Articles | Volume 15, issue 24
https://doi.org/10.5194/acp-15-13819-2015
https://doi.org/10.5194/acp-15-13819-2015
Research article
 | 
16 Dec 2015
Research article |  | 16 Dec 2015

Thermodynamic derivation of the activation energy for ice nucleation

D. Barahona

Related authors

Earth system model parameter adjustment using a Green's functions approach
Ehud Strobach, Andrea Molod, Donifan Barahona, Atanas Trayanov, Dimitris Menemenlis, and Gael Forget
Geosci. Model Dev., 15, 2309–2324, https://doi.org/10.5194/gmd-15-2309-2022,https://doi.org/10.5194/gmd-15-2309-2022, 2022
Short summary
The response of the Amazon ecosystem to the photosynthetically active radiation fields: integrating impacts of biomass burning aerosol and clouds in the NASA GEOS Earth system model
Huisheng Bian, Eunjee Lee, Randal D. Koster, Donifan Barahona, Mian Chin, Peter R. Colarco, Anton Darmenov, Sarith Mahanama, Michael Manyin, Peter Norris, John Shilling, Hongbin Yu, and Fanwei Zeng
Atmos. Chem. Phys., 21, 14177–14197, https://doi.org/10.5194/acp-21-14177-2021,https://doi.org/10.5194/acp-21-14177-2021, 2021
Short summary
Effect of volcanic emissions on clouds during the 2008 and 2018 Kilauea degassing events
Katherine H. Breen, Donifan Barahona, Tianle Yuan, Huisheng Bian, and Scott C. James
Atmos. Chem. Phys., 21, 7749–7771, https://doi.org/10.5194/acp-21-7749-2021,https://doi.org/10.5194/acp-21-7749-2021, 2021
Short summary
Linkage among ice crystal microphysics, mesoscale dynamics, and cloud and precipitation structures revealed by collocated microwave radiometer and multifrequency radar observations
Jie Gong, Xiping Zeng, Dong L. Wu, S. Joseph Munchak, Xiaowen Li, Stefan Kneifel, Davide Ori, Liang Liao, and Donifan Barahona
Atmos. Chem. Phys., 20, 12633–12653, https://doi.org/10.5194/acp-20-12633-2020,https://doi.org/10.5194/acp-20-12633-2020, 2020
Short summary
On the thermodynamic and kinetic aspects of immersion ice nucleation
Donifan Barahona
Atmos. Chem. Phys., 18, 17119–17141, https://doi.org/10.5194/acp-18-17119-2018,https://doi.org/10.5194/acp-18-17119-2018, 2018
Short summary

Related subject area

Subject: Clouds and Precipitation | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Bacteria in clouds biodegrade atmospheric formic and acetic acids
Leslie Nuñez López, Pierre Amato, and Barbara Ervens
Atmos. Chem. Phys., 24, 5181–5198, https://doi.org/10.5194/acp-24-5181-2024,https://doi.org/10.5194/acp-24-5181-2024, 2024
Short summary
Long-term variability in immersion-mode marine ice-nucleating particles from climate model simulations and observations
Aishwarya Raman, Thomas Hill, Paul J. DeMott, Balwinder Singh, Kai Zhang, Po-Lun Ma, Mingxuan Wu, Hailong Wang, Simon P. Alexander, and Susannah M. Burrows
Atmos. Chem. Phys., 23, 5735–5762, https://doi.org/10.5194/acp-23-5735-2023,https://doi.org/10.5194/acp-23-5735-2023, 2023
Short summary
Trifluoroacetic acid deposition from emissions of HFO-1234yf in India, China, and the Middle East
Liji M. David, Mary Barth, Lena Höglund-Isaksson, Pallav Purohit, Guus J. M. Velders, Sam Glaser, and A. R. Ravishankara
Atmos. Chem. Phys., 21, 14833–14849, https://doi.org/10.5194/acp-21-14833-2021,https://doi.org/10.5194/acp-21-14833-2021, 2021
Short summary
Convective uplift of pollution from the Sichuan Basin into the Asian monsoon anticyclone during the StratoClim aircraft campaign
Keun-Ok Lee, Brice Barret, Eric L. Flochmoën, Pierre Tulet, Silvia Bucci, Marc von Hobe, Corinna Kloss, Bernard Legras, Maud Leriche, Bastien Sauvage, Fabrizio Ravegnani, and Alexey Ulanovsky
Atmos. Chem. Phys., 21, 3255–3274, https://doi.org/10.5194/acp-21-3255-2021,https://doi.org/10.5194/acp-21-3255-2021, 2021
Short summary
Biodegradation by bacteria in clouds: an underestimated sink for some organics in the atmospheric multiphase system
Amina Khaled, Minghui Zhang, Pierre Amato, Anne-Marie Delort, and Barbara Ervens
Atmos. Chem. Phys., 21, 3123–3141, https://doi.org/10.5194/acp-21-3123-2021,https://doi.org/10.5194/acp-21-3123-2021, 2021

Cited articles

Adam, G. and Gibbs, J. H.: On the temperature dependence of cooperative relaxation properties in glass-forming liquids, J. Chem. Phys., 43, 139–146, 1965.
Alpert, P. A., Aller, J. Y., and Knopf, D. A.: Ice nucleation from aqueous NaCl droplets with and without marine diatoms, Atmos. Chem. Phys., 11, 5539–5555, https://doi.org/10.5194/acp-11-5539-2011, 2011.
Barahona, D.: Analysis of the effect of water activity on ice formation using a new thermodynamic framework, Atmos. Chem. Phys., 14, 7665–7680, https://doi.org/10.5194/acp-14-7665-2014, 2014.
Barahona, D. and Nenes, A.: Parameterization of cirrus formation in large scale models: Homogeneous nucleation, J. Geophys. Res., 113, D11211, https://doi.org/10.1029/2007JD009355, 2008.
Barahona, D. and Nenes, A.: Dynamical states of low temperature cirrus, Atmos. Chem. Phys., 11, 3757–3771, https://doi.org/10.5194/acp-11-3757-2011, 2011.
Download
Short summary
This paper describes the process of the transfer of water molecules between liquid and the ice during the early stages of ice formation. Using concepts of nonreversible thermodynamics, it is shown that the activation energy can be defined in terms of the bulk self-diffusivity of water and the probability of interface transfer. The application of this model to classical nucleation theory shows good agreement of measured nucleation rates with experimental results for temperatures as low as 190K.
Altmetrics
Final-revised paper
Preprint