Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 25, issue 18
Articles | Volume 25, issue 18
https://doi.org/10.5194/acp-25-11247-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-11247-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 25, issue 18
Research article
 | 
25 Sep 2025
Research article |  | 25 Sep 2025

Formation of chlorinated organic compounds from Cl atom-initiated reactions of aromatics and their detection in suburban Shanghai

Chuang Li, Lei Yao, Yuwei Wang, Mingliang Fang, Xiaojia Chen, Lihong Wang, Yueyang Li, Gan Yang, and Lin Wang

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Latest update: 02 Oct 2025
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Short summary
Abundant chlorine-containing oxygenated organic molecules (Cl-OOMs) were formed from the reactions between Cl atoms and aromatics, and Cl-addition was identified as a non-negligible pathway for the formation of Cl-OOMs. Furthermore, many ambient Cl-OOMs potentially derived from Cl atoms and aromatics were measured in suburban Shanghai and most of them have adverse health effects. These findings provide critical insights into the formation mechanisms of Cl-OOMs in polluted settings.
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