Articles | Volume 21, issue 17
https://doi.org/10.5194/acp-21-13333-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-13333-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Sep 2021
Research article |
| 09 Sep 2021
| 09 Sep 2021
Role of Criegee intermediates in the formation of sulfuric acid at a Mediterranean (Cape Corsica) site under influence of biogenic emissions
Alexandre Kukui
CORRESPONDING AUTHOR
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace
(LPC2E), CNRS Orléans, France
Michel Chartier
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace
(LPC2E), CNRS Orléans, France
Jinhe Wang
Resources and Environment Innovation Research Institute, School of
Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan, 250101, China
ICARE-CNRS, 1 C Av. de la Recherche Scientifique, 45071 Orléans
CEDEX 2, France
ICARE-CNRS, 1 C Av. de la Recherche Scientifique, 45071 Orléans
CEDEX 2, France
now at: Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Institute
of Atmospheric Sciences, Fudan University, Shanghai 200438, China
Sébastien Dusanter
IMT Lille Douai, Institut Mines-Télécom, Univ. Lille, Centre
for Energy and Environment, 59000 Lille, France
Stéphane Sauvage
IMT Lille Douai, Institut Mines-Télécom, Univ. Lille, Centre
for Energy and Environment, 59000 Lille, France
Vincent Michoud
IMT Lille Douai, Institut Mines-Télécom, Univ. Lille, Centre
for Energy and Environment, 59000 Lille, France
now at: Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR CNRS 7583, Université Paris Est Créteil (UPEC) et Université Paris Diderot (UPD), Créteil, France
Nadine Locoge
IMT Lille Douai, Institut Mines-Télécom, Univ. Lille, Centre
for Energy and Environment, 59000 Lille, France
Valérie Gros
Laboratoire des Sciences du Climat et de l'Environnement (LSCE), UMR
CNRS-CEA-UVSQ, IPSL, Univ. Paris-Saclay, 91191 Gif-sur-Yvette, France
Thierry Bourrianne
Centre National de Recherches Météorologiques (CNRM), GMEI,
MNP, Météo-France, 31057 Toulouse, France
Karine Sellegri
Laboratoire de Météorologie Physique Observatoire de Physique
du Globe (LAMP), Clermont-Ferrand, France
Jean-Marc Pichon
Laboratoire de Météorologie Physique Observatoire de Physique
du Globe (LAMP), Clermont-Ferrand, France
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Cited
10 citations as recorded by crossref.
- Traffic, marine ships and nucleation as the main sources of ultrafine particles in suburban Shanghai, China Q. Wang et al. 10.1039/D3EA00096F
- Unimolecular Reactions of E -Glycolaldehyde Oxide and Its Reactions with One and Two Water Molecules Y. Sun et al. 10.34133/research.0143
- Reaction between peracetic acid and carbonyl oxide: Quantitative kinetics and insight into implications in the atmosphere C. Xie et al. 10.1016/j.atmosenv.2024.120928
- Evaluation of reaction between SO2 and CH2OO in MCM mechanism against smog chamber data from ethylene ozonolysis H. Zhang et al. 10.1071/EN23029
- Interfacial Extraction to Trap and Characterize the Criegee Intermediates from Phospholipid Ozonolysis J. He et al. 10.1021/acs.analchem.2c05472
- Master Equation Studies of the Unimolecular Decay of Thermalized Methacrolein Oxide: The Impact of Atmospheric Conditions H. Lee et al. 10.1021/acs.jpca.3c00542
- Role of Heterogeneous Reactions in the Atmospheric Oxidizing Capacity in Island Environments C. Xue et al. 10.1021/acs.est.4c11647
- Kinetics of the Gas-Phase Reactions of syn- and anti-CH3CHOO Criegee Intermediate Conformers with SO2 as a Function of Temperature and Pressure R. Lade et al. 10.1021/acs.jpca.4c00199
- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. 10.1039/D2CP02849B
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. 10.34133/research.0525
10 citations as recorded by crossref.
- Traffic, marine ships and nucleation as the main sources of ultrafine particles in suburban Shanghai, China Q. Wang et al. 10.1039/D3EA00096F
- Unimolecular Reactions of E -Glycolaldehyde Oxide and Its Reactions with One and Two Water Molecules Y. Sun et al. 10.34133/research.0143
- Reaction between peracetic acid and carbonyl oxide: Quantitative kinetics and insight into implications in the atmosphere C. Xie et al. 10.1016/j.atmosenv.2024.120928
- Evaluation of reaction between SO2 and CH2OO in MCM mechanism against smog chamber data from ethylene ozonolysis H. Zhang et al. 10.1071/EN23029
- Interfacial Extraction to Trap and Characterize the Criegee Intermediates from Phospholipid Ozonolysis J. He et al. 10.1021/acs.analchem.2c05472
- Master Equation Studies of the Unimolecular Decay of Thermalized Methacrolein Oxide: The Impact of Atmospheric Conditions H. Lee et al. 10.1021/acs.jpca.3c00542
- Role of Heterogeneous Reactions in the Atmospheric Oxidizing Capacity in Island Environments C. Xue et al. 10.1021/acs.est.4c11647
- Kinetics of the Gas-Phase Reactions of syn- and anti-CH3CHOO Criegee Intermediate Conformers with SO2 as a Function of Temperature and Pressure R. Lade et al. 10.1021/acs.jpca.4c00199
- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. 10.1039/D2CP02849B
- Reaction of Carbonyl Oxide with Hydroperoxymethyl Thioformate: Quantitative Kinetics and Atmospheric Implications B. Long et al. 10.34133/research.0525
Latest update: 02 May 2025
Short summary
Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles. It is generally accepted that the major atmospheric source of H2SO4 is the reaction of OH radicals with SO2. In this study, importance of an additional H2SO4 source via oxidation of SO2 by stabilized Criegee intermediates was estimated based on measurements at a remote site on Cape Corsica. It was found that the oxidation of SO2 by SCI may be an important source of H2SO4, especially during nighttime.
Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles....
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