Articles | Volume 19, issue 6
Atmos. Chem. Phys., 19, 4075–4091, 2019
https://doi.org/10.5194/acp-19-4075-2019
Atmos. Chem. Phys., 19, 4075–4091, 2019
https://doi.org/10.5194/acp-19-4075-2019

Research article 02 Apr 2019

Research article | 02 Apr 2019

Mechanistic and kinetics investigations of oligomer formation from Criegee intermediate reactions with hydroxyalkyl hydroperoxides

Long Chen et al.

Viewed

Total article views: 1,332 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
931 376 25 1,332 109 18 20
  • HTML: 931
  • PDF: 376
  • XML: 25
  • Total: 1,332
  • Supplement: 109
  • BibTeX: 18
  • EndNote: 20
Views and downloads (calculated since 06 Nov 2018)
Cumulative views and downloads (calculated since 06 Nov 2018)

Viewed (geographical distribution)

Total article views: 1,304 (including HTML, PDF, and XML) Thereof 1,292 with geography defined and 12 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 

Cited

Latest update: 23 Jun 2021
Download
Short summary
The present calculations show that the sequential addition of CIs to HHPs affords oligomers containing CIs as chain units. The addition of an –OOH group in HHPs to the central carbon atom of CIs is identified as the most energetically favorable channel, with a barrier height strongly dependent on both CI substituent number (one or two) and position (syn- or anti-). In particular, the introduction of a methyl group into the anti-position significantly increases the rate coefficient.
Altmetrics
Final-revised paper
Preprint