Articles | Volume 20, issue 16
https://doi.org/10.5194/acp-20-9725-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-9725-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique
Jacob T. Shaw
Wolfson Atmospheric Chemistry Laboratories, Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
now at: Department of Earth and Environmental Science, University of
Manchester, Manchester, M13 9PL, UK
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York,
Heslington, York, YO10 5DD, UK
Mike J. Newland
Wolfson Atmospheric Chemistry Laboratories, Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
Wolfson Atmospheric Chemistry Laboratories, Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
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Cited
14 citations as recorded by crossref.
- Kinetic and mechanism of the reaction between Cl and several mono-methyl branched alkanes Y. Chen et al. https://doi.org/10.1016/j.jes.2022.08.010
- Recent Developments in Photocatalytic Nanotechnology for Purifying Air Polluted with Volatile Organic Compounds: Effect of Operating Parameters and Catalyst Deactivation A. Jaison et al. https://doi.org/10.3390/catal13020407
- From real-driving emissions to urban air quality: composition of aged PM from modern diesel, gasoline, and CNG fueled cars and plug-in hybrid electric vehicles L. Simon et al. https://doi.org/10.1016/j.aeaoa.2025.100375
- Rate coefficients for the reactions of OH radicals with C3–C11 alkanes determined by the relative-rate technique Y. Xin et al. https://doi.org/10.5194/acp-24-11409-2024
- Emissions and health risk assessment of process-based volatile organic compounds of a representative petrochemical enterprise in East China S. Gao et al. https://doi.org/10.1007/s11869-021-01117-4
- Gas-phase degradation of the aroma compound ethyl butyrate and its methylated derivatives: UV-C photolysis and reactions with the hydroxyl radical F. Löher et al. https://doi.org/10.5194/acp-26-9277-2026
- The Combined Effect of NOx and NH3 on Toluene Photooxidation and SOA Formation L. Shijie et al. https://doi.org/10.1021/acsearthspacechem.5c00207
- Comprehensive analysis of chemical and physical characteristics of co-pollution by ozone and PM2.5 over 2017–2024 in a typical industrial city of Zibo Y. Song et al. https://doi.org/10.1016/j.apr.2026.103087
- Sources-oriented contributions to ozone and secondary organic aerosol formation potential based on initial VOCs in an urban area of Eastern Asia Z. Chen et al. https://doi.org/10.1016/j.scitotenv.2023.164392
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al. https://doi.org/10.1039/D5EA00091B
- Downdraft energy tower for negative emissions: Analysis on methane removal and other co‐benefits T. Tao et al. https://doi.org/10.1002/ghg.2233
- Investigation on ozone formation mechanism and control strategy of VOCs in petrochemical region: Insights from chemical reactivity and photochemical loss H. Ren et al. https://doi.org/10.1016/j.scitotenv.2024.169891
- Evaluating the feasibility of formaldehyde derived from hyperspectral remote sensing as a proxy for volatile organic compounds Q. Hong et al. https://doi.org/10.1016/j.atmosres.2021.105777
- Pesticide fate and transport in the atmosphere and implications for risk assessment C. Bedos et al. https://doi.org/10.1016/j.jhazmat.2026.141769
14 citations as recorded by crossref.
- Kinetic and mechanism of the reaction between Cl and several mono-methyl branched alkanes Y. Chen et al. https://doi.org/10.1016/j.jes.2022.08.010
- Recent Developments in Photocatalytic Nanotechnology for Purifying Air Polluted with Volatile Organic Compounds: Effect of Operating Parameters and Catalyst Deactivation A. Jaison et al. https://doi.org/10.3390/catal13020407
- From real-driving emissions to urban air quality: composition of aged PM from modern diesel, gasoline, and CNG fueled cars and plug-in hybrid electric vehicles L. Simon et al. https://doi.org/10.1016/j.aeaoa.2025.100375
- Rate coefficients for the reactions of OH radicals with C3–C11 alkanes determined by the relative-rate technique Y. Xin et al. https://doi.org/10.5194/acp-24-11409-2024
- Emissions and health risk assessment of process-based volatile organic compounds of a representative petrochemical enterprise in East China S. Gao et al. https://doi.org/10.1007/s11869-021-01117-4
- Gas-phase degradation of the aroma compound ethyl butyrate and its methylated derivatives: UV-C photolysis and reactions with the hydroxyl radical F. Löher et al. https://doi.org/10.5194/acp-26-9277-2026
- The Combined Effect of NOx and NH3 on Toluene Photooxidation and SOA Formation L. Shijie et al. https://doi.org/10.1021/acsearthspacechem.5c00207
- Comprehensive analysis of chemical and physical characteristics of co-pollution by ozone and PM2.5 over 2017–2024 in a typical industrial city of Zibo Y. Song et al. https://doi.org/10.1016/j.apr.2026.103087
- Sources-oriented contributions to ozone and secondary organic aerosol formation potential based on initial VOCs in an urban area of Eastern Asia Z. Chen et al. https://doi.org/10.1016/j.scitotenv.2023.164392
- Comparison of oxidation products generated from the reaction of α-pinene with hydroxyl radicals, chlorine atoms, and bromine atoms measured using ammonium adduct chemical ionization mass spectrometry A. Lambe et al. https://doi.org/10.1039/D5EA00091B
- Downdraft energy tower for negative emissions: Analysis on methane removal and other co‐benefits T. Tao et al. https://doi.org/10.1002/ghg.2233
- Investigation on ozone formation mechanism and control strategy of VOCs in petrochemical region: Insights from chemical reactivity and photochemical loss H. Ren et al. https://doi.org/10.1016/j.scitotenv.2024.169891
- Evaluating the feasibility of formaldehyde derived from hyperspectral remote sensing as a proxy for volatile organic compounds Q. Hong et al. https://doi.org/10.1016/j.atmosres.2021.105777
- Pesticide fate and transport in the atmosphere and implications for risk assessment C. Bedos et al. https://doi.org/10.1016/j.jhazmat.2026.141769
Saved (final revised paper)
Latest update: 22 Jul 2026
Short summary
This work expands upon the recently developed multivariate relative rate technique, presented in Shaw et al. (2019), for the measurement of rates of reaction between aromatic and aliphatic volatile organic compounds (VOCs) and OH. Knowledge of the rates of such reactions are important for understanding air quality in urban environments. This work also provides a key validation of structure–activity relationship models, which provide a theoretical method for estimating OH + VOC kinetics.
This work expands upon the recently developed multivariate relative rate technique, presented in...
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