Articles | Volume 21, issue 24
https://doi.org/10.5194/acp-21-18557-2021
https://doi.org/10.5194/acp-21-18557-2021
Research article
 | 
21 Dec 2021
Research article |  | 21 Dec 2021

Biomass burning plume chemistry: OH-radical-initiated oxidation of 3-penten-2-one and its main oxidation product 2-hydroxypropanal

Niklas Illmann, Iulia Patroescu-Klotz, and Peter Wiesen

Related authors

Atmospheric oxidation of α,β-unsaturated ketones: kinetics and mechanism of the OH radical reaction
Niklas Illmann, Rodrigo Gastón Gibilisco, Iustinian Gabriel Bejan, Iulia Patroescu-Klotz, and Peter Wiesen
Atmos. Chem. Phys., 21, 13667–13686, https://doi.org/10.5194/acp-21-13667-2021,https://doi.org/10.5194/acp-21-13667-2021, 2021
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement of Henry's law and liquid-phase loss rate constants of peroxypropionic nitric anhydride (PPN) in deionized water and in n-octanol
Kevin D. Easterbrook, Mitchell A. Vona, Kiana Nayebi-Astaneh, Amanda M. Miller, and Hans D. Osthoff
Atmos. Chem. Phys., 23, 311–322, https://doi.org/10.5194/acp-23-311-2023,https://doi.org/10.5194/acp-23-311-2023, 2023
Short summary
Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes
Qing Ye, Matthew B. Goss, Jordan E. Krechmer, Francesca Majluf, Alexander Zaytsev, Yaowei Li, Joseph R. Roscioli, Manjula Canagaratna, Frank N. Keutsch, Colette L. Heald, and Jesse H. Kroll
Atmos. Chem. Phys., 22, 16003–16015, https://doi.org/10.5194/acp-22-16003-2022,https://doi.org/10.5194/acp-22-16003-2022, 2022
Short summary
Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals
Caterina Mapelli, Juliette V. Schleicher, Alex Hawtin, Conor D. Rankine, Fiona C. Whiting, Fergal Byrne, C. Rob McElroy, Claudiu Roman, Cecilia Arsene, Romeo I. Olariu, Iustinian G. Bejan, and Terry J. Dillon
Atmos. Chem. Phys., 22, 14589–14602, https://doi.org/10.5194/acp-22-14589-2022,https://doi.org/10.5194/acp-22-14589-2022, 2022
Short summary
Impact of cooking style and oil on semi-volatile and intermediate volatility organic compound emissions from Chinese domestic cooking
Kai Song, Song Guo, Yuanzheng Gong, Daqi Lv, Yuan Zhang, Zichao Wan, Tianyu Li, Wenfei Zhu, Hui Wang, Ying Yu, Rui Tan, Ruizhe Shen, Sihua Lu, Shuangde Li, Yunfa Chen, and Min Hu
Atmos. Chem. Phys., 22, 9827–9841, https://doi.org/10.5194/acp-22-9827-2022,https://doi.org/10.5194/acp-22-9827-2022, 2022
Short summary
Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes
Michelia Dam, Danielle C. Draper, Andrey Marsavin, Juliane L. Fry, and James N. Smith
Atmos. Chem. Phys., 22, 9017–9031, https://doi.org/10.5194/acp-22-9017-2022,https://doi.org/10.5194/acp-22-9017-2022, 2022
Short summary

Cited articles

Allen, G., Remedios, J. J., Newnham, D. A., Smith, K. M., and Monks, P. S.: Improved mid-infrared cross-sections for peroxyacetyl nitrate (PAN) vapour, Atmos. Chem. Phys., 5, 47–56, https://doi.org/10.5194/acp-5-47-2005, 2005. 
Alvarado, M. J., Lonsdale, C. R., Yokelson, R. J., Akagi, S. K., Coe, H., Craven, J. S., Fischer, E. V., McMeeking, G. R., Seinfeld, J. H., Soni, T., Taylor, J. W., Weise, D. R., and Wold, C. E.: Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a prescribed fire in California chaparral, Atmos. Chem. Phys., 15, 6667–6688, https://doi.org/10.5194/acp-15-6667-2015, 2015. 
Aschmann, S. M., Arey, J., and Atkinson, R.: Atmospheric Chemistry of Selected Hydroxycarbonyls, J. Phys. Chem. A, 104, 3998–4003, https://doi.org/10.1021/jp9939874, 2000. 
Atkinson, R.: Rate constants for the atmospheric reactions of alkoxy radicals: An updated estimation method, Atmos. Environ., 41, 8468–8485, https://doi.org/10.1016/j.atmosenv.2007.07.002, 2007. 
Download
Short summary
Understanding the chemistry of biomass burning plumes is of global interest. Within this work we investigated the OH radical reaction of 3-penten-2-one, which has been identified in biomass burning emissions. We observed the primary formation of peroxyacetyl nitrate (PAN), a key NOx reservoir species. Besides, PAN precursors were also identified as main oxidation products. 3-Penten-2-one is shown to be an example explaining rapid PAN formation within young biomass burning plumes.
Altmetrics
Final-revised paper
Preprint