Articles | Volume 25, issue 22
https://doi.org/10.5194/acp-25-16435-2025
https://doi.org/10.5194/acp-25-16435-2025
Research article
 | 
21 Nov 2025
Research article |  | 21 Nov 2025

Key Role of Nitrogen-containing Oxygenated Organic Molecules (OOMs) in SOA Formation Evidenced by OH/NO3-induced Terpinolene Oxidation

Hongjin Wu, Juan Dang, Xiaomeng Zhang, Weichen Yang, Shuai Tian, Shibo Zhang, Qingzhu Zhang, and Wenxing Wang

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Cited articles

Arey, J., Atkinson, R., and Aschmann, S. M.: Product Study of the Gas-Phase Reactions of Monoterpenes With the OH Radical in the Presence of NOx, Journal of Geophysical Research-Atmospheres, 95, 18539–18546, https://doi.org/10.1029/JD095iD11p18539, 1990. 
Aschmann, S. M., Arey, J., and Atkinson, R.: OH radical formation from the gas-phase reactions of O3 with a series of terpenes, Atmospheric Environment, 36, 4347–4355, https://doi.org/10.1016/s1352-2310(02)00355-2, 2002. 
Atkinson, R. and Arey, J.: Atmospheric Degradation of Volatile Organic Compounds, Chemical Reviews, 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003. 
Atkinson, R., Hasegawa, D., and Aschmann, S. M.: Rate Constants for the Gas-Phase Reactions of O3 with a Series of Monoterpenes and Related Compounds at 296 ± 2 K, International Journal of Chemical Kinetics, 22, 871–887, https://doi.org/10.1002/kin.550220807, 1990. 
Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH Radicals in the Gas Phase Reactions of O3 With a Series of Terpenes, Journal of Geophysical Research-Atmospheres, 97, 6065–6073, https://doi.org/10.1029/92jd00062, 1992. 
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Terpinolene is an isomeride of limonene, with a high secondary organic aerosol (SOA) yield. The comparative analysis of OH-initiated (daytime) and NO3-driven (nocturnal) terpinolene oxidation mechanism, highlighted the formation of nitrogen-containing oxygenated organic molecules (OOMs), would be conducive to molecular structures identification of OOMs in atmospheric monitoring and atmospheric chemical model refinement.
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