Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 21, issue 24
Articles | Volume 21, issue 24
https://doi.org/10.5194/acp-21-18557-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-21-18557-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 21, issue 24
Research article
 | 
21 Dec 2021
Research article |  | 21 Dec 2021

Biomass burning plume chemistry: OH-radical-initiated oxidation of 3-penten-2-one and its main oxidation product 2-hydroxypropanal

Niklas Illmann, Iulia Patroescu-Klotz, and Peter Wiesen

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This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
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Cited articles

Allen, G., Remedios, J. J., Newnham, D. A., Smith, K. M., and Monks, P. S.: Improved mid-infrared cross-sections for peroxyacetyl nitrate (PAN) vapour, Atmos. Chem. Phys., 5, 47–56, https://doi.org/10.5194/acp-5-47-2005, 2005. 
Alvarado, M. J., Logan, J. A., Mao, J., Apel, E., Riemer, D., Blake, D., Cohen, R. C., Min, K.-E., Perring, A. E., Browne, E. C., Wooldridge, P. J., Diskin, G. S., Sachse, G. W., Fuelberg, H., Sessions, W. R., Harrigan, D. L., Huey, G., Liao, J., Case-Hanks, A., Jimenez, J. L., Cubison, M. J., Vay, S. A., Weinheimer, A. J., Knapp, D. J., Montzka, D. D., Flocke, F. M., Pollack, I. B., Wennberg, P. O., Kurten, A., Crounse, J., Clair, J. M. St., Wisthaler, A., Mikoviny, T., Yantosca, R. M., Carouge, C. C., and Le Sager, P.: Nitrogen oxides and PAN in plumes from boreal fires during ARCTAS-B and their impact on ozone: an integrated analysis of aircraft and satellite observations, Atmos. Chem. Phys., 10, 9739–9760, https://doi.org/10.5194/acp-10-9739-2010, 2010. 
Alvarado, M. J., Lonsdale, C. R., Yokelson, R. J., Akagi, S. K., Coe, H., Craven, J. S., Fischer, E. V., McMeeking, G. R., Seinfeld, J. H., Soni, T., Taylor, J. W., Weise, D. R., and Wold, C. E.: Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a prescribed fire in California chaparral, Atmos. Chem. Phys., 15, 6667–6688, https://doi.org/10.5194/acp-15-6667-2015, 2015. 
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Understanding the chemistry of biomass burning plumes is of global interest. Within this work we investigated the OH radical reaction of 3-penten-2-one, which has been identified in biomass burning emissions. We observed the primary formation of peroxyacetyl nitrate (PAN), a key NOx reservoir species. Besides, PAN precursors were also identified as main oxidation products. 3-Penten-2-one is shown to be an example explaining rapid PAN formation within young biomass burning plumes.
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