis, G. Abbaszade, R. Zimmermann, U. Baltensperger, A. S. H. Prévôt, and S. Szidat
Atmos. Chem. Phys., 15, 1299–1312, https://doi.org/10.5194/acp-15-1299-2015, https://doi.org/10.5194/acp-15-1299-2015, 2015
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Source apportionment of fine carbonaceous aerosols using radiocarbon and other organic markers measurements during 2013 winter haze episodes was conducted at four megacities in China. Our results demonstrate that fossil emissions predominate EC with a mean contribution of 75±8%, whereas non-fossil sources account for 55±10% of OC; and the increment of TC on heavily polluted days was mainly driven by the increase of secondary OC from both fossil-fuel and non-fossil emissions.
P. Zotter, V. G. Ciobanu, Y. L. Zhang, I. El-Haddad, M. Macchia, K. R. Daellenbach, G. A. Salazar, R.-J. Huang, L. Wacker, C. Hueglin, A. Piazzalunga, P. Fermo, M. Schwikowski, U. Baltensperger, S. Szidat, and A. S. H. Prévôt
Atmos. Chem. Phys., 14, 13551–13570, https://doi.org/10.5194/acp-14-13551-2014, https://doi.org/10.5194/acp-14-13551-2014, 2014
M. M. Ruppel, E. Isaksson, J. Ström, E. Beaudon, J. Svensson, C. A. Pedersen, and A. Korhola
Atmos. Chem. Phys., 14, 11447–11460, https://doi.org/10.5194/acp-14-11447-2014, https://doi.org/10.5194/acp-14-11447-2014, 2014
A. Spolaor, P. Vallelonga, J. Gabrieli, T. Martma, M. P. Björkman, E. Isaksson, G. Cozzi, C. Turetta, H. A. Kjær, M. A. J. Curran, A. D. Moy, A. Schönhardt, A.-M. Blechschmidt, J. P. Burrows, J. M. C. Plane, and C. Barbante
Atmos. Chem. Phys., 14, 9613–9622, https://doi.org/10.5194/acp-14-9613-2014, https://doi.org/10.5194/acp-14-9613-2014, 2014
I. A. Wendl, J. A. Menking, R. Färber, M. Gysel, S. D. Kaspari, M. J. G. Laborde, and M. Schwikowski
Atmos. Meas. Tech., 7, 2667–2681, https://doi.org/10.5194/amt-7-2667-2014, https://doi.org/10.5194/amt-7-2667-2014, 2014
S. Kaspari, T. H. Painter, M. Gysel, S. M. Skiles, and M. Schwikowski
Atmos. Chem. Phys., 14, 8089–8103, https://doi.org/10.5194/acp-14-8089-2014, https://doi.org/10.5194/acp-14-8089-2014, 2014
I. Mariani, A. Eichler, T. M. Jenk, S. Brönnimann, R. Auchmann, M. C. Leuenberger, and M. Schwikowski
Clim. Past, 10, 1093–1108, https://doi.org/10.5194/cp-10-1093-2014, https://doi.org/10.5194/cp-10-1093-2014, 2014
A. Spolaor, J. Gabrieli, T. Martma, J. Kohler, M. B. Björkman, E. Isaksson, C. Varin, P. Vallelonga, J. M. C. Plane, and C. Barbante
The Cryosphere, 7, 1645–1658, https://doi.org/10.5194/tc-7-1645-2013, https://doi.org/10.5194/tc-7-1645-2013, 2013
T. Papina, T. Blyakharchuk, A. Eichler, N. Malygina, E. Mitrofanova, and M. Schwikowski
Clim. Past, 9, 2399–2411, https://doi.org/10.5194/cp-9-2399-2013, https://doi.org/10.5194/cp-9-2399-2013, 2013
M. Schwikowski, M. Schläppi, P. Santibañez, A. Rivera, and G. Casassa
The Cryosphere, 7, 1635–1644, https://doi.org/10.5194/tc-7-1635-2013, https://doi.org/10.5194/tc-7-1635-2013, 2013
S. Brönnimann, I. Mariani, M. Schwikowski, R. Auchmann, and A. Eichler
Clim. Past, 9, 2013–2022, https://doi.org/10.5194/cp-9-2013-2013, https://doi.org/10.5194/cp-9-2013-2013, 2013
W. J. J. van Pelt, J. Oerlemans, C. H. Reijmer, R. Pettersson, V. A. Pohjola, E. Isaksson, and D. Divine
The Cryosphere, 7, 987–1006, https://doi.org/10.5194/tc-7-987-2013, https://doi.org/10.5194/tc-7-987-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Measurement report: Characteristics of nitrogen-containing organics in PM2.5 in Ürümqi, northwestern China – differential impacts of combustion of fresh and aged biomass materials
Measurement report: Bio-physicochemistry of tropical clouds at Maïdo (Réunion, Indian Ocean): overview of results from the BIO-MAÏDO campaign
Chemical properties and single-particle mixing state of soot aerosol in Houston during the TRACER campaign
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Evaluation of the TOF-ACSM-CV for PM1.0 and PM2.5 measurements during the RITA-2021 field campaign
Sea salt reactivity over the northwest Atlantic: an in-depth look using the airborne ACTIVATE dataset
Measurement report: Atmospheric ice nuclei in the Changbai Mountains (2623 m a.s.l.) in northeastern Asia
Morphological and optical properties of carbonaceous aerosol particles from ship emissions and biomass burning during a summer cruise measurement in the South China Sea
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Tropical tropospheric aerosol sources and chemical composition observed at high altitude in the Bolivian Andes
Chemical composition, sources and formation mechanism of urban PM2.5 in Southwest China: a case study at the beginning of 2023
Chemical characterization of atmospheric aerosols at a high-altitude mountain site: a study of source apportionment
Composition and sources of carbonaceous aerosol in the European Arctic at Zeppelin Observatory, Svalbard (2017 to 2020)
Measurement Report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments
Elucidating the mechanisms of atmospheric new particle formation in the highly polluted Po Valley, Italy
Water-insoluble organic carbon in PM2.5 over China: light-absorbing properties, potential sources, radiative forcing effects and possible light-absorbing continuum
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic on Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Local ship speed reduction effect on black carbon emissions measured at remote marine station
Roles of marine biota in the formation of atmospheric bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the North Pacific Ocean, Bering Sea, and Arctic Ocean
Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study
Fractional solubility of iron in mineral dust aerosols over coastal Namibia: a link to marine biogenic emissions?
Real-world observations of reduced nitrogen and ultrafine particles in commercial cooking organic aerosol emissions
Source apportionment of PM2.5 in Montréal, Canada, and health risk assessment for potentially toxic elements
Physicochemical and temporal characteristics of individual atmospheric aerosol particles in urban Seoul during KORUS-AQ campaign: insights from single-particle analysis
Mass spectrometric analysis of unprecedented high levels of carbonaceous aerosol particles long-range transported from wildfires in the Siberian Arctic
Short-term source apportionment of fine particulate matter with time-dependent profiles using SoFi Pro: exploring the reliability of rolling positive matrix factorization (PMF) applied to bihourly molecular and elemental tracer data
Particulate-bound alkyl nitrate pollution and formation mechanisms in Beijing, China
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – A short-term case study in Beijing
Characterization of water-soluble brown carbon chromophores from wildfire plumes in the western USA using size-exclusion chromatography
Marine carbohydrates in Arctic aerosol particles and fog – diversity of oceanic sources and atmospheric transformations
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 1: Observational data analysis
Measurement report: Brown carbon aerosol in polluted urban air of the North China Plain – day–night differences in the chromophores and optical properties
Measurement report: Secondary organic aerosols at a forested mountain site in southeastern China
Source apportionment of soot particles and aqueous-phase processing of black carbon coatings in an urban environment
Seasonal variations in composition and sources of atmospheric ultrafine particles in urban Beijing based on near-continuous measurements
Summertime response of ozone and fine particulate matter to mixing layer meteorology over the North China Plain
Trace elements in PM2.5 aerosols in East Asian outflow in the spring of 2018: emission, transport, and source apportionment
Measurement Report: Investigation on the sources and formation processes of dicarboxylic acids and related species in urban aerosols before and during the COVID-19 lockdown in Jinan, East China
pH dependence of brown-carbon optical properties in cloud water
Oxidative potential in rural, suburban and city centre atmospheric environments in central Europe
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
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Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
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The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
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The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
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We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Yi-Jia Ma, Yu Xu, Ting Yang, Hong-Wei Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 24, 4331–4346, https://doi.org/10.5194/acp-24-4331-2024, https://doi.org/10.5194/acp-24-4331-2024, 2024
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This study provides field-based evidence about the differential impacts of combustion of fresh and aged biomass materials on aerosol nitrogen-containing organic compounds (NOCs) in different seasons in Ürümqi, bridging the linkages between the observations and previous laboratory studies showing the formation mechanisms of NOCs.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Ryan N. Farley, James E. Lee, Laura-Hélèna Rivellini, Alex K. Y. Lee, Rachael Dal Porto, Christopher D. Cappa, Kyle Gorkowski, Abu Sayeed Md Shawon, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey, and Qi Zhang
Atmos. Chem. Phys., 24, 3953–3971, https://doi.org/10.5194/acp-24-3953-2024, https://doi.org/10.5194/acp-24-3953-2024, 2024
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The black carbon aerosol composition and mixing state were characterized using a soot particle aerosol mass spectrometer. Single-particle measurements revealed the major role of atmospheric processing in modulating the black carbon mixing state. A significant fraction of soot particles were internally mixed with oxidized organic aerosol and sulfate, with implications for activation as cloud nuclei.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
EGUsphere, https://doi.org/10.5194/egusphere-2024-736, https://doi.org/10.5194/egusphere-2024-736, 2024
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The water solubility of secondary organic aerosols (SOA) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOA with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Xinya Liu, Bas Henzing, Arjan Hensen, Jan Mulder, Peng Yao, Danielle van Dinther, Jerry van Bronckhorst, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 3405–3420, https://doi.org/10.5194/acp-24-3405-2024, https://doi.org/10.5194/acp-24-3405-2024, 2024
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We evaluated the time-of-flight aerosol chemical speciation monitor (TOF-ACSM) following the implementation of the PM2.5 aerodynamic lens and a capture vaporizer (CV). The results showed that it significantly improved the accuracy and precision of ACSM in the field observations. The paper elucidates the measurement outcomes of various instruments and provides an analysis of their biases. This comprehensive evaluation is expected to benefit the ACSM community and other aerosol field measurements.
Eva-Lou Edwards, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Claire E. Robinson, Michael A. Shook, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 3349–3378, https://doi.org/10.5194/acp-24-3349-2024, https://doi.org/10.5194/acp-24-3349-2024, 2024
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We investigate Cl− depletion in sea salt particles over the northwest Atlantic from December 2021 to June 2022 using an airborne dataset. Losses of Cl− are greatest in May and least in December–February and March. Inorganic acidic species can account for all depletion observed for December–February, March, and June near Bermuda but none in May. Quantifying Cl− depletion as a percentage captures seasonal trends in depletion but fails to convey the effects it may have on atmospheric oxidation.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Cuizhi Sun, Yongyun Zhang, Baoling Liang, Min Gao, Xi Sun, Fei Li, Xue Ni, Qibin Sun, Hengjia Ou, Dexian Chen, Shengzhen Zhou, and Jun Zhao
Atmos. Chem. Phys., 24, 3043–3063, https://doi.org/10.5194/acp-24-3043-2024, https://doi.org/10.5194/acp-24-3043-2024, 2024
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In a May–June 2021 expedition in the South China Sea, we analyzed black and brown carbon in marine aerosols, key to light absorption and climate impact. Using advanced in situ and microscope techniques, we observed particle size, structure, and tar balls mixed with various elements. Results showed biomass burning and fossil fuels majorly influence light absorption, especially during significant burning events. This research aids the understanding of carbonaceous aerosols' role in marine climate.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
EGUsphere, https://doi.org/10.5194/egusphere-2024-37, https://doi.org/10.5194/egusphere-2024-37, 2024
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Targeted derivatization and non-targeted analysis with FT-ICR MS were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in the real samples.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Elena Barbaro, Matteo Feltracco, Fabrizio De Blasi, Clara Turetta, Marta Radaelli, Warren Cairns, Giulio Cozzi, Giovanna Mazzi, Marco Casula, Jacopo Gabrieli, Carlo Barbante, and Andrea Gambaro
Atmos. Chem. Phys., 24, 2821–2835, https://doi.org/10.5194/acp-24-2821-2024, https://doi.org/10.5194/acp-24-2821-2024, 2024
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The study analyzed a year of atmospheric aerosol composition at Col Margherita in the Italian Alps. Over 100 chemical markers were identified, including major ions, organic compounds, and trace elements. It revealed sources of aerosol, highlighted impacts of Saharan dust events, and showed anthropogenic pollution's influence despite the site's remoteness. Enrichment factors emphasized non-natural sources of trace elements. Source apportionment identified four key factors affecting the area.
Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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We discuss carbonaceous aerosol (CA) observed at the high Arctic Zeppelin Observatory (2017 to 2020). We find that organic aerosol is a significant fraction of the Arctic aerosol, though less than sea salt aerosol and mineral dust, as well as non-sea-salt sulfate, originating mainly from anthropogenic sources in winter and from natural sources in summer, emphasizing the importance of wildfires for biogenic secondary organic aerosol and primary biological aerosol particles observed in the Arctic.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O’Dowd
EGUsphere, https://doi.org/10.5194/egusphere-2024-573, https://doi.org/10.5194/egusphere-2024-573, 2024
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The chemical composition of atmospheric particles showed significant changes in recent years. We investigated the potential effects of inorganics changes on aerosol water uptake and thus secondary organic aerosol formation in wintertime haze, based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, Northwest China. This study highlights the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Wei Huang, Cheng Wu, Linyu Gao, Yvette Gramlich, Sophie L. Haslett, Joel Thornton, Felipe D. Lopez-Hilfiker, Ben H. Lee, Junwei Song, Harald Saathoff, Xiaoli Shen, Ramakrishna Ramisetty, Sachchida N. Tripathi, Dilip Ganguly, Feng Jiang, Magdalena Vallon, Siegfried Schobesberger, Taina Yli-Juuti, and Claudia Mohr
Atmos. Chem. Phys., 24, 2607–2624, https://doi.org/10.5194/acp-24-2607-2024, https://doi.org/10.5194/acp-24-2607-2024, 2024
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We present distinct molecular composition and volatility of oxygenated organic aerosol particles in different rural, urban, and mountain environments. We do a comprehensive investigation of the relationship between the chemical composition and volatility of oxygenated organic aerosol particles across different systems and environments. This study provides implications for volatility descriptions of oxygenated organic aerosol particles in different model frameworks.
Jing Cai, Juha Sulo, Yifang Gu, Sebastian Holm, Runlong Cai, Steven Thomas, Almuth Neuberger, Fredrik Mattsson, Marco Paglione, Stefano Decesari, Matteo Rinaldi, Rujing Yin, Diego Aliaga, Wei Huang, Yuanyuan Li, Yvette Gramlich, Giancarlo Ciarelli, Lauriane Quéléver, Nina Sarnela, Katrianne Lehtipalo, Nora Zannoni, Cheng Wu, Wei Nie, Juha Kangasluoma, Claudia Mohr, Markku Kulmala, Qiaozhi Zha, Dominik Stolzenburg, and Federico Bianchi
Atmos. Chem. Phys., 24, 2423–2441, https://doi.org/10.5194/acp-24-2423-2024, https://doi.org/10.5194/acp-24-2423-2024, 2024
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By combining field measurements, simulations and recent chamber experiments, we investigate new particle formation (NPF) and growth in the Po Valley, where both haze and frequent NPF occur. Our results show that sulfuric acid, ammonia and amines are the dominant NPF precursors there. A high NPF rate and a lower condensation sink lead to a greater survival probability for newly formed particles, highlighting the importance of gas-to-particle conversion for aerosol concentrations.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-130, https://doi.org/10.5194/egusphere-2024-130, 2024
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In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %), were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibited the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
EGUsphere, https://doi.org/10.5194/egusphere-2024-11, https://doi.org/10.5194/egusphere-2024-11, 2024
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To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate at Barbados and compared to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions of sulfur dioxide (SO2) in the U.S. and Europe, then increased in the 2000s due to anthropogenic emissions from Africa and more efficient oxidation of SO2.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
EGUsphere, https://doi.org/10.5194/egusphere-2023-2823, https://doi.org/10.5194/egusphere-2023-2823, 2024
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Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams/kilograms fuel. Ships using exhaust gas cleaning systems (EGCS) were found to emit 80 % less BC than ships without EGCS. Emission factors were used to model BC emissions as a function of speed to define the effect of speed reduction. BC emissions increased with a decrease in speed from the ship’s service speed.
Kaori Kawana, Fumikazu Taketani, Kazuhiko Matsumoto, Yutaka Tobo, Yoko Iwamoto, Takuma Miyakawa, Akinori Ito, and Yugo Kanaya
Atmos. Chem. Phys., 24, 1777–1799, https://doi.org/10.5194/acp-24-1777-2024, https://doi.org/10.5194/acp-24-1777-2024, 2024
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Based on comprehensive shipborne observations, we found strong links between sea-surface biological materials and the formation of atmospheric fluorescent bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the Arctic Ocean and Bering Sea during autumn 2019. Taking the wind-speed effect into account, we propose equations to approximate the links for this cruise, which can be used as a guide for modeling as well as for systematic comparisons with other observations.
Chen He, Hanxiong Che, Zier Bao, Yiliang Liu, Qing Li, Miao Hu, Jiawei Zhou, Shumin Zhang, Xiaojiang Yao, Quan Shi, Chunmao Chen, Yan Han, Lingshuo Meng, Xin Long, Fumo Yang, and Yang Chen
Atmos. Chem. Phys., 24, 1627–1639, https://doi.org/10.5194/acp-24-1627-2024, https://doi.org/10.5194/acp-24-1627-2024, 2024
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We examined the daily evolution of high molecular-weight organic compounds with a molecular weight of up to 1000 Da in order to comprehend their behaviors in the atmosphere under actual conditions. These compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and nighttime chemistry.
Karine Desboeufs, Paola Formenti, Raquel Torres-Sánchez, Kerstin Schepanski, Jean-Pierre Chaboureau, Hendrik Andersen, Jan Cermak, Stefanie Feuerstein, Benoit Laurent, Danitza Klopper, Andreas Namwoonde, Mathieu Cazaunau, Servanne Chevaillier, Anaïs Feron, Cécile Mirande-Bret, Sylvain Triquet, and Stuart J. Piketh
Atmos. Chem. Phys., 24, 1525–1541, https://doi.org/10.5194/acp-24-1525-2024, https://doi.org/10.5194/acp-24-1525-2024, 2024
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This study investigates the fractional solubility of iron (Fe) in dust particles along the coast of Namibia, a critical region for the atmospheric Fe supply of the South Atlantic Ocean. Our results suggest a possible two-way interplay whereby marine biogenic emissions from the coastal marine ecosystems into the atmosphere would increase the solubility of Fe-bearing dust by photo-reduction processes. The subsequent deposition of soluble Fe could act to further enhance marine biogenic emissions.
Sunhye Kim, Jo Machesky, Drew R. Gentner, and Albert A. Presto
Atmos. Chem. Phys., 24, 1281–1298, https://doi.org/10.5194/acp-24-1281-2024, https://doi.org/10.5194/acp-24-1281-2024, 2024
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Cooking emissions are often an overlooked source of air pollution. We used a mobile lab to measure the characteristics of particles emitted from cooking sites in two cities. Our findings showed that cooking releases a substantial number of fine particles. While most emissions were similar, a bakery site showed distinctive chemical compositions with higher nitrogen compound levels. Thus, understanding the particle emissions from different cooking activities is crucial.
Nansi Fakhri, Robin Stevens, Arnold Downey, Konstantina Oikonomou, Jean Sciare, Charbel Afif, and Patrick L. Hayes
Atmos. Chem. Phys., 24, 1193–1212, https://doi.org/10.5194/acp-24-1193-2024, https://doi.org/10.5194/acp-24-1193-2024, 2024
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We investigated the chemical composition of atmospheric fine particles, their emission sources, and the potential human health risk associated with trace elements in particles for an urban site in Montréal over a 3-month period (August–November). This study represents the first time that such extensive composition measurements were included in an urban source apportionment study in Canada, and it provides greater resolution of fine-particle sources than has been previously achieved in Canada.
Hanjin Yoo, Li Wu, Hong Geng, and Chul-Un Ro
Atmos. Chem. Phys., 24, 853–867, https://doi.org/10.5194/acp-24-853-2024, https://doi.org/10.5194/acp-24-853-2024, 2024
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We conducted an investigation of atmospheric aerosols collected in Seoul, South Korea, during the KORUS-AQ campaign on a single-particle basis. We were able to identify their sources, the atmospheric fate, and the impacts of local emissions and long-range transport on aerosol composition. Additionally, we traced potential sources of non-exhaust heavy-metal particles. This comprehensive analysis provides valuable insights into the complex dynamics of urban aerosols.
Eric Schneider, Hendryk Czech, Olga Popovicheva, Marina Chichaeva, Vasily Kobelev, Nikolay Kasimov, Tatiana Minkina, Christopher Paul Rüger, and Ralf Zimmermann
Atmos. Chem. Phys., 24, 553–576, https://doi.org/10.5194/acp-24-553-2024, https://doi.org/10.5194/acp-24-553-2024, 2024
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This study provides insights into the complex chemical composition of long-range-transported wildfire plumes from Yakutia, which underwent different levels of atmospheric processing. With complementary mass spectrometric techniques, we improve our understanding of the chemical processes and atmospheric fate of wildfire plumes. Unprecedented high levels of carbonaceous aerosols crossed the polar circle with implications for the Arctic ecosystem and consequently climate.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yusen Duan, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 475–486, https://doi.org/10.5194/acp-24-475-2024, https://doi.org/10.5194/acp-24-475-2024, 2024
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We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 d during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Jiyuan Yang, Guoyang Lei, Jinfeng Zhu, Yutong Wu, Chang Liu, Kai Hu, Junsong Bao, Zitong Zhang, Weili Lin, and Jun Jin
Atmos. Chem. Phys., 24, 123–136, https://doi.org/10.5194/acp-24-123-2024, https://doi.org/10.5194/acp-24-123-2024, 2024
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The atmospheric pollution and formation mechanisms of particulate-bound alkyl nitrate in Beijing were studied. C9–C16 long-chain n-alkyl nitrates negatively correlated with O3 but positively correlated with PM2.5 and NO2, so they may not be produced during gas-phase homogeneous reactions in the photochemical process but form through reactions between alkanes and nitrates on PM surfaces. Particulate-bound n-alkyl nitrates strongly affect both haze pollution and atmospheric visibility.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-2703, https://doi.org/10.5194/egusphere-2023-2703, 2024
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Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROS) play an active role in the atmosphere. We quantified the impact of control measures on EPFRs and ROS and found that strict control measures have effectively reduced their emissions, largely linked to a significant decrease in secondary aerosols. Our findings have great implications for further understanding the formation and sources and for developing future air quality management policies targeting EPFRs and ROS.
Lisa Azzarello, Rebecca A. Washenfelder, Michael A. Robinson, Alessandro Franchin, Caroline C. Womack, Christopher D. Holmes, Steven S. Brown, Ann Middlebrook, Tim Newberger, Colm Sweeney, and Cora J. Young
Atmos. Chem. Phys., 23, 15643–15654, https://doi.org/10.5194/acp-23-15643-2023, https://doi.org/10.5194/acp-23-15643-2023, 2023
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We present a molecular size-resolved offline analysis of water-soluble brown carbon collected on an aircraft during FIREX-AQ. The smoke plumes were aged 0 to 5 h, where absorption was dominated by small molecular weight molecules, brown carbon absorption downwind did not consistently decrease, and the measurements differed from online absorption measurements of the same samples. We show how differences between online and offline absorption could be related to different measurement conditions.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 15561–15587, https://doi.org/10.5194/acp-23-15561-2023, https://doi.org/10.5194/acp-23-15561-2023, 2023
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Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles, and potentially contribute to the formation of fog and clouds. Here, we present the results of a sea–air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Xing Wei, Yanjie Shen, Xiao-Ying Yu, Yang Gao, Huiwang Gao, Ming Chu, Yujiao Zhu, and Xiaohong Yao
Atmos. Chem. Phys., 23, 15325–15350, https://doi.org/10.5194/acp-23-15325-2023, https://doi.org/10.5194/acp-23-15325-2023, 2023
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We investigate the contribution of grown new particles to Nccn at a rural mountain site in the North China Plain. The total particle number concentrations (Ncn) observed on 8 new particle formation (NPF) days were higher compared to non-NPF days. The Nccn at 0.2 % supersaturation (SS) and 0.4 % SS on the NPF days was significantly lower than on non-NPF days. Only one of eight NPF events had detectable net contributions to Nccn at 0.4 % SS and 1.0 % SS with increased κ values.
Yuquan Gong, Ru-Jin Huang, Lu Yang, Ting Wang, Wei Yuan, Wei Xu, Wenjuan Cao, Yang Wang, and Yongjie Li
Atmos. Chem. Phys., 23, 15197–15207, https://doi.org/10.5194/acp-23-15197-2023, https://doi.org/10.5194/acp-23-15197-2023, 2023
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This study reveals the large day–night differences in brown carbon (BrC) chromophore composition, which was not known previously. The results provide insights into the effects of atmospheric processes and emissions on BrC composition.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyang Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
EGUsphere, https://doi.org/10.5194/egusphere-2023-2684, https://doi.org/10.5194/egusphere-2023-2684, 2023
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We investigated aerosol composition, sources, and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more-oxidized SOA; however, cloud evaporation leads to the production of less-oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Ryan N. Farley, Sonya Collier, Christopher D. Cappa, Leah R. Williams, Timothy B. Onasch, Lynn M. Russell, Hwajin Kim, and Qi Zhang
Atmos. Chem. Phys., 23, 15039–15056, https://doi.org/10.5194/acp-23-15039-2023, https://doi.org/10.5194/acp-23-15039-2023, 2023
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Soot particles, also known as black carbon (BC), have important implications for global climate and regional air quality. After the particles are emitted, BC can be coated with other material, impacting the aerosol properties. We selectively measured the composition of particles containing BC to explore their sources and chemical transformations in the atmosphere. We focus on a persistent, multiday fog event in order to study the effects of chemical reactions occurring within liquid droplets.
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023, https://doi.org/10.5194/acp-23-14801-2023, 2023
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Near-continuous measurements show the composition, sources, and seasonal variations of ultrafine particles (UFPs) in urban Beijing. Vehicle and cooking emissions and new particle formation are the main sources of UFPs, and aqueous/heterogeneous processes increase UFP mode diameters. UFPs are the highest in winter due to the highest primary particle emission rates and new particle formation rates, and CHO fractions are the highest in summer due to the strongest photooxidation.
Jiaqi Wang, Jian Gao, Fei Che, Xin Yang, Yuanqin Yang, Lei Liu, Yan Xiang, and Haisheng Li
Atmos. Chem. Phys., 23, 14715–14733, https://doi.org/10.5194/acp-23-14715-2023, https://doi.org/10.5194/acp-23-14715-2023, 2023
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Regional-scale observations of surface O3, PM2.5 and its major chemical species, mixing layer height (MLH), and other meteorological parameters were made in the North China Plain during summer. Unlike the cold season, synchronized increases in MDA8 O3 and PM2.5 under medium MLH conditions have been witnessed. The increasing trend of PM2.5 was associated with enhanced secondary chemical formation. The correlation between MLH and secondary air pollutants should be treated with care in hot seasons.
Takuma Miyakawa, Akinori Ito, Chunmao Zhu, Atsushi Shimizu, Erika Matsumoto, Yusuke Mizuno, and Yugo Kanaya
Atmos. Chem. Phys., 23, 14609–14626, https://doi.org/10.5194/acp-23-14609-2023, https://doi.org/10.5194/acp-23-14609-2023, 2023
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This study conducted semi-continuous measurements of PM2.5 aerosols and their elemental composition in western Japan, during spring 2018. It analyzed the emissions, transport, and wet removal of elements such as Pb, Cu, Fe, and Mn. It also assessed the accuracy of modeled concentrations and found overestimations of BC and underestimations of Cu and anthropogenic Fe in East Asia. Insights into emissions, removals, and source apportionment of trace metals in the East Asian outflow were provided.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
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This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Christopher J. Hennigan, Michael McKee, Vikram Pratap, Bryanna Boegner, Jasper Reno, Lucia Garcia, Madison McLaren, and Sara M. Lance
Atmos. Chem. Phys., 23, 14437–14449, https://doi.org/10.5194/acp-23-14437-2023, https://doi.org/10.5194/acp-23-14437-2023, 2023
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This study characterized the optical properties of light-absorbing organic compounds, called brown carbon (BrC), in atmospheric cloud water samples. In all samples, light absorption by BrC increased linearly with increasing pH. There was variability in the sensitivity of the absorption–pH relationship, depending on the degree of influence from fire emissions. Overall, these results show that the climate forcing of BrC is quite strongly affected by its pH-dependent absorption.
Máté Vörösmarty, Gaëlle Uzu, Jean-Luc Jaffrezo, Pamela Dominutti, Zsófia Kertész, Enikő Papp, and Imre Salma
Atmos. Chem. Phys., 23, 14255–14269, https://doi.org/10.5194/acp-23-14255-2023, https://doi.org/10.5194/acp-23-14255-2023, 2023
Short summary
Short summary
Poor air quality caused by high concentrations of particulate matter is one of the most severe public health concerns for humans worldwide. One of the most important biological mechanisms inducing adverse health effects is the oxidant–antioxidant imbalance. We showed that the oxidative stress changed substantially and in a complex manner with location and season. Biomass burning exhibited the dominant influence, while motor vehicles played an important role in the non-heating period.
Cited articles
Abram, N. J., Wolff, E. W., and Curran, M. A. J.: A review of sea ice proxy information from polar ice cores, Quaternary Sci. Rev., 79, 168–183, https://doi.org/10.1016/j.quascirev.2013.01.011, 2013.
Adams, P. J., Seinfeld, J. H., and Koch, D. M.: Global concentrations of tropospheric sulfate, nitrate, and ammonium aerosol simulated in a general circulation model, J. Geophys. Res.-Atmos., 104, 13791–13823, https://doi.org/10.1029/1999JD900083, 1999.
Baltensperger, U., Schwikowski, M., Gäggeler, H. W., Jost, D. T., Beer, J., Siegenthaler, U., Wagenbach, D., Hofmann, H. J., and Synal, H. A.: Transfer of atmospheric constituents into an alpine snow field, Atmos. Environ. A-Gen., 27, 1881–1890, https://doi.org/10.1016/0960-1686(93)90293-8, 1993.
Beaudon, E., Moore, J. C., Martma, T., Pohjola, V. A., Van De Wal, R. S. W., Kohler, J., and Isaksson, E.: Lomonosovfonna and Holtedahlfonna ice cores reveal east–west disparities of the Spitsbergen environment since AD 1700, J. Glaciol., 59, 1069–1083, https://doi.org/10.3189/2013JoG12J203, 2013.
Becagli, S., Castellano, E., Cerri, O., Curran, M., Frezzotti, M., Marino, F., Morganti, A., Proposito, M., Severi, M., and Traversi, R.: Methanesulphonic acid (MSA) stratigraphy from a Talos Dome ice core as a tool in depicting sea ice changes and southern atmospheric circulation over the previous 140 years, Atmos. Environ., 43, 1051–1058, 2009.
Beine, H. J., Dominè, F., Ianniello, A., Nardino, M., Allegrini, I., Teinilä, K., and Hillamo, R.: Fluxes of nitrates between snow surfaces and the atmosphere in the European high Arctic, Atmos. Chem. Phys., 3, 335–346, https://doi.org/10.5194/acp-3-335-2003, 2003.
Bergin, M. H., Jaffrezo, J.-L., Davidson, C. I., Dibb, J. E., Pandis, S. N., Hillamo, R., Maenhaut, W., Kuhns, H. D., and Makela, T.: The contributions of snow, fog, and dry deposition to the summer flux of anions and cations at Summit, Greenland, J. Geophys. Res.-Atmos., 100, 16275–16288, https://doi.org/10.1029/95JD01267, 1995.
Björkman, M. P., Kühnel, R., Partridge, D. G., Roberts, T. J., Aas, W., Mazzola, M., Viola, A., Hodson, A., Ström, J. and Isaksson, E.: Nitrate dry deposition in Svalbard, Tellus B, 65, 19071, https://doi.org/10.3402/tellusb.v65i0.19071, 2013.
Brimblecombe, P., Tranter, M., Abrahams, P. W., Blackwood, I., Davies, T. D., and Vincent, C. E.: Relocation and preferential elution of acidic solute through the snowpack of a small, remote, high-altitude Scottish catchment, Ann. Glaciol., 7, 141–147, 1985.
Chester, R. and Jickells, T. D.: Marine Geochemistry, John Wiley & Sons, Chichester, West Sussex, UK, 2012.
Codispoti, L. A., Kelly, V., Thessen, A., Matrai, P., Suttles, S., Hill, V., Steele, M., and Light, B.: Synthesis of primary production in the Arctic Ocean: III. Nitrate and phosphate based estimates of net community production, Prog. Oceanogr., 110, 126–150, https://doi.org/10.1016/j.pocean.2012.11.006, 2013.
Dickerson, R. R.: Reactive nitrogen compounds in the Arctic, J. Geophys. Res.-Atmos., 90, 10739–10743, https://doi.org/10.1029/JD090iD06p10739, 1985.
Divine, D. V. and Dick, C.: Historical variability of sea ice edge position in the Nordic Seas, J. Geophys. Res.-Oceans, 111, C01001, https://doi.org/10.1029/2004JC002851, 2006.
Divine, D. V., Isaksson, E., Martma, T., Meijer, H. A., Moore, J., Pohjola, V., van de Wal, R. S. W., and Godtliebsen, F.: Thousand years of winter surface air temperature variations in Svalbard and northern Norway reconstructed from ice core data, Polar Res., 30, 7379, https://doi.org/10.3402/polar.v30i0.7379, 2011.
Döscher, A., Gäggeler, H. W., Schotterer, U., and Schwikowski, M.: A historical record of ammonium concentrations from a glacier in the Alps, Geophys. Res. Lett., 23, 2741–2744, 1996.
Duce, R. A., LaRoche, J., Altieri, K., Arrigo, K. R., Baker, A. R., Capone, D. G., Cornell, S., Dentener, F., Galloway, J., Ganeshram, R. S., Geider, R. J., Jickells, T., Kuypers, M. M., Langlois, R., Liss, P. S., Liu, S. M., Middelburg, J. J., Moore, C. M., Nickovic, S., Oschlies, A., Pedersen, T., Prospero, J., Schlitzer, R., Seitzinger, S., Sorensen, L. L., Uematsu, M., Ulloa, O., Voss, M., Ward, B., and Zamora, L.: Impacts of atmospheric anthropogenic nitrogen on the open ocean, Science, 320, 893–897, https://doi.org/10.1126/science.1150369, 2008.
Eichler, A., Schwikowski, M., Gäggeler, H. W., Furrer, V., Synal, H.-A., Beer, J., Saurer, M., and Funk, M.: Glaciochemical dating of an ice core from upper Grenzgletscher (4200 m a.s.l.), J. Glaciol., 46, 507–515, https://doi.org/10.3189/172756500781833098, 2000.
Eichler, A., Schwikowski, M., and Gäggeler, H. W.: Meltwater-induced relocation of chemical species in Alpine firn, Tellus B, 53, 192–203, 2001.
Eichler, A., Brütsch, S., Olivier, S., Papina, T., and Schwikowski, M.: A 750 year ice core record of past biogenic emissions from Siberian boreal forests, Geophys. Res. Lett., 36, L18813, https://doi.org/10.1029/2009GL038807, 2009.
Eichler, A., Tinner, W., Brütsch, S., Olivier, S., Papina, T., and Schwikowski, M.: An ice-core based history of Siberian forest fires since AD 1250, Quaternary Sci. Rev., 30, 1027–1034, https://doi.org/10.1016/j.quascirev.2011.02.007, 2011.
Eleftheriadis, K., Vratolis, S., and Nyeki, S.: Aerosol black carbon in the European Arctic: measurements at Zeppelin station, Ny-Ålesund, Svalbard from 1998–2007, Geophys. Res. Lett., 36, L02809, https://doi.org/10.1029/2008GL035741, 2009.
Eneroth, K., Kjellström, E., and Holmén, K.: A trajectory climatology for Svalbard; investigating how atmospheric flow patterns influence observed tracer concentrations, Phys. Chem. Earth, 28, 1191–1203, 2003.
Feng, Y. and Penner, J. E.: Global modeling of nitrate and ammonium: Interaction of aerosols and tropospheric chemistry, J. Geophys. Res.-Atmos., 112, D01304, https://doi.org/10.1029/2005JD006404, 2007.
Fibiger, D. L., Hastings, M. G., Dibb, J. E., and Huey, L. G.: The preservation of atmospheric nitrate in snow at Summit, Greenland, Geophys. Res. Lett., 40, 3484–3489, https://doi.org/10.1002/grl.50659, 2013.
Fischer, H., Wagenbach, D., and Kipfstuhl, J.: Sulfate and nitrate firn concentrations on the Greenland ice sheet: 2. Temporal anthropogenic deposition changes, J. Geophys. Res.–Atmos., 103, 21935–21942, https://doi.org/10.1029/98JD01886, 1998.
Forsström, S., Ström, J., Pedersen, C. A., Isaksson, E., and Gerland, S.: Elemental carbon distribution in Svalbard snow, J. Geophys. Res.-Atmos., 114, D19112, https://doi.org/10.1029/2008JD011480, 2009.
Fuhrer, K., Neftel, A., Anklin, M., Staffelbach, T., and Legrand, M.: High-resolution ammonium ice core record covering a complete glacial-interglacial cycle, J. Geophys. Res.-Atmos., 101, 4147–4164, https://doi.org/10.1029/95JD02903, 1996.
Galloway, J. N., Dentener, F. J., Capone, D. G., Boyer, E. W., Howarth, R. W., Seitzinger, S. P., Asner, G. P., Cleveland, C. C., Green, P. A., Holland, E. A., Karl, D. M., Michaels, A. F., Porter, J. H., Townsend, A. R., and Vöosmarty, C. J.: Nitrogen cycles: Past, present, and future, Biogeochemistry, 70, 153–226, https://doi.org/10.1007/s10533-004-0370-0, 2004.
Geng, H., Ryu, J. Y., Jung, H. J., Chung, H., Ahn, K. H., and Ro, C. U.: Single-particle characterization of summertime Arctic aerosols collected at Ny-Ålesund, Svalbard, Environ. Sci. Technol., 44, 2348–2353, 2010.
Geng, L., Alexander, B., Cole-Dai, J., Steig, E. J., Savarino, J., Sofen, E. D., and Schauer, A. J.: Nitrogen isotopes in ice core nitrate linked to anthropogenic atmospheric acidity change, P. Natl. Acad. Sci. USA, 111, 5808–5812, https://doi.org/10.1073/pnas.1319441111, 2014.
Ginot, P., Stampfli, F., Stampfli, D., Schwikowski, M., and Gäggeler, H. W.: FELICS, a new ice core drilling system for high-altitude glaciers, Mem. Natl. Inst. Polar Res. Spec. Issue, 56, 38–48, 2002.
Ginot, P., Schotterer, U., Stichler, W., Godoi, M. A., Francou, B., and Schwikowski, M.: Influence of the Tungurahua eruption on the ice core records of Chimborazo, Ecuador, The Cryosphere, 4, 561–568, https://doi.org/10.5194/tc-4-561-2010, 2010.
Goto-Azuma, K. and Koerner, R. M.: Ice core studies of anthropogenic sulfate and nitrate trends in the Arctic, J. Geophys. Res., 106, 4959–4969, 2001.
Greenaway, K. R.: Experience with Arctic flying weather, Royal Meteorological Society, Canadian Branch, Toronto, Canada, 1950.
Hastings, M. G., Steig, E. J., and Sigman, D. M.: Seasonal variations in N and O isotopes of nitrate in snow at Summit, Greenland: Implications for the study of nitrate in snow and ice cores, J. Geophys. Res.-Atmos., 109, 1984–2012, 2004.
Henderson, K., Laube, A., Gäggeler, H. W., Olivier, S., Papina, T., and Schwikowski, M.: Temporal variations of accumulation and temperature during the past two centuries from Belukha ice core, Siberian Altai, J. Geophys. Res., 111, D03104, https://doi.org/10.1029/2005JD005819, 2006.
Hicks, S. and Isaksson, E.: Assessing source areas of pollutants from studies of fly ash, charcoal, and pollen from Svalbard snow and ice, J. Geophys. Res.-Atmos., 111, D02113, https://doi.org/10.1029/2005JD006167, 2006.
Hirdman, D., Sodemann, H., Eckhardt, S., Burkhart, J. F., Jefferson, A., Mefford, T., Quinn, P. K., Sharma, S., Ström, J., and Stohl, A.: Source identification of short-lived air pollutants in the Arctic using statistical analysis of measurement data and particle dispersion model output, Atmos. Chem. Phys., 10, 669–693, https://doi.org/10.5194/acp-10-669-2010, 2010a.
Hirdman, D., Burkhart, J. F., Sodemann, H., Eckhardt, S., Jefferson, A., Quinn, P. K., Sharma, S., Ström, J., and Stohl, A.: Long-term trends of black carbon and sulphate aerosol in the Arctic: changes in atmospheric transport and source region emissions, Atmos. Chem. Phys., 10, 9351–9368, https://doi.org/10.5194/acp-10-9351-2010, 2010b.
Honrath, R. E., Peterson, M. C., Guo, S., Dibb, J. E., Shepson, P. B., and Campbell, B.: Evidence of NOx production within or upon ice particles in the Greenland snowpack, Geophys. Res. Lett., 26, 695–698, https://doi.org/10.1029/1999GL900077, 1999.
Isaksson, E., Pohjola, V., Jauhiainen, T., Moore, J., Pinglot, J. F., Vaikmaae, R., van de Wal, R. S. W., Hagen, J. O., Ivask, J., Karlöf, L., Martma, T., Meijer, H. A., Mulvaney, R., Thomassen, M., and van den Broeke, M.: A new ice-core record from Lomonosovfonna, Svalbard: viewing the 1920–97 data in relation to present climate and environmental conditions, J. Glaciol., 47, 335–345, 2001.
Isaksson, E., Kekonen, T., Moore, J., and Mulvaney, R.: The methanesulfonic acid (MSA) record in a Svalbard ice core, Ann. Glaciol., 42, 345–351, 2005.
Jauhiainen, T., Moore, J., Perämäki, P., Derome, J., and Derome, K.: Simple procedure for ion chromatographic determination of anions and cations at trace levels in ice core samples, Anal. Chim. Acta, 389, 21–29, 1999.
Kaufmann, P., Fundel, F., Fischer, H., Bigler, M., Ruth, U., Udisti, R., Hansson, M., de Angelis, M., Barbante, C., Wolff, E. W., Hutterli, M., and Wagenbach, D.: Ammonium and non-sea salt sulfate in the EPICA ice cores as indicator of biological activity in the Southern Ocean, Quaternary Sci. Rev., 29, 313–323, https://doi.org/10.1016/j.quascirev.2009.11.009, 2010.
Keene, W. C., Pszenny, A. A. P., Galloway, J. N., and Hawley, M. E.: Sea-salt corrections and interpretation of constituent ratios in marine precipitation, J. Geophys. Res.-Atmos., 91, 6647–6658, https://doi.org/10.1029/JD091iD06p06647, 1986.
Kehrwald, N., Zangrando, R., Gambaro, A., and Barbante, C.: Fire and climate: Biomass burning recorded in ice and lake cores, EPJ Web Conf., 9, 105–114, https://doi.org/10.1051/epjconf/201009008, 2010.
Kehrwald, N., Zangrando, R., Gabrielli, P., Jaffrezo, J.-L., Boutron, C., Barbante, C., and Gambaro, A.: Levoglucosan as a specific marker of fire events in Greenland snow, Tellus B, 64, 18196, https://doi.org/10.3402/tellusb.v64i0.18196, 2012.
Kekonen, T., Moore, J. C., Mulvaney, R., Isaksson, E., Pohjola, V., and Van De Wal, R. S. W.: A 800 year record of nitrate from the Lomonosovfonna ice core, Svalbard, Ann. Glaciol., 35, 261–265, 2002.
Kekonen, T., Moore, J., Perämäki, P., Mulvaney, R., Isaksson, E., Pohjola, V., and van de Wal, R. S. W.: The 800 year long ion record from the Lomonosovfonna (Svalbard) ice core, J. Geophys. Res., 110, D07304, https://doi.org/10.1029/2004JD005223, 2005.
Kellerhals, T., Brütsch, S., Sigl, M., Knüsel, S., Gäggeler, H. W., and Schwikowski, M.: Ammonium concentration in ice cores: A new proxy for regional temperature reconstruction?, J. Geophys. Res.-Atmos., 115, D16123, https://doi.org/10.1029/2009JD012603, 2010.
Kinnard, C., Zdanowicz, C. M., Fisher, D. A., Isaksson, E., de Vernal, A., and Thompson, L. G.: Reconstructed changes in Arctic sea ice over the past 1450 years, Nature, 479, 509–512, 2011.
Kühnel, R., Roberts, T. J., Björkman, M. P., Isaksson, E., Aas, W., Holmén, K., and Ström, J.: 20-year climatology of NO3- and NH4+ wet deposition at Ny-Ålesund, Svalbard, Adv. Meteorol., 406508, https://doi.org/10.1155/2011/406508, 2011.
Lavigne, F., Degeai, J.-P., Komorowski, J.-C., Guillet, S., Robert, V., Lahitte, P., Oppenheimer, C., Stoffel, M., Vidal, C. M., Surono, Pratomo, I., Wassmer, P., Hajdas, I., Hadmoko, D. S., and Belizal, E. de: Source of the great A.D. 1257 mystery eruption unveiled, Samalas volcano, Rinjani Volcanic Complex, Indonesia, P. Natl. Acad. Sci. USA, 110, 16742–16747, https://doi.org/10.1073/pnas.1307520110, 2013.
Law, K. S. and Stohl, A.: Arctic air pollution: Origins and impacts, Science, 315, 1537–1540, 2007.
Legrand, M.: Ice–core records of atmospheric sulphur, Philos. T. Roy. Soc. B, 352, 241–250, 1997.
Legrand, M. and De Angelis, M.: Light carboxylic acids in Greenland ice: A record of past forest fires and vegetation emissions from the boreal zone, J. Geophys. Res.-Atmos., 101, 4129–4145, 1996.
Legrand, M. and Mayewski, P.: Glaciochemistry of polar ice cores: a review, Rev. Geophys., 35, 219–244, 1997.
Legrand, M., de Angelis, M., and Delmas, R. J.: Ion chromatographic determination of common ions at ultratrace levels in Antarctic snow and ice, Anal. Chim. Acta, 156, 181–192, https://doi.org/10.1016/S0003-2670(00)85549-X, 1984.
Legrand, M., De Angelis, M., Staffelbach, T., Neftel, A., and Stauffer, B.: Large perturbations of ammonium and organic acids content in the summit-Greenland Ice Core. Fingerprint from forest fires?, Geophys. Res. Lett., 19, 473–475, https://doi.org/10.1029/91GL03121, 1992.
Legrand, M., De Angelis, M., and Maupetit, F.: Field investigation of major and minor ions along Summit (Central Greenland) ice cores by ion chromatography, J. Chromatogr. A, 640, 251–258, https://doi.org/10.1016/0021-9673(93)80188-E, 1993.
Legrand, M., Hammer, C., Angelis, M. D., Savarino, J., Delmas, R., Clausen, H., and Johnsen, S. J.: Sulfur-containing species (methanesulfonate and SO4) over the last climatic cycle in the Greenland Ice Core Project (central Greenland) ice core, J. Geophys. Res., 102, 26663–26679, https://doi.org/10.1029/97JC01436, 1997.
Legrand, M., Wolff, E., and Wagenbach, D.: Antarctic aerosol and snowfall chemistry: implications for deep Antarctic ice-core chemistry, Ann. Glaciol., 29, 66–72, https://doi.org/10.3189/172756499781821094, 1999.
Macias Fauria, M., Grinsted, A., Helama, S., Moore, J., Timonen, M., Martma, T., Isaksson, E., and Eronen, M.: Unprecedented low twentieth century winter sea ice extent in the Western Nordic Seas since AD 1200, Clim. Dyn., 34, 781–795, 2010.
Matoba, S., Narita, H., Motoyama, H., Kamiyama, K., and Watanabe, O.: Ice core chemistry of Vestfonna ice cap in Svalbard, Norway, J. Geophys. Res., 107, 4721, https://doi.org/10.1029/2002JD002205, 2002.
Moore, J. C. and Grinsted, A.: Ion Fractionation and Percolation in Ice Cores with Seasonal Melting, in Physics of Ice Core Records II, vol. 68, Institute of Low Temperature Science, Hokkaido University, Hokkaido University Press, Sapporo, Japan, 287–298, 2009.
Moore, J. C., Grinsted, A., Kekonen, T., and Pohjola, V.: Separation of melting and environmental signals in an ice core with seasonal melt, Geophys. Res. Lett., 32, L10501, https://doi.org/10.1029/2005GL023039, 2005.
Moore, J., Kekonen, T., Grinsted, A., and Isaksson, E.: Sulfate source inventories from a Svalbard ice core record spanning the Industrial Revolution, J. Geophys. Res., 111, D15307, https://doi.org/10.1029/2005JD006453, 2006.
Moore, J. C., Beaudon, E., Kang, S., Divine, D., Isaksson, E., Pohjola, V. A., and van de Wal, R. S. W.: Statistical extraction of volcanic sulphate from nonpolar ice cores, J. Geophys. Res., 117, D03306, https://doi.org/10.1029/2011JD016592, 2012.
O'Dwyer, J., Isaksson, E., Vinje, T., Jauhiainen, T., Moore, J., Pohjola, V., Vaikmae, R., and van de Wal, R. S. W.: Methanesulfonic acid in a Svalbard ice core as an indicator of ocean climate, Geophys. Res. Lett., 27, 1159–1162, 2000.
Opel, T., Fritzsche, D., and Meyer, H.: Eurasian Arctic climate over the past millennium as recorded in the Akademii Nauk ice core (Severnaya Zemlya), Clim. Past, 9, 2379–2389, https://doi.org/10.5194/cp-9-2379-2013, 2013.
Perrette, M., Yool, A., Quartly, G. D., and Popova, E. E.: Near-ubiquity of ice-edge blooms in the Arctic, Biogeosciences, 8, 515–524, https://doi.org/10.5194/bg-8-515-2011, 2011.
Pohjola, V. A., Moore, J. C., Isaksson, E., Jauhiainen, T., Van de Wal, R. S. W., Martma, T., Meijer, H. A. J., and Vaikmäe, R.: Effect of periodic melting on geochemical and isotopic signals in an ice core from Lomonosovfonna, Svalbard, J. Geophys. Res., 107, ACL 1-1–ACL 1-14, https://doi.org/10.1029/2000JD000149, 2002.
Quinn, P. K., Shaw, G., Andrews, E., Dutton, E. G., Ruoho-Airola, T., and Gong, S. L.: Arctic haze: current trends and knowledge gaps, Tellus B, 59, 99–114, 2007.
Rhodes, R. H., Bertler, N. A. N., Baker, J. A., Sneed, S. B., Oerter, H., and Arrigo, K. R.: Sea ice variability and primary productivity in the Ross Sea, Antarctica, from methylsulphonate snow record, Geophys. Res. Lett., 36, L10704, https://doi.org/10.1029/2009GL037311, 2009.
Röthlisberger, R., Hutterli, M. A., Sommer, S., Wolff, E. W., and Mulvaney, R.: Factors controlling nitrate in ice cores: Evidence from the Dome C deep ice core, J. Geophys. Res.-Atmos., 105, 20565–20572, https://doi.org/10.1029/2000JD900264, 2000.
Röthlisberger, R., Hutterli, M. A., Wolff, E. W., Mulvaney, R., Fischer, H., Bigler, M., Goto-Azuma, K., Hansson, M. E., Ruth, U., Siggaard-Andersen, M.-L., and Steffensen, J. P.: Nitrate in Greenland and Antarctic ice cores: a detailed description of post-depositional processes, Ann. Glaciol., 35, 209–216, https://doi.org/10.3189/172756402781817220, 2002.
Samuelsson, H.: Distribution of melt layers on the ice field Lomonosovfonna, Spitsbergen, Master thesis, Uppsala University, Uppsala, Sweden, 2001.
Sharma, S., Chan, E., Ishizawa, M., Toom-Sauntry, D., Gong, S. L., Li, S. M., Tarasick, D. W., Leaitch, W. R., Norman, A., Quinn, P. K., Bates, T. S., Levasseur, M., Barrie, L. A., and Maenhaut, W.: Influence of transport and ocean ice extent on biogenic aerosol sulfur in the Arctic atmosphere, J. Geophys. Res., 117, D12209, https://doi.org/10.1029/2011JD017074, 2012.
Shaw, G. E.: The arctic haze phenomenon, B. Am. Meteorol. Soc., 76, 2403–2414, 1995.
Sigl, M.: Ice core based reconstruction of past climate conditions from Colle Gnifetti, Swiss Alps, PhD thesis, University of Bern, Bern, Switzerland, 2009.
Sigl, M., McConnell, J. R., Layman, L., Maselli, O., McGwire, K., Pasteris, D., Dahl-Jensen, D., Steffensen, J. P., Vinther, B., Edwards, R., Mulvaney, R., and Kipfstuhl, S.: A new bipolar ice core record of volcanism from WAIS Divide and NEEM and implications for climate forcing of the last 2000 years, J. Geophys. Res.-Atmos., 118, 1151–1169, https://doi.org/10.1029/2012JD018603, 2013.
Simões, J. C. and Zagorodnov, V. S.: The record of anthropogenic pollution in snow and ice in Svalbard, Norway, Atmos. Environ., 35, 403–413, 2001.
Stefels, J., Steinke, M., Turner, S., Malin, G., and Belviso, S.: Environmental constraints on the production and removal of the climatically active gas dimethylsulphide (DMS) and implications for ecosystem modelling, Biogeochemistry, 83, 245–275, https://doi.org/10.1007/s10533-007-9091-5, 2007.
Stohl, A.: Characteristics of atmospheric transport into the Arctic troposphere, J. Geophys. Res., 111, D11306, https://doi.org/10.1029/2005JD006888, 2006.
Stohl, A., Berg, T., Burkhart, J. F., Fjæraa, A. M., Forster, C., Herber, A., Hov, Ø., Lunder, C., McMillan, W. W., Oltmans, S., Shiobara, M., Simpson, D., Solberg, S., Stebel, K., Ström, J., Tørseth, K., Treffeisen, R., Virkkunen, K., and Yttri, K. E.: Arctic smoke – record high air pollution levels in the European Arctic due to agricultural fires in Eastern Europe in spring 2006, Atmos. Chem. Phys., 7, 511–534, https://doi.org/10.5194/acp-7-511-2007, 2007.
Teinilä, K., Hillamo, R., Kerminen, V.-M., and Beine, H. J.: Aerosol chemistry during the NICE dark and light campaigns, Atmos. Environ., 37, 563–575, https://doi.org/10.1016/S1352-2310(02)00826-9, 2003.
Thompson, L. G., Davis, M. E., Mosley-Thompson, E., Sowers, T. A., Henderson, K. A., Zagorodnov, V. S., Lin, P.-N., Mikhalenko, V. N., Campen, R. K., Bolzan, J. F., Cole-Dai, J., and Francou, B.: A 25 000-year tropical climate history from Bolivian ice cores, Science, 282, 1858–1864, https://doi.org/10.1126/science.282.5395.1858, 1998.
Tunved, P., Ström, J., and Krejci, R.: Arctic aerosol life cycle: linking aerosol size distributions observed between 2000 and 2010 with air mass transport and precipitation at Zeppelin station, Ny-Ålesund, Svalbard, Atmos. Chem. Phys., 13, 3643–3660, https://doi.org/10.5194/acp-13-3643-2013, 2013.
Udisti, R., Bellandi, S., and Piccardi, G.: Analysis of snow from Antarctica: a critical approach to ion-chromatographic methods, Fresen. J. Anal. Chem., 349, 289–293, https://doi.org/10.1007/BF00323205, 1994.
Van De Wal, R. S. W., Mulvaney, R., Isaksson, E., Moore, J. C., Pinglot, J. F., Pohjola, V. A., and Thomassen, M. P. A.: Reconstruction of the historical temperature trend from measurements in a medium-length borehole on the Lomonosovfonna plateau, Svalbard, Ann. Glaciol., 35, 371–378, 2002.
Vinje, T.: Anomalies and trends of sea-ice extent and atmospheric circulation in the Nordic seas during the period 1864–1998, J. Climate, 14, 255–267, 2001.
Vogt, M. and Liss, P. S.: Dimethylsulfide and Climate, in Surface Ocean–Lower Atmosphere Processes, edited by: Quéré, C. L. and Saltzman, E. S., American Geophysical Union, Washington, D. C., 197–232, https://doi.org/10.1029/2008GM000790, 2009.
Weiler, K., Fischer, H., Fritzsche, D., Ruth, U., Wilhelms, F., and Miller, H.: Glaciochemical reconnaissance of a new ice core from Severnaya Zemlya, Eurasian Arctic, J. Glaciol., 51, 64–74, https://doi.org/10.3189/172756505781829629, 2005.
Whitlow, S., Mayewski, P., Dibb, J., Holdsworth, G., and Twickler, M.: An ice-core-based record of biomass burning in the Arctic and Subarctic, 1750–1980, Tellus B, 46, 234–242, 1994.
Wolff, E. W.: Ice sheets and nitrogen, Philos. T. Roy. Soc. B, 368, 20130127, https://doi.org/10.1098/rstb.2013.0127, 2013.
Wolff, E. W., Jones, A. E., Bauguitte, S. J.-B., and Salmon, R. A.: The interpretation of spikes and trends in concentration of nitrate in polar ice cores, based on evidence from snow and atmospheric measurements, Atmos. Chem. Phys., 8, 5627–5634, https://doi.org/10.5194/acp-8-5627-2008, 2008.
Zennaro, P., Kehrwald, N., McConnell, J. R., Schüpbach, S., Maselli, O. J., Marlon, J., Vallelonga, P., Leuenberger, D., Zangrando, R., Spolaor, A., Borrotti, M., Barbaro, E., Gambaro, A., and Barbante, C.: Fire in ice: two millennia of boreal forest fire history from the Greenland NEEM ice core, Clim. Past, 10, 1905–1924, https://doi.org/10.5194/cp-10-1905-2014, 2014.
Short summary
Nitrate and ammonium ice core records from Lomonosovfonna, Svalbard, indicated anthropogenic pollution from Eurasia as major source during the 20th century. In pre-industrial times nitrate is correlated with methane sulfonate, which we explain with a fertilising effect, presumably triggered by enhanced atmospheric nitrogen input to the ocean. Eurasia was likely the main source area also of pre-industrial nitrate, but for ammonium, biogenic emissions from Siberian boreal forests were dominant.
Nitrate and ammonium ice core records from Lomonosovfonna, Svalbard, indicated anthropogenic...
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