Articles | Volume 26, issue 15
https://doi.org/10.5194/acp-26-10751-2026
https://doi.org/10.5194/acp-26-10751-2026
Research article
 | 
03 Aug 2026
Research article |  | 03 Aug 2026

Secondary processes driven by multi-factor interactions dominate the aerosol nitroaromatic compound pollution during winter in China

Yu Xu, Yu-Cheng You, Ting Yang, Lin Gui, Jun-Liang Tao, Tian-Shu Chen, Hao Xiao, Mei-Ju Yin, Hong-Wei Xiao, and Hua-Yun Xiao

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Cited articles

Atkinson, R., Aschmann, S. M., and Arey, J.: Reactions of hydroxyl and nitrogen trioxide radicals with phenol, cresols, and 2-nitrophenol at 296 .+-. 2 K, Environ. Sci. Technol., 26, 1397-1403, https://doi.org/10.1021/es00031a018, 1992. 
Boreddy, S. K. R. and Kawamura, K.: A 12-year observation of water-soluble ions in TSP aerosols collected at a remote marine location in the western North Pacific: an outflow region of Asian dust, Atmos. Chem. Phys., 15, 6437–6453, https://doi.org/10.5194/acp-15-6437-2015, 2015. 
Cai, D., Wang, X., George, C., Cheng, T., Herrmann, H., Li, X., and Chen, J.: Formation of Secondary Nitroaromatic Compounds in Polluted Urban Environments, J. Geophys. Res.-Atmos., 127, e2021JD036167, https://doi.org/10.1029/2021JD036167, 2022. 
Chen, Y., Zheng, P., Wang, Z., Pu, W., Tan, Y., Yu, C., Xia, M., Wang, W., Guo, J., Huang, D., Yan, C., Nie, W., Ling, Z., Chen, Q., Lee, S., and Wang, T.: Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China, Environ. Sci. Technol., 56, 6933–6943, https://doi.org/10.1021/acs.est.1c04596, 2022. 
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Short summary
This study presents the characteristics and potential origins of nitroaromatics (NACs) in winter PM2.5 across 11 Chinese cities, along with key factors controlling their formation. We propose that relative humidity- or aerosol liquid water-promoted NAC formation from lab studies may not be universally interpretable in real atmospheres, where multi-factor interactions are critical. This work highlights the need to consider complex field conditions in future research on NAC formation mechanisms.
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