Articles | Volume 18, issue 16
Research article
22 Aug 2018
Research article |  | 22 Aug 2018

Direct measurements of NO3 reactivity in and above the boundary layer of a mountaintop site: identification of reactive trace gases and comparison with OH reactivity

Jonathan M. Liebmann, Jennifer B. A. Muller, Dagmar Kubistin, Anja Claude, Robert Holla, Christian Plass-Dülmer, Jos Lelieveld, and John N. Crowley


Interactive discussion

Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision
AR by Liebmann Jonathan on behalf of the Authors (04 Jul 2018)  Author's response    Manuscript
ED: Publish subject to technical corrections (04 Aug 2018) by James Roberts
AR by Liebmann Jonathan on behalf of the Authors (06 Aug 2018)  Author's response    Manuscript
Short summary
We present direct measurements of the summertime total reactivity (inverse lifetime) of NO3 towards organic trace gases at a rural mountain site. High daytime and low night-time values were found. The reactivity was dominated by reaction with monoterpenes and sufficiently high to compete with photolysis and reaction with NO during daytime. NO3 radical measurements from one night are presented. For the first time, direct measurements of OH and NO3 reactivity are compared.
Final-revised paper