Articles | Volume 20, issue 21
https://doi.org/10.5194/acp-20-13399-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-13399-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Nov 2020
Research article |
| 11 Nov 2020
| 11 Nov 2020
Volatile organic compound fluxes in a subarctic peatland and lake
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
Thomas Holst
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Department of Physical Geography and Ecosystem Science, Lund
University, Lund, Sweden
Mikkel Sillesen Matzen
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Andreas Westergaard-Nielsen
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
Tihomir Simin
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
Joachim Jansen
Department of Geological Sciences, Stockholm University, Stockholm,
Sweden
Bolin Centre for Climate Research, Stockholm, Sweden
Patrick Crill
Department of Geological Sciences, Stockholm University, Stockholm,
Sweden
Bolin Centre for Climate Research, Stockholm, Sweden
Thomas Friborg
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
Janne Rinne
Department of Physical Geography and Ecosystem Science, Lund
University, Lund, Sweden
Riikka Rinnan
Terrestrial Ecology Section, Department of Biology, University of
Copenhagen, Copenhagen, Denmark
Center for Permafrost (CENPERM), Department of Geosciences and Natural
Resource Management, University of Copenhagen, Copenhagen, Denmark
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The study uses the stable isotope 13C of carbon in methane to investigate the origins of spatial and temporal variation in methane emitted by a temperate wetland ecosystem. The results indicate that methane production is more important for spatial variation than methane consumption by micro-organisms. Temporal variation on a seasonal timescale is most likely affected by more than one driver simultaneously.
Deanna C. Myers, Saewung Kim, Steven Sjostedt, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 22, 10061–10076, https://doi.org/10.5194/acp-22-10061-2022, https://doi.org/10.5194/acp-22-10061-2022, 2022
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We present the first measurements of gas-phase sulfuric acid from the Amazon basin and evaluate the efficacy of existing sulfuric acid parameterizations in this understudied region. Sulfuric acid is produced during the daytime and nighttime, though current proxies underestimate nighttime production. These results illustrate the need for better parameterizations of sulfuric acid and its precursors that are informed by measurements across a broad range of locations.
Noah D. Smith, Eleanor J. Burke, Kjetil Schanke Aas, Inge H. J. Althuizen, Julia Boike, Casper Tai Christiansen, Bernd Etzelmüller, Thomas Friborg, Hanna Lee, Heather Rumbold, Rachael H. Turton, Sebastian Westermann, and Sarah E. Chadburn
Geosci. Model Dev., 15, 3603–3639, https://doi.org/10.5194/gmd-15-3603-2022, https://doi.org/10.5194/gmd-15-3603-2022, 2022
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The Arctic has large areas of small mounds that are caused by ice lifting up the soil. Snow blown by wind gathers in hollows next to these mounds, insulating them in winter. The hollows tend to be wetter, and thus the soil absorbs more heat in summer. The warm wet soil in the hollows decomposes, releasing methane. We have made a model of this, and we have tested how it behaves and whether it looks like sites in Scandinavia and Siberia. Sometimes we get more methane than a model without mounds.
Joel Dawson White, Lena Ström, Veiko Lehsten, Janne Rinne, and Dag Ahrén
Biogeosciences Discuss., https://doi.org/10.5194/bg-2021-353, https://doi.org/10.5194/bg-2021-353, 2022
Revised manuscript not accepted
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Microbes that produce CH4 play an important role to climate. Microbes which emit CH4 from wetlands is poorly understood. We observed that microbial community was of importance in explaining CH4 emission. We found, that microbes that produce CH4 hold the ability to produce and consume CH4 in multiple ways. This is important in terms of future climate scenarios, where wetlands are expected to shift. Therefore, we expect the community to be highly adaptive to future climate scenarios.
David Olefeldt, Mikael Hovemyr, McKenzie A. Kuhn, David Bastviken, Theodore J. Bohn, John Connolly, Patrick Crill, Eugénie S. Euskirchen, Sarah A. Finkelstein, Hélène Genet, Guido Grosse, Lorna I. Harris, Liam Heffernan, Manuel Helbig, Gustaf Hugelius, Ryan Hutchins, Sari Juutinen, Mark J. Lara, Avni Malhotra, Kristen Manies, A. David McGuire, Susan M. Natali, Jonathan A. O'Donnell, Frans-Jan W. Parmentier, Aleksi Räsänen, Christina Schädel, Oliver Sonnentag, Maria Strack, Suzanne E. Tank, Claire Treat, Ruth K. Varner, Tarmo Virtanen, Rebecca K. Warren, and Jennifer D. Watts
Earth Syst. Sci. Data, 13, 5127–5149, https://doi.org/10.5194/essd-13-5127-2021, https://doi.org/10.5194/essd-13-5127-2021, 2021
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Wetlands, lakes, and rivers are important sources of the greenhouse gas methane to the atmosphere. To understand current and future methane emissions from northern regions, we need maps that show the extent and distribution of specific types of wetlands, lakes, and rivers. The Boreal–Arctic Wetland and Lake Dataset (BAWLD) provides maps of five wetland types, seven lake types, and three river types for northern regions and will improve our ability to predict future methane emissions.
McKenzie A. Kuhn, Ruth K. Varner, David Bastviken, Patrick Crill, Sally MacIntyre, Merritt Turetsky, Katey Walter Anthony, Anthony D. McGuire, and David Olefeldt
Earth Syst. Sci. Data, 13, 5151–5189, https://doi.org/10.5194/essd-13-5151-2021, https://doi.org/10.5194/essd-13-5151-2021, 2021
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Methane (CH4) emissions from the boreal–Arctic region are globally significant, but the current magnitude of annual emissions is not well defined. Here we present a dataset of surface CH4 fluxes from northern wetlands, lakes, and uplands that was built alongside a compatible land cover dataset, sharing the same classifications. We show CH4 fluxes can be split by broad land cover characteristics. The dataset is useful for comparison against new field data and model parameterization or validation.
Patryk Łakomiec, Jutta Holst, Thomas Friborg, Patrick Crill, Niklas Rakos, Natascha Kljun, Per-Ola Olsson, Lars Eklundh, Andreas Persson, and Janne Rinne
Biogeosciences, 18, 5811–5830, https://doi.org/10.5194/bg-18-5811-2021, https://doi.org/10.5194/bg-18-5811-2021, 2021
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Methane emission from the subarctic mire with heterogeneous permafrost status was measured for the years 2014–2016. Lower methane emission was measured from the palsa mire sector while the thawing wet sector emitted more. Both sectors have a similar annual pattern with a gentle rise during spring and a decrease during autumn. The highest emission was observed in the late summer. Winter emissions were positive during the measurement period and have a significant impact on the annual budgets.
Kyle B. Delwiche, Sara Helen Knox, Avni Malhotra, Etienne Fluet-Chouinard, Gavin McNicol, Sarah Feron, Zutao Ouyang, Dario Papale, Carlo Trotta, Eleonora Canfora, You-Wei Cheah, Danielle Christianson, Ma. Carmelita R. Alberto, Pavel Alekseychik, Mika Aurela, Dennis Baldocchi, Sheel Bansal, David P. Billesbach, Gil Bohrer, Rosvel Bracho, Nina Buchmann, David I. Campbell, Gerardo Celis, Jiquan Chen, Weinan Chen, Housen Chu, Higo J. Dalmagro, Sigrid Dengel, Ankur R. Desai, Matteo Detto, Han Dolman, Elke Eichelmann, Eugenie Euskirchen, Daniela Famulari, Kathrin Fuchs, Mathias Goeckede, Sébastien Gogo, Mangaliso J. Gondwe, Jordan P. Goodrich, Pia Gottschalk, Scott L. Graham, Martin Heimann, Manuel Helbig, Carole Helfter, Kyle S. Hemes, Takashi Hirano, David Hollinger, Lukas Hörtnagl, Hiroki Iwata, Adrien Jacotot, Gerald Jurasinski, Minseok Kang, Kuno Kasak, John King, Janina Klatt, Franziska Koebsch, Ken W. Krauss, Derrick Y. F. Lai, Annalea Lohila, Ivan Mammarella, Luca Belelli Marchesini, Giovanni Manca, Jaclyn Hatala Matthes, Trofim Maximov, Lutz Merbold, Bhaskar Mitra, Timothy H. Morin, Eiko Nemitz, Mats B. Nilsson, Shuli Niu, Walter C. Oechel, Patricia Y. Oikawa, Keisuke Ono, Matthias Peichl, Olli Peltola, Michele L. Reba, Andrew D. Richardson, William Riley, Benjamin R. K. Runkle, Youngryel Ryu, Torsten Sachs, Ayaka Sakabe, Camilo Rey Sanchez, Edward A. Schuur, Karina V. R. Schäfer, Oliver Sonnentag, Jed P. Sparks, Ellen Stuart-Haëntjens, Cove Sturtevant, Ryan C. Sullivan, Daphne J. Szutu, Jonathan E. Thom, Margaret S. Torn, Eeva-Stiina Tuittila, Jessica Turner, Masahito Ueyama, Alex C. Valach, Rodrigo Vargas, Andrej Varlagin, Alma Vazquez-Lule, Joseph G. Verfaillie, Timo Vesala, George L. Vourlitis, Eric J. Ward, Christian Wille, Georg Wohlfahrt, Guan Xhuan Wong, Zhen Zhang, Donatella Zona, Lisamarie Windham-Myers, Benjamin Poulter, and Robert B. Jackson
Earth Syst. Sci. Data, 13, 3607–3689, https://doi.org/10.5194/essd-13-3607-2021, https://doi.org/10.5194/essd-13-3607-2021, 2021
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Methane is an important greenhouse gas, yet we lack knowledge about its global emissions and drivers. We present FLUXNET-CH4, a new global collection of methane measurements and a critical resource for the research community. We use FLUXNET-CH4 data to quantify the seasonality of methane emissions from freshwater wetlands, finding that methane seasonality varies strongly with latitude. Our new database and analysis will improve wetland model accuracy and inform greenhouse gas budgets.
Dianne Sanchez, Roger Seco, Dasa Gu, Alex Guenther, John Mak, Youngjae Lee, Danbi Kim, Joonyoung Ahn, Don Blake, Scott Herndon, Daun Jeong, John T. Sullivan, Thomas Mcgee, Rokjin Park, and Saewung Kim
Atmos. Chem. Phys., 21, 6331–6345, https://doi.org/10.5194/acp-21-6331-2021, https://doi.org/10.5194/acp-21-6331-2021, 2021
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We present observations of total reactive gases in a suburban forest observatory in the Seoul metropolitan area. The quantitative comparison with speciated trace gas observations illustrated significant underestimation in atmospheric reactivity from the speciated trace gas observational dataset. We present scientific discussion about potential causes.
Kuang-Yu Chang, William J. Riley, Patrick M. Crill, Robert F. Grant, and Scott R. Saleska
Biogeosciences, 17, 5849–5860, https://doi.org/10.5194/bg-17-5849-2020, https://doi.org/10.5194/bg-17-5849-2020, 2020
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Methane (CH4) is a strong greenhouse gas that can accelerate climate change and offset mitigation efforts. A key assumption embedded in many large-scale climate models is that ecosystem CH4 emissions can be estimated by fixed temperature relations. Here, we demonstrate that CH4 emissions cannot be parameterized by emergent temperature response alone due to variability driven by microbial and abiotic interactions. We also provide mechanistic understanding for observed CH4 emission hysteresis.
Samuel T. Wilson, Alia N. Al-Haj, Annie Bourbonnais, Claudia Frey, Robinson W. Fulweiler, John D. Kessler, Hannah K. Marchant, Jana Milucka, Nicholas E. Ray, Parvadha Suntharalingam, Brett F. Thornton, Robert C. Upstill-Goddard, Thomas S. Weber, Damian L. Arévalo-Martínez, Hermann W. Bange, Heather M. Benway, Daniele Bianchi, Alberto V. Borges, Bonnie X. Chang, Patrick M. Crill, Daniela A. del Valle, Laura Farías, Samantha B. Joye, Annette Kock, Jabrane Labidi, Cara C. Manning, John W. Pohlman, Gregor Rehder, Katy J. Sparrow, Philippe D. Tortell, Tina Treude, David L. Valentine, Bess B. Ward, Simon Yang, and Leonid N. Yurganov
Biogeosciences, 17, 5809–5828, https://doi.org/10.5194/bg-17-5809-2020, https://doi.org/10.5194/bg-17-5809-2020, 2020
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The oceans are a net source of the major greenhouse gases; however there has been little coordination of oceanic methane and nitrous oxide measurements. The scientific community has recently embarked on a series of capacity-building exercises to improve the interoperability of dissolved methane and nitrous oxide measurements. This paper derives from a workshop which discussed the challenges and opportunities for oceanic methane and nitrous oxide research in the near future.
Marielle Saunois, Ann R. Stavert, Ben Poulter, Philippe Bousquet, Josep G. Canadell, Robert B. Jackson, Peter A. Raymond, Edward J. Dlugokencky, Sander Houweling, Prabir K. Patra, Philippe Ciais, Vivek K. Arora, David Bastviken, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Kimberly M. Carlson, Mark Carrol, Simona Castaldi, Naveen Chandra, Cyril Crevoisier, Patrick M. Crill, Kristofer Covey, Charles L. Curry, Giuseppe Etiope, Christian Frankenberg, Nicola Gedney, Michaela I. Hegglin, Lena Höglund-Isaksson, Gustaf Hugelius, Misa Ishizawa, Akihiko Ito, Greet Janssens-Maenhout, Katherine M. Jensen, Fortunat Joos, Thomas Kleinen, Paul B. Krummel, Ray L. Langenfelds, Goulven G. Laruelle, Licheng Liu, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Joe McNorton, Paul A. Miller, Joe R. Melton, Isamu Morino, Jurek Müller, Fabiola Murguia-Flores, Vaishali Naik, Yosuke Niwa, Sergio Noce, Simon O'Doherty, Robert J. Parker, Changhui Peng, Shushi Peng, Glen P. Peters, Catherine Prigent, Ronald Prinn, Michel Ramonet, Pierre Regnier, William J. Riley, Judith A. Rosentreter, Arjo Segers, Isobel J. Simpson, Hao Shi, Steven J. Smith, L. Paul Steele, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Francesco N. Tubiello, Aki Tsuruta, Nicolas Viovy, Apostolos Voulgarakis, Thomas S. Weber, Michiel van Weele, Guido R. van der Werf, Ray F. Weiss, Doug Worthy, Debra Wunch, Yi Yin, Yukio Yoshida, Wenxin Zhang, Zhen Zhang, Yuanhong Zhao, Bo Zheng, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
Earth Syst. Sci. Data, 12, 1561–1623, https://doi.org/10.5194/essd-12-1561-2020, https://doi.org/10.5194/essd-12-1561-2020, 2020
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Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. We have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. This is the second version of the review dedicated to the decadal methane budget, integrating results of top-down and bottom-up estimates.
Nguyen Thanh Duc, Samuel Silverstein, Martin Wik, Patrick Crill, David Bastviken, and Ruth K. Varner
Hydrol. Earth Syst. Sci., 24, 3417–3430, https://doi.org/10.5194/hess-24-3417-2020, https://doi.org/10.5194/hess-24-3417-2020, 2020
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Under rapid ongoing climate change, accurate quantification of natural greenhouse gas emissions in aquatic environments such as lakes and ponds is needed to understand regulation and feedbacks. Building on the rapid development in wireless communication, sensors, and computation technology, we present a low-cost, open-source, automated and remotely accessed and controlled device for carbon dioxide and methane fluxes from open-water environments along with tests showing their potential.
Chinmoy Sarkar, Alex B. Guenther, Jeong-Hoo Park, Roger Seco, Eliane Alves, Sarah Batalha, Raoni Santana, Saewung Kim, James Smith, Julio Tóta, and Oscar Vega
Atmos. Chem. Phys., 20, 7179–7191, https://doi.org/10.5194/acp-20-7179-2020, https://doi.org/10.5194/acp-20-7179-2020, 2020
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Biogenic volatile organic compounds (BVOCs) are important components of the atmosphere due to their contribution to atmospheric chemistry and biogeochemical cycles. In this study, we report major BVOCs, e.g. isoprene and total monoterpene flux measurements with a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) using the eddy covariance (EC) method at a primary rainforest in eastern Amazonia. We used the measured data to evaluate the MEGAN2.1 model for the emission site.
Sheila Wachiye, Lutz Merbold, Timo Vesala, Janne Rinne, Matti Räsänen, Sonja Leitner, and Petri Pellikka
Biogeosciences, 17, 2149–2167, https://doi.org/10.5194/bg-17-2149-2020, https://doi.org/10.5194/bg-17-2149-2020, 2020
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Limited data on emissions in Africa translate into uncertainty during GHG budgeting. We studied annual CO2, N2O, and CH4 emissions in four land-use types in Kenyan savanna using static chambers and gas chromatography. CO2 emissions varied between seasons and land-use types. Soil moisture and vegetation explained the seasonal variation, while soil temperature was insignificant. N2O and CH4 emissions did not vary at all sites. Our results are useful in climate change mitigation interventions.
Joachim Jansen, Brett F. Thornton, Alicia Cortés, Jo Snöälv, Martin Wik, Sally MacIntyre, and Patrick M. Crill
Biogeosciences, 17, 1911–1932, https://doi.org/10.5194/bg-17-1911-2020, https://doi.org/10.5194/bg-17-1911-2020, 2020
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Lakes are important emitters of the greenhouse gas methane. We use field observations and a model to evaluate the importance of known drivers of methane production and release. Fast and slow changes of the diffusive flux were governed by wind speed and sediment temperature, respectively. Increased turbulence enhanced release, but storms depleted the lakes of gas and limited emissions. Our findings may inform model studies on the effects of weather and climate change on lake methane emissions.
Antoine Berchet, Isabelle Pison, Patrick M. Crill, Brett Thornton, Philippe Bousquet, Thibaud Thonat, Thomas Hocking, Joël Thanwerdas, Jean-Daniel Paris, and Marielle Saunois
Atmos. Chem. Phys., 20, 3987–3998, https://doi.org/10.5194/acp-20-3987-2020, https://doi.org/10.5194/acp-20-3987-2020, 2020
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Methane isotopes in the atmosphere can help us differentiate between emission processes. A large variety of natural and anthropogenic emission types are active in the Arctic and are unsatisfactorily understood and documented up to now. A ship-based campaign was carried out in summer 2014, providing a unique dataset of isotopic measurements in the Arctic Ocean. Using a chemistry-transport model, we link these measurements to circumpolar emissions and retrieve information about their signature.
Matti Räsänen, Mika Aurela, Ville Vakkari, Johan P. Beukes, Juha-Pekka Tuovinen, Pieter G. Van Zyl, Miroslav Josipovic, Stefan J. Siebert, Tuomas Laurila, Markku Kulmala, Lauri Laakso, Janne Rinne, Ram Oren, and Gabriel Katul
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2019-651, https://doi.org/10.5194/hess-2019-651, 2020
Revised manuscript not accepted
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The annual ET is approximately equal to precipitation during six measured years for grazed savanna grassland. The computed annual transpiration was highly constrained when rainfall was near or above the long-term mean but was reduced during severe drought year. The developed methodologies can be used in a wide range of arid and semi-arid ecosystems.
Daun Jeong, Roger Seco, Dasa Gu, Youngro Lee, Benjamin A. Nault, Christoph J. Knote, Tom Mcgee, John T. Sullivan, Jose L. Jimenez, Pedro Campuzano-Jost, Donald R. Blake, Dianne Sanchez, Alex B. Guenther, David Tanner, L. Gregory Huey, Russell Long, Bruce E. Anderson, Samuel R. Hall, Kirk Ullmann, Hye-jung Shin, Scott C. Herndon, Youngjae Lee, Danbi Kim, Joonyoung Ahn, and Saewung Kim
Atmos. Chem. Phys., 19, 12779–12795, https://doi.org/10.5194/acp-19-12779-2019, https://doi.org/10.5194/acp-19-12779-2019, 2019
Thibaud Thonat, Marielle Saunois, Isabelle Pison, Antoine Berchet, Thomas Hocking, Brett F. Thornton, Patrick M. Crill, and Philippe Bousquet
Atmos. Chem. Phys., 19, 12141–12161, https://doi.org/10.5194/acp-19-12141-2019, https://doi.org/10.5194/acp-19-12141-2019, 2019
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This paper discusses the methane isotopic signals that could be detected at instrumental surface sites in the northern high latitudes using a 3–D chemistry transport model. Isotopic signals may be used in atmospheric inverse systems to better characterize methane emissions and changes. We show that depending on the source magnitude and the location of the site, detecting isotopic signals of specific individual sources may be challenging for the new generation of methane isotope instruments.
Olli Peltola, Timo Vesala, Yao Gao, Olle Räty, Pavel Alekseychik, Mika Aurela, Bogdan Chojnicki, Ankur R. Desai, Albertus J. Dolman, Eugenie S. Euskirchen, Thomas Friborg, Mathias Göckede, Manuel Helbig, Elyn Humphreys, Robert B. Jackson, Georg Jocher, Fortunat Joos, Janina Klatt, Sara H. Knox, Natalia Kowalska, Lars Kutzbach, Sebastian Lienert, Annalea Lohila, Ivan Mammarella, Daniel F. Nadeau, Mats B. Nilsson, Walter C. Oechel, Matthias Peichl, Thomas Pypker, William Quinton, Janne Rinne, Torsten Sachs, Mateusz Samson, Hans Peter Schmid, Oliver Sonnentag, Christian Wille, Donatella Zona, and Tuula Aalto
Earth Syst. Sci. Data, 11, 1263–1289, https://doi.org/10.5194/essd-11-1263-2019, https://doi.org/10.5194/essd-11-1263-2019, 2019
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Here we develop a monthly gridded dataset of northern (> 45 N) wetland methane (CH4) emissions. The data product is derived using a random forest machine-learning technique and eddy covariance CH4 fluxes from 25 wetland sites. Annual CH4 emissions from these wetlands calculated from the derived data product are comparable to prior studies focusing on these areas. This product is an independent estimate of northern wetland CH4 emissions and hence could be used, e.g. for process model evaluation.
Kuang-Yu Chang, William J. Riley, Patrick M. Crill, Robert F. Grant, Virginia I. Rich, and Scott R. Saleska
The Cryosphere, 13, 647–663, https://doi.org/10.5194/tc-13-647-2019, https://doi.org/10.5194/tc-13-647-2019, 2019
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Permafrost peatlands store large amounts of carbon potentially vulnerable to decomposition under changing climate. We estimated effects of climate forcing biases on carbon cycling at a thawing permafrost peatland in subarctic Sweden. Our results indicate that many climate reanalysis products are cold and wet biased in our study region, leading to erroneous active layer depth and carbon budget estimates. Future studies should recognize the effects of climate forcing uncertainty on carbon cycling.
Anna L. Hodshire, Brett B. Palm, M. Lizabeth Alexander, Qijing Bian, Pedro Campuzano-Jost, Eben S. Cross, Douglas A. Day, Suzane S. de Sá, Alex B. Guenther, Armin Hansel, James F. Hunter, Werner Jud, Thomas Karl, Saewung Kim, Jesse H. Kroll, Jeong-Hoo Park, Zhe Peng, Roger Seco, James N. Smith, Jose L. Jimenez, and Jeffrey R. Pierce
Atmos. Chem. Phys., 18, 12433–12460, https://doi.org/10.5194/acp-18-12433-2018, https://doi.org/10.5194/acp-18-12433-2018, 2018
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We investigate the nucleation and growth processes that shape the aerosol size distribution inside oxidation flow reactors (OFRs) that sampled ambient air from Colorado and the Amazon rainforest. Results indicate that organics are important for both nucleation and growth, vapor uptake was limited to accumulation-mode particles, fragmentation reactions were important to limit particle growth at higher OH exposures, and an H2SO4-organics nucleation mechanism captured new particle formation well.
Maite Bauwens, Trissevgeni Stavrakou, Jean-François Müller, Bert Van Schaeybroeck, Lesley De Cruz, Rozemien De Troch, Olivier Giot, Rafiq Hamdi, Piet Termonia, Quentin Laffineur, Crist Amelynck, Niels Schoon, Bernard Heinesch, Thomas Holst, Almut Arneth, Reinhart Ceulemans, Arturo Sanchez-Lorenzo, and Alex Guenther
Biogeosciences, 15, 3673–3690, https://doi.org/10.5194/bg-15-3673-2018, https://doi.org/10.5194/bg-15-3673-2018, 2018
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Biogenic isoprene fluxes are simulated over Europe with the MEGAN–MOHYCAN model for the recent past and end-of-century climate at high spatiotemporal resolution (0.1°, 3 min). Due to climate change, fluxes increased by 40 % over 1979–2014. Climate scenarios for 2070–2099 suggest an increase by 83 % due to climate, and an even stronger increase when the potential impact of CO2 fertilization is considered (up to 141 %). Accounting for CO2 inhibition cancels out a large part of these increases.
Christian Nyrop Albers, Magnus Kramshøj, and Riikka Rinnan
Biogeosciences, 15, 3591–3601, https://doi.org/10.5194/bg-15-3591-2018, https://doi.org/10.5194/bg-15-3591-2018, 2018
Aino Korrensalo, Elisa Männistö, Pavel Alekseychik, Ivan Mammarella, Janne Rinne, Timo Vesala, and Eeva-Stiina Tuittila
Biogeosciences, 15, 1749–1761, https://doi.org/10.5194/bg-15-1749-2018, https://doi.org/10.5194/bg-15-1749-2018, 2018
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We measured methane fluxes of a boreal bog from six different plant community types in 2012–2014. We found only little variation in methane fluxes among plant community types. Peat temperature as well as both leaf area of plant species with air channels and of all vegetation are important factors controlling the fluxes. We also detected negative net fluxes indicating methane consumption each year. Our results can be used to improve the models of peatland methane dynamics under climate change.
Magnus Gålfalk, Martin Karlson, Patrick Crill, Philippe Bousquet, and David Bastviken
Biogeosciences, 15, 1549–1557, https://doi.org/10.5194/bg-15-1549-2018, https://doi.org/10.5194/bg-15-1549-2018, 2018
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We describe a quick in situ method for mapping ground surface cover, calculating areas of each surface type in a 10 x 10 m plot for each measurement. The method is robust, weather-independent, easily carried out, and uses wide-field imaging with a standard remote-controlled camera mounted on a very long extendible monopod from a height of 3–4.5 m. The method enables collection of detailed field reference data, critical in many remote sensing applications, such as wetland mapping.
Chunjing Qiu, Dan Zhu, Philippe Ciais, Bertrand Guenet, Gerhard Krinner, Shushi Peng, Mika Aurela, Christian Bernhofer, Christian Brümmer, Syndonia Bret-Harte, Housen Chu, Jiquan Chen, Ankur R. Desai, Jiří Dušek, Eugénie S. Euskirchen, Krzysztof Fortuniak, Lawrence B. Flanagan, Thomas Friborg, Mateusz Grygoruk, Sébastien Gogo, Thomas Grünwald, Birger U. Hansen, David Holl, Elyn Humphreys, Miriam Hurkuck, Gerard Kiely, Janina Klatt, Lars Kutzbach, Chloé Largeron, Fatima Laggoun-Défarge, Magnus Lund, Peter M. Lafleur, Xuefei Li, Ivan Mammarella, Lutz Merbold, Mats B. Nilsson, Janusz Olejnik, Mikaell Ottosson-Löfvenius, Walter Oechel, Frans-Jan W. Parmentier, Matthias Peichl, Norbert Pirk, Olli Peltola, Włodzimierz Pawlak, Daniel Rasse, Janne Rinne, Gaius Shaver, Hans Peter Schmid, Matteo Sottocornola, Rainer Steinbrecher, Torsten Sachs, Marek Urbaniak, Donatella Zona, and Klaudia Ziemblinska
Geosci. Model Dev., 11, 497–519, https://doi.org/10.5194/gmd-11-497-2018, https://doi.org/10.5194/gmd-11-497-2018, 2018
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Northern peatlands store large amount of soil carbon and are vulnerable to climate change. We implemented peatland hydrological and carbon accumulation processes into the ORCHIDEE land surface model. The model was evaluated against EC measurements from 30 northern peatland sites. The model generally well reproduced the spatial gradient and temporal variations in GPP and NEE at these sites. Water table depth was not well predicted but had only small influence on simulated NEE.
Brett B. Palm, Suzane S. de Sá, Douglas A. Day, Pedro Campuzano-Jost, Weiwei Hu, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Joel Brito, Florian Wurm, Paulo Artaxo, Ryan Thalman, Jian Wang, Lindsay D. Yee, Rebecca Wernis, Gabriel Isaacman-VanWertz, Allen H. Goldstein, Yingjun Liu, Stephen R. Springston, Rodrigo Souza, Matt K. Newburn, M. Lizabeth Alexander, Scot T. Martin, and Jose L. Jimenez
Atmos. Chem. Phys., 18, 467–493, https://doi.org/10.5194/acp-18-467-2018, https://doi.org/10.5194/acp-18-467-2018, 2018
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Ambient air was oxidized by OH or O3 in an oxidation flow reactor during both wet and dry seasons in the GoAmazon2014/5 campaign to study secondary organic aerosol (SOA) formation. We investigated how much biogenic, urban, and biomass burning sources contributed to the ambient concentrations of SOA precursor gases and how their contributions changed diurnally and seasonally. SOA yields and hygroscopicity of organic aerosol in the oxidation flow reactor were also studied.
Maarit Raivonen, Sampo Smolander, Leif Backman, Jouni Susiluoto, Tuula Aalto, Tiina Markkanen, Jarmo Mäkelä, Janne Rinne, Olli Peltola, Mika Aurela, Annalea Lohila, Marin Tomasic, Xuefei Li, Tuula Larmola, Sari Juutinen, Eeva-Stiina Tuittila, Martin Heimann, Sanna Sevanto, Thomas Kleinen, Victor Brovkin, and Timo Vesala
Geosci. Model Dev., 10, 4665–4691, https://doi.org/10.5194/gmd-10-4665-2017, https://doi.org/10.5194/gmd-10-4665-2017, 2017
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Wetlands are one of the most significant natural sources of the strong greenhouse gas methane. We developed a model that can be used within a larger wetland carbon model to simulate the methane emissions. In this study, we present the model and results of its testing. We found that the model works well with different settings and that the results depend primarily on the rate of input anoxic soil respiration and also on factors that affect the simulated oxygen concentrations in the wetland soil.
Mathilde Jammet, Sigrid Dengel, Ernesto Kettner, Frans-Jan W. Parmentier, Martin Wik, Patrick Crill, and Thomas Friborg
Biogeosciences, 14, 5189–5216, https://doi.org/10.5194/bg-14-5189-2017, https://doi.org/10.5194/bg-14-5189-2017, 2017
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The quantitative importance of northern lakes in terrestrial carbon budgets is uncertain, as year-round observations of carbon fluxes are rare. We measured CH4 and CO2 fluxes from a subarctic lake and nearby fen during 2.5 years with one eddy covariance system. We identified drivers of seasonal variability in lake fluxes and show the importance of winter and spring for annual carbon exchange in both ecosystems. The lake as a source of atmospheric carbon partially compensates the fen carbon sink.
Sarah E. Chadburn, Gerhard Krinner, Philipp Porada, Annett Bartsch, Christian Beer, Luca Belelli Marchesini, Julia Boike, Altug Ekici, Bo Elberling, Thomas Friborg, Gustaf Hugelius, Margareta Johansson, Peter Kuhry, Lars Kutzbach, Moritz Langer, Magnus Lund, Frans-Jan W. Parmentier, Shushi Peng, Ko Van Huissteden, Tao Wang, Sebastian Westermann, Dan Zhu, and Eleanor J. Burke
Biogeosciences, 14, 5143–5169, https://doi.org/10.5194/bg-14-5143-2017, https://doi.org/10.5194/bg-14-5143-2017, 2017
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Earth system models (ESMs) are our main tools for understanding future climate. The Arctic is important for the future carbon cycle, particularly due to the large carbon stocks in permafrost. We evaluated the performance of the land component of three major ESMs at Arctic tundra sites, focusing on the fluxes and stocks of carbon.
We show that the next steps for model improvement are to better represent vegetation dynamics, to include mosses and to improve below-ground carbon cycle processes.
Efrén López-Blanco, Magnus Lund, Mathew Williams, Mikkel P. Tamstorf, Andreas Westergaard-Nielsen, Jean-François Exbrayat, Birger U. Hansen, and Torben R. Christensen
Biogeosciences, 14, 4467–4483, https://doi.org/10.5194/bg-14-4467-2017, https://doi.org/10.5194/bg-14-4467-2017, 2017
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An improvement in our process-based understanding of CO2 exchanges in the Arctic and their climate sensitivity is critical. With continued warming temperatures and longer growing seasons, tundra systems will likely increase rates of C cycling, although shifts in sink strength could take place, challenging the forecast of upcoming C states. In this context, we investigated the functional responses of C exchange to environmental characteristics across 8 consecutive years in West Greenland.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Ray Weiss, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Atmos. Chem. Phys., 17, 11135–11161, https://doi.org/10.5194/acp-17-11135-2017, https://doi.org/10.5194/acp-17-11135-2017, 2017
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Following the Global Methane Budget 2000–2012 published in Saunois et al. (2016), we use the same dataset of bottom-up and top-down approaches to discuss the variations in methane emissions over the period 2000–2012. The changes in emissions are discussed both in terms of trends and quasi-decadal changes. The ensemble gathered here allows us to synthesise the robust changes in terms of regional and sectorial contributions to the increasing methane emissions.
Ylva van Meeningen, Guy Schurgers, Riikka Rinnan, and Thomas Holst
Biogeosciences, 14, 4045–4060, https://doi.org/10.5194/bg-14-4045-2017, https://doi.org/10.5194/bg-14-4045-2017, 2017
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Leaf scale measurements have been performed on English oak, European beech and Norway spruce at a field site in Denmark to study the release of volatile compounds in response to a change in light. Whilst some compounds, like isoprene and sabinene, increased with increasing light, other compounds, like camphene, showed no light response for most of the trees. This can help to increase our knowledge of how species and compounds respond to light and to possibly improve how they can be modeled.
Thibaud Thonat, Marielle Saunois, Philippe Bousquet, Isabelle Pison, Zeli Tan, Qianlai Zhuang, Patrick M. Crill, Brett F. Thornton, David Bastviken, Ed J. Dlugokencky, Nikita Zimov, Tuomas Laurila, Juha Hatakka, Ove Hermansen, and Doug E. J. Worthy
Atmos. Chem. Phys., 17, 8371–8394, https://doi.org/10.5194/acp-17-8371-2017, https://doi.org/10.5194/acp-17-8371-2017, 2017
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Atmospheric methane simulations in the Arctic have been made for 2012 and compared to continuous observations at six measurement sites. All methane sources significantly affect the measurements at all stations, at least at the synoptic scale, except for biomass burning. An appropriate modelling framework combined with continuous observations of atmospheric methane enables us to gain knowledge on regional methane sources, including those which are usually poorly represented, such as freshwater.
Célia J. Sapart, Natalia Shakhova, Igor Semiletov, Joachim Jansen, Sönke Szidat, Denis Kosmach, Oleg Dudarev, Carina van der Veen, Matthias Egger, Valentine Sergienko, Anatoly Salyuk, Vladimir Tumskoy, Jean-Louis Tison, and Thomas Röckmann
Biogeosciences, 14, 2283–2292, https://doi.org/10.5194/bg-14-2283-2017, https://doi.org/10.5194/bg-14-2283-2017, 2017
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The Arctic Ocean, especially the Siberian shelves, overlays large areas of subsea permafrost that is degrading. We show that methane with a biogenic origin is emitted from this permafrost. At locations where bubble plumes have been observed, methane can escape oxidation in the surface sediment and rapidly migrate through the very shallow water column of this region to escape to the atmosphere, generating a positive radiative feedback.
Matti Räsänen, Mika Aurela, Ville Vakkari, Johan P. Beukes, Juha-Pekka Tuovinen, Pieter G. Van Zyl, Miroslav Josipovic, Andrew D. Venter, Kerneels Jaars, Stefan J. Siebert, Tuomas Laurila, Janne Rinne, and Lauri Laakso
Biogeosciences, 14, 1039–1054, https://doi.org/10.5194/bg-14-1039-2017, https://doi.org/10.5194/bg-14-1039-2017, 2017
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This study presents measurements of carbon dioxide exchange between the atmosphere and a grazed savanna grassland ecosystem for 3 years. We find that the yearly variation in carbon dioxide balance is largely determined by the changes in the early wet season balance (September to November) and in the mid-growing season balance (December to January).
Aino Korrensalo, Pavel Alekseychik, Tomáš Hájek, Janne Rinne, Timo Vesala, Lauri Mehtätalo, Ivan Mammarella, and Eeva-Stiina Tuittila
Biogeosciences, 14, 257–269, https://doi.org/10.5194/bg-14-257-2017, https://doi.org/10.5194/bg-14-257-2017, 2017
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Photosynthetic parameters of peatland plant species were measured over one growing season in an ombrotrophic bog. Based on these measurements, ecosystem-level photosynthesis was calculated for the whole growing season and compared with an estimate derived from micrometeorological measurements. These two estimates corresponded well. Species with low areal cover at the site but high photosynthetic efficiency appeared to be potentially important for the ecosystem-level carbon balance.
Kerneels Jaars, Pieter G. van Zyl, Johan P. Beukes, Heidi Hellén, Ville Vakkari, Micky Josipovic, Andrew D. Venter, Matti Räsänen, Leandra Knoetze, Dirk P. Cilliers, Stefan J. Siebert, Markku Kulmala, Janne Rinne, Alex Guenther, Lauri Laakso, and Hannele Hakola
Atmos. Chem. Phys., 16, 15665–15688, https://doi.org/10.5194/acp-16-15665-2016, https://doi.org/10.5194/acp-16-15665-2016, 2016
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Biogenic volatile organic compounds (BVOCs) – important in tropospheric ozone and secondary organic aerosol formation – were measured at a savannah grassland in South Africa. Results presented are the most extensive for this type of landscape. Compared to other parts of the world, monoterpene levels were similar, while very low isoprene levels led to significantly lower total BVOC levels. BVOC levels were an order of magnitude lower compared to anthropogenic VOC levels measured at Welgegund.
Jing Tang, Guy Schurgers, Hanna Valolahti, Patrick Faubert, Päivi Tiiva, Anders Michelsen, and Riikka Rinnan
Biogeosciences, 13, 6651–6667, https://doi.org/10.5194/bg-13-6651-2016, https://doi.org/10.5194/bg-13-6651-2016, 2016
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Arctic is warming at twice the global average speed and the warming-induced increases in biogenic volatile organic compound (BVOC) emissions from Arctic plants are expected to be drastic. This modelling study aims to investigate BVOC emission responses to warming. The results show that 2 °C summer warming can increase annual emissions by 56 % and the short-term warming responses are strongly impacted by leaf temperature, while the long-time responses are interacted with vegetation changes.
Helene Hoffmann, Rasmus Jensen, Anton Thomsen, Hector Nieto, Jesper Rasmussen, and Thomas Friborg
Biogeosciences, 13, 6545–6563, https://doi.org/10.5194/bg-13-6545-2016, https://doi.org/10.5194/bg-13-6545-2016, 2016
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This study investigates whether the UAV (drone) based WDI can determine crop water stress from fields with open canopies (land surface consisting of both soil and canopy) and from fields where canopies are starting to senesce. This utility could solve issues that arise when applying the commonly used CWSI stress index. The WDI succeeded in providing accurate, high-resolution estimates of crop water stress at different growth stages of barley.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Victor Brovkin, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Charles Curry, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Julia Marshall, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Catherine Prigent, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Paul Steele, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Michiel van Weele, Guido R. van der Werf, Ray Weiss, Christine Wiedinmyer, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Earth Syst. Sci. Data, 8, 697–751, https://doi.org/10.5194/essd-8-697-2016, https://doi.org/10.5194/essd-8-697-2016, 2016
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An accurate assessment of the methane budget is important to understand the atmospheric methane concentrations and trends and to provide realistic pathways for climate change mitigation. The various and diffuse sources of methane as well and its oxidation by a very short lifetime radical challenge this assessment. We quantify the methane sources and sinks as well as their uncertainties based on both bottom-up and top-down approaches provided by a broad international scientific community.
Ylva van Meeningen, Guy Schurgers, Riikka Rinnan, and Thomas Holst
Biogeosciences, 13, 6067–6080, https://doi.org/10.5194/bg-13-6067-2016, https://doi.org/10.5194/bg-13-6067-2016, 2016
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English oak and European beech are common European trees known to release volatile compounds such as isoprene and monoterpenes. By doing leaf chamber measurements at three sites in Europe, the aim was to study how the emission differed for cloned trees growing at different sites. The measured emission rates from clones varied between sites, but the relative compound contribution was stable both within and between sites. This can help to increase our knowledge of emission pattern variability.
Ivan Kourtchev, Ricardo H. M. Godoi, Sarah Connors, James G. Levine, Alex T. Archibald, Ana F. L. Godoi, Sarah L. Paralovo, Cybelli G. G. Barbosa, Rodrigo A. F. Souza, Antonio O. Manzi, Roger Seco, Steve Sjostedt, Jeong-Hoo Park, Alex Guenther, Saewung Kim, James Smith, Scot T. Martin, and Markus Kalberer
Atmos. Chem. Phys., 16, 11899–11913, https://doi.org/10.5194/acp-16-11899-2016, https://doi.org/10.5194/acp-16-11899-2016, 2016
Weiwei Hu, Brett B. Palm, Douglas A. Day, Pedro Campuzano-Jost, Jordan E. Krechmer, Zhe Peng, Suzane S. de Sá, Scot T. Martin, M. Lizabeth Alexander, Karsten Baumann, Lina Hacker, Astrid Kiendler-Scharr, Abigail R. Koss, Joost A. de Gouw, Allen H. Goldstein, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Francesco Canonaco, André S. H. Prévôt, William H. Brune, and Jose L. Jimenez
Atmos. Chem. Phys., 16, 11563–11580, https://doi.org/10.5194/acp-16-11563-2016, https://doi.org/10.5194/acp-16-11563-2016, 2016
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IEPOX-SOA is biogenically derived secondary organic aerosol under anthropogenic influence, which has been shown to comprise a substantial fraction of OA globally. We investigated the lifetime of ambient IEPOX-SOA in the SE US and Amazonia, with an oxidation flow reactor and thermodenuder coupled with MS-based instrumentation. The low volatility and long lifetime of IEPOX-SOA against OH radicals' oxidation (> 2 weeks) was observed, which can help to constrain OA impact on air quality and climate.
Pekka Rantala, Leena Järvi, Risto Taipale, Terhi K. Laurila, Johanna Patokoski, Maija K. Kajos, Mona Kurppa, Sami Haapanala, Erkki Siivola, Tuukka Petäjä, Taina M. Ruuskanen, and Janne Rinne
Atmos. Chem. Phys., 16, 7981–8007, https://doi.org/10.5194/acp-16-7981-2016, https://doi.org/10.5194/acp-16-7981-2016, 2016
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Fluxes of volatile organic compounds (VOCs) were measured above an urban landscape in Helsinki, northern Europe. We found that traffic was a major source for many oxygenated and aromatic VOCs, whereas isoprene originated mostly from the urban vegetation. Overall, the VOC fluxes were quite small in comparison with the earlier urban VOC flux measurements.
Simon Schallhart, Pekka Rantala, Eiko Nemitz, Ditte Taipale, Ralf Tillmann, Thomas F. Mentel, Benjamin Loubet, Giacomo Gerosa, Angelo Finco, Janne Rinne, and Taina M. Ruuskanen
Atmos. Chem. Phys., 16, 7171–7194, https://doi.org/10.5194/acp-16-7171-2016, https://doi.org/10.5194/acp-16-7171-2016, 2016
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We present ecosystem exchange fluxes from a mixed oak–hornbeam forest in the Po Valley, Italy. Detectable fluxes were observed for 29 compounds, dominated by isoprene, which comprised over 60 % of the upward flux. Methanol seemed to be deposited to dew, as the deposition happened in the early morning. We estimated that up to 30 % of the upward flux of methyl vinyl ketone and methacrolein originated from atmospheric oxidation of isoprene.
Dominique E. Young, Hwajin Kim, Caroline Parworth, Shan Zhou, Xiaolu Zhang, Christopher D. Cappa, Roger Seco, Saewung Kim, and Qi Zhang
Atmos. Chem. Phys., 16, 5427–5451, https://doi.org/10.5194/acp-16-5427-2016, https://doi.org/10.5194/acp-16-5427-2016, 2016
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Aerosol chemistry and the sources and processes driving the observed temporal and diurnal variations of PM were studied in a polluted urban environment during winter 2013. These results were compared to a similar campaign from winter 2010. Meteorology strongly influenced PM composition, both directly and indirectly. Nighttime reactions played a more important role in 2013 and the influence from a nighttime formed residual layer that mixed down in the morning was also much more intense in 2013.
Almut Arneth, Risto Makkonen, Stefan Olin, Pauli Paasonen, Thomas Holst, Maija K. Kajos, Markku Kulmala, Trofim Maximov, Paul A. Miller, and Guy Schurgers
Atmos. Chem. Phys., 16, 5243–5262, https://doi.org/10.5194/acp-16-5243-2016, https://doi.org/10.5194/acp-16-5243-2016, 2016
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We study the potentially contrasting effects of enhanced ecosystem CO2 release in response to warmer temperatures vs. emissions of biogenic volatile organic compounds and their formation of secondary organic aerosol through a combination of measurements and modelling at a remote location in Eastern Siberia. The study aims to highlight the number of potentially opposing processes and complex interactions between vegetation physiology, soil processes and trace-gas exchanges in the climate system.
Norbert Pirk, Mikhail Mastepanov, Frans-Jan W. Parmentier, Magnus Lund, Patrick Crill, and Torben R. Christensen
Biogeosciences, 13, 903–912, https://doi.org/10.5194/bg-13-903-2016, https://doi.org/10.5194/bg-13-903-2016, 2016
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The exchange of greenhouse gases between the land and the atmosphere is often measured by monitoring the gas concentrations inside a chamber which is placed on the ground. We investigated different ways to calculate the gas exchange rate and identified several different processes which influence the gas exchange measurement.
S. Osterwalder, J. Fritsche, C. Alewell, M. Schmutz, M. B. Nilsson, G. Jocher, J. Sommar, J. Rinne, and K. Bishop
Atmos. Meas. Tech., 9, 509–524, https://doi.org/10.5194/amt-9-509-2016, https://doi.org/10.5194/amt-9-509-2016, 2016
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Human activities have increased mercury (Hg) cycling between land and atmosphere. To define landscapes as sinks or sources of Hg we have developed an advanced REA system for long-term measurements of gaseous elemental Hg exchange. It was tested in two contrasting environments: above Basel, Switzerland, and a peatland in Sweden. Both landscapes showed net Hg emission (15 and 3 ng m−2 h−1, respectively). The novel system will help to advance our understanding of Hg exchange on an ecosystem scale.
H. Hoffmann, H. Nieto, R. Jensen, R. Guzinski, P. Zarco-Tejada, and T. Friborg
Hydrol. Earth Syst. Sci., 20, 697–713, https://doi.org/10.5194/hess-20-697-2016, https://doi.org/10.5194/hess-20-697-2016, 2016
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Thermal images collected with an unmanned aerial vehicle (UAV) are applied to algorithms originally developed to be operational with satellite images, in order to estimate evapotranspiration in very high resolution.
It is concluded that the thermal UAV data can be used for model input and for other potential applications requiring good quality, consistent, and high resolution land surface temperature.
M. E. Marushchak, T. Friborg, C. Biasi, M. Herbst, T. Johansson, I. Kiepe, M. Liimatainen, S. E. Lind, P. J. Martikainen, T. Virtanen, H. Soegaard, and N. J. Shurpali
Biogeosciences, 13, 597–608, https://doi.org/10.5194/bg-13-597-2016, https://doi.org/10.5194/bg-13-597-2016, 2016
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Arctic region is experiencing an unprecedented rise in permafrost temperatures leading to permafrsot thawing with dire implications for ecosystem structure and functioning. Therefore, it imperative to understand the behaviour of Arctic ecosystems under present climatic conditions so that we are equipped with the information to predict their future behaviour. This study presents field data on methane exchange from Seida, located in NW Siberia, Russia measured using various biogeochemical tools.
J. Patokoski, T. M. Ruuskanen, M. K. Kajos, R. Taipale, P. Rantala, J. Aalto, T. Ryyppö, T. Nieminen, H. Hakola, and J. Rinne
Atmos. Chem. Phys., 15, 13413–13432, https://doi.org/10.5194/acp-15-13413-2015, https://doi.org/10.5194/acp-15-13413-2015, 2015
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In this study, main source areas for long-lived VOCs at the boreal forest in SMEAR II were determined. Air masses arriving from eastern and western directions were more polluted than those arriving from the northern direction. The biogenic and anthropogenic influences of three different source profiles were determined. The elevated trace gas concentrations from forest fire episodes were observed clearly in the trajectory analysis.
M. K. Kajos, P. Rantala, M. Hill, H. Hellén, J. Aalto, J. Patokoski, R. Taipale, C. C. Hoerger, S. Reimann, T. M. Ruuskanen, J. Rinne, and T. Petäjä
Atmos. Meas. Tech., 8, 4453–4473, https://doi.org/10.5194/amt-8-4453-2015, https://doi.org/10.5194/amt-8-4453-2015, 2015
P. Rantala, J. Aalto, R. Taipale, T. M. Ruuskanen, and J. Rinne
Biogeosciences, 12, 5753–5770, https://doi.org/10.5194/bg-12-5753-2015, https://doi.org/10.5194/bg-12-5753-2015, 2015
M. S. Torn, A. Chabbi, P. Crill, P. J. Hanson, I. A. Janssens, Y. Luo, C. H. Pries, C. Rumpel, M. W. I. Schmidt, J. Six, M. Schrumpf, and B. Zhu
SOIL, 1, 575–582, https://doi.org/10.5194/soil-1-575-2015, https://doi.org/10.5194/soil-1-575-2015, 2015
G. Wohlfahrt, C. Amelynck, C. Ammann, A. Arneth, I. Bamberger, A. H. Goldstein, L. Gu, A. Guenther, A. Hansel, B. Heinesch, T. Holst, L. Hörtnagl, T. Karl, Q. Laffineur, A. Neftel, K. McKinney, J. W. Munger, S. G. Pallardy, G. W. Schade, R. Seco, and N. Schoon
Atmos. Chem. Phys., 15, 7413–7427, https://doi.org/10.5194/acp-15-7413-2015, https://doi.org/10.5194/acp-15-7413-2015, 2015
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Methanol is the second most abundant volatile organic compound in the troposphere and plays a significant role in atmospheric chemistry. While there is consensus about the dominant role of plants as the major source and the reaction with OH as the major sink, global methanol budgets diverge considerably in terms of source/sink estimates. Here we present micrometeorological methanol flux data from eight sites in order to provide a first cross-site synthesis of the terrestrial methanol exchange.
R. Thalman, M. T. Baeza-Romero, S. M. Ball, E. Borrás, M. J. S. Daniels, I. C. A. Goodall, S. B. Henry, T. Karl, F. N. Keutsch, S. Kim, J. Mak, P. S. Monks, A. Muñoz, J. Orlando, S. Peppe, A. R. Rickard, M. Ródenas, P. Sánchez, R. Seco, L. Su, G. Tyndall, M. Vázquez, T. Vera, E. Waxman, and R. Volkamer
Atmos. Meas. Tech., 8, 1835–1862, https://doi.org/10.5194/amt-8-1835-2015, https://doi.org/10.5194/amt-8-1835-2015, 2015
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Measurements of α-dicarbonyl compounds, like glyoxal (CHOCHO) and methyl glyoxal (CH3C(O)CHO), are informative about the rate of hydrocarbon oxidation, oxidative capacity, and secondary organic aerosol (SOA) formation in the atmosphere. We have compared nine instruments and seven techniques to measure α-dicarbonyl, using simulation chamber facilities in the US and Europe. We assess our understanding of calibration, precision, accuracy and detection limits, as well as possible sampling biases.
E. Sundqvist, P. Vestin, P. Crill, T. Persson, and A. Lindroth
Biogeosciences, 11, 6095–6105, https://doi.org/10.5194/bg-11-6095-2014, https://doi.org/10.5194/bg-11-6095-2014, 2014
H. N. Mbufong, M. Lund, M. Aurela, T. R. Christensen, W. Eugster, T. Friborg, B. U. Hansen, E. R. Humphreys, M. Jackowicz-Korczynski, L. Kutzbach, P. M. Lafleur, W. C. Oechel, F. J. W. Parmentier, D. P. Rasse, A. V. Rocha, T. Sachs, M. K. van der Molen, and M. P. Tamstorf
Biogeosciences, 11, 4897–4912, https://doi.org/10.5194/bg-11-4897-2014, https://doi.org/10.5194/bg-11-4897-2014, 2014
J. Deng, C. Li, S. Frolking, Y. Zhang, K. Bäckstrand, and P. Crill
Biogeosciences, 11, 4753–4770, https://doi.org/10.5194/bg-11-4753-2014, https://doi.org/10.5194/bg-11-4753-2014, 2014
J. P. Greenberg, J. Peñuelas, A. Guenther, R. Seco, A. Turnipseed, X. Jiang, I. Filella, M. Estiarte, J. Sardans, R. Ogaya, J. Llusia, and F. Rapparini
Atmos. Meas. Tech., 7, 2263–2271, https://doi.org/10.5194/amt-7-2263-2014, https://doi.org/10.5194/amt-7-2263-2014, 2014
A. Arneth, S. Olin, R. Makkonen, P. Paasonen, T. Holst, M. Kajos, M. Kulmala, T. Maximov, P. A. Miller, and G. Schurgers
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-19149-2014, https://doi.org/10.5194/acpd-14-19149-2014, 2014
Revised manuscript not accepted
A. Virkkula, J. Levula, T. Pohja, P. P. Aalto, P. Keronen, S. Schobesberger, C. B. Clements, L. Pirjola, A.-J. Kieloaho, L. Kulmala, H. Aaltonen, J. Patokoski, J. Pumpanen, J. Rinne, T. Ruuskanen, M. Pihlatie, H. E. Manninen, V. Aaltonen, H. Junninen, T. Petäjä, J. Backman, M. Dal Maso, T. Nieminen, T. Olsson, T. Grönholm, J. Aalto, T. H. Virtanen, M. Kajos, V.-M. Kerminen, D. M. Schultz, J. Kukkonen, M. Sofiev, G. De Leeuw, J. Bäck, P. Hari, and M. Kulmala
Atmos. Chem. Phys., 14, 4473–4502, https://doi.org/10.5194/acp-14-4473-2014, https://doi.org/10.5194/acp-14-4473-2014, 2014
J. D. Watts, J. S. Kimball, F. J. W. Parmentier, T. Sachs, J. Rinne, D. Zona, W. Oechel, T. Tagesson, M. Jackowicz-Korczyński, and M. Aurela
Biogeosciences, 11, 1961–1980, https://doi.org/10.5194/bg-11-1961-2014, https://doi.org/10.5194/bg-11-1961-2014, 2014
A. L. Corrigan, L. M. Russell, S. Takahama, M. Äijälä, M. Ehn, H. Junninen, J. Rinne, T. Petäjä, M. Kulmala, A. L. Vogel, T. Hoffmann, C. J. Ebben, F. M. Geiger, P. Chhabra, J. H. Seinfeld, D. R. Worsnop, W. Song, J. Auld, and J. Williams
Atmos. Chem. Phys., 13, 12233–12256, https://doi.org/10.5194/acp-13-12233-2013, https://doi.org/10.5194/acp-13-12233-2013, 2013
N. Unger, K. Harper, Y. Zheng, N. Y. Kiang, I. Aleinov, A. Arneth, G. Schurgers, C. Amelynck, A. Goldstein, A. Guenther, B. Heinesch, C. N. Hewitt, T. Karl, Q. Laffineur, B. Langford, K. A. McKinney, P. Misztal, M. Potosnak, J. Rinne, S. Pressley, N. Schoon, and D. Serça
Atmos. Chem. Phys., 13, 10243–10269, https://doi.org/10.5194/acp-13-10243-2013, https://doi.org/10.5194/acp-13-10243-2013, 2013
M. K. Kajos, H. Hakola, T. Holst, T. Nieminen, V. Tarvainen, T. Maximov, T. Petäjä, A. Arneth, and J. Rinne
Biogeosciences, 10, 4705–4719, https://doi.org/10.5194/bg-10-4705-2013, https://doi.org/10.5194/bg-10-4705-2013, 2013
R. Seco, J. Peñuelas, I. Filella, J. Llusia, S. Schallhart, A. Metzger, M. Müller, and A. Hansel
Atmos. Chem. Phys., 13, 4291–4306, https://doi.org/10.5194/acp-13-4291-2013, https://doi.org/10.5194/acp-13-4291-2013, 2013
H. Hakola, H. Hellén, M. Hemmilä, J. Rinne, and M. Kulmala
Atmos. Chem. Phys., 12, 11665–11678, https://doi.org/10.5194/acp-12-11665-2012, https://doi.org/10.5194/acp-12-11665-2012, 2012
Related subject area
Subject: Biosphere Interactions | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Interannual variability in the ecosystem CO2 fluxes at a paludified spruce forest and ombrotrophic bog in the southern taiga
Overview: Recent advances in the understanding of the northern Eurasian environments and of the urban air quality in China – a Pan-Eurasian Experiment (PEEX) programme perspective
Volatile organic compound fluxes over a winter wheat field by PTR-Qi-TOF-MS and eddy covariance
OH and HO2 radical chemistry in a midlatitude forest: measurements and model comparisons
Consumption of CH3Cl, CH3Br, and CH3I and emission of CHCl3, CHBr3, and CH2Br2 from the forefield of a retreating Arctic glacier
PTR-TOF-MS eddy covariance measurements of isoprene and monoterpene fluxes from an eastern Amazonian rainforest
Significant emissions of dimethyl sulfide and monoterpenes by big-leaf mahogany trees: discovery of a missing dimethyl sulfide source to the atmospheric environment
Plant assemblages in atmospheric deposition
Emission of trace gases and aerosols from biomass burning – an updated assessment
Investigation of coastal sea-fog formation using the WIBS (wideband integrated bioaerosol sensor) technique
Soil–atmosphere exchange of carbonyl sulfide in a Mediterranean citrus orchard
Measurements of nitric oxide and ammonia soil fluxes from a wet savanna ecosystem site in West Africa during the DACCIWA field campaign
Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air
Interactions between the atmosphere, cryosphere, and ecosystems at northern high latitudes
Impacts of an intense wildfire smoke episode on surface radiation, energy and carbon fluxes in southwestern British Columbia, Canada
Surface–atmosphere exchange of inorganic water-soluble gases and associated ions in bulk aerosol above agricultural grassland pre- and postfertilisation
Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland
Drivers for spatial, temporal and long-term trends in atmospheric ammonia and ammonium in the UK
Annual cycle of Scots pine photosynthesis
Ethene, propene, butene and isoprene emissions from a ponderosa pine forest measured by relaxed eddy accumulation
Adverse effects of increasing drought on air quality via natural processes
A synthesis of research needs for improving the understanding of atmospheric mercury cycling
Arctic regional methane fluxes by ecotope as derived using eddy covariance from a low-flying aircraft
Effect of mid-term drought on Quercus pubescens BVOCs' emission seasonality and their dependency on light and/or temperature
Field observations of volatile organic compound (VOC) exchange in red oaks
Terpenoid and carbonyl emissions from Norway spruce in Finland during the growing season
A top-down approach of surface carbonyl sulfide exchange by a Mediterranean oak forest ecosystem in southern France
Air–surface exchange of gaseous mercury over permafrost soil: an investigation at a high-altitude (4700 m a.s.l.) and remote site in the central Qinghai–Tibet Plateau
Imbalanced phosphorus and nitrogen deposition in China's forests
Role of needle surface waxes in dynamic exchange of mono- and sesquiterpenes
Canopy-scale flux measurements and bottom-up emission estimates of volatile organic compounds from a mixed oak and hornbeam forest in northern Italy
Methanol and isoprene emissions from the fast growing tropical pioneer species Vismia guianensis (Aubl.) Pers. (Hypericaceae) in the central Amazon forest
Future vegetation–climate interactions in Eastern Siberia: an assessment of the competing effects of CO2 and secondary organic aerosols
Conceptual design of a measurement network of the global change
Effects of global change during the 21st century on the nitrogen cycle
Introduction: The Pan-Eurasian Experiment (PEEX) – multidisciplinary, multiscale and multicomponent research and capacity-building initiative
The Amazon Tall Tower Observatory (ATTO): overview of pilot measurements on ecosystem ecology, meteorology, trace gases, and aerosols
An ecosystem-scale perspective of the net land methanol flux: synthesis of micrometeorological flux measurements
Arctic microbial and next-generation sequencing approach for bacteria in snow and frost flowers: selected identification, abundance and freezing nucleation
Diel and seasonal changes of biogenic volatile organic compounds within and above an Amazonian rainforest
Sources and fluxes of organic nitrogen in precipitation over the southern East Sea/Sea of Japan
Influence of local air pollution on the deposition of peroxyacetyl nitrate to a nutrient-poor natural grassland ecosystem
Variability of BVOC emissions from a Mediterranean mixed forest in southern France with a focus on Quercus pubescens
Forest canopy interactions with nucleation mode particles
The balances of mixing ratios and segregation intensity: a case study from the field (ECHO 2003)
Concentrations and fluxes of isoprene and oxygenated VOCs at a French Mediterranean oak forest
From emissions to ambient mixing ratios: online seasonal field measurements of volatile organic compounds over a Norway spruce-dominated forest in central Germany
Overview of the Manitou Experimental Forest Observatory: site description and selected science results from 2008 to 2013
Eddy covariance fluxes and vertical concentration gradient measurements of NO and NO2 over a ponderosa pine ecosystem: observational evidence for within-canopy chemical removal of NOx
Biogenic volatile organic compound emissions during BEARPEX 2009 measured by eddy covariance and flux–gradient similarity methods
Vadim Mamkin, Vitaly Avilov, Dmitry Ivanov, Andrey Varlagin, and Julia Kurbatova
Atmos. Chem. Phys., 23, 2273–2291, https://doi.org/10.5194/acp-23-2273-2023, https://doi.org/10.5194/acp-23-2273-2023, 2023
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We collected 6 years of flux measurements at two southern taiga peatland ecosystems, namely a paludified spruce forest and ombrotrophic bog located in the same landscape in western Russia, which showed that the interannual variability in the environmental conditions affect CO2 ecosystem–atmosphere exchange differently in forest and non-forest peatlands. We observed that an anomalously warm winter and spring led to increasing CO2 uptake at the paludified forest (more than at the bog).
Hanna K. Lappalainen, Tuukka Petäjä, Timo Vihma, Jouni Räisänen, Alexander Baklanov, Sergey Chalov, Igor Esau, Ekaterina Ezhova, Matti Leppäranta, Dmitry Pozdnyakov, Jukka Pumpanen, Meinrat O. Andreae, Mikhail Arshinov, Eija Asmi, Jianhui Bai, Igor Bashmachnikov, Boris Belan, Federico Bianchi, Boris Biskaborn, Michael Boy, Jaana Bäck, Bin Cheng, Natalia Chubarova, Jonathan Duplissy, Egor Dyukarev, Konstantinos Eleftheriadis, Martin Forsius, Martin Heimann, Sirkku Juhola, Vladimir Konovalov, Igor Konovalov, Pavel Konstantinov, Kajar Köster, Elena Lapshina, Anna Lintunen, Alexander Mahura, Risto Makkonen, Svetlana Malkhazova, Ivan Mammarella, Stefano Mammola, Stephany Buenrostro Mazon, Outi Meinander, Eugene Mikhailov, Victoria Miles, Stanislav Myslenkov, Dmitry Orlov, Jean-Daniel Paris, Roberta Pirazzini, Olga Popovicheva, Jouni Pulliainen, Kimmo Rautiainen, Torsten Sachs, Vladimir Shevchenko, Andrey Skorokhod, Andreas Stohl, Elli Suhonen, Erik S. Thomson, Marina Tsidilina, Veli-Pekka Tynkkynen, Petteri Uotila, Aki Virkkula, Nadezhda Voropay, Tobias Wolf, Sayaka Yasunaka, Jiahua Zhang, Yubao Qiu, Aijun Ding, Huadong Guo, Valery Bondur, Nikolay Kasimov, Sergej Zilitinkevich, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 22, 4413–4469, https://doi.org/10.5194/acp-22-4413-2022, https://doi.org/10.5194/acp-22-4413-2022, 2022
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We summarize results during the last 5 years in the northern Eurasian region, especially from Russia, and introduce recent observations of the air quality in the urban environments in China. Although the scientific knowledge in these regions has increased, there are still gaps in our understanding of large-scale climate–Earth surface interactions and feedbacks. This arises from limitations in research infrastructures and integrative data analyses, hindering a comprehensive system analysis.
Benjamin Loubet, Pauline Buysse, Lais Gonzaga-Gomez, Florence Lafouge, Raluca Ciuraru, Céline Decuq, Julien Kammer, Sandy Bsaibes, Christophe Boissard, Brigitte Durand, Jean-Christophe Gueudet, Olivier Fanucci, Olivier Zurfluh, Letizia Abis, Nora Zannoni, François Truong, Dominique Baisnée, Roland Sarda-Estève, Michael Staudt, and Valérie Gros
Atmos. Chem. Phys., 22, 2817–2842, https://doi.org/10.5194/acp-22-2817-2022, https://doi.org/10.5194/acp-22-2817-2022, 2022
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Volatile organic compounds (VOCs) are precursors of tropospheric pollutants like ozone or aerosols. Emission by agricultural land was still poorly characterized. We report experimental measurements of ecosystem-scale VOC fluxes above a wheat field with a highly sensitive proton transfer mass spectrometer. We report the fluxes of 123 compounds and confirm that methanol is the most emitted VOC by wheat. The second most emitted compound was C6H4O. Around 75 % of the compounds were deposited.
Michelle M. Lew, Pamela S. Rickly, Brandon P. Bottorff, Emily Reidy, Sofia Sklaveniti, Thierry Léonardis, Nadine Locoge, Sebastien Dusanter, Shuvashish Kundu, Ezra Wood, and Philip S. Stevens
Atmos. Chem. Phys., 20, 9209–9230, https://doi.org/10.5194/acp-20-9209-2020, https://doi.org/10.5194/acp-20-9209-2020, 2020
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The OH radical is the primary oxidant in the atmosphere, and measurements of its concentration provide a rigorous test of our understanding of atmospheric chemistry. Previous measurements of OH concentrations in forest environments have shown large discrepancies with model predictions. In this paper, we present measurements of OH in a forest in Indiana, USA, and compare the results to model predictions to test our understanding of this important chemistry.
Moya L. Macdonald, Jemma L. Wadham, Dickon Young, Chris R. Lunder, Ove Hermansen, Guillaume Lamarche-Gagnon, and Simon O'Doherty
Atmos. Chem. Phys., 20, 7243–7258, https://doi.org/10.5194/acp-20-7243-2020, https://doi.org/10.5194/acp-20-7243-2020, 2020
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Climate change has caused glaciers in the Arctic to shrink, uncovering new soils. We used field measurements to study the exchange of a group of gases involved in ozone destruction, called halocarbons, between these new soils and the atmosphere. We found that mats of cyanobacteria, early colonisers of soils, are linked to a larger-than-expected exchange of halocarbons with the atmosphere. We also found that gases which are commonly thought to be marine in origin were released from these soils.
Chinmoy Sarkar, Alex B. Guenther, Jeong-Hoo Park, Roger Seco, Eliane Alves, Sarah Batalha, Raoni Santana, Saewung Kim, James Smith, Julio Tóta, and Oscar Vega
Atmos. Chem. Phys., 20, 7179–7191, https://doi.org/10.5194/acp-20-7179-2020, https://doi.org/10.5194/acp-20-7179-2020, 2020
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Biogenic volatile organic compounds (BVOCs) are important components of the atmosphere due to their contribution to atmospheric chemistry and biogeochemical cycles. In this study, we report major BVOCs, e.g. isoprene and total monoterpene flux measurements with a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) using the eddy covariance (EC) method at a primary rainforest in eastern Amazonia. We used the measured data to evaluate the MEGAN2.1 model for the emission site.
Lejish Vettikkat, Vinayak Sinha, Savita Datta, Ashish Kumar, Haseeb Hakkim, Priya Yadav, and Baerbel Sinha
Atmos. Chem. Phys., 20, 375–389, https://doi.org/10.5194/acp-20-375-2020, https://doi.org/10.5194/acp-20-375-2020, 2020
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There are several widely grown tree species whose BVOC emission potentials are still unknown. Studies over the Amazon rainforest have reported presence of terrestrial dimethyl sulfide sources. Here, we show that mahogany, which is grown widely in several regions of the world, is a high emitter of dimethyl sulfide and monoterpenes. With future land use and land cover changes promoting plantations of this tree for economic purposes, its impact on air quality could be quite significant.
Ke Dong, Cheolwoon Woo, and Naomichi Yamamoto
Atmos. Chem. Phys., 19, 11969–11983, https://doi.org/10.5194/acp-19-11969-2019, https://doi.org/10.5194/acp-19-11969-2019, 2019
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The work reported here is the first, the most comprehensive molecularly based study of atmospheric deposition of plants. Plants disperse spores, pollen, and fragments into the atmosphere. The emitted plant particles return to the pedosphere by sedimentation (dry deposition) and/or by precipitation (wet deposition), comprising part of the Earth's cycling of substances. This study reports plant assemblages in dry and wet atmospheric deposits collected together at the same sampling point.
Meinrat O. Andreae
Atmos. Chem. Phys., 19, 8523–8546, https://doi.org/10.5194/acp-19-8523-2019, https://doi.org/10.5194/acp-19-8523-2019, 2019
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Biomass burning is one of the largest sources of atmospheric pollutants worldwide. This paper presents an up-to-date compilation of emission factors for over 120 trace gas and aerosol species from the different forms of open vegetation fires and domestic biofuel use, based on an analysis of over 370 published studies. Using these emission factors and current global burning activity data, the annual emissions of important species released by the various types of biomass burning are estimated.
Shane M. Daly, David J. O'Connor, David A. Healy, Stig Hellebust, Jovanna Arndt, Eoin J. McGillicuddy, Patrick Feeney, Michael Quirke, John C. Wenger, and John R. Sodeau
Atmos. Chem. Phys., 19, 5737–5751, https://doi.org/10.5194/acp-19-5737-2019, https://doi.org/10.5194/acp-19-5737-2019, 2019
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For a long time sea-salt particles were considered the only types of particles that drive sea-fog formation but recently iodine oxide particles released from kelp have been identified as a source. There are no previous field studies to provide a direct timeline link between molecular iodine release, particle formation and sea-fog formation. The present observations from Cork Harbour provide such a link. A stabilizing mechanism enhancing distribution of iodine in the troposphere is suggested.
Fulin Yang, Rafat Qubaja, Fyodor Tatarinov, Rafael Stern, and Dan Yakir
Atmos. Chem. Phys., 19, 3873–3883, https://doi.org/10.5194/acp-19-3873-2019, https://doi.org/10.5194/acp-19-3873-2019, 2019
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The contribution of soil carbonyl sulfate (COS) flux is probably the major limitation to the application of COS as a novel tracer of canopy-scale CO2 uptake. We provide new, field-based high-resolution results on the spatial and temporal variations in soil COS flux, its relationships to CO2 exchange and the key factors influencing it. We furthermore provide the only study, to our knowledge, that validate the surface dynamic chamber approach, increasingly used, with soil concentration profiles.
Federica Pacifico, Claire Delon, Corinne Jambert, Pierre Durand, Eleanor Morris, Mat J. Evans, Fabienne Lohou, Solène Derrien, Venance H. E. Donnou, Arnaud V. Houeto, Irene Reinares Martínez, and Pierre-Etienne Brilouet
Atmos. Chem. Phys., 19, 2299–2325, https://doi.org/10.5194/acp-19-2299-2019, https://doi.org/10.5194/acp-19-2299-2019, 2019
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Biogenic fluxes from soil at a local and regional scale are crucial to study air pollution and climate. Here we present field measurements of soil fluxes of nitric oxide (NO) and ammonia (NH3) observed over four different land cover types, i.e. bare soil, grassland, maize field, and forest, at an inland rural site in Benin, West Africa, during the DACCIWA field campaign in
June and July 2016.
Guo Li, Yafang Cheng, Uwe Kuhn, Rongjuan Xu, Yudong Yang, Hannah Meusel, Zhibin Wang, Nan Ma, Yusheng Wu, Meng Li, Jonathan Williams, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Hang Su
Atmos. Chem. Phys., 19, 2209–2232, https://doi.org/10.5194/acp-19-2209-2019, https://doi.org/10.5194/acp-19-2209-2019, 2019
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VOCs play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air–soil exchange of 13 VOCs at ambient air conditions of an urban background site in Beijing.
Michael Boy, Erik S. Thomson, Juan-C. Acosta Navarro, Olafur Arnalds, Ekaterina Batchvarova, Jaana Bäck, Frank Berninger, Merete Bilde, Zoé Brasseur, Pavla Dagsson-Waldhauserova, Dimitri Castarède, Maryam Dalirian, Gerrit de Leeuw, Monika Dragosics, Ella-Maria Duplissy, Jonathan Duplissy, Annica M. L. Ekman, Keyan Fang, Jean-Charles Gallet, Marianne Glasius, Sven-Erik Gryning, Henrik Grythe, Hans-Christen Hansson, Margareta Hansson, Elisabeth Isaksson, Trond Iversen, Ingibjorg Jonsdottir, Ville Kasurinen, Alf Kirkevåg, Atte Korhola, Radovan Krejci, Jon Egill Kristjansson, Hanna K. Lappalainen, Antti Lauri, Matti Leppäranta, Heikki Lihavainen, Risto Makkonen, Andreas Massling, Outi Meinander, E. Douglas Nilsson, Haraldur Olafsson, Jan B. C. Pettersson, Nønne L. Prisle, Ilona Riipinen, Pontus Roldin, Meri Ruppel, Matthew Salter, Maria Sand, Øyvind Seland, Heikki Seppä, Henrik Skov, Joana Soares, Andreas Stohl, Johan Ström, Jonas Svensson, Erik Swietlicki, Ksenia Tabakova, Throstur Thorsteinsson, Aki Virkkula, Gesa A. Weyhenmeyer, Yusheng Wu, Paul Zieger, and Markku Kulmala
Atmos. Chem. Phys., 19, 2015–2061, https://doi.org/10.5194/acp-19-2015-2019, https://doi.org/10.5194/acp-19-2015-2019, 2019
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The Nordic Centre of Excellence CRAICC (Cryosphere–Atmosphere Interactions in a Changing Arctic Climate), funded by NordForsk in the years 2011–2016, is the largest joint Nordic research and innovation initiative to date and aimed to strengthen research and innovation regarding climate change issues in the Nordic region. The paper presents an overview of the main scientific topics investigated and provides a state-of-the-art comprehensive summary of what has been achieved in CRAICC.
Ian G. McKendry, Andreas Christen, Sung-Ching Lee, Madison Ferrara, Kevin B. Strawbridge, Norman O'Neill, and Andrew Black
Atmos. Chem. Phys., 19, 835–846, https://doi.org/10.5194/acp-19-835-2019, https://doi.org/10.5194/acp-19-835-2019, 2019
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Wildfire smoke in July 2015 had a significant impact on air quality, radiation, and energy budgets across British Columbia. With lighter smoke, a wetland and forested site showed enhanced photosynthetic activity (taking in carbon dioxide). However, with dense smoke the forested site became a strong source. These results suggest that smoke during the growing season potentially plays an important role in the carbon budget, and this effect will likely increase as climate changes.
Robbie Ramsay, Chiara F. Di Marco, Mathew R. Heal, Marsailidh M. Twigg, Nicholas Cowan, Matthew R. Jones, Sarah R. Leeson, William J. Bloss, Louisa J. Kramer, Leigh Crilley, Matthias Sörgel, Meinrat Andreae, and Eiko Nemitz
Atmos. Chem. Phys., 18, 16953–16978, https://doi.org/10.5194/acp-18-16953-2018, https://doi.org/10.5194/acp-18-16953-2018, 2018
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Understanding the impact of agricultural activities on the atmosphere requires more measurements of inorganic trace gases and associated aerosol counterparts. This research presents 1 month of measurements above agricultural grassland during a period of fertiliser application. It was found that emissions of the important trace gases ammonia and nitrous acid peaked after fertiliser use and that the velocity at which the measured aerosols were deposited was dependent upon their size.
Wu Sun, Linda M. J. Kooijmans, Kadmiel Maseyk, Huilin Chen, Ivan Mammarella, Timo Vesala, Janne Levula, Helmi Keskinen, and Ulli Seibt
Atmos. Chem. Phys., 18, 1363–1378, https://doi.org/10.5194/acp-18-1363-2018, https://doi.org/10.5194/acp-18-1363-2018, 2018
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Most soils consume carbonyl sulfide (COS) and CO due to microbial uptake, but whether boreal forest soils act like this is uncertain. We measured growing season soil COS and CO fluxes in a Finnish pine forest. The soil behaved as a consistent and relatively invariant sink of COS and CO. Uptake rates of COS and CO decrease with soil moisture due to diffusion limitation and increase with respiration because of microbial control. Using COS to infer photosynthesis is not affected by soil COS flux.
Yuk S. Tang, Christine F. Braban, Ulrike Dragosits, Anthony J. Dore, Ivan Simmons, Netty van Dijk, Janet Poskitt, Gloria Dos Santos Pereira, Patrick O. Keenan, Christopher Conolly, Keith Vincent, Rognvald I. Smith, Mathew R. Heal, and Mark A. Sutton
Atmos. Chem. Phys., 18, 705–733, https://doi.org/10.5194/acp-18-705-2018, https://doi.org/10.5194/acp-18-705-2018, 2018
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A unique long-term dataset of NH3 and NH4+ data from the NAMN is used to assess spatial, seasonal and long-term variability across the UK. NH3 is spatially variable, with distinct temporal profiles according to source types. NH4+ is spatially smoother, with peak concentrations in spring from long-range transport. Decrease in NH3 is smaller than emissions, but NH4+ decreased faster than NH3, due to a shift from stable (NH4)2SO4 to semi-volatile NH4NO3, increasing the atmospheric lifetime of NH3.
Pertti Hari, Veli-Matti Kerminen, Liisa Kulmala, Markku Kulmala, Steffen Noe, Tuukka Petäjä, Anni Vanhatalo, and Jaana Bäck
Atmos. Chem. Phys., 17, 15045–15053, https://doi.org/10.5194/acp-17-15045-2017, https://doi.org/10.5194/acp-17-15045-2017, 2017
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We developed a theory on the seasonal behaviour of photosynthesis in natural conditions and tested the theory with intensive measurements. Light, temperature, water vapor and CO2 concentration explained the daily variation in photosynthesis, and the physiological state of the photosynthetic machinery explained the annual pattern of photosynthesis. The theory explained about 95 % of the variance of photosynthesis measured with chambers in the field in northern Finland.
Robert C. Rhew, Malte Julian Deventer, Andrew A. Turnipseed, Carsten Warneke, John Ortega, Steve Shen, Luis Martinez, Abigail Koss, Brian M. Lerner, Jessica B. Gilman, James N. Smith, Alex B. Guenther, and Joost A. de Gouw
Atmos. Chem. Phys., 17, 13417–13438, https://doi.org/10.5194/acp-17-13417-2017, https://doi.org/10.5194/acp-17-13417-2017, 2017
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Alkenes emanate from both natural and anthropogenic sources and can contribute to atmospheric ozone production. This study measured
lightalkene (ethene, propene and butene) fluxes from a ponderosa pine forest using a novel relaxed eddy accumulation method, revealing much larger emissions than previously estimated and accounting for a significant fraction of OH reactivity. Emissions have a diurnal cycle related to sunlight and temperature, and the forest canopy appears to be the source.
Yuxuan Wang, Yuanyu Xie, Wenhao Dong, Yi Ming, Jun Wang, and Lu Shen
Atmos. Chem. Phys., 17, 12827–12843, https://doi.org/10.5194/acp-17-12827-2017, https://doi.org/10.5194/acp-17-12827-2017, 2017
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Besides the well-known large impact on agriculture and water resources, drought is associated with significant adverse effects on air quality. Drought-induced degradation of air quality is largely due to natural processes, offsetting the effort of anthropogenic emission reduction during the past decades. Such adverse impacts should be included in modeling processes under current and future climate for mitigation policy.
Leiming Zhang, Seth Lyman, Huiting Mao, Che-Jen Lin, David A. Gay, Shuxiao Wang, Mae Sexauer Gustin, Xinbin Feng, and Frank Wania
Atmos. Chem. Phys., 17, 9133–9144, https://doi.org/10.5194/acp-17-9133-2017, https://doi.org/10.5194/acp-17-9133-2017, 2017
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Future research needs are proposed for improving the understanding of atmospheric mercury cycling. These include refinement of mercury emission estimations, quantification of dry deposition and air–surface exchange, improvement of the treatment of chemical mechanisms in chemical transport models, increase in the accuracy of oxidized mercury measurements, better interpretation of atmospheric mercury chemistry data, and harmonization of network operation.
David S. Sayres, Ronald Dobosy, Claire Healy, Edward Dumas, John Kochendorfer, Jason Munster, Jordan Wilkerson, Bruce Baker, and James G. Anderson
Atmos. Chem. Phys., 17, 8619–8633, https://doi.org/10.5194/acp-17-8619-2017, https://doi.org/10.5194/acp-17-8619-2017, 2017
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Arctic temperatures have risen faster than the global average, causing the depth of melting of the frozen ground to increase. Previously frozen organic carbon, once exposed to air, water, and microbes, is turned into carbon dioxide and methane, both of which are important greenhouse gases. Due to the large and varied surface area of the Arctic and the difficulty of making measurements there we use a low flying aircraft (<25 m) to measure the amount of methane released from different regions.
Amélie Saunier, Elena Ormeño, Christophe Boissard, Henri Wortham, Brice Temime-Roussel, Caroline Lecareux, Alexandre Armengaud, and Catherine Fernandez
Atmos. Chem. Phys., 17, 7555–7566, https://doi.org/10.5194/acp-17-7555-2017, https://doi.org/10.5194/acp-17-7555-2017, 2017
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We investigated the BVOC emissions variations of Quercus Pubescens, under natural and amplified drought, in situ, in order to determine the dependency to light and/or temperature of these emissions. Our results showed that all BVOC emissions were reduced with amplified drought.
Moreover, we highlighted two dependences: (i) light and temperature and (ii) light and temperature during the day and to temperature during the night. These results can be useful to enhance emission models.
Luca Cappellin, Alberto Algarra Alarcon, Irina Herdlinger-Blatt, Juaquin Sanchez, Franco Biasioli, Scot T. Martin, Francesco Loreto, and Karena A. McKinney
Atmos. Chem. Phys., 17, 4189–4207, https://doi.org/10.5194/acp-17-4189-2017, https://doi.org/10.5194/acp-17-4189-2017, 2017
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The role of volatile organic compounds (VOCs) in plant interactions with the atmosphere is investigated through field observations of branch-level VOC exchange in a New England forest. The data reveal previously unknown sources and sinks of oxygenated VOCs. The emission of methyl ethyl ketone is linked to uptake of methyl vinyl ketone, suggesting the possibility of within-leaf isoprene oxidation. Bidirectional fluxes of some VOCs are also reported, including for benzaldehyde for the first time.
Hannele Hakola, Virpi Tarvainen, Arnaud P. Praplan, Kerneels Jaars, Marja Hemmilä, Markku Kulmala, Jaana Bäck, and Heidi Hellén
Atmos. Chem. Phys., 17, 3357–3370, https://doi.org/10.5194/acp-17-3357-2017, https://doi.org/10.5194/acp-17-3357-2017, 2017
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We present spring and summer VOC emission rate measurements from Norway spruce using an in situ gas chromatograph. Monoterpene and C4–C10 aldehyde emission rates reached maxima in July. SQT emissions increased at the end of July and in August SQT were the most abundant group. The MT emission pattern varied a lot from tree to tree and therefore emission fluxes on canopy level should be conducted for more representative measurements. However, leaf level measurements produce more reliable SQT data.
Sauveur Belviso, Ilja Marco Reiter, Benjamin Loubet, Valérie Gros, Juliette Lathière, David Montagne, Marc Delmotte, Michel Ramonet, Cerise Kalogridis, Benjamin Lebegue, Nicolas Bonnaire, Victor Kazan, Thierry Gauquelin, Catherine Fernandez, and Bernard Genty
Atmos. Chem. Phys., 16, 14909–14923, https://doi.org/10.5194/acp-16-14909-2016, https://doi.org/10.5194/acp-16-14909-2016, 2016
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The role that soil, foliage, and atmospheric dynamics have on surface OCS exchange in a Mediterranean forest ecosystem in southern France (O3HP) was investigated in June of 2012 and 2013 with essentially a top-down approach. Atmospheric data suggest that the site is appropriate for estimating GPP directly from eddy covariance measurements of OCS fluxes, but it is less adequate for scaling NEE to GPP from observations of vertical gradients of OCS relative to CO2 during the daytime.
Zhijia Ci, Fei Peng, Xian Xue, and Xiaoshan Zhang
Atmos. Chem. Phys., 16, 14741–14754, https://doi.org/10.5194/acp-16-14741-2016, https://doi.org/10.5194/acp-16-14741-2016, 2016
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We performed field measurements and controlled field experiments to examine the flux, temporal variation and influencing factors of air–surface Hg(0) exchange at a high-altitude and remote site in the central Qinghai–Tibet Plateau. We found that the environmental conditions greatly influenced the air–surface Hg dynamics. Our results have important implications for the Hg biogeochemical cycle in the soils of Qinghai–Tibet Plateau under rapid climate warming and environmental change.
Enzai Du, Wim de Vries, Wenxuan Han, Xuejun Liu, Zhengbing Yan, and Yuan Jiang
Atmos. Chem. Phys., 16, 8571–8579, https://doi.org/10.5194/acp-16-8571-2016, https://doi.org/10.5194/acp-16-8571-2016, 2016
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Accelerated N emissions in China may lead to an imbalance of atmospheric nutrient inputs in various ecosystems. Our assessment of P and N deposition in China's forests showed relatively high rates of P deposition, but they were accompanied by even much higher N deposition, resulting in high N : P deposition ratios. P and N deposition both showed a power-law increase with closer distance to the nearest large cities. Our results suggest an anthropogenic imbalance of regional N and P cycling.
Johanna Joensuu, Nuria Altimir, Hannele Hakola, Michael Rostás, Maarit Raivonen, Mika Vestenius, Hermanni Aaltonen, Markus Riederer, and Jaana Bäck
Atmos. Chem. Phys., 16, 7813–7823, https://doi.org/10.5194/acp-16-7813-2016, https://doi.org/10.5194/acp-16-7813-2016, 2016
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Plants produce volatile compounds (BVOCs) that have a major role in atmospheric chemistry. Our aim was to see if terpenes, a key group of BVOCs, can be found on surfaces of pine needles and, if so, how they compare with the emissions of the same tree. Both emissions and wax extracts were clearly dominated by monoterpenes, but there were also differences in the emission and wax spectra. The results support the existence of BVOCs on needle surfaces, with possible implications for air chemistry.
W. Joe F. Acton, Simon Schallhart, Ben Langford, Amy Valach, Pekka Rantala, Silvano Fares, Giulia Carriero, Ralf Tillmann, Sam J. Tomlinson, Ulrike Dragosits, Damiano Gianelle, C. Nicholas Hewitt, and Eiko Nemitz
Atmos. Chem. Phys., 16, 7149–7170, https://doi.org/10.5194/acp-16-7149-2016, https://doi.org/10.5194/acp-16-7149-2016, 2016
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Volatile organic compounds (VOCs) represent a large source of reactive carbon in the atmosphere and hence have a significant impact on air quality. It is therefore important that we can accurately quantify their emission. In this paper we use three methods to determine the fluxes of reactive VOCs from a woodland canopy. We show that two different canopy-scale measurement methods give good agreement, whereas estimates based on leaf-level-based emission underestimate isoprene fluxes.
Kolby J. Jardine, Angela B. Jardine, Vinicius F. Souza, Vilany Carneiro, Joao V. Ceron, Bruno O. Gimenez, Cilene P. Soares, Flavia M. Durgante, Niro Higuchi, Antonio O. Manzi, José F. C. Gonçalves, Sabrina Garcia, Scot T. Martin, Raquel F. Zorzanelli, Luani R. Piva, and Jeff Q. Chambers
Atmos. Chem. Phys., 16, 6441–6452, https://doi.org/10.5194/acp-16-6441-2016, https://doi.org/10.5194/acp-16-6441-2016, 2016
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In this study, high light-dependent isoprene emissions were observed from mature V. guianensis leaves in the central Amazon. As predicted by energetic models, isoprene emission increased nonlinearly with net photosynthesis. High leaf temperatures resulted in the classic uncoupling of net photosynthesis from isoprene emissions. Finally, leaf phenology differentially controlled methanol and isoprene emissions.
Almut Arneth, Risto Makkonen, Stefan Olin, Pauli Paasonen, Thomas Holst, Maija K. Kajos, Markku Kulmala, Trofim Maximov, Paul A. Miller, and Guy Schurgers
Atmos. Chem. Phys., 16, 5243–5262, https://doi.org/10.5194/acp-16-5243-2016, https://doi.org/10.5194/acp-16-5243-2016, 2016
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We study the potentially contrasting effects of enhanced ecosystem CO2 release in response to warmer temperatures vs. emissions of biogenic volatile organic compounds and their formation of secondary organic aerosol through a combination of measurements and modelling at a remote location in Eastern Siberia. The study aims to highlight the number of potentially opposing processes and complex interactions between vegetation physiology, soil processes and trace-gas exchanges in the climate system.
P. Hari, T. Petäjä, J. Bäck, V.-M. Kerminen, H. K. Lappalainen, T. Vihma, T. Laurila, Y. Viisanen, T. Vesala, and M. Kulmala
Atmos. Chem. Phys., 16, 1017–1028, https://doi.org/10.5194/acp-16-1017-2016, https://doi.org/10.5194/acp-16-1017-2016, 2016
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This manuscript introduces a conceptual design of a global, hierarchical observation network which provides tools and increased understanding to tackle the inter-connected environmental and societal challenges that we will face in the coming decades. Each ecosystem type on the globe has its own characteristic features that need to be taken into consideration. The hierarchical network is able to tackle problems related to large spatial scales, heterogeneity of ecosystems and their complexity.
D. Fowler, C. E. Steadman, D. Stevenson, M. Coyle, R. M. Rees, U. M. Skiba, M. A. Sutton, J. N. Cape, A. J. Dore, M. Vieno, D. Simpson, S. Zaehle, B. D. Stocker, M. Rinaldi, M. C. Facchini, C. R. Flechard, E. Nemitz, M. Twigg, J. W. Erisman, K. Butterbach-Bahl, and J. N. Galloway
Atmos. Chem. Phys., 15, 13849–13893, https://doi.org/10.5194/acp-15-13849-2015, https://doi.org/10.5194/acp-15-13849-2015, 2015
M. Kulmala, H. K. Lappalainen, T. Petäjä, T. Kurten, V.-M. Kerminen, Y. Viisanen, P. Hari, S. Sorvari, J. Bäck, V. Bondur, N. Kasimov, V. Kotlyakov, G. Matvienko, A. Baklanov, H. D. Guo, A. Ding, H.-C. Hansson, and S. Zilitinkevich
Atmos. Chem. Phys., 15, 13085–13096, https://doi.org/10.5194/acp-15-13085-2015, https://doi.org/10.5194/acp-15-13085-2015, 2015
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The Pan-European Experiment (PEEX) is introduced. PEEX is a multidisciplinary, multiscale and multicomponent research, research infrastructure and capacity-building program. This paper outlines the mission, vision and objectives of PEEX and introduces its main components, including the research agenda, research infrastructure, knowledge transfer and potential impacts on society. The paper also summarizes the main scientific questions that PEEX is going to tackle in the future.
M. O. Andreae, O. C. Acevedo, A. Araùjo, P. Artaxo, C. G. G. Barbosa, H. M. J. Barbosa, J. Brito, S. Carbone, X. Chi, B. B. L. Cintra, N. F. da Silva, N. L. Dias, C. Q. Dias-Júnior, F. Ditas, R. Ditz, A. F. L. Godoi, R. H. M. Godoi, M. Heimann, T. Hoffmann, J. Kesselmeier, T. Könemann, M. L. Krüger, J. V. Lavric, A. O. Manzi, A. P. Lopes, D. L. Martins, E. F. Mikhailov, D. Moran-Zuloaga, B. W. Nelson, A. C. Nölscher, D. Santos Nogueira, M. T. F. Piedade, C. Pöhlker, U. Pöschl, C. A. Quesada, L. V. Rizzo, C.-U. Ro, N. Ruckteschler, L. D. A. Sá, M. de Oliveira Sá, C. B. Sales, R. M. N. dos Santos, J. Saturno, J. Schöngart, M. Sörgel, C. M. de Souza, R. A. F. de Souza, H. Su, N. Targhetta, J. Tóta, I. Trebs, S. Trumbore, A. van Eijck, D. Walter, Z. Wang, B. Weber, J. Williams, J. Winderlich, F. Wittmann, S. Wolff, and A. M. Yáñez-Serrano
Atmos. Chem. Phys., 15, 10723–10776, https://doi.org/10.5194/acp-15-10723-2015, https://doi.org/10.5194/acp-15-10723-2015, 2015
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This paper describes the Amazon Tall Tower Observatory (ATTO), a new atmosphere-biosphere observatory located in the remote Amazon Basin. It presents results from ecosystem ecology, meteorology, trace gas, and aerosol measurements collected at the ATTO site during the first 3 years of operation.
G. Wohlfahrt, C. Amelynck, C. Ammann, A. Arneth, I. Bamberger, A. H. Goldstein, L. Gu, A. Guenther, A. Hansel, B. Heinesch, T. Holst, L. Hörtnagl, T. Karl, Q. Laffineur, A. Neftel, K. McKinney, J. W. Munger, S. G. Pallardy, G. W. Schade, R. Seco, and N. Schoon
Atmos. Chem. Phys., 15, 7413–7427, https://doi.org/10.5194/acp-15-7413-2015, https://doi.org/10.5194/acp-15-7413-2015, 2015
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Methanol is the second most abundant volatile organic compound in the troposphere and plays a significant role in atmospheric chemistry. While there is consensus about the dominant role of plants as the major source and the reaction with OH as the major sink, global methanol budgets diverge considerably in terms of source/sink estimates. Here we present micrometeorological methanol flux data from eight sites in order to provide a first cross-site synthesis of the terrestrial methanol exchange.
R. Mortazavi, S. Attiya, and P. A. Ariya
Atmos. Chem. Phys., 15, 6183–6204, https://doi.org/10.5194/acp-15-6183-2015, https://doi.org/10.5194/acp-15-6183-2015, 2015
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Next-generation sequencing revealed the existence of diverse community of bacteria in the Arctic samples with many originating from distinct ecological environments. The observed varied range in ice nucleation of cultivable bacteria and in all of the melted samples further revealed the existence of the heterogeneous pool of bacteria. Changes in the microbial pool and its impact on the freezing and melting process may potentially lead to changing the Arctic environment and thus global climate.
A. M. Yáñez-Serrano, A. C. Nölscher, J. Williams, S. Wolff, E. Alves, G. A. Martins, E. Bourtsoukidis, J. Brito, K. Jardine, P. Artaxo, and J. Kesselmeier
Atmos. Chem. Phys., 15, 3359–3378, https://doi.org/10.5194/acp-15-3359-2015, https://doi.org/10.5194/acp-15-3359-2015, 2015
G. Yan and G. Kim
Atmos. Chem. Phys., 15, 2761–2774, https://doi.org/10.5194/acp-15-2761-2015, https://doi.org/10.5194/acp-15-2761-2015, 2015
A. Moravek, P. Stella, T. Foken, and I. Trebs
Atmos. Chem. Phys., 15, 899–911, https://doi.org/10.5194/acp-15-899-2015, https://doi.org/10.5194/acp-15-899-2015, 2015
A.-C. Genard-Zielinski, C. Boissard, C. Fernandez, C. Kalogridis, J. Lathière, V. Gros, N. Bonnaire, and E. Ormeño
Atmos. Chem. Phys., 15, 431–446, https://doi.org/10.5194/acp-15-431-2015, https://doi.org/10.5194/acp-15-431-2015, 2015
S. C. Pryor, K. E. Hornsby, and K. A. Novick
Atmos. Chem. Phys., 14, 11985–11996, https://doi.org/10.5194/acp-14-11985-2014, https://doi.org/10.5194/acp-14-11985-2014, 2014
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What role do forests play in determining the concentration (and composition) of climate-relevant aerosol particles? This study seeks to address two aspects of this question. Firstly, we document high in-canopy removal of recently formed particles. Then we show evidence that growth rates of particles are a function of soil water availability via a reduction in canopy emissions of gases responsible for particle growth to climate-relevant sizes during drought conditions.
R. Dlugi, M. Berger, M. Zelger, A. Hofzumahaus, F. Rohrer, F. Holland, K. Lu, and G. Kramm
Atmos. Chem. Phys., 14, 10333–10362, https://doi.org/10.5194/acp-14-10333-2014, https://doi.org/10.5194/acp-14-10333-2014, 2014
C. Kalogridis, V. Gros, R. Sarda-Esteve, B. Langford, B. Loubet, B. Bonsang, N. Bonnaire, E. Nemitz, A.-C. Genard, C. Boissard, C. Fernandez, E. Ormeño, D. Baisnée, I. Reiter, and J. Lathière
Atmos. Chem. Phys., 14, 10085–10102, https://doi.org/10.5194/acp-14-10085-2014, https://doi.org/10.5194/acp-14-10085-2014, 2014
E. Bourtsoukidis, J. Williams, J. Kesselmeier, S. Jacobi, and B. Bonn
Atmos. Chem. Phys., 14, 6495–6510, https://doi.org/10.5194/acp-14-6495-2014, https://doi.org/10.5194/acp-14-6495-2014, 2014
J. Ortega, A. Turnipseed, A. B. Guenther, T. G. Karl, D. A. Day, D. Gochis, J. A. Huffman, A. J. Prenni, E. J. T. Levin, S. M. Kreidenweis, P. J. DeMott, Y. Tobo, E. G. Patton, A. Hodzic, Y. Y. Cui, P. C. Harley, R. S. Hornbrook, E. C. Apel, R. K. Monson, A. S. D. Eller, J. P. Greenberg, M. C. Barth, P. Campuzano-Jost, B. B. Palm, J. L. Jimenez, A. C. Aiken, M. K. Dubey, C. Geron, J. Offenberg, M. G. Ryan, P. J. Fornwalt, S. C. Pryor, F. N. Keutsch, J. P. DiGangi, A. W. H. Chan, A. H. Goldstein, G. M. Wolfe, S. Kim, L. Kaser, R. Schnitzhofer, A. Hansel, C. A. Cantrell, R. L. Mauldin, and J. N. Smith
Atmos. Chem. Phys., 14, 6345–6367, https://doi.org/10.5194/acp-14-6345-2014, https://doi.org/10.5194/acp-14-6345-2014, 2014
K.-E. Min, S. E. Pusede, E. C. Browne, B. W. LaFranchi, and R. C. Cohen
Atmos. Chem. Phys., 14, 5495–5512, https://doi.org/10.5194/acp-14-5495-2014, https://doi.org/10.5194/acp-14-5495-2014, 2014
J.-H. Park, S. Fares, R. Weber, and A. H. Goldstein
Atmos. Chem. Phys., 14, 231–244, https://doi.org/10.5194/acp-14-231-2014, https://doi.org/10.5194/acp-14-231-2014, 2014
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Short summary
Northern ecosystems exchange climate-relevant trace gases with the atmosphere, including volatile organic compounds (VOCs). We measured VOC fluxes from a subarctic permafrost-free fen and its adjacent lake in northern Sweden. The graminoid-dominated fen emitted mainly isoprene during the peak of the growing season, with a pronounced response to increasing temperatures stronger than assumed by biogenic emission models. The lake was a sink of acetone and acetaldehyde during both periods measured.
Northern ecosystems exchange climate-relevant trace gases with the atmosphere, including...
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