Articles | Volume 17, issue 22
https://doi.org/10.5194/acp-17-13891-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-17-13891-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
22 Nov 2017
Research article |
| 22 Nov 2017
Insight into the in-cloud formation of oxalate based on in situ measurement by single particle mass spectrometry
Guohua Zhang
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
Qinhao Lin
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
University of Chinese Academy of Sciences, Beijing 100039, PR China
Long Peng
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
University of Chinese Academy of Sciences, Beijing 100039, PR China
Yuxiang Yang
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
University of Chinese Academy of Sciences, Beijing 100039, PR China
Yuzhen Fu
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
University of Chinese Academy of Sciences, Beijing 100039, PR China
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
Mei Li
Institute of Mass Spectrometer and Atmospheric Environment, Jinan
University, Guangzhou 510632, PR China
Duohong Chen
State Environmental Protection Key Laboratory of Regional Air
Quality Monitoring, Guangdong Environmental Monitoring Center, Guangzhou
510308, PR China
Jianxin Chen
Shaoguan Environmental Monitoring Center, Shaoguan 512026, PR China
Zhang Cai
John and Willie Leone Family Department of Energy and Mineral
Engineering, Pennsylvania State University, University Park, PA 16802,
USA
Xinming Wang
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
Ping'an Peng
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
Guoying Sheng
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Resources Utilization and Protection, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, PR
China
Zhen Zhou
Institute of Mass Spectrometer and Atmospheric Environment, Jinan
University, Guangzhou 510632, PR China
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Cited
22 citations as recorded by crossref.
- Raman spectra of atmospheric particles measured in Maryland, USA over 22.5 h using an automated aerosol Raman spectrometer D. Doughty & S. Hill 10.1016/j.jqsrt.2020.106839
- Field Evidence of Fe-Mediated Photochemical Degradation of Oxalate and Subsequent Sulfate Formation Observed by Single Particle Mass Spectrometry Y. Zhou et al. 10.1021/acs.est.0c00443
- Overview of the CPOC Pilot Study at Whiteface Mountain, NY: Cloud Processing of Organics within Clouds (CPOC) S. Lance et al. 10.1175/BAMS-D-19-0022.1
- Chemical characteristics of cloud water and the impacts on aerosol properties at a subtropical mountain site in Hong Kong SAR T. Li et al. 10.5194/acp-20-391-2020
- Characterization of humic-like substances in PM2.5 during biomass burning episodes on Weizhou Island, China X. Zhou et al. 10.1016/j.atmosenv.2018.08.023
- In-cloud formation of secondary species in iron-containing particles Q. Lin et al. 10.5194/acp-19-1195-2019
- Insight into the photochemistry of atmospheric oxalate through hourly measurements in the northern suburbs of Nanjing, China C. Zhang et al. 10.1016/j.scitotenv.2020.137416
- Oxalate Formation Enhanced by Fe-Containing Particles and Environmental Implications G. Zhang et al. 10.1021/acs.est.8b05280
- Observed below-Cloud and Cloud Interstitial Submicron Aerosol Chemical and Physical Properties at Whiteface Mountain, New York, during August 2017 J. Zhang et al. 10.1021/acsearthspacechem.9b00117
- High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium G. Zhang et al. 10.5194/acp-20-1469-2020
- The single-particle mixing state and cloud scavenging of black carbon: a case study at a high-altitude mountain site in southern China G. Zhang et al. 10.5194/acp-17-14975-2017
- Speciation of organic fractions does matter for aerosol source apportionment. Part 3: Combining off-line and on-line measurements D. Srivastava et al. 10.1016/j.scitotenv.2019.06.378
- Impact of in-cloud aqueous processes on the chemical compositions and morphology of individual atmospheric aerosols Y. Fu et al. 10.5194/acp-20-14063-2020
- Elevated particulate methanesulfonate, oxalate and iron over Sydney Harbour in the austral summer of 2019-20 during unprecedented bushfire activity H. Swan & J. Ivey 10.1016/j.atmosenv.2021.118739
- Microphysics of aerosol, fog and droplet residuals on the Canadian Atlantic coast P. Duplessis et al. 10.1016/j.atmosres.2021.105859
- Single particle diversity and mixing state of carbonaceous aerosols in Guangzhou, China C. Cheng et al. 10.1016/j.scitotenv.2020.142182
- The enhanced mixing states of oxalate with metals in single particles in Guangzhou, China H. Gong et al. 10.1016/j.scitotenv.2021.146962
- Enhanced photochemical formation of secondary organic aerosols during the COVID-19 lockdown in Northern China J. Meng et al. 10.1016/j.scitotenv.2020.143709
- Size-resolved characteristics of water-soluble particulate elements in a coastal area: Source identification, influence of wildfires, and diurnal variability L. Ma et al. 10.1016/j.atmosenv.2019.02.045
- The reductions of oxalate and its precursors in cloud droplets relative to wet particles Q. Lin et al. 10.1016/j.atmosenv.2020.117632
- Humic-like substances (HULIS) in springtime aerosols at a high-altitude background station in the western North Pacific: Source attribution, abundance, and light-absorption S. Pani et al. 10.1016/j.scitotenv.2021.151180
- Atmospheric Chemistry of Oxalate: Insight Into the Role of Relative Humidity and Aerosol Acidity From High‐Resolution Observation C. Yang et al. 10.1029/2021JD035364
22 citations as recorded by crossref.
- Raman spectra of atmospheric particles measured in Maryland, USA over 22.5 h using an automated aerosol Raman spectrometer D. Doughty & S. Hill 10.1016/j.jqsrt.2020.106839
- Field Evidence of Fe-Mediated Photochemical Degradation of Oxalate and Subsequent Sulfate Formation Observed by Single Particle Mass Spectrometry Y. Zhou et al. 10.1021/acs.est.0c00443
- Overview of the CPOC Pilot Study at Whiteface Mountain, NY: Cloud Processing of Organics within Clouds (CPOC) S. Lance et al. 10.1175/BAMS-D-19-0022.1
- Chemical characteristics of cloud water and the impacts on aerosol properties at a subtropical mountain site in Hong Kong SAR T. Li et al. 10.5194/acp-20-391-2020
- Characterization of humic-like substances in PM2.5 during biomass burning episodes on Weizhou Island, China X. Zhou et al. 10.1016/j.atmosenv.2018.08.023
- In-cloud formation of secondary species in iron-containing particles Q. Lin et al. 10.5194/acp-19-1195-2019
- Insight into the photochemistry of atmospheric oxalate through hourly measurements in the northern suburbs of Nanjing, China C. Zhang et al. 10.1016/j.scitotenv.2020.137416
- Oxalate Formation Enhanced by Fe-Containing Particles and Environmental Implications G. Zhang et al. 10.1021/acs.est.8b05280
- Observed below-Cloud and Cloud Interstitial Submicron Aerosol Chemical and Physical Properties at Whiteface Mountain, New York, during August 2017 J. Zhang et al. 10.1021/acsearthspacechem.9b00117
- High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium G. Zhang et al. 10.5194/acp-20-1469-2020
- The single-particle mixing state and cloud scavenging of black carbon: a case study at a high-altitude mountain site in southern China G. Zhang et al. 10.5194/acp-17-14975-2017
- Speciation of organic fractions does matter for aerosol source apportionment. Part 3: Combining off-line and on-line measurements D. Srivastava et al. 10.1016/j.scitotenv.2019.06.378
- Impact of in-cloud aqueous processes on the chemical compositions and morphology of individual atmospheric aerosols Y. Fu et al. 10.5194/acp-20-14063-2020
- Elevated particulate methanesulfonate, oxalate and iron over Sydney Harbour in the austral summer of 2019-20 during unprecedented bushfire activity H. Swan & J. Ivey 10.1016/j.atmosenv.2021.118739
- Microphysics of aerosol, fog and droplet residuals on the Canadian Atlantic coast P. Duplessis et al. 10.1016/j.atmosres.2021.105859
- Single particle diversity and mixing state of carbonaceous aerosols in Guangzhou, China C. Cheng et al. 10.1016/j.scitotenv.2020.142182
- The enhanced mixing states of oxalate with metals in single particles in Guangzhou, China H. Gong et al. 10.1016/j.scitotenv.2021.146962
- Enhanced photochemical formation of secondary organic aerosols during the COVID-19 lockdown in Northern China J. Meng et al. 10.1016/j.scitotenv.2020.143709
- Size-resolved characteristics of water-soluble particulate elements in a coastal area: Source identification, influence of wildfires, and diurnal variability L. Ma et al. 10.1016/j.atmosenv.2019.02.045
- The reductions of oxalate and its precursors in cloud droplets relative to wet particles Q. Lin et al. 10.1016/j.atmosenv.2020.117632
- Humic-like substances (HULIS) in springtime aerosols at a high-altitude background station in the western North Pacific: Source attribution, abundance, and light-absorption S. Pani et al. 10.1016/j.scitotenv.2021.151180
- Atmospheric Chemistry of Oxalate: Insight Into the Role of Relative Humidity and Aerosol Acidity From High‐Resolution Observation C. Yang et al. 10.1029/2021JD035364
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Short summary
We first reported the size-resolved mixing state of oxalate in the cloud droplet residual, the cloud interstitial, and cloud-free particles by single particle mass spectrometry. Individual particle analysis provides unique insight into the formation and evolution of oxalate during in-cloud processing. The data show that in-cloud aqueous reactions dramatically improved the formation of oxalate from organic acids that were strongly associated with the aged biomass burning particles.
We first reported the size-resolved mixing state of oxalate in the cloud droplet residual, the...
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