Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique

Shaw, Jacob T.; Rickard, Andrew R.; Newland, Mike J.; Dillon, Terry J.

doi:https://doi.org/10.5194/acp-20-9725-2020

Articles | Volume 20, issue 16

https://doi.org/10.5194/acp-20-9725-2020

© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

https://doi.org/10.5194/acp-20-9725-2020

© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Articles | Volume 20, issue 16

Research article

|

19 Aug 2020

Research article |

| 19 Aug 2020

Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique

Jacob T. Shaw, Andrew R. Rickard, Mike J. Newland, and Terry J. Dillon

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Final revised paper (published on 19 Aug 2020)
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Preprint (discussion started on 22 Apr 2020)
Supplement to the preprint

Interactive discussion

Status: closed

AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment

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RC1: 'Reiew on Shaw et al.', Anonymous Referee #1, 26 May 2020
RC2: 'acp-2020-281 - referee comment', Anonymous Referee #2, 27 May 2020
RC3: 'acp-202-281', Anonymous Referee #3, 31 May 2020
RC4: 'Anonymous Referee #4', Anonymous Referee #4, 03 Jun 2020
AC1: 'Authors’ response', Jacob Shaw, 01 Jul 2020

Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision

AR by Jacob Shaw on behalf of the Authors (01 Jul 2020) Author's response Manuscript

ED: Publish as is (14 Jul 2020) by James B. Burkholder

AR by Jacob Shaw on behalf of the Authors (15 Jul 2020)

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Short summary

This work expands upon the recently developed multivariate relative rate technique, presented in Shaw et al. (2019), for the measurement of rates of reaction between aromatic and aliphatic volatile organic compounds (VOCs) and OH. Knowledge of the rates of such reactions are important for understanding air quality in urban environments. This work also provides a key validation of structure–activity relationship models, which provide a theoretical method for estimating OH + VOC kinetics.