Articles | Volume 22, issue 17
https://doi.org/10.5194/acp-22-11543-2022
https://doi.org/10.5194/acp-22-11543-2022
Research article
 | 
07 Sep 2022
Research article |  | 07 Sep 2022

Atmospheric oxidation mechanism and kinetics of indole initiated by OH and Cl: a computational study

Jingwen Xue, Fangfang Ma, Jonas Elm, Jingwen Chen, and Hong-Bin Xie

Viewed

Total article views: 2,270 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
1,617 584 69 2,270 136 28 36
  • HTML: 1,617
  • PDF: 584
  • XML: 69
  • Total: 2,270
  • Supplement: 136
  • BibTeX: 28
  • EndNote: 36
Views and downloads (calculated since 26 Apr 2022)
Cumulative views and downloads (calculated since 26 Apr 2022)

Viewed (geographical distribution)

Total article views: 2,270 (including HTML, PDF, and XML) Thereof 2,289 with geography defined and -19 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 

Cited

Latest update: 17 Jul 2024
Download
Short summary
·OH/·Cl initiated indole reactions mainly form organonitrates, alkoxy radicals and hydroperoxide products, showing a varying mechanism from previously reported amines reactions. This study reveals carcinogenic nitrosamines cannot be formed in indole oxidation reactions despite radicals formed from -NH- H abstraction. The results are important to understand the atmospheric impact of indole oxidation and extend current understanding on the atmospheric chemistry of organic nitrogen compounds.
Altmetrics
Final-revised paper
Preprint