Articles | Volume 26, issue 15
https://doi.org/10.5194/acp-26-10751-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-26-10751-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Secondary processes driven by multi-factor interactions dominate the aerosol nitroaromatic compound pollution during winter in China
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Yu-Cheng You
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Ting Yang
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Lin Gui
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Jun-Liang Tao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Tian-Shu Chen
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Hao Xiao
CORRESPONDING AUTHOR
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Mei-Ju Yin
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Hong-Wei Xiao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
Hua-Yun Xiao
School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China
Shanghai Yangtze River Delta Eco-Environmental Change and Management Observation and Research Station (Shanghai Urban Ecosystem Research Station), Ministry of Science and Technology, National Forestry and Grassland Administration, 800 Dongchuan Rd., Shanghai 200240, China
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Cited articles
Atkinson, R., Aschmann, S. M., and Arey, J.: Reactions of hydroxyl and nitrogen trioxide radicals with phenol, cresols, and 2-nitrophenol at 296 .+-. 2 K, Environ. Sci. Technol., 26, 1397-1403, https://doi.org/10.1021/es00031a018, 1992.
Boreddy, S. K. R. and Kawamura, K.: A 12-year observation of water-soluble ions in TSP aerosols collected at a remote marine location in the western North Pacific: an outflow region of Asian dust, Atmos. Chem. Phys., 15, 6437–6453, https://doi.org/10.5194/acp-15-6437-2015, 2015.
Cai, D., Wang, X., George, C., Cheng, T., Herrmann, H., Li, X., and Chen, J.: Formation of Secondary Nitroaromatic Compounds in Polluted Urban Environments, J. Geophys. Res.-Atmos., 127, e2021JD036167, https://doi.org/10.1029/2021JD036167, 2022.
Chen, Y., Zheng, P., Wang, Z., Pu, W., Tan, Y., Yu, C., Xia, M., Wang, W., Guo, J., Huang, D., Yan, C., Nie, W., Ling, Z., Chen, Q., Lee, S., and Wang, T.: Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China, Environ. Sci. Technol., 56, 6933–6943, https://doi.org/10.1021/acs.est.1c04596, 2022.
Ehhalt, D. H. and Rohrer, F.: Dependence of the OH concentration on solar UV, J. Geophys. Res.-Atmos., 105, 3565–3571, https://doi.org/10.1029/1999jd901070, 2000.
Finewax, Z., de Gouw, J. A., and Ziemann, P. J.: Identification and Quantification of 4-Nitrocatechol Formed from OH and NO3 Radical-Initiated Reactions of Catechol in Air in the Presence of NOx: Implications for Secondary Organic Aerosol Formation from Biomass Burning, Environ. Sci. Technol., 52, 1981–1989, https://doi.org/10.1021/acs.est.7b05864, 2018.
Frka, S., Šala, M., Brodnik, H., Štefane, B., Kroflič, A., and Grgić, I.: Seasonal variability of nitroaromatic compounds in ambient aerosols: Mass size distribution, possible sources and contribution to water-soluble brown carbon light absorption, Chemosphere, 299, 134381, https://doi.org/10.1016/j.chemosphere.2022.134381, 2022.
Gu, C., Cui, S., Ge, X., Wang, Z., Chen, M., Qian, Z., Liu, Z., Wang, X., and Zhang, Y.: Chemical composition, sources and optical properties of nitrated aromatic compounds in fine particulate matter during winter foggy days in Nanjing, China, Environ. Res., 212, 113255, https://doi.org/10.1016/j.envres.2022.113255, 2022.
Gui, L., Xu, Y., You, Y.-C., Ma, Y.-J., Yang, T., Liu, T., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Oxidative Degradation of Higher-Molecular-Weight Aromatic Amine Compounds Is a Potential Source of Anilinium in Urban Aerosols, Environ. Sci. Tech. Let., 11, 1355–1361, https://doi.org/10.1021/acs.estlett.4c00935, 2024.
Gui, L., Xu, Y., Ma, Y.-J., Yang, T., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Firework Display Is a Newly Identified Source of Gaseous and Particulate Amines, Environ. Sci. Tech. Let., 12, 1387–1393, https://doi.org/10.1021/acs.estlett.5c00806, 2025.
Guo, Z., Hu, X., Sun, W., Peng, X., Fu, Y., Liu, K., Liu, F., Meng, H., Zhu, Y., Zhang, G., Wang, X., Xue, L., Wang, J., Wang, X., Peng, P. a., and Bi, X.: Mixing state and influence factors controlling diurnal variation of particulate nitrophenol compounds at a suburban area in northern China, Environ. Pollut., 344, 123368, https://doi.org/10.1016/j.envpol.2024.123368, 2024.
Hao, Y., Sun, G., Fan, T., Tang, X., Zhang, J., Liu, Y., Zhang, N., Zhao, L., Zhong, R., and Peng, Y.: In vivo toxicity of nitroaromatic compounds to rats: QSTR modelling and interspecies toxicity relationship with mouse, J. Hazard. Mater., 399, 122981, https://doi.org/10.1016/j.jhazmat.2020.122981, 2020.
Harrison, M. A. J., Barra, S., Borghesi, D., Vione, D., Arsene, C., and Iulian Olariu, R.: Nitrated phenols in the atmosphere: a review, Atmos. Environ., 39, 231–248, https://doi.org/10.1016/j.atmosenv.2004.09.044, 2005.
Huang, S., Yang, X., Xu, H., Zeng, Y., Li, D., Sun, J., Ho, S. S. H., Zhang, Y., Cao, J., and Shen, Z.: Insights into the nitroaromatic compounds, formation, and light absorption contributing emissions from various geological maturity coals, Sci. Total Environ., 870, 162033, https://doi.org/10.1016/j.scitotenv.2023.162033, 2023.
Huang, S., Shen, Z., Yang, X., Bai, G., Zhang, L., Zeng, Y., Sun, J., Xu, H., Ho, S. S. H., Zhang, Y., and Cao, J.: Nitroaromatic compounds in six major Chinese cities: Influence of different formation mechanisms on light absorption properties, Sci. Total Environ., 930, 172672, https://doi.org/10.1016/j.scitotenv.2024.172672, 2024.
Huang, S., Shen, Z., Bai, G., Zhang, L., Wang, D., Li, C., Zheng, H., Xu, H., and Zhang, Y.: Photochemical Aging of PM2.5 Nitroaromatic Compounds From Solid Fuel Combustion Enhanced Light Absorption and Oxidation Potential, J. Geophys. Res.-Atmos., 130, e2025JD043471, https://doi.org/10.1029/2025JD043471, 2025.
Huo, Y., Li, M., Wang, X., Sun, J., Zhou, Y., Ma, Y., and He, M.: Rapid oxidation of phenolic compounds by O3 and HO⚫: effects of the air–water interface and mineral dust in tropospheric chemical processes, Atmos. Chem. Phys., 24, 12409–12423, https://doi.org/10.5194/acp-24-12409-2024, 2024.
Kahnt, A., Behrouzi, S., Vermeylen, R., Safi Shalamzari, M., Vercauteren, J., Roekens, E., Claeys, M., and Maenhaut, W.: One-year study of nitro-organic compounds and their relation to wood burning in PM10 aerosol from a rural site in Belgium, Atmos. Environ., 81, 561–568, https://doi.org/10.1016/j.atmosenv.2013.09.041, 2013.
Kitanovski, Z., Grgić, I., Vermeylen, R., Claeys, M., and Maenhaut, W.: Liquid chromatography tandem mass spectrometry method for characterization of monoaromatic nitro-compounds in atmospheric particulate matter, J. Chromatogr. A, 1268, 35–43, https://doi.org/10.1016/j.chroma.2012.10.021, 2012.
Kroflič, A., Anders, J., Drventić, I., Mettke, P., Böge, O., Mutzel, A., Kleffmann, J., and Herrmann, H.: Guaiacol Nitration in a Simulated Atmospheric Aerosol with an Emphasis on Atmospheric Nitrophenol Formation Mechanisms, ACS Earth Space Chem., 5, 1083–1093, https://doi.org/10.1021/acsearthspacechem.1c00014, 2021.
Li, K., Li, J., Tong, S., Wang, W., Huang, R.-J., and Ge, M.: Characteristics of wintertime VOCs in suburban and urban Beijing: concentrations, emission ratios, and festival effects, Atmos. Chem. Phys., 19, 8021–8036, https://doi.org/10.5194/acp-19-8021-2019, 2019.
Li, M., Wang, X., Lu, C., Li, R., Zhang, J., Dong, S., Yang, L., Xue, L., Chen, J., and Wang, W.: Nitrated phenols and the phenolic precursors in the atmosphere in urban Jinan, China, Sci. Total Environ., 714, 136760, https://doi.org/10.1016/j.scitotenv.2020.136760, 2020a.
Li, X., Jiang, L., Hoa, L. P., Lyu, Y., Xu, T., Yang, X., Iinuma, Y., Chen, J., and Herrmann, H.: Size distribution of particle-phase sugar and nitrophenol tracers during severe urban haze episodes in Shanghai, Atmos. Environ., 145, 115–127, https://doi.org/10.1016/j.atmosenv.2016.09.030, 2016.
Li, X., Yang, Y., Liu, S., Zhao, Q., Wang, G., and Wang, Y.: Light absorption properties of brown carbon (BrC) in autumn and winter in Beijing: Composition, formation and contribution of nitrated aromatic compounds, Atmos. Environ., 223, 117289, https://doi.org/10.1016/j.atmosenv.2020.117289, 2020b.
Li, X., Wang, Y., Hu, M., Tan, T., Li, M., Wu, Z., Chen, S., and Tang, X.: Characterizing chemical composition and light absorption of nitroaromatic compounds in the winter of Beijing, Atmos. Environ., 237, 117712, https://doi.org/10.1016/j.atmosenv.2020.117712, 2020c.
Liao, T., Wang, S., Ai, J., Gui, K., Duan, B., Zhao, Q., Zhang, X., Jiang, W., and Sun, Y.: Heavy pollution episodes, transport pathways and potential sources of PM2.5 during the winter of 2013 in Chengdu (China), Sci. Total Environ., 584–585, 1056–1065, https://doi.org/10.1016/j.scitotenv.2017.01.160, 2017.
Liu, S., Wang, H., Hu, Z., Zhang, X., Sun, Y., and Dong, F.: Resolving the overlooked photochemical nitrophenol transformation mechanism induced by nonradical species under visible light, P. Natl. Acad. Sci. USA, 121, e2401452121, https://doi.org/10.1073/pnas.2401452121, 2024.
Liu, T., Xu, Y., Sun, Q.-B., Xiao, H.-W., Zhu, R.-G., Li, C.-X., Li, Z.-Y., Zhang, K.-Q., Sun, C.-X., and Xiao, H.-Y.: Characteristics, Origins, and Atmospheric Processes of Amines in Fine Aerosol Particles in Winter in China, J. Geophys. Res.-Atmos., 128, e2023JD038974, https://doi.org/10.1029/2023JD038974, 2023a.
Liu, X., Wang, H., Wang, F., Lv, S., Wu, C., Zhao, Y., Zhang, S., Liu, S., Xu, X., Lei, Y., and Wang, G.: Secondary Formation of Atmospheric Brown Carbon in China Haze: Implication for an Enhancing Role of Ammonia, Environ. Sci. Technol., 57, 11163–11172, https://doi.org/10.1021/acs.est.3c03948, 2023b.
Liu, Y., Huang, R.-J., Lin, C., Yuan, W., Li, Y. J., Zhong, H., Yang, L., Wang, T., Huang, W., Xu, W., Huang, D. D., and Huang, C.: Nitrate-Photolysis Shortens the Lifetimes of Brown Carbon Tracers from Biomass Burning, Environ. Sci. Technol., 59, 640–649, https://doi.org/10.1021/acs.est.4c06123, 2025.
Lu, C., Wang, X., Dong, S., Zhang, J., Li, J., Zhao, Y., Liang, Y., Xue, L., Xie, H., Zhang, Q., and Wang, W.: Emissions of fine particulate nitrated phenols from various on-road vehicles in China, Environ. Res., 179, 108709, https://doi.org/10.1016/j.envres.2019.108709, 2019.
Ma, Y.-J., Xu, Y., Yang, T., Xiao, H.-W., and Xiao, H.-Y.: Measurement report: Characteristics of nitrogen-containing organics in PM2.5 in Ürümqi, northwestern China – differential impacts of combustion of fresh and aged biomass materials, Atmos. Chem. Phys., 24, 4331–4346, https://doi.org/10.5194/acp-24-4331-2024, 2024.
Ma, Y.-J., Xu, Y., Yang, T., Gui, L., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: The critical role of aqueous-phase processes in aromatic-derived nitrogen-containing organic aerosol formation in cities with different energy consumption patterns, Atmos. Chem. Phys., 25, 2763–2780, https://doi.org/10.5194/acp-25-2763-2025, 2025.
MacFarlane, S. M., Fisher, J. A., Xu, L., Wennberg, P. O., Crounse, J. D., Ball, K., Zhai, S., Bates, K. H., Kim, Y., Zhang, Q., and Blake, D. R.: Sources, Sinks, and Oxidation Pathways of Phenolic Compounds in South Korea Constrained Using KORUS-AQ Airborne Observations, J. Geophys. Res.-Atmos., 130, e2024JD043110, https://doi.org/10.1029/2024JD043110, 2025.
Mayorga, R. J., Zhao, Z., and Zhang, H.: Formation of secondary organic aerosol from nitrate radical oxidation of phenolic VOCs: Implications for nitration mechanisms and brown carbon formation, Atmos. Environ., 244, 117910, https://doi.org/10.1016/j.atmosenv.2020.117910, 2021.
Mohr, C., Lopez-Hilfiker, F. D., Zotter, P., Prévôt, A. S. H., Xu, L., Ng, N. L., Herndon, S. C., Williams, L. R., Franklin, J. P., Zahniser, M. S., Worsnop, D. R., Knighton, W. B., Aiken, A. C., Gorkowski, K. J., Dubey, M. K., Allan, J. D., and Thornton, J. A.: Contribution of Nitrated Phenols to Wood Burning Brown Carbon Light Absorption in Detling, United Kingdom during Winter Time, Environ. Sci. Technol., 47, 6316–6324, https://doi.org/10.1021/es400683v, 2013.
Morales, J. A., Pirela, D., de Nava, M. G., de Borrego, B. S., Velásquez, H., and Durán, J.: Inorganic water soluble ions in atmospheric particles over Maracaibo Lake Basin in the western region of Venezuela, Atmos. Res., 46, 307–320, https://doi.org/10.1016/S0169-8095(97)00071-9, 1998.
Nguyen, T. K. V., Zhang, Q., Jimenez, J. L., Pike, M., and Carlton, A. G.: Liquid water: ubiquitous contributor to aerosol mass, Environ. Sci. Tech. Let., 3, 257–263, 2016.
Olariu, R. I., Klotz, B., Barnes, I., Becker, K. H., and Mocanu, R.: FT–IR study of the ring-retaining products from the reaction of OH radicals with phenol, o-, m-, and p-cresol, Atmos. Environ., 36, 3685–3697, https://doi.org/10.1016/S1352-2310(02)00202-9, 2002.
Olariu, R. I., Barnes, I., Bejan, I., Arsene, C., Vione, D., Klotz, B., and Becker, K. H.: FT-IR Product Study of the Reactions of NO3 Radicals With ortho-, meta-, and para-Cresol, Environ. Sci. Technol., 47, 7729–7738, https://doi.org/10.1021/es401096w, 2013.
Rana, M. S. and Guzman, M. I.: Oxidation of Catechols at the Air–Water Interface by Nitrate Radicals, Environ. Sci. Technol., 56, 15437–15448, https://doi.org/10.1021/acs.est.2c05640, 2022.
Salvador, C. M. G., Tang, R., Priestley, M., Li, L., Tsiligiannis, E., Le Breton, M., Zhu, W., Zeng, L., Wang, H., Yu, Y., Hu, M., Guo, S., and Hallquist, M.: Ambient nitro-aromatic compounds – biomass burning versus secondary formation in rural China, Atmos. Chem. Phys., 21, 1389–1406, https://doi.org/10.5194/acp-21-1389-2021, 2021.
Sareen, N., Waxman, E. M., Turpin, B. J., Volkamer, R., and Carlton, A. G.: Potential of aerosol liquid water to facilitate organic aerosol formation: assessing knowledge gaps about precursors and partitioning, Environ. Sci. Technol., 51, 3327–3335, 2017.
Selimovic, V., Yokelson, R. J., McMeeking, G. R., and Coefield, S.: Aerosol Mass and Optical Properties, Smoke Influence on O3, and High NO3 Production Rates in a Western U.S. City Impacted by Wildfires, J. Geophys. Res.-Atmos., 125, e2020JD032791, https://doi.org/10.1029/2020JD032791, 2020.
Shi, X., Qiu, X., Li, A., Jiang, X., Wei, G., Zheng, Y., Chen, Q., Chen, S., Hu, M., Rudich, Y., and Zhu, T.: Polar Nitrated Aromatic Compounds in Urban Fine Particulate Matter: A Focus on Formation via an Aqueous-Phase Radical Mechanism, Environ. Sci. Technol., 57, 5160–5168, https://doi.org/10.1021/acs.est.2c07324, 2023.
Vidović, K., Lašič Jurković, D., Šala, M., Kroflič, A., and Grgić, I.: Nighttime Aqueous-Phase Formation of Nitrocatechols in the Atmospheric Condensed Phase, Environ. Sci. Technol., 52, 9722–9730, https://doi.org/10.1021/acs.est.8b01161, 2018.
Wang, D., Shen, Z., Zhang, Q., Lei, Y., Zhang, T., Huang, S., Sun, J., Xu, H., and Cao, J.: Winter brown carbon over six of China's megacities: light absorption, molecular characterization, and improved source apportionment revealed by multilayer perceptron neural network, Atmos. Chem. Phys., 22, 14893–14904, https://doi.org/10.5194/acp-22-14893-2022, 2022.
Wang, H., Gao, Y., Wang, S., Wu, X., Liu, Y., Li, X., Huang, D., Lou, S., Wu, Z., Guo, S., Jing, S., Li, Y., Huang, C., Tyndall, G. S., Orlando, J. J., and Zhang, X.: Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions, J. Geophys. Res.-Atmos., 125, e2020JD033401, https://doi.org/10.1029/2020JD033401, 2020.
Wang, S. and Li, H.: NO3⚫-Initiated Gas-Phase Formation of Nitrated Phenolic Compounds in Polluted Atmosphere, Environ. Sci. Technol., 55, 2899–2907, https://doi.org/10.1021/acs.est.0c08041, 2021.
Wang, X., Gu, R., Wang, L., Xu, W., Zhang, Y., Chen, B., Li, W., Xue, L., Chen, J., and Wang, W.: Emissions of fine particulate nitrated phenols from the burning of five common types of biomass, Environ. Pollut., 230, 405–412, https://doi.org/10.1016/j.envpol.2017.06.072, 2017.
Wang, Y., Hu, M., Wang, Y., Zheng, J., Shang, D., Yang, Y., Liu, Y., Li, X., Tang, R., Zhu, W., Du, Z., Wu, Y., Guo, S., Wu, Z., Lou, S., Hallquist, M., and Yu, J. Z.: The formation of nitro-aromatic compounds under high NOx and anthropogenic VOC conditions in urban Beijing, China, Atmos. Chem. Phys., 19, 7649–7665, https://doi.org/10.5194/acp-19-7649-2019, 2019.
Wang, Y., Zhao, Y., Wang, Y., Yu, J.-Z., Shao, J., Liu, P., Zhu, W., Cheng, Z., Li, Z., Yan, N., and Xiao, H.: Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms, Atmos. Chem. Phys., 21, 2959–2980, https://doi.org/10.5194/acp-21-2959-2021, 2021.
Xie, M., Chen, X., Hays, M. D., and Holder, A. L.: Composition and light absorption of N-containing aromatic compounds in organic aerosols from laboratory biomass burning, Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, 2019.
Xiong, H., Liu, X., Sun, C., Zhang, X., Wang, X., Lin, J., Xue, L., Sun, X., Shang, X., Ma, F., Xie, H., Chen, J., Yan, G., Shu, J., Fu, H., Wang, L., Rudich, Y., George, C., Mellouki, A., Zhao, D., Wang, X., Herrmann, H., and Chen, J.: Atmospheric water cluster–catalyzed formation of nitroaromatics as a secondary aerosol source, Sci. Adv., 11, eadv7805, https://doi.org/10.1126/sciadv.adv7805, 2025.
Xu, Y., Xiao, H., Wu, D., and Long, C.: Abiotic and Biological Degradation of Atmospheric Proteinaceous Matter Can Contribute Significantly to Dissolved Amino Acids in Wet Deposition, Environ. Sci. Technol., 54, 6551–6561, 2020a.
Xu, Y., Dong, X.-N., Xiao, H.-Y., Zhou, J.-X., and Wu, D.-S.: Proteinaceous Matter and Liquid Water in Fine Aerosols in Nanchang, Eastern China: Seasonal Variations, Sources, and Potential Connections, J. Geophys. Res.-Atmos., 127, e2022JD036589, https://doi.org/10.1029/2022JD036589, 2022.
Xu, Y., Miyazaki, Y., Tachibana, E., Sato, K., Ramasamy, S., Mochizuki, T., Sadanaga, Y., Nakashima, Y., Sakamoto, Y., Matsuda, K., and Kajii, Y.: Aerosol Liquid Water Promotes the Formation of Water-Soluble Organic Nitrogen in Submicrometer Aerosols in a Suburban Forest, Environ. Sci. Technol., 54, 1406–1414, 2020b.
Xu, Y., Dong, X.-N., He, C., Wu, D.-S., Xiao, H.-W., and Xiao, H.-Y.: Mist cannon trucks can exacerbate the formation of water-soluble organic aerosol and PM2.5 pollution in the road environment, Atmos. Chem. Phys., 23, 6775–6788, https://doi.org/10.5194/acp-23-6775-2023, 2023.
Xu, Y., Lin, X., Sun, Q.-B., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Elaborating the Atmospheric Transformation of Combined and Free Amino Acids From the Perspective of Observational Studies, J. Geophys. Res.-Atmos., 129, e2024JD040730, https://doi.org/10.1029/2024JD040730, 2024a.
Xu, Y., Liu, T., Ma, Y.-J., Sun, Q.-B., Xiao, H.-W., Xiao, H., Xiao, H.-Y., and Liu, C.-Q.: Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints, Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, 2024b.
Xu, Y., Ma, Y.-J., Yang, T., Sun, Q.-B., Wang, Y.-C., Gui, L., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Molecular evidence on potential contribution of marine emissions to aromatic and aliphatic organic sulfur and nitrogen aerosols in the South China Sea, Atmos. Chem. Phys., 25, 13621–13634, https://doi.org/10.5194/acp-25-13621-2025, 2025.
Yang, T., Xu, Y., Ye, Q., Ma, Y.-J., Wang, Y.-C., Yu, J.-Z., Duan, Y.-S., Li, C.-X., Xiao, H.-W., Li, Z.-Y., Zhao, Y., and Xiao, H.-Y.: Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution, Atmos. Chem. Phys., 23, 13433–13450, https://doi.org/10.5194/acp-23-13433-2023, 2023.
Yang, T., Xu, Y., Ma, Y.-J., Wang, Y.-C., Yu, J. Z., Sun, Q.-B., Xiao, H.-W., Xiao, H.-Y., and Liu, C.-Q.: Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates, Environ. Sci. Tech. Let., 11, 981–987, https://doi.org/10.1021/acs.estlett.4c00522, 2024.
Yang, T., Xu, Y., Wang, Y.-C., Ma, Y.-J., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China, Atmos. Chem. Phys., 25, 2967–2978, https://doi.org/10.5194/acp-25-2967-2025, 2025.
Yang, W., You, D., Li, C., Han, C., Tang, N., Yang, H., and Xue, X.: Photolysis of Nitroaromatic Compounds under Sunlight: A Possible Daytime Photochemical Source of Nitrous Acid?, Environ. Sci. Tech. Let., 8, 747–752, https://doi.org/10.1021/acs.estlett.1c00614, 2021.
Yang, Y., Li, X., Shen, R., Liu, Z., Ji, D., and Wang, Y.: Seasonal variation and sources of derivatized phenols in atmospheric fine particulate matter in North China Plain, J. Environ. Sci., 89, 136–144, https://doi.org/10.1016/j.jes.2019.10.015, 2020.
Yin, M.-J., Xu, Y., Zhu, R.-G., Wang, Y., Sun, Q.-B., Gui, L., You, Y.-C., Tao, J.-L., Xiao, H.-W., Xiao, H., and Xiao, H.-Y.: Field New Insights into Bioaerosol Amino Acid Origin and Atmospheric Degradation: Significant Dust Contribution and Drying Effect, Environ. Sci. Technol., 60, 688–699, https://doi.org/10.1021/acs.est.5c12980, 2026.
You, Y.-C., Yang, T., Xu, Y., Gui, L., Wang, Y.-C., Yin, M.-J., Xiao, H., Xiao, H.-W., and Xiao, H.-Y.: Novel Discoveries about the Potential Nonsecondary Origins of C2–C3 Organosulfates in Ambient Aerosol Particles, Environ. Sci. Technol., 60, 6298–6309, https://doi.org/10.1021/acs.est.5c18511, 2026.
Yu, X.: Dataset, Zenodo [data set], https://doi.org/10.5281/zenodo.21510754, 2026.
Zhang, B., Shen, Z., He, K., Sun, J., Huang, S., Xu, H., Li, J., Ho, S. S. H., and Cao, J.-j.: Insight into the Primary and Secondary Particle-Bound Methoxyphenols and Nitroaromatic Compound Emissions from Solid Fuel Combustion and the Updated Source Tracers, Environ. Sci. Technol., 57, 14280–14288, https://doi.org/10.1021/acs.est.3c04370, 2023.
Zhang, Y.-L. and Cao, F.: Fine particulate matter (PM2.5) in China at a city level, Sci. Rep., 5, 14884, https://doi.org/10.1038/srep14884, 2015.
Short summary
This study presents the characteristics and potential origins of nitroaromatics (NACs) in winter PM2.5 across 11 Chinese cities, along with key factors controlling their formation. We propose that relative humidity- or aerosol liquid water-promoted NAC formation from lab studies may not be universally interpretable in real atmospheres, where multi-factor interactions are critical. This work highlights the need to consider complex field conditions in future research on NAC formation mechanisms.
This study presents the characteristics and potential origins of nitroaromatics (NACs) in winter...
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