Articles | Volume 25, issue 5
https://doi.org/10.5194/acp-25-2967-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-2967-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China
Ting Yang
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station, Ministry of Science and Technology, Ministry of Education, Shanghai 200240, China
Yu-Chen Wang
Division of Environment and Sustainability, Hong Kong University of Science and Technology, Hong Kong SAR 00000, China
Yi-Jia Ma
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Hong-Wei Xiao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station, Ministry of Science and Technology, Ministry of Education, Shanghai 200240, China
Hao Xiao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station, Ministry of Science and Technology, Ministry of Education, Shanghai 200240, China
Hua-Yun Xiao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station, Ministry of Science and Technology, Ministry of Education, Shanghai 200240, China
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Cited articles
Andreae, M. O.: Emission of trace gases and aerosols from biomass burning – an updated assessment, Atmos. Chem. Phys., 19, 8523–8546, https://doi.org/10.5194/acp-19-8523-2019, 2019.
Aoki, E., Sarrimanolis, J. N., Lyon, S. A., and Elrod, M. J.: Determining the Relative Reactivity of Sulfate, Bisulfate, and Organosulfates with Epoxides on Secondary Organic Aerosol, ACS Earth Space Chem., 4, 1793–1801, https://doi.org/10.1021/acsearthspacechem.0c00178, 2020.
Brüggemann, M., Riva, M., Perrier, S., Poulain, L., George, C., and Herrmann, H.: Overestimation of Monoterpene Organosulfate Abundance in Aerosol Particles by Sampling in the Presence of SO2, Environ. Sci. Tech. Let., 8, 206–211, https://doi.org/10.1021/acs.estlett.0c00814, 2020a.
Brüggemann, M., Xu, R., Tilgner, A., Kwong, K. C., Mutzel, A., Poon, H. Y., Otto, T., Schaefer, T., Poulain, L., Chan, M. N., and Herrmann, H.: Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance, Environ. Sci. Technol., 54, 3767–3782, https://doi.org/10.1021/acs.est.9b06751, 2020b.
Bryant, D. J., Elzein, A., Newland, M., White, E., Swift, S., Watkins, A., Deng, W., Song, W., Wang, S., Zhang, Y., Wang, X., Rickard, A. R., and Hamilton, J. F.: Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates, ACS Earth Space Chem., 5, 2291–2306, https://doi.org/10.1021/acsearthspacechem.1c00204, 2021.
Chen, Y., Dombek, T., Hand, J., Zhang, Z., Gold, A., Ault, A. P., Levine, K. E., and Surratt, J. D.: Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States, ACS Earth Space Chem., 5, 2419–2432, https://doi.org/10.1021/acsearthspacechem.1c00102, 2021.
Cui, T., Zeng, Z., dos Santos, E. O., Zhang, Z., Chen, Y., Zhang, Y., Rose, C. A., Budisulistiorini, S. H., Collins, L. B., Bodnar, W. M., de Souza, R. A. F., Martin, S. T., Machado, C. M. D., Turpin, B. J., Gold, A., Ault, A. P., and Surratt, J. D.: Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol, Environ. Sci.-Proc. Imp., 20, 1524–1536, https://doi.org/10.1039/c8em00308d, 2018.
Darer, A. I., Cole-Filipiak, N. C., O'Connor, A. E., and Elrod, M. J.: Formation and Stability of Atmospherically Relevant Isoprene-Derived Organosulfates and Organonitrates, Environ. Sci. Technol., 45, 1895–1902, https://doi.org/10.1021/es103797z, 2011.
Ding, S., Chen, Y., Devineni, S. R., Pavuluri, C. M., and Li, X.-D.: Distribution characteristics of organosulfates (OSs) in PM2.5 in Tianjin, Northern China: Quantitative analysis of total and three OS species, Sci. Total Environ., 834, 155314, https://doi.org/10.1016/j.scitotenv.2022.155314, 2022.
Ding, X., He, Q.-F., Shen, R.-Q., Yu, Q.-Q., and Wang, X.-M.: Spatial distributions of secondary organic aerosols from isoprene, monoterpenes, β-caryophyllene, and aromatics over China during summer, J. Geophys. Res.-Atmos., 119, 11877–11891, https://doi.org/10.1002/2014jd021748, 2014.
Ding, X., He, Q.-F., Shen, R.-Q., Yu, Q.-Q., Zhang, Y.-Q., Xin, J.-Y., Wen, T.-X., and Wang, X.-M.: Spatial and seasonal variations of isoprene secondary organic aerosol in China: Significant impact of biomass burning during winter, Sci. Rep., 6, 20411, https://doi.org/10.1038/srep20411, 2016a.
Ding, X., Zhang, Y. Q., He, Q. F., Yu, Q. Q., Shen, R. Q., Zhang, Y., Zhang, Z., Lyu, S. J., Hu, Q. H., Wang, Y. S., Li, L. F., Song, W., and Wang, X. M.: Spatial and seasonal variations of secondary organic aerosol from terpenoids over China, J. Geophys. Res.-Atmos., 121, 14661–14678, https://doi.org/10.1002/2016jd025467, 2016b.
Ding, X., Zhang, Y.-Q., He, Q.-F., Yu, Q.-Q., Wang, J.-Q., Shen, R.-Q., Song, W., Wang, Y.-S., and Wang, X.-M.: Significant Increase of Aromatics-Derived Secondary Organic Aerosol during Fall to Winter in China, Environ. Sci. Technol., 51, 7432–7441, https://doi.org/10.1021/acs.est.6b06408, 2017.
Duporté, G., Flaud, P. M., Geneste, E., Augagneur, S., Pangui, E., Lamkaddam, H., Gratien, A., Doussin, J. F., Budzinski, H., Villenave, E., and Perraudin, E.: Experimental Study of the Formation of Organosulfates from α-Pinene Oxidation. Part I: Product Identification, Formation Mechanisms and Effect of Relative Humidity, J. Phys. Chem. A, 120, 7909–7923, https://doi.org/10.1021/acs.jpca.6b08504, 2016.
Duporté, G., Flaud, P. M., Kammer, J., Geneste, E., Augagneur, S., Pangui, E., Lamkaddam, H., Gratien, A., Doussin, J. F., Budzinski, H., Villenave, E., and Perraudin, E.: Experimental Study of the Formation of Organosulfates from α-Pinene Oxidation. 2. Time Evolution and Effect of Particle Acidity, J. Phys. Chem. A, 124, 409–421, https://doi.org/10.1021/acs.jpca.9b07156, 2019.
Fleming, L. T., Ali, N. N., Blair, S. L., Roveretto, M., George, C., and Nizkorodov, S. A.: Formation of Light-Absorbing Organosulfates during Evaporation of Secondary Organic Material Extracts in the Presence of Sulfuric Acid, ACS Earth Space Chem., 3, 947–957, https://doi.org/10.1021/acsearthspacechem.9b00036, 2019.
Gilardoni, S., Massoli, P., Paglione, M., Giulianelli, L., Carbone, C., Rinaldi, M., Decesari, S., Sandrini, S., Costabile, F., Gobbi, G. P., Pietrogrande, M. C., Visentin, M., Scotto, F., Fuzzi, S., and Facchini, M. C.: Direct observation of aqueous secondary organic aerosol from biomass-burning emissions, P. Natl. Acad. Sci. USA, 113, 10013–10018, https://doi.org/10.1073/pnas.1602212113, 2016.
Guenther, A. B., Zimmerman, P. R., Harley, P. C., Monson, R. K., and Fall, R.: Isoprene and monoterpene emission rate variability J. Geophys. Res.-Atmos., 98, 12609–12617, 1993.
He, L.-Y., Lin, Y., Huang, X.-F., Guo, S., Xue, L., Su, Q., Hu, M., Luan, S.-J., and Zhang, Y.-H.: Characterization of high-resolution aerosol mass spectra of primary organic aerosol emissions from Chinese cooking and biomass burning, Atmos. Chem. Phys., 10, 11535–11543, https://doi.org/10.5194/acp-10-11535-2010, 2010.
Hettiyadura, A. P. S., Stone, E. A., Kundu, S., Baker, Z., Geddes, E., Richards, K., and Humphry, T.: Determination of atmospheric organosulfates using HILIC chromatography with MS detection, Atmos. Meas. Tech., 8, 2347–2358, https://doi.org/10.5194/amt-8-2347-2015, 2015.
Hettiyadura, A. P. S., Jayarathne, T., Baumann, K., Goldstein, A. H., de Gouw, J. A., Koss, A., Keutsch, F. N., Skog, K., and Stone, E. A.: Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama, Atmos. Chem. Phys., 17, 1343–1359, https://doi.org/10.5194/acp-17-1343-2017, 2017.
Hettiyadura, A. P. S., Al-Naiema, I. M., Hughes, D. D., Fang, T., and Stone, E. A.: Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation, Atmos. Chem. Phys., 19, 3191–3206, https://doi.org/10.5194/acp-19-3191-2019, 2019.
Huang, L., Wang, Y., Zhao, Y., Hu, H., Yang, Y., Wang, Y., Yu, J. Z., Chen, T., Cheng, Z., Li, C., Li, Z., and Xiao, H.: Biogenic and Anthropogenic Contributions to Atmospheric Organosulfates in a Typical Megacity in Eastern China, J. Geophys. Res.-Atmos., 128, e2023JD038848, https://doi.org/10.1029/2023jd038848, 2023.
Jiang, H., Cai, J., Feng, X., Chen, Y., Wang, L., Jiang, B., Liao, Y., Li, J., Zhang, G., Mu, Y., and Chen, J.: Aqueous-Phase Reactions of Anthropogenic Emissions Lead to the High Chemodiversity of Atmospheric Nitrogen-Containing Compounds during the Haze Event, Environ. Sci. Technol., 57, 16500–16511, https://doi.org/10.1021/acs.est.3c06648, 2023.
Kanellopoulos, P. G., Kotsaki, S. P., Chrysochou, E., Koukoulakis, K., Zacharopoulos, N., Philippopoulos, A., and Bakeas, E.: PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates, Chemosphere, 297, 134103, https://doi.org/10.1016/j.chemosphere.2022.134103, 2022.
Kristensen, K., Bilde, M., Aalto, P. P., Petäjä, T., and Glasius, M.: Denuder/filter sampling of organic acids and organosulfates at urban and boreal forest sites: Gas/particle distribution and possible sampling artifacts, Atmos. Environ., 130, 36–53, https://doi.org/10.1016/j.atmosenv.2015.10.046, 2016.
Li, J., Wang, G., Wu, C., Cao, C., Ren, Y., Wang, J., Li, J., Cao, J., Zeng, L., and Zhu, T.: Characterization of isoprene-derived secondary organic aerosols at a rural site in North China Plain with implications for anthropogenic pollution effects, Sci. Rep., 8, 535, https://doi.org/10.1038/s41598-017-18983-7, 2018.
Li, L., Yang, W., Xie, S., and Wu, Y.: Estimations and uncertainty of biogenic volatile organic compound emission inventory in China for 2008–2018, Sci. Total Environ., 733, 139301, https://doi.org/10.1016/j.scitotenv.2020.139301, 2020.
Li, L. Y. and Xie, S. D.: Historical variations of biogenic volatile organic compound emission inventories in China, 1981–2003, Atmos. Environ., 95, 185–196, https://doi.org/10.1016/j.atmosenv.2014.06.033, 2014.
Lin, X., Xu, Y., Zhu, R. G., Xiao, H. W., and Xiao, H. Y.: Proteinaceous Matter in PM2.5 in Suburban Guiyang, Southwestern China: Decreased Importance in Long-Range Transport and Atmospheric Degradation, J. Geophys. Res.-Atmos., 128, e2023JD038516, https://doi.org/10.1029/2023jd038516, 2023.
Liu, T., Xu, Y., Sun, Q. B., Xiao, H. W., Zhu, R. G., Li, C. X., Li, Z. Y., Zhang, K. Q., Sun, C. X., and Xiao, H. Y.: Characteristics, Origins, and Atmospheric Processes of Amines in Fine Aerosol Particles in Winter in China, J. Geophys. Res.-Atmos., 128, e2023JD038974, https://doi.org/10.1029/2023jd038974, 2023.
Lukács, H., Gelencsér, A., Hoffer, A., Kiss, G., Horváth, K., and Hartyáni, Z.: Quantitative assessment of organosulfates in size-segregated rural fine aerosol, Atmos. Chem. Phys., 9, 231–238, https://doi.org/10.5194/acp-9-231-2009, 2009.
Ma, Q., Cai, S., Wang, S., Zhao, B., Martin, R. V., Brauer, M., Cohen, A., Jiang, J., Zhou, W., Hao, J., Frostad, J., Forouzanfar, M. H., and Burnett, R. T.: Impacts of coal burning on ambient PM2.5 pollution in China, Atmos. Chem. Phys., 17, 4477–4491, https://doi.org/10.5194/acp-17-4477-2017, 2017.
Mason, S. A., Field, R. J., Yokelson, R. J., Kochivar, M. A., Tinsley, M. R., Ward, D. E., and Hao, W. M.: Complex effects arising in smoke plume simulations due to inclusion of direct emissions of oxygenated organic species from biomass combustion, J. Geophys. Res.-Atmos., 106, 12527–12539, https://doi.org/10.1029/2001jd900003, 2001.
Nozière, B., Ekström, S., Alsberg, T., and Holmström, S.: Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols, Geophys. Res. Lett., 37, L05806, https://doi.org/10.1029/2009gl041683, 2010.
Riva, M., Tomaz, S., Cui, T., Lin, Y.-H., Perraudin, E., Gold, A., Stone, E. A., Villenave, E., and Surratt, J. D.: Evidence for an Unrecognized Secondary Anthropogenic Source of Organosulfates and Sulfonates: Gas-Phase Oxidation of Polycyclic Aromatic Hydrocarbons in the Presence of Sulfate Aerosol, Environ. Sci. Technol., 49, 6654–6664, https://doi.org/10.1021/acs.est.5b00836, 2015.
Riva, M., Chen, Y., Zhang, Y., Lei, Z., Olson, N. E., Boyer, H. C., Narayan, S., Yee, L. D., Green, H. S., Cui, T., Zhang, Z., Baumann, K., Fort, M., Edgerton, E., Budisulistiorini, S. H., Rose, C. A., Ribeiro, I. O., e Oliveira, R. L., dos Santos, E. O., Machado, C. M. D., Szopa, S., Zhao, Y., Alves, E. G., de Sá, S. S., Hu, W., Knipping, E. M., Shaw, S. L., Duvoisin Junior, S., de Souza, R. A. F., Palm, B. B., Jimenez, J.-L., Glasius, M., Goldstein, A. H., Pye, H. O. T., Gold, A., Turpin, B. J., Vizuete, W., Martin, S. T., Thornton, J. A., Dutcher, C. S., Ault, A. P., and Surratt, J. D.: Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties, Environ. Sci. Technol., 53, 8682–8694, https://doi.org/10.1021/acs.est.9b01019, 2019.
Schindelka, J., Iinuma, Y., Hoffmann, D., and Herrmann, H.: Sulfate radical-initiated formation of isoprene-derived organosulfates in atmospheric aerosols, Faraday Discuss., 165, 237–259, https://doi.org/10.1039/c3fd00042g, 2013.
Simpson, I. J., Akagi, S. K., Barletta, B., Blake, N. J., Choi, Y., Diskin, G. S., Fried, A., Fuelberg, H. E., Meinardi, S., Rowland, F. S., Vay, S. A., Weinheimer, A. J., Wennberg, P. O., Wiebring, P., Wisthaler, A., Yang, M., Yokelson, R. J., and Blake, D. R.: Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN, Atmos. Chem. Phys., 11, 6445–6463, https://doi.org/10.5194/acp-11-6445-2011, 2011.
Song, J., Li, M., Jiang, B., Wei, S., Fan, X., and Peng, P.: Molecular Characterization of Water-Soluble Humic like Substances in Smoke Particles Emitted from Combustion of Biomass Materials and Coal Using Ultrahigh-Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Environ. Sci. Technol., 52, 2575–2585, https://doi.org/10.1021/acs.est.7b06126, 2018.
Song, J., Li, M., Fan, X., Zou, C., Zhu, M., Jiang, B., Yu, Z., Jia, W., Liao, Y., and Peng, P.: Molecular Characterization of Water- and Methanol-Soluble Organic Compounds Emitted from Residential Coal Combustion Using Ultrahigh-Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Environ. Sci. Technol., 53, 13607–13617, https://doi.org/10.1021/acs.est.9b04331, 2019.
Surratt, J. D., Kroll, J. H., Kleindienst, T. E., Edney, E. O., Claeys, M., Sorooshian, A., Ng, L., Offenberg, J. H., Lewandowski, M., Jaoui, M., Flagan, R. C., and Seinfeld, J. H.: Evidence for organosulfates in secondary organic aerosol., Environ. Sci. Technol., 41, 517–527, 2007.
Surratt, J. D., Gómez-González, Y., Chan, A. W., Vermeylen, R., Shahgholi, M., Kleindienst, T. E., Edney, E. O., Offenberg, J. H., Lewandowski, M., Jaoui, M., Maenhaut, M. W., Claeys, M., Flagan, R. C., and Seinfeld, J. H.: Organosulfate Formation in Biogenic Secondary Organic Aerosol, J. Phys. Chem. A, 112, 8345–8378, 2008.
Tang, J., Li, J., Su, T., Han, Y., Mo, Y., Jiang, H., Cui, M., Jiang, B., Chen, Y., Tang, J., Song, J., Peng, P., and Zhang, G.: Molecular compositions and optical properties of dissolved brown carbon in biomass burning, coal combustion, and vehicle emission aerosols illuminated by excitation–emission matrix spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry analysis, Atmos. Chem. Phys., 20, 2513–2532, https://doi.org/10.5194/acp-20-2513-2020, 2020.
Tao, S., Lu, X., Levac, N., Bateman, A. P., Nguyen, T. B., Bones, D. L., Nizkorodov, S. A., Laskin, J., Laskin, A., and Yang, X.: Molecular Characterization of Organosulfates in Organic Aerosols from Shanghai and Los Angeles Urban Areas by Nanospray-Desorption Electrospray Ionization High-Resolution Mass Spectrometry, Environ. Sci. Technol., 48, 10993–11001, https://doi.org/10.1021/es5024674, 2014.
Wach, P., Spólnik, G., Rudziński, K. J., Skotak, K., Claeys, M., Danikiewicz, W., and Szmigielski, R.: Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications, Chemosphere, 214, 1–9, https://doi.org/10.1016/j.chemosphere.2018.09.026, 2019.
Wang, Y., Hu, M., Lin, P., Guo, Q., Wu, Z., Li, M., Zeng, L., Song, Y., Zeng, L., Wu, Y., Guo, S., Huang, X., and He, L.: Molecular Characterization of Nitrogen-Containing Organic Compounds in Humic-like Substances Emitted from Straw Residue Burning, Environ. Sci. Technol., 51, 5951–5961, https://doi.org/10.1021/acs.est.7b00248, 2017.
Wang, Y., Hu, M., Guo, S., Wang, Y., Zheng, J., Yang, Y., Zhu, W., Tang, R., Li, X., Liu, Y., Le Breton, M., Du, Z., Shang, D., Wu, Y., Wu, Z., Song, Y., Lou, S., Hallquist, M., and Yu, J.: The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing, Atmos. Chem. Phys., 18, 10693–10713, https://doi.org/10.5194/acp-18-10693-2018, 2018.
Wang, K., Zhang, Y., Huang, R.-J., Wang, M., Ni, H., Kampf, C. J., Cheng, Y., Bilde, M., Glasius, M., and Hoffmann, T.: Molecular Characterization and Source Identification of Atmospheric Particulate Organosulfates Using Ultrahigh Resolution Mass Spectrometry, Environ. Sci. Technol., 53, 6192–6202, https://doi.org/10.1021/acs.est.9b02628, 2019.
Wang, Y., Hu, M., Wang, Y.-C., Li, X., Fang, X., Tang, R., Lu, S., Wu, Y., Guo, S., Wu, Z., Hallquist, M., and Yu, J. Z.: Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx, Environ. Sci. Tech. Let., 7, 787–794, https://doi.org/10.1021/acs.estlett.0c00550, 2020.
Wang, Y., Zhao, Y., Wang, Y., Yu, J.-Z., Shao, J., Liu, P., Zhu, W., Cheng, Z., Li, Z., Yan, N., and Xiao, H.: Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms, Atmos. Chem. Phys., 21, 2959–2980, https://doi.org/10.5194/acp-21-2959-2021, 2021.
Wang, Y., Ma, Y., Kuang, B., Lin, P., Liang, Y., Huang, C., and Yu, J. Z.: Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China, Sci. Total Environ., 806, 151275, https://doi.org/10.1016/j.scitotenv.2021.151275, 2022.
Wang, Y., Zhang, Y., Li, W., Wu, G., Qi, Y., Li, S., Zhu, W., Yu, J. Z., Yu, X., Zhang, H.-H., Sun, J., Wang, W., Sheng, L., Yao, X., Gao, H., Huang, C., Ma, Y., and Zhou, Y.: Important Roles and Formation of Atmospheric Organosulfates in Marine Organic Aerosols: Influence of Phytoplankton Emissions and Anthropogenic Pollutants, Environ. Sci. Technol., 57, 10284–10294, https://doi.org/10.1021/acs.est.3c01422, 2023.
Xu, Y., Miyazaki, Y., Tachibana, E., Sato, K., Ramasamy, S., Mochizuki, T., Sadanaga, Y., Nakashima, Y., Sakamoto, Y., Matsuda, K., and Kajii, Y.: Aerosol Liquid Water Promotes the Formation of Water-Soluble Organic Nitrogen in Submicrometer Aerosols in a Suburban Forest, Environ. Sci. Technol., 54, 1406–1414, https://doi.org/10.1021/acs.est.9b05849, 2020.
Xu, Y., Dong, X. N., Xiao, H. Y., Zhou, J. X., and Wu, D. S.: Proteinaceous Matter and Liquid Water in Fine Aerosols in Nanchang, Eastern China: Seasonal Variations, Sources, and Potential Connections, J. Geophys. Res.-Atmos., 127, e2022JD036589, https://doi.org/10.1029/2022jd036589, 2022.
Xu, Y., Dong, X.-N., He, C., Wu, D.-S., Xiao, H.-W., and Xiao, H.-Y.: Mist cannon trucks can exacerbate the formation of water-soluble organic aerosol and PM2.5 pollution in the road environment, Atmos. Chem. Phys., 23, 6775–6788, https://doi.org/10.5194/acp-23-6775-2023, 2023.
Xu, Y., Lin, X., Sun, Q. B., Xiao, H. W., Xiao, H., and Xiao, H. Y.: Elaborating the Atmospheric Transformation of Combined and Free Amino Acids From the Perspective of Observational Studies, J. Geophys. Res.-Atmos., 129, e2024JD040730, https://doi.org/10.1029/2024jd040730, 2024a.
Xu, Y., Liu, T., Ma, Y.-J., Sun, Q.-B., Xiao, H.-W., Xiao, H., Xiao, H.-Y., and Liu, C.-Q.: Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints, Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, 2024b.
Yang, T., Xu, Y., Ye, Q., Ma, Y.-J., Wang, Y.-C., Yu, J.-Z., Duan, Y.-S., Li, C.-X., Xiao, H.-W., Li, Z.-Y., Zhao, Y., and Xiao, H.-Y.: Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution, Atmos. Chem. Phys., 23, 13433–13450, https://doi.org/10.5194/acp-23-13433-2023, 2023.
Yang, T., Xu, Y., Ma, Y.-J., Wang, Y.-C., Yu, J. Z., Sun, Q.-B., Xiao, H.-W., Xiao, H.-Y., and Liu, C.-Q.: Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates, Environ. Sci. Tech. Let., 11, 981–987, https://doi.org/10.1021/acs.estlett.4c00522, 2024.
Yang, Y. R., Liu, X. G., Qu, Y., An, J. L., Jiang, R., Zhang, Y. H., Sun, Y. L., Wu, Z. J., Zhang, F., Xu, W. Q., and Ma, Q. X.: Characteristics and formation mechanism of continuous hazes in China: a case study during the autumn of 2014 in the North China Plain, Atmos. Chem. Phys., 15, 8165–8178, https://doi.org/10.5194/acp-15-8165-2015, 2015.
Yu, Q., Ding, X., He, Q., Yang, W., Zhu, M., Li, S., Zhang, R., Shen, R., Zhang, Y., Bi, X., Wang, Y., Peng, P., and Wang, X.: Nationwide increase of polycyclic aromatic hydrocarbons in ultrafine particles during winter over China revealed by size-segregated measurements, Atmos. Chem. Phys., 20, 14581–14595, https://doi.org/10.5194/acp-20-14581-2020, 2020.
Zhang, L., Li, J., Li, Y., Liu, X., Luo, Z., Shen, G., and Tao, S.: Comparison of water-soluble and water-insoluble organic compositions attributing to different light absorption efficiency between residential coal and biomass burning emissions, Atmos. Chem. Phys., 24, 6323–6337, https://doi.org/10.5194/acp-24-6323-2024, 2024.
Zhang, Y., Zhang, R., Yu, J., Zhang, Z., Yang, W., Zhang, H., Lyu, S., Wang, Y., Dai, W., Wang, Y., and Wang, X.: Isoprene Mixing Ratios Measured at Twenty Sites in China During 2012–2014: Comparison With Model Simulation, J. Geophys. Res.-Atmos., 125, e2020JD033523, https://doi.org/10.1029/2020jd033523, 2020.
Zhou, Y., Xing, X., Lang, J., Chen, D., Cheng, S., Wei, L., Wei, X., and Liu, C.: A comprehensive biomass burning emission inventory with high spatial and temporal resolution in China, Atmos. Chem. Phys., 17, 2839–2864, https://doi.org/10.5194/acp-17-2839-2017, 2017.
Zhu, Y., Yang, L., Chen, J., Wang, X., Xue, L., Sui, X., Wen, L., Xu, C., Yao, L., Zhang, J., Shao, M., Lu, S., and Wang, W.: Characteristics of ambient volatile organic compounds and the influence of biomass burning at a rural site in Northern China during summer 2013, Atmos. Environ., 124, 156–165, https://doi.org/10.1016/j.atmosenv.2015.08.097, 2016.
Short summary
Previous measurement–model comparisons of atmospheric isoprene levels showed a significant unidentified source of isoprene in some northern Chinese cities during winter. Here, the first combination of large-scale observations and field combustion experiments provides novel insights into biomass burning emissions as a significant source of isoprene-derived organosulfates during winter in northern cities of China.
Previous measurement–model comparisons of atmospheric isoprene levels showed a significant...
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