Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-1549-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-1549-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
01 Feb 2022
Research article |
| 01 Feb 2022
| 01 Feb 2022
Exploring dimethyl sulfide (DMS) oxidation and implications for global aerosol radiative forcing
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA, USA
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA, USA
Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA, USA
Jesse H. Kroll
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA, USA
Siyuan Wang
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Chemical Sciences Laboratory, National Oceanic and Atmospheric
Administration, Boulder, CO, USA
Duseong S. Jo
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Andrew Gettelman
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Zheng Lu
Department of Atmospheric Sciences, Texas A&M University, College Station, TX, USA
Xiaohong Liu
Department of Atmospheric Sciences, Texas A&M University, College Station, TX, USA
Rahul A. Zaveri
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA, USA
Eric C. Apel
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Donald R. Blake
Department of Chemistry, University of California Irvine, Irvine, CA, USA
Jose-Luis Jimenez
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Department of Chemistry, University of Colorado Boulder, Boulder, CO, USA
Pedro Campuzano-Jost
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Department of Chemistry, University of Colorado Boulder, Boulder, CO, USA
Patrick R. Veres
Chemical Sciences Laboratory, National Oceanic and Atmospheric
Administration, Boulder, CO, USA
Timothy S. Bates
The Cooperative Institute for Climate, Ocean, and Ecosystem Studies, College of the Environment, University of Washington, Seattle, WA, USA
John E. Shilling
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA, USA
Maria Zawadowicz
Environmental and Climate Sciences Department, Brookhaven National
Laboratory, Upton, NY, USA
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Cited
34 citations as recorded by crossref.
- A new working fluid for condensation particle counters for use in sensitive working environments P. Weber et al. 10.5194/ar-1-1-2023
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- Global Health and Climate Effects of Organic Aerosols from Different Sources D. Jo et al. 10.1021/acs.est.3c02823
- Examining the Impact of Dimethyl Sulfide Emissions on Atmospheric Sulfate over the Continental U.S. G. Sarwar et al. 10.3390/atmos14040660
- Marine aerosol feedback on biogeochemical cycles and the climate in the Anthropocene: lessons learned from the Pacific Ocean A. Ito et al. 10.1039/D2EA00156J
- Importance of Atmospheric Transport on Methanesulfonic Acid (MSA) Concentrations in the Arctic Ocean During Summer Under Global Warming B. Jiang et al. 10.1029/2022JD037271
- Effective radiative forcing of anthropogenic aerosols in E3SM version 1: historical changes, causality, decomposition, and parameterization sensitivities K. Zhang et al. 10.5194/acp-22-9129-2022
- Effects of drought and recovery on soil volatile organic compound fluxes in an experimental rainforest G. Pugliese et al. 10.1038/s41467-023-40661-8
- Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism M. Goss & J. Kroll 10.5194/acp-24-1299-2024
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Assessing the Intensity of Marine Biogenic Influence on the Lower Atmosphere: An Insight into the Distribution of Marine Biogenic Aerosols over the Eastern China Seas S. Zhou et al. 10.1021/acs.est.3c04382
- Assessing the Isomerization of a Primary Intermediate (CH3SCH2O2• Radical) in Dimethyl Sulfide Degradation in the Marine Boundary Layer M. Lily et al. 10.1021/acsearthspacechem.3c00209
- Extension, development, and evaluation of the representation of the OH-initiated dimethyl sulfide (DMS) oxidation mechanism in the Master Chemical Mechanism (MCM) v3.3.1 framework L. Jacob et al. 10.5194/acp-24-3329-2024
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- The Potential for Great Barrier Reef Regional Climate Regulation via Dimethylsulfide Atmospheric Oxidation Products H. Swan 10.3389/fmars.2022.869166
- Microwave and Computational Study of Methanesulfonic Acid and Its Complex with Water A. Huff et al. 10.1021/acs.jpca.3c01395
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
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- Reactive Uptake of Hydroperoxymethyl Thioformate to Sodium Chloride and Sodium Iodide Aerosol Particles C. Jernigan et al. 10.1021/acs.jpca.2c03222
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Robust quantification of the burst of OH radicals generated by ambient particles in nascent cloud droplets using a direct-to-reagent approach S. Taghvaee et al. 10.1016/j.scitotenv.2023.165736
- Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model B. Cala et al. 10.5194/acp-23-14735-2023
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Factors controlling atmospheric DMS and its oxidation products (MSA and nssSO42−) in the aerosol at Terra Nova Bay, Antarctica S. Becagli et al. 10.5194/acp-22-9245-2022
- Intercomparison of Atmospheric Carbonyl Sulfide (TransCom‐COS): 2. Evaluation of Optimized Fluxes Using Ground‐Based and Aircraft Observations J. Ma et al. 10.1029/2023JD039198
- Improving Estimates of Dynamic Global Marine DMS and Implications for Aerosol Radiative Effect J. Zhao et al. 10.1029/2023JD039314
- Observationally constrained analysis of sulfur cycle in the marine atmosphere with NASA ATom measurements and AeroCom model simulations H. Bian et al. 10.5194/acp-24-1717-2024
- The biogeochemistry of marine dimethylsulfide F. Hopkins et al. 10.1038/s43017-023-00428-7
- Climate Change Impacts on the Marine Cycling of Biogenic Sulfur: A Review R. Jackson & A. Gabric 10.3390/microorganisms10081581
- Influence of Air Mass Source Regions on Signatures of Surface-Active Organic Molecules in Size Resolved Atmospheric Aerosol Particles T. Burdette et al. 10.1021/acsearthspacechem.3c00161
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
34 citations as recorded by crossref.
- A new working fluid for condensation particle counters for use in sensitive working environments P. Weber et al. 10.5194/ar-1-1-2023
- Sulfate and Carbonyl Sulfide Production in Aqueous Reactions of Hydroperoxymethyl Thioformate C. Jernigan et al. 10.1021/acsestair.3c00098
- Chemical characterization of sub-micron aerosols over the East Sea (Sea of Japan) A. Loh et al. 10.1016/j.scitotenv.2022.159173
- Global Health and Climate Effects of Organic Aerosols from Different Sources D. Jo et al. 10.1021/acs.est.3c02823
- Examining the Impact of Dimethyl Sulfide Emissions on Atmospheric Sulfate over the Continental U.S. G. Sarwar et al. 10.3390/atmos14040660
- Marine aerosol feedback on biogeochemical cycles and the climate in the Anthropocene: lessons learned from the Pacific Ocean A. Ito et al. 10.1039/D2EA00156J
- Importance of Atmospheric Transport on Methanesulfonic Acid (MSA) Concentrations in the Arctic Ocean During Summer Under Global Warming B. Jiang et al. 10.1029/2022JD037271
- Effective radiative forcing of anthropogenic aerosols in E3SM version 1: historical changes, causality, decomposition, and parameterization sensitivities K. Zhang et al. 10.5194/acp-22-9129-2022
- Effects of drought and recovery on soil volatile organic compound fluxes in an experimental rainforest G. Pugliese et al. 10.1038/s41467-023-40661-8
- Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism M. Goss & J. Kroll 10.5194/acp-24-1299-2024
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Assessing the Intensity of Marine Biogenic Influence on the Lower Atmosphere: An Insight into the Distribution of Marine Biogenic Aerosols over the Eastern China Seas S. Zhou et al. 10.1021/acs.est.3c04382
- Assessing the Isomerization of a Primary Intermediate (CH3SCH2O2• Radical) in Dimethyl Sulfide Degradation in the Marine Boundary Layer M. Lily et al. 10.1021/acsearthspacechem.3c00209
- Extension, development, and evaluation of the representation of the OH-initiated dimethyl sulfide (DMS) oxidation mechanism in the Master Chemical Mechanism (MCM) v3.3.1 framework L. Jacob et al. 10.5194/acp-24-3329-2024
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
- The Potential for Great Barrier Reef Regional Climate Regulation via Dimethylsulfide Atmospheric Oxidation Products H. Swan 10.3389/fmars.2022.869166
- Microwave and Computational Study of Methanesulfonic Acid and Its Complex with Water A. Huff et al. 10.1021/acs.jpca.3c01395
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
- Butene Emissions From Coastal Ecosystems May Contribute to New Particle Formation C. Giorio et al. 10.1029/2022GL098770
- Reactive Uptake of Hydroperoxymethyl Thioformate to Sodium Chloride and Sodium Iodide Aerosol Particles C. Jernigan et al. 10.1021/acs.jpca.2c03222
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Robust quantification of the burst of OH radicals generated by ambient particles in nascent cloud droplets using a direct-to-reagent approach S. Taghvaee et al. 10.1016/j.scitotenv.2023.165736
- Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model B. Cala et al. 10.5194/acp-23-14735-2023
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Factors controlling atmospheric DMS and its oxidation products (MSA and nssSO42−) in the aerosol at Terra Nova Bay, Antarctica S. Becagli et al. 10.5194/acp-22-9245-2022
- Intercomparison of Atmospheric Carbonyl Sulfide (TransCom‐COS): 2. Evaluation of Optimized Fluxes Using Ground‐Based and Aircraft Observations J. Ma et al. 10.1029/2023JD039198
- Improving Estimates of Dynamic Global Marine DMS and Implications for Aerosol Radiative Effect J. Zhao et al. 10.1029/2023JD039314
- Observationally constrained analysis of sulfur cycle in the marine atmosphere with NASA ATom measurements and AeroCom model simulations H. Bian et al. 10.5194/acp-24-1717-2024
- The biogeochemistry of marine dimethylsulfide F. Hopkins et al. 10.1038/s43017-023-00428-7
- Climate Change Impacts on the Marine Cycling of Biogenic Sulfur: A Review R. Jackson & A. Gabric 10.3390/microorganisms10081581
- Influence of Air Mass Source Regions on Signatures of Surface-Active Organic Molecules in Size Resolved Atmospheric Aerosol Particles T. Burdette et al. 10.1021/acsearthspacechem.3c00161
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
Discussed (final revised paper)
Latest update: 25 Apr 2024
Short summary
Understanding the natural aerosol burden in the preindustrial era is crucial for us to assess how atmospheric aerosols affect the Earth's radiative budgets. Our study explores how a detailed description of dimethyl sulfide (DMS) oxidation (implemented in the Community Atmospheric Model version 6 with chemistry, CAM6-chem) could help us better estimate the present-day and preindustrial concentrations of sulfate and other relevant chemicals, as well as the resulting aerosol radiative impacts.
Understanding the natural aerosol burden in the preindustrial era is crucial for us to assess...
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Final-revised paper
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