Articles | Volume 23, issue 7
https://doi.org/10.5194/acp-23-4489-2023
https://doi.org/10.5194/acp-23-4489-2023
Measurement report
 | 
14 Apr 2023
Measurement report |  | 14 Apr 2023

Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3

Beni Adi Trisna, Seungnam Park, Injun Park, Jeongsoon Lee, and Jeong Sik Lim

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Revised manuscript not accepted
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Cited articles

Allen, M. R., Shine, K. P., Fuglestvedt, J. S., Millar, R. J., Cain, M., Frame, D. J., and Macey, A. H.: A solution to the misrepresentations of CO2-equivalent emissions of short-lived climate pollutants under ambitious mitigation, NPJ Clim. Atmos. Sci., 1, 1–8, https://doi.org/10.1038/s41612-018-0026-8, 2018. 
Beni, A. T., Park, S., Park, I., Lee, J., and Lim, J. S.: Measurement report: Radiative efficiency estimates of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3 using high-resolution Fourier transform infrared spectroscopy, Zenodo [data set], https://doi.org/10.5281/zenodo.7132870, 2022. 
Bravo, I., Aranda, A., Hurley, M. D., Marston, G., Nutt, D. R., Shine, K. P., Smith, K., and Wallington, T. J.: Infrared absorption spectra, radiative efficiencies, and global warming potentials of perfluorocarbons: Comparison between experiment and theory, J. Geophys. Res.-Atmos., 115, D24317, https://doi.org/10.1029/2010JD014771, 2010. 
Denison, S., Forster, P. M., and Smith, C. J.: Guidance on emissions metrics for nationally determined contributions under the Paris Agreement, Environ. Res. Lett., 14, 124002, https://doi.org/10.1088/1748-9326/ab4df4, 2019. 
Fleisher, A. J., Adkins, E. M., Reed, Z. D., Yi, H., Long, D. A., Fleurbaey, H. M., and Hodges, J. T.: Twenty-five-fold reduction in measurement uncertainty for a molecular line intensity, Phys. Rev. Lett., 123, 043001, https://doi.org/10.1103/PhysRevLett.123.043001, 2019. 
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Short summary
An accurate estimate of radiative efficiency (RE) is substantial for an accurate assessment of global warming potential (GWP). In this study, we report accurate estimates of RE values of emerging greenhouse gases (GHGs) by using high-resolution Fourier transform infrared spectroscopy (FTIR). CF3OCFCF2 and CF3OCF2CF3 are reported for the first time. In addition, hidden errors in RE values of (CF3)2CFCN and CF3OCFCF2 in previous studies are pointed out.
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