Articles | Volume 22, issue 19
https://doi.org/10.5194/acp-22-13137-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-13137-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Oct 2022
Research article |
| 12 Oct 2022
| 12 Oct 2022
Seasonal variation in nitryl chloride and its relation to gas-phase precursors during the JULIAC campaign in Germany
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Hendrik Fuchs
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Physikalisches Institut, Universität zu Köln, Cologne, Germany
Andreas Hofzumahaus
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
William J. Bloss
School of Geography, Earth, and Environmental Sciences, University of Birmingham, Birmingham, UK
Birger Bohn
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Changmin Cho
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Thorsten Hohaus
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Frank Holland
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Chandrakiran Lakshmisha
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Paul S. Monks
School of Chemistry, University of Leicester, Leicester, UK
Anna Novelli
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Doreen Niether
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Franz Rohrer
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Thalassa S. E. Valkenburg
School of Chemistry, University of Leicester, Leicester, UK
Vaishali Vardhan
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Department of Chemistry, University College Cork, Cork, Ireland
Astrid Kiendler-Scharr
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Physikalisches Institut, Universität zu Köln, Cologne, Germany
Andreas Wahner
IEK-8: Troposphere, Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
School of Chemistry, University of Leicester, Leicester, UK
School of Geography, Earth, and Environmental Sciences, University of Birmingham, Birmingham, UK
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Cited
5 citations as recorded by crossref.
- Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR M. von Hobe et al. 10.5194/acp-23-10609-2023
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al. 10.1016/j.atmosres.2023.106674
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Wildfire plume ageing in the Photochemical Large Aerosol Chamber (PHOTO-LAC) H. Czech et al. 10.1039/D3EM00280B
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
5 citations as recorded by crossref.
- Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR M. von Hobe et al. 10.5194/acp-23-10609-2023
- Observationally constrained modelling of NO3 radical in different altitudes: Implication to vertically resolved nocturnal chemistry Z. Sun et al. 10.1016/j.atmosres.2023.106674
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Wildfire plume ageing in the Photochemical Large Aerosol Chamber (PHOTO-LAC) H. Czech et al. 10.1039/D3EM00280B
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
Latest update: 13 Dec 2024
Short summary
During the 2019 JULIAC campaign, ClNO2 was measured at a rural site in Germany in different seasons. The highest ClNO2 level was 1.6 ppbv in September. ClNO2 production was more sensitive to the availability of NO2 than O3. The average ClNO2 production efficiency was up to 18 % in February and September and down to 3 % in December. These numbers are at the high end of the values reported in the literature, indicating the importance of ClNO2 chemistry in rural environments in midwestern Europe.
During the 2019 JULIAC campaign, ClNO2 was measured at a rural site in Germany in different...
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