Articles | Volume 18, issue 16
Atmos. Chem. Phys., 18, 12045–12059, 2018
https://doi.org/10.5194/acp-18-12045-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 12045–12059, 2018
https://doi.org/10.5194/acp-18-12045-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
22 Aug 2018
Research article
| 22 Aug 2018
Direct measurements of NO3 reactivity in and above the boundary layer of a mountaintop site: identification of reactive trace gases and comparison with OH reactivity
Jonathan M. Liebmann et al.
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Cited
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- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
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- Atmospheric oxidizing capacity in autumn Beijing: Analysis of the O3 and PM2.5 episodes based on observation-based model C. Jia et al. 10.1016/j.jes.2021.11.020
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
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14 citations as recorded by crossref.
- Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals T. Dillon & J. Crowley 10.5194/acp-18-14005-2018
- Measurement report: Observation-based formaldehyde production rates and their relation to OH reactivity around the Arabian Peninsula D. Dienhart et al. 10.5194/acp-21-17373-2021
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- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Characterizing nitrate radical budget trends in Beijing during 2013–2019 H. Wang et al. 10.1016/j.scitotenv.2021.148869
- An instrument for in situ measurement of total ozone reactivity R. Sommariva et al. 10.5194/amt-13-1655-2020
- Evolution of NO<sub>3</sub> reactivity during the oxidation of isoprene P. Dewald et al. 10.5194/acp-20-10459-2020
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- Abundance of NO3 Derived Organo-Nitrates and Their Importance in the Atmosphere A. Foulds et al. 10.3390/atmos12111381
- Atmospheric oxidizing capacity in autumn Beijing: Analysis of the O3 and PM2.5 episodes based on observation-based model C. Jia et al. 10.1016/j.jes.2021.11.020
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
1 citations as recorded by crossref.
Latest update: 19 May 2022
Short summary
We present direct measurements of the summertime total reactivity (inverse lifetime) of NO3 towards organic trace gases at a rural mountain site. High daytime and low night-time values were found. The reactivity was dominated by reaction with monoterpenes and sufficiently high to compete with photolysis and reaction with NO during daytime. NO3 radical measurements from one night are presented. For the first time, direct measurements of OH and NO3 reactivity are compared.
We present direct measurements of the summertime total reactivity (inverse lifetime) of NO3 ...
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