Articles | Volume 23, issue 2
https://doi.org/10.5194/acp-23-1619-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-1619-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
27 Jan 2023
Research article |
| 27 Jan 2023
| 27 Jan 2023
Long-term monitoring of cloud water chemistry at Whiteface Mountain: the emergence of a new chemical regime
Christopher E. Lawrence
Atmospheric Sciences Research Center (ASRC), University at Albany, SUNY ETEC building, 1220 Washington Ave, Albany NY 12226, USA
Paul Casson
Atmospheric Sciences Research Center (ASRC), University at Albany, SUNY ETEC building, 1220 Washington Ave, Albany NY 12226, USA
Richard Brandt
Atmospheric Sciences Research Center (ASRC), University at Albany, SUNY ETEC building, 1220 Washington Ave, Albany NY 12226, USA
James J. Schwab
Atmospheric Sciences Research Center (ASRC), University at Albany, SUNY ETEC building, 1220 Washington Ave, Albany NY 12226, USA
James E. Dukett
Adirondack Lake Survey Corporation (ALSC), 1115 NYS Rt.86, P.O. Box 296, Ray Brook NY 12977, USA
Phil Snyder
Adirondack Lake Survey Corporation (ALSC), 1115 NYS Rt.86, P.O. Box 296, Ray Brook NY 12977, USA
Elizabeth Yerger
Paul Smith's College Adirondack Watershed Institute (AWI), P.O. Box 265, Routes 86 and 30, Paul Smiths NY 12970, USA
Daniel Kelting
Paul Smith's College Adirondack Watershed Institute (AWI), P.O. Box 265, Routes 86 and 30, Paul Smiths NY 12970, USA
Trevor C. VandenBoer
Department of Chemistry, York University, Toronto, Ontario, M3J 1P3, Canada
Sara Lance
CORRESPONDING AUTHOR
Atmospheric Sciences Research Center (ASRC), University at Albany, SUNY ETEC building, 1220 Washington Ave, Albany NY 12226, USA
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Cited
12 citations as recorded by crossref.
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- Online headspace monitoring of volatile organic compounds using proton transfer reaction-mass spectrometry: Application to the multiphase atmospheric fate of 2,4-hexadienedial N. Brun et al. 10.1016/j.talanta.2024.126176
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Suppressor and calibration standard limitations in cation chromatography of ammonium and 10 alkylamines in atmospheric samples L. Salehpoor & T. VandenBoer 10.1039/D3AY01158E
- pH dependence of brown-carbon optical properties in cloud water C. Hennigan et al. 10.5194/acp-23-14437-2023
- Cost-effective off-grid automatic precipitation samplers for pollutant and biogeochemical atmospheric deposition A. Colussi et al. 10.5194/amt-17-3697-2024
- Methylglyoxal-Urea Brown Carbon Aerosol: A Loss Process for Urea Z. Schiffman et al. 10.1021/acsestair.4c00047
- Comparison of acidity and chemical composition of summertime cloud water and aerosol at an alpine site in Northwest China: Implications for the neutral property of clouds in the free troposphere M. Shen et al. 10.1016/j.scitotenv.2024.171775
- Changed mercury speciation in clouds driven by changing cloud water chemistry and impacts on photoreduction: Field evidence at Mt. Tai in eastern China J. Zhen et al. 10.1016/j.watres.2023.120402
- Bacteria in clouds biodegrade atmospheric formic and acetic acids L. Nuñez López et al. 10.5194/acp-24-5181-2024
- Modeling atmospheric brown carbon in the GISS ModelE Earth system model M. DeLessio et al. 10.5194/acp-24-6275-2024
- Long-term monitoring of cloud water chemistry at Whiteface Mountain: the emergence of a new chemical regime C. Lawrence et al. 10.5194/acp-23-1619-2023
11 citations as recorded by crossref.
- The Chemical Landscape of Leaf Surfaces and Its Interaction with the Atmosphere R. Ossola & D. Farmer 10.1021/acs.chemrev.3c00763
- Online headspace monitoring of volatile organic compounds using proton transfer reaction-mass spectrometry: Application to the multiphase atmospheric fate of 2,4-hexadienedial N. Brun et al. 10.1016/j.talanta.2024.126176
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Suppressor and calibration standard limitations in cation chromatography of ammonium and 10 alkylamines in atmospheric samples L. Salehpoor & T. VandenBoer 10.1039/D3AY01158E
- pH dependence of brown-carbon optical properties in cloud water C. Hennigan et al. 10.5194/acp-23-14437-2023
- Cost-effective off-grid automatic precipitation samplers for pollutant and biogeochemical atmospheric deposition A. Colussi et al. 10.5194/amt-17-3697-2024
- Methylglyoxal-Urea Brown Carbon Aerosol: A Loss Process for Urea Z. Schiffman et al. 10.1021/acsestair.4c00047
- Comparison of acidity and chemical composition of summertime cloud water and aerosol at an alpine site in Northwest China: Implications for the neutral property of clouds in the free troposphere M. Shen et al. 10.1016/j.scitotenv.2024.171775
- Changed mercury speciation in clouds driven by changing cloud water chemistry and impacts on photoreduction: Field evidence at Mt. Tai in eastern China J. Zhen et al. 10.1016/j.watres.2023.120402
- Bacteria in clouds biodegrade atmospheric formic and acetic acids L. Nuñez López et al. 10.5194/acp-24-5181-2024
- Modeling atmospheric brown carbon in the GISS ModelE Earth system model M. DeLessio et al. 10.5194/acp-24-6275-2024
Latest update: 17 Jul 2024
Short summary
Atmospheric aqueous chemistry can have profound effects on our environment, as illustrated by historical data from Whiteface Mountain (WFM) that were critical for uncovering the process of acid rain. The current study updates the long-term trends in cloud water composition at WFM for the period 1994 to 2021. We highlight the emergence of a new chemical regime at WFM dominated by organics and ammonium, quite different from the highly acidic regime observed in the past but not necessarily
clean.
Atmospheric aqueous chemistry can have profound effects on our environment, as illustrated by...
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