College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Zhe Peng
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Wenjie Wang
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz 55128, Germany
Suxia Yang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Jipeng Qi
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Xianjun He
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yibo Huangfu
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Xiao-Bing Li
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong-Hongkong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
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A structural-based parameterization for the photolysis rates of oxygenated volatile organic compounds (OVOCs) was integrated into an updated chemical mechanism. This method links photolysis rates to species' structure, bypassing limitations of insufficient quantum yield data. Box model results show that non-HCHO OVOCs, particularly multifunctional carbonyl compounds, significantly contribute to radical production, with alkene and aromatic oxidation products playing key roles.
A structural-based parameterization for the photolysis rates of oxygenated volatile organic...