Articles | Volume 21, issue 16
https://doi.org/10.5194/acp-21-12413-2021
https://doi.org/10.5194/acp-21-12413-2021
Research article
 | 
19 Aug 2021
Research article |  | 19 Aug 2021

Observation and modelling of ozone-destructive halogen chemistry in a passively degassing volcanic plume

Luke Surl, Tjarda Roberts, and Slimane Bekki

Related authors

A regional modelling study of halogen chemistry within a volcanic plume of Mt Etna's Christmas 2018 eruption
Herizo Narivelo, Paul David Hamer, Virginie Marécal, Luke Surl, Tjarda Roberts, Sophie Pelletier, Béatrice Josse, Jonathan Guth, Mickaël Bacles, Simon Warnach, Thomas Wagner, Stefano Corradini, Giuseppe Salerno, and Lorenzo Guerrieri
Atmos. Chem. Phys., 23, 10533–10561, https://doi.org/10.5194/acp-23-10533-2023,https://doi.org/10.5194/acp-23-10533-2023, 2023
Short summary
Halogen chemistry in volcanic plumes: a 1D framework based on MOCAGE 1D (version R1.18.1) preparing 3D global chemistry modelling
Virginie Marécal, Ronan Voisin-Plessis, Tjarda Jane Roberts, Alessandro Aiuppa, Herizo Narivelo, Paul David Hamer, Béatrice Josse, Jonathan Guth, Luke Surl, and Lisa Grellier
Geosci. Model Dev., 16, 2873–2898, https://doi.org/10.5194/gmd-16-2873-2023,https://doi.org/10.5194/gmd-16-2873-2023, 2023
Short summary
Which processes drive observed variations of HCHO columns over India?
Luke Surl, Paul I. Palmer, and Gonzalo González Abad
Atmos. Chem. Phys., 18, 4549–4566, https://doi.org/10.5194/acp-18-4549-2018,https://doi.org/10.5194/acp-18-4549-2018, 2018
Short summary
Quantification of the depletion of ozone in the plume of Mount Etna
L. Surl, D. Donohoue, A. Aiuppa, N. Bobrowski, and R. von Glasow
Atmos. Chem. Phys., 15, 2613–2628, https://doi.org/10.5194/acp-15-2613-2015,https://doi.org/10.5194/acp-15-2613-2015, 2015
Short summary

Related subject area

Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Regional and sectoral contributions of NOx and reactive carbon emission sources to global trends in tropospheric ozone during the 2000–2018 period
Aditya Nalam, Aura Lupaşcu, Tabish Ansari, and Tim Butler
Atmos. Chem. Phys., 25, 5287–5311, https://doi.org/10.5194/acp-25-5287-2025,https://doi.org/10.5194/acp-25-5287-2025, 2025
Short summary
Underappreciated contributions of biogenic volatile organic compounds from urban green spaces to ozone pollution
Haofan Wang, Yuejin Li, Yiming Liu, Xiao Lu, Yang Zhang, Qi Fan, Chong Shen, Senchao Lai, Yan Zhou, Tao Zhang, and Dingli Yue
Atmos. Chem. Phys., 25, 5233–5250, https://doi.org/10.5194/acp-25-5233-2025,https://doi.org/10.5194/acp-25-5233-2025, 2025
Short summary
Chemistry–climate feedback of atmospheric methane in a methane-emission-flux-driven chemistry–climate model
Laura Stecher, Franziska Winterstein, Patrick Jöckel, Michael Ponater, Mariano Mertens, and Martin Dameris
Atmos. Chem. Phys., 25, 5133–5158, https://doi.org/10.5194/acp-25-5133-2025,https://doi.org/10.5194/acp-25-5133-2025, 2025
Short summary
Surface ozone trend variability across the United States and the impact of heat waves (1990–2023)
Kai-Lan Chang, Brian C. McDonald, Colin Harkins, and Owen R. Cooper
Atmos. Chem. Phys., 25, 5101–5132, https://doi.org/10.5194/acp-25-5101-2025,https://doi.org/10.5194/acp-25-5101-2025, 2025
Short summary
Sensitivity of climate effects of hydrogen to leakage size, location, and chemical background
Ragnhild Bieltvedt Skeie, Marit Sandstad, Srinath Krishnan, Gunnar Myhre, and Maria Sand
Atmos. Chem. Phys., 25, 4929–4942, https://doi.org/10.5194/acp-25-4929-2025,https://doi.org/10.5194/acp-25-4929-2025, 2025
Short summary

Cited articles

Aiuppa, A., Bellomo, S., D'Alessandro, W., Federico, C., Ferm, M., and Valenza, M.: Volcanic plume monitoring at Mount Etna by diffusive (passive) sampling, J. Geophys. Res.-Atmos., 109, D21308, https://doi.org/10.1029/2003JD004481, 2004. a
Aiuppa, A., Federico, C., Franco, A., Giudice, G., Gurrieri, S., Inguaggiato, S., Liuzzo, M., McGonigle, A. J. S., and Valenza, M.: Emission of bromine and iodine from Mount Etna volcano, Geochem. Geophy. Geosy., 6, Q08008, https://doi.org/10.1029/2005gc000965, 2005. a, b
Aiuppa, A., Franco, A., von Glasow, R., Allen, A. G., D'Alessandro, W., Mather, T. A., Pyle, D. M., and Valenza, M.: The tropospheric processing of acidic gases and hydrogen sulphide in volcanic gas plumes as inferred from field and model investigations, Atmos. Chem. Phys., 7, 1441–1450, https://doi.org/10.5194/acp-7-1441-2007, 2007. a
Aiuppa, A., Giudice, G., Gurrieri, S., Liuzzo, M., Burton, M., Caltabiano, T., McGonigle, A. J. S., Salerno, G., Shinohara, H., and Valenza, M.: Total volatile flux from Mount Etna, Geophys. Res. Lett., 35, L24302, https://doi.org/10.1029/2008GL035871, 2008. a
Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013. a
Download
Short summary
Many different chemical reactions happen when the gases from a volcano mix with air, but what effects do they have? We present aircraft measurements which show that there is less ozone within the plume of Etna than outside it. We have also made a computer model of this chemistry. This model can reproduce the effects seen when halogens (bromine and chlorine) are included in the volcanic emissions. We look closely at the simulation to discover how complicated halogen reactions cause ozone loss.
Share
Altmetrics
Final-revised paper
Preprint