Articles | Volume 24, issue 14
https://doi.org/10.5194/acp-24-8263-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-8263-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report
| 
22 Jul 2024
Measurement report |
| 22 Jul 2024
| 22 Jul 2024
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Maya Abou-Ghanem
CORRESPONDING AUTHOR
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, 80305, USA
Daniel M. Murphy
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, 80305, USA
Gregory P. Schill
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, 80305, USA
Michael J. Lawler
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, 80309, USA
Karl D. Froyd
Chemical Sciences Laboratory, National Oceanic and Atmospheric Administration, Boulder, 80305, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, 80309, USA
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Kane Stone, Susan Solomon, Pengfei Yu, Daniel M. Murphy, Douglas Kinnison, and Jian Guan
Atmos. Chem. Phys., 25, 7683–7697, https://doi.org/10.5194/acp-25-7683-2025, https://doi.org/10.5194/acp-25-7683-2025, 2025
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The Australian 2019–2020 wildfires injected a substantial amount of smoke into the upper atmosphere, causing unusual chemical reactions that altered the chemical makeup of the upper atmosphere. This led to ozone depletion in the Southern Hemisphere midlatitudes that likely did not fully recover until 2 years after the initial event due to the persistent chemical effects of the smoke.
Paul J. DeMott, Jessica A. Mirrielees, Sarah Suda Petters, Daniel J. Cziczo, Markus D. Petters, Heinz G. Bingemer, Thomas C. J. Hill, Karl Froyd, Sarvesh Garimella, A. Gannet Hallar, Ezra J. T. Levin, Ian B. McCubbin, Anne E. Perring, Christopher N. Rapp, Thea Schiebel, Jann Schrod, Kaitlyn J. Suski, Daniel Weber, Martin J. Wolf, Maria Zawadowicz, Jake Zenker, Ottmar Möhler, and Sarah D. Brooks
Atmos. Meas. Tech., 18, 639–672, https://doi.org/10.5194/amt-18-639-2025, https://doi.org/10.5194/amt-18-639-2025, 2025
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The Fifth International Ice Nucleation Workshop Phase 3 (FIN-03) compared the ambient atmospheric performance of ice-nucleating particle (INP) measuring systems and explored general methods for discerning atmospheric INP compositions. Mirroring laboratory results, INP concentrations agreed within 5–10 factors. Measurements of total aerosol properties and investigations of INP compositions supported a dominant role of soil and plant organic aerosol elements as INPs during the study.
Kasper Juurikkala, Christina J. Williamson, Karl D. Froyd, Jonathan Dean-Day, and Ari Laaksonen
EGUsphere, https://doi.org/10.5194/egusphere-2025-163, https://doi.org/10.5194/egusphere-2025-163, 2025
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This study uses UCLALES-SALSA simulations to investigate synoptic cirrus clouds from NASA’s MACPEX campaign. Results show that prior heterogeneous ice nucleation depletes ice nuclei, creating conditions for subsequent homogeneous freezing. The findings highlight limitations of ice residual analysis in capturing cirrus evolution and provide insights into aerosol-cloud interactions critical to atmospheric and climate processes.
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles A. Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
Atmos. Chem. Phys., 25, 45–71, https://doi.org/10.5194/acp-25-45-2025, https://doi.org/10.5194/acp-25-45-2025, 2025
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Using single-particle mass spectrometry, we show that trace concentrations of bromine and iodine are ubiquitous in remote tropospheric aerosol and suggest that aerosols are an important part of the global reactive iodine budget. Comparisons to a global climate model with detailed iodine chemistry are favorable in the background atmosphere; however, the model cannot replicate our measurements near the ocean surface, in biomass burning plumes, and in the stratosphere.
Xiaoli Shen, David M. Bell, Hugh Coe, Naruki Hiranuma, Fabian Mahrt, Nicholas A. Marsden, Claudia Mohr, Daniel M. Murphy, Harald Saathoff, Johannes Schneider, Jacqueline Wilson, Maria A. Zawadowicz, Alla Zelenyuk, Paul J. DeMott, Ottmar Möhler, and Daniel J. Cziczo
Atmos. Chem. Phys., 24, 10869–10891, https://doi.org/10.5194/acp-24-10869-2024, https://doi.org/10.5194/acp-24-10869-2024, 2024
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Single-particle mass spectrometry (SPMS) is commonly used to measure the chemical composition and mixing state of aerosol particles. Intercomparison of SPMS instruments was conducted. All instruments reported similar size ranges and common spectral features. The instrument-specific detection efficiency was found to be more dependent on particle size than type. All differentiated secondary organic aerosol, soot, and soil dust but had difficulties differentiating among minerals and dusts.
Huisheng Bian, Mian Chin, Peter R. Colarco, Eric C. Apel, Donald R. Blake, Karl Froyd, Rebecca S. Hornbrook, Jose Jimenez, Pedro Campuzano Jost, Michael Lawler, Mingxu Liu, Marianne Tronstad Lund, Hitoshi Matsui, Benjamin A. Nault, Joyce E. Penner, Andrew W. Rollins, Gregory Schill, Ragnhild B. Skeie, Hailong Wang, Lu Xu, Kai Zhang, and Jialei Zhu
Atmos. Chem. Phys., 24, 1717–1741, https://doi.org/10.5194/acp-24-1717-2024, https://doi.org/10.5194/acp-24-1717-2024, 2024
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This work studies sulfur in the remote troposphere at global and seasonal scales using aircraft measurements and multi-model simulations. The goal is to understand the sulfur cycle over remote oceans, spread of model simulations, and observation–model discrepancies. Such an understanding and comparison with real observations are crucial to narrow down the uncertainties in model sulfur simulations and improve understanding of the sulfur cycle in atmospheric air quality, climate, and ecosystems.
Siying Lian, Luxi Zhou, Daniel M. Murphy, Karl D. Froyd, Owen B. Toon, and Pengfei Yu
Atmos. Chem. Phys., 22, 13659–13676, https://doi.org/10.5194/acp-22-13659-2022, https://doi.org/10.5194/acp-22-13659-2022, 2022
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Parameterizations of dust lifting and microphysical properties of dust in climate models are still subject to large uncertainty. Here we use a sectional aerosol climate model to investigate the global vertical distributions of the dust. Constrained by a suite of observations, the model suggests that, although North African dust dominates global dust mass loading at the surface, the relative contribution of Asian dust increases with altitude and becomes dominant in the upper troposphere.
Meloë S. F. Kacenelenbogen, Qian Tan, Sharon P. Burton, Otto P. Hasekamp, Karl D. Froyd, Yohei Shinozuka, Andreas J. Beyersdorf, Luke Ziemba, Kenneth L. Thornhill, Jack E. Dibb, Taylor Shingler, Armin Sorooshian, Reed W. Espinosa, Vanderlei Martins, Jose L. Jimenez, Pedro Campuzano-Jost, Joshua P. Schwarz, Matthew S. Johnson, Jens Redemann, and Gregory L. Schuster
Atmos. Chem. Phys., 22, 3713–3742, https://doi.org/10.5194/acp-22-3713-2022, https://doi.org/10.5194/acp-22-3713-2022, 2022
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The impact of aerosols on Earth's radiation budget and human health is important and strongly depends on their composition. One desire of our scientific community is to derive the composition of the aerosol from satellite sensors. However, satellites observe aerosol optical properties (and not aerosol composition) based on remote sensing instrumentation. This study assesses how much aerosol optical properties can tell us about aerosol composition.
Adam T. Ahern, Frank Erdesz, Nicholas L. Wagner, Charles A. Brock, Ming Lyu, Kyra Slovacek, Richard H. Moore, Elizabeth B. Wiggins, and Daniel M. Murphy
Atmos. Meas. Tech., 15, 1093–1105, https://doi.org/10.5194/amt-15-1093-2022, https://doi.org/10.5194/amt-15-1093-2022, 2022
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Particles in the atmosphere play a significant role in climate change by scattering light back into space, reducing the amount of energy available to be absorbed by greenhouse gases. We built a new instrument to measure what direction light is scattered by particles, e.g., wildfire smoke. This is important because, depending on the angle of the sun, some particles scatter light into space (cooling the planet), but some light is also scattered towards the Earth (not cooling the planet).
Li Zhang, Georg A. Grell, Stuart A. McKeen, Ravan Ahmadov, Karl D. Froyd, and Daniel Murphy
Geosci. Model Dev., 15, 467–491, https://doi.org/10.5194/gmd-15-467-2022, https://doi.org/10.5194/gmd-15-467-2022, 2022
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Applying the chemistry package from WRF-Chem into the Flow-following finite-volume Icosahedra Model, we essentially make it possible to explore the importance of different levels of complexity in gas and aerosol chemistry, as well as in physics parameterizations, for the interaction processes in global modeling systems. The model performance validated by the Atmospheric Tomography Mission aircraft measurements in summer 2016 shows good performance in capturing the aerosol and gas-phase tracers.
Charles A. Brock, Karl D. Froyd, Maximilian Dollner, Christina J. Williamson, Gregory Schill, Daniel M. Murphy, Nicholas J. Wagner, Agnieszka Kupc, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jason C. Schroder, Douglas A. Day, Derek J. Price, Bernadett Weinzierl, Joshua P. Schwarz, Joseph M. Katich, Siyuan Wang, Linghan Zeng, Rodney Weber, Jack Dibb, Eric Scheuer, Glenn S. Diskin, Joshua P. DiGangi, ThaoPaul Bui, Jonathan M. Dean-Day, Chelsea R. Thompson, Jeff Peischl, Thomas B. Ryerson, Ilann Bourgeois, Bruce C. Daube, Róisín Commane, and Steven C. Wofsy
Atmos. Chem. Phys., 21, 15023–15063, https://doi.org/10.5194/acp-21-15023-2021, https://doi.org/10.5194/acp-21-15023-2021, 2021
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The Atmospheric Tomography Mission was an airborne study that mapped the chemical composition of the remote atmosphere. From this, we developed a comprehensive description of aerosol properties that provides a unique, global-scale dataset against which models can be compared. The data show the polluted nature of the remote atmosphere in the Northern Hemisphere and quantify the contributions of sea salt, dust, soot, biomass burning particles, and pollution particles to the haziness of the sky.
Christina J. Williamson, Agnieszka Kupc, Andrew Rollins, Jan Kazil, Karl D. Froyd, Eric A. Ray, Daniel M. Murphy, Gregory P. Schill, Jeff Peischl, Chelsea Thompson, Ilann Bourgeois, Thomas B. Ryerson, Glenn S. Diskin, Joshua P. DiGangi, Donald R. Blake, Thao Paul V. Bui, Maximilian Dollner, Bernadett Weinzierl, and Charles A. Brock
Atmos. Chem. Phys., 21, 9065–9088, https://doi.org/10.5194/acp-21-9065-2021, https://doi.org/10.5194/acp-21-9065-2021, 2021
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Aerosols in the stratosphere influence climate by scattering and absorbing sunlight and through chemical reactions occurring on the particles’ surfaces. We observed more nucleation mode aerosols (small aerosols, with diameters below 12 nm) in the mid- and high-latitude lowermost stratosphere (8–13 km) in the Northern Hemisphere (NH) than in the Southern Hemisphere. The most likely cause of this is aircraft emissions, which are concentrated in the NH at similar altitudes to our observations.
Daniel M. Murphy, Karl D. Froyd, Ilann Bourgeois, Charles A. Brock, Agnieszka Kupc, Jeff Peischl, Gregory P. Schill, Chelsea R. Thompson, Christina J. Williamson, and Pengfei Yu
Atmos. Chem. Phys., 21, 8915–8932, https://doi.org/10.5194/acp-21-8915-2021, https://doi.org/10.5194/acp-21-8915-2021, 2021
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New measurements in the lower stratosphere highlight differences between particles that originated in the troposphere or the stratosphere. The stratospheric-origin particles have relatively large radiative effects because they are at nearly the optimum diameter for light scattering. The tropospheric particles contribute significantly to surface area. These and other chemical and physical properties are then extended to study the implications if material were to be added to the stratosphere.
Michael J. Lawler, Savannah L. Lewis, Lynn M. Russell, Patricia K. Quinn, Timothy S. Bates, Derek J. Coffman, Lucia M. Upchurch, and Eric S. Saltzman
Atmos. Chem. Phys., 20, 16007–16022, https://doi.org/10.5194/acp-20-16007-2020, https://doi.org/10.5194/acp-20-16007-2020, 2020
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This work describes new measurements of aerosol (particles) composition over the North Atlantic Ocean. It provides concentrations of polysaccharide material likely made from organisms in the surface ocean and improves our understanding of the relative importance of such fresh biogenic material compared to more recalcitrant organic carbon in forming marine organic aerosol. We aim ultimately to understand the role that ocean biology plays in cloud formation in marine regions.
Agnieszka Kupc, Christina J. Williamson, Anna L. Hodshire, Jan Kazil, Eric Ray, T. Paul Bui, Maximilian Dollner, Karl D. Froyd, Kathryn McKain, Andrew Rollins, Gregory P. Schill, Alexander Thames, Bernadett B. Weinzierl, Jeffrey R. Pierce, and Charles A. Brock
Atmos. Chem. Phys., 20, 15037–15060, https://doi.org/10.5194/acp-20-15037-2020, https://doi.org/10.5194/acp-20-15037-2020, 2020
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Tropical upper troposphere over the Atlantic and Pacific oceans is a major source region of new particles. These particles are associated with the outflow from deep convection. We investigate the processes that govern the formation of these particles and their initial growth and show that none of the formation schemes commonly used in global models are consistent with observations. Using newer schemes indicates that organic compounds are likely important as nucleating and initial growth agents.
Cited articles
Adachi, A., Ogawa, K., Tsushi, Y., Nagao, N., and Kobayashi, T.: Determination of vanadium in environmental samples by atomic absorption spectrophotometry, Water Res., 31, 1247–1250, https://doi.org/10.1016/S0043-1354(96)00379-X, 1997.
Agrawal, H., Malloy, Q. G. J., Welch, W. A., Wayne Miller, J., and Cocker, D. R.: In-use gaseous and particulate matter emissions from a modern ocean going container vessel, Atmos. Environ., 42, 5504–5510, https://doi.org/10.1016/j.atmosenv.2008.02.053, 2008.
Alexander, B., Park, R. J., Jacob, D. J., and Gong, S.: Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget, J. Geophys. Res.-Atmos., 114, D02309, https://doi.org/10.1029/2008JD010486, 2009.
Al-Gaashani, R., Radiman, S., Tabet, N., and Daud, A. R.: Rapid synthesis and optical properties of hematite (α-Fe2O3) nanostructures using a simple thermal decomposition method, J. Alloy. Compd., 550, 395–401, https://doi.org/10.1016/j.jallcom.2012.10.150, 2013.
Ali, M. F. and Abbas, S.: A review of methods for the demetallization of residual fuel oils, Fuel Process. Technol., 87, 573–584, https://doi.org/10.1016/j.fuproc.2006.03.001, 2006.
Anders, L., Schade, J., Rosewig, E. I., Kröger-Badge, T., Irsig, R., Jeong, S., Bendl, J., Saraji-Bozorgzad, M. R., Huang, J.-H., Zhang, F.-Y., C. Wang, C., Adam, T., Sklorz, M., Etzien, U., Buchholz, B., Czech, H., Streibel, T., Passig, J., and Zimmermann, R.: Detection of ship emissions from distillate fuel operation via single-particle profiling of polycyclic aromatic hydrocarbons, Environ. Sci.-Atmos., 3, 1134, https://doi.org/10.1039/d3ea00056g, 2023.
Ault, A. P., Gaston, C. J., Wang, Y., Dominguez, G., Thiemens, M. H., and Prather, K. A.: Characterization of the Single Particle Mixing State of Individual Ship Plume Events Measured at the Port of Los Angeles, Environ. Sci. Technol., 44, 1954–1961, https://doi.org/10.1021/es902985h, 2010.
Barbaray, B., Contour, J. P., and Mouvier, G.: Effects of nitrogen dioxide and water vapor on oxidation of sulfur dioxide over vanadium pentoxide particles, Environ. Sci. Technol., 12, 1294–1297, https://doi.org/10.1021/es60147a012, 1978.
Beke, S.: A review of the growth of V2O5 films from 1885 to 2010, Thin Solid Films, 519, 1761–1771, https://doi.org/10.1016/j.tsf.2010.11.001, 2011.
Bollati, V., Marinelli, B., Apostoli, P., Bonzini, M., Nordio, F., Hoxha, M., Pegoraro, V., Motta, V., Tarantini, L., Cantone, L., Schwartz, J., Bertazzi, P. A., and Baccarelli, A.: Exposure to Metal-Rich Particulate Matter Modifies the Expression of Candidate MicroRNAs in Peripheral Blood Leukocytes, Environ. Health Persp., 118, 763–768, https://doi.org/10.1289/ehp.0901300, 2010.
Brock, C. A., Froyd, K. D., Dollner, M., Williamson, C. J., Schill, G., Murphy, D. M., Wagner, N. J., Kupc, A., Jimenez, J. L., Campuzano-Jost, P., Nault, B. A., Schroder, J. C., Day, D. A., Price, D. J., Weinzierl, B., Schwarz, J. P., Katich, J. M., Wang, S., Zeng, L., Weber, R., Dibb, J., Scheuer, E., Diskin, G. S., DiGangi, J. P., Bui, T., Dean-Day, J. M., Thompson, C. R., Peischl, J., Ryerson, T. B., Bourgeois, I., Daube, B. C., Commane, R., and Wofsy, S. C.: Ambient aerosol properties in the remote atmosphere from global-scale in situ measurements, Atmos. Chem. Phys., 21, 15023–15063, https://doi.org/10.5194/acp-21-15023-2021, 2021.
Celo, V., Dabek-Zlotorzynska, E., and McCurdy, M.: Chemical Characterization of Exhaust Emissions from Selected Canadian Marine Vessels: The Case of Trace Metals and Lanthanoids, Environ. Sci. Technol., 49, 5220–5226, https://doi.org/10.1021/acs.est.5b00127, 2015.
Chen, C., Cao, Y., Liu, S., Chen, J., and Jia, W.: Review on the latest developments in modified vanadium-titanium-based SCR catalysts, Chinese J. Catal., 39, 1347–1365, https://doi.org/10.1016/S1872-2067(18)63090-6, 2018.
Chen, H., Navea, J. G., Young, M. A., and Grassian, V. H.: Heterogeneous Photochemistry of Trace Atmospheric Gases with Components of Mineral Dust Aerosol, J. Phys. Chem. A, 115, 490–499, https://doi.org/10.1021/jp110164j, 2011.
Coggon, M. M., Sorooshian, A., Wang, Z., Metcalf, A. R., Frossard, A. A., Lin, J. J., Craven, J. S., Nenes, A., Jonsson, H. H., Russell, L. M., Flagan, R. C., and Seinfeld, J. H.: Ship impacts on the marine atmosphere: insights into the contribution of shipping emissions to the properties of marine aerosol and clouds, Atmos. Chem. Phys., 12, 8439–8458, https://doi.org/10.5194/acp-12-8439-2012, 2012.
Corbett, J. J., Winebrake, J. J., Green, E. H., Kasibhatla, P., Eyring, V., and Lauer, A.: Mortality from Ship Emissions: A Global Assessment, Environ. Sci. Technol., 41, 8512–8518, https://doi.org/10.1021/es071686z, 2007.
Corbin, J. C., Mensah, A. A., Pieber, S. M., Orasche, J., Michalke, B., Zanatta, M., Czech, H., Massabò, D., Buatier de Mongeot, F., Mennucci, C., El Haddad, I., Kumar, N. K., Stengel, B., Huang, Y., Zimmermann, R., Prévôt, A. S. H., and Gysel, M.: Trace Metals in Soot and PM2.5 from Heavy-Fuel-Oil Combustion in a Marine Engine, Environ. Sci. Technol., 52, 6714–6722, https://doi.org/10.1021/acs.est.8b01764, 2018.
Enami, S., Sakamoto, Y., and Colussi, A. J.: Fenton chemistry at aqueous interfaces, P. Natl. Acad. Sci. USA, 111, 623–628, https://doi.org/10.1073/pnas.1314885111, 2014.
Eyring, V., Köhler, H. W., van Aardenne, J., and Lauer, A.: Emissions from international shipping: 1. The last 50 years, J. Geophys. Res.-Atmos., 110, D17305, https://doi.org/10.1029/2004JD005619, 2005.
Falkovich, A. H., Ganor, E., Levin, Z., Formenti, P., and Rudich, Y.: Chemical and mineralogical analysis of individual mineral dust particles, J. Geophys. Res.-Atmos., 106, 18029–18036, https://doi.org/10.1029/2000JD900430, 2001.
Finlayson-Pitts, B. J. and Pitts Jr., J. N.: Chemistry of the Upper and Lower Atmosphere: Theory, Experiments, and Applications, Elsevier, ISBN 978-0122570605, 1999.
Froyd, K. D., Murphy, D. M., Brock, C. A., Campuzano-Jost, P., Dibb, J. E., Jimenez, J.-L., Kupc, A., Middlebrook, A. M., Schill, G. P., Thornhill, K. L., Williamson, C. J., Wilson, J. C., and Ziemba, L. D.: A new method to quantify mineral dust and other aerosol species from aircraft platforms using single-particle mass spectrometry, Atmos. Meas. Tech., 12, 6209–6239, https://doi.org/10.5194/amt-12-6209-2019, 2019.
Fu, H., Wang, X., Wu, H., Yin, Y., and Chen, J.: Heterogeneous Uptake and Oxidation of SO2 on Iron Oxides, J. Phys. Chem. C, 111, 6077–6085, https://doi.org/10.1021/jp070087b, 2007.
Healy, R. M., O'Connor, I. P., Hellebust, S., Allanic, A., Sodeau, J. R., and Wenger, J. C.: Characterisation of single particles from in-port ship emissions, Atmos. Environ., 43, 6408–6414, https://doi.org/10.1016/j.atmosenv.2009.07.039, 2009.
Hobbs, P. V., Garrett, T. J., Ferek, R. J., Strader, S. R., Hegg, D. A., Frick, G. M., Hoppel, W. A., Gasparovic, R. F., Russell, L. M., Johnson, D. W., O'Dowd, C., Durkee, P. A., Nielsen, K. E., and Innis, G.: Emissions from Ships with respect to Their Effects on Clouds, J. Atmos. Sci., 57, 2570–2590, https://doi.org/10.1175/1520-0469(2000)057<2570:EFSWRT>2.0.CO;2, 2000.
Hoffmann, M. and Jacob, D. J.: Kinetics and Mechanism of the Catalytic Oxidation of Sulfur Dioxide in Aqueous Solution: Application to Nighttime Fog and Cloud Water Chemistry, in: SO2, NO, and NO2 Oxidation Mechanisms: Atmospheric Considerations, Butterworth Publishers, Boston, MA, 101–172, ISBN 978-0250405688, 1984.
Hosny, N. M.: Synthesis, characterization and optical band gap of NiO nanoparticles derived from anthranilic acid precursors via a thermal decomposition route, Polyhedron, 30, 470–476, https://doi.org/10.1016/j.poly.2010.11.020, 2011.
Hudson, P. K., Murphy, D. M., Cziczo, D. J., Thomson, D. S., de Gouw, J. A., Warneke, C., Holloway, J., Jost, H.-J., and Hübler, G.: Biomass-burning particle measurements: Characteristic composition and chemical processing, J. Geophys. Res.-Atmos., 109, D23S27, https://doi.org/10.1029/2003JD004398, 2004.
IMO 2020: Cutting sulphur oxide emissions, https://www.imo.org/en/MediaCentre/HotTopics/Pages/Sulphur-2020.aspx, last access: 14 July 2023.
Khaled, A., Zhang, M., and Ervens, B.: The number fraction of iron-containing particles affects OH, HO2 and H2O2 budgets in the atmospheric aqueous phase, Atmos. Chem. Phys., 22, 1989–2009, https://doi.org/10.5194/acp-22-1989-2022, 2022.
Kim, Y., Moon, N., Chung, Y., and Seo, J.: Impact of IMO Sulfur Regulations on Air Quality in Busan, Republic of Korea, Atmosphere, 13, 1631, https://doi.org/10.3390/atmos13101631, 2022.
Lauer, A., Eyring, V., Hendricks, J., Jöckel, P., and Lohmann, U.: Global model simulations of the impact of ocean-going ships on aerosols, clouds, and the radiation budget, Atmos. Chem. Phys., 7, 5061–5079, https://doi.org/10.5194/acp-7-5061-2007, 2007.
Lehtoranta, K., Aakko-Saksa, P., Murtonen, T., Vesala, H., Ntziachristos, L., Rönkkö, T., Karjalainen, P., Kuittinen, N., and Timonen, H.: Particulate Mass and Nonvolatile Particle Number Emissions from Marine Engines Using Low-Sulfur Fuels, Natural Gas, or Scrubbers, Environ. Sci. Technol., 53, 3315–3322, https://doi.org/10.1021/acs.est.8b05555, 2019.
Liao, J., Froyd, K. D., Murphy, D. M., Keutsch, F. N., Yu, G., Wennberg, P. O., St. Clair, J. M., Crounse, J. D., Wisthaler, A., Mikoviny, T., Jimenez, J. L., Campuzano-Jost, P., Day, D. A., Hu, W., Ryerson, T. B., Pollack, I. B., Peischl, J., Anderson, B. E., Ziemba, L. D., Blake, D. R., Meinardi, S., and Diskin, G.: Airborne measurements of organosulfates over the continental U.S., J. Geophys. Res.-Atmos., 120, 2990–3005, https://doi.org/10.1002/2014JD022378, 2015.
Liu, Z., Chen, H., Li, L., Xie, G., Ouyang, H., Tang, X., Ju, R., Li, B., Zhang, R., and Chen, J.: Real-time single particle characterization of oxidized organic aerosols in the East China Sea, NPJ Clim. Atmos. Sci., 5, 1–9, https://doi.org/10.1038/s41612-022-00267-1, 2022.
Lousada, C. M., Johansson, A. J., Brinck, T., and Jonsson, M.: Mechanism of H2O2 Decomposition on Transition Metal Oxide Surfaces, J. Phys. Chem. C, 116, 9533–9543, https://doi.org/10.1021/jp300255h, 2012.
Mizuno, N. and Kamata, K.: Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates, Coord. Chem. Rev., 255, 2358–2370, https://doi.org/10.1016/j.ccr.2011.01.041, 2011.
Moldanová, J., Fridell, E., Winnes, H., Holmin-Fridell, S., Boman, J., Jedynska, A., Tishkova, V., Demirdjian, B., Joulie, S., Bladt, H., Ivleva, N. P., and Niessner, R.: Physical and chemical characterisation of PM emissions from two ships operating in European Emission Control Areas, Atmos. Meas. Tech., 6, 3577–3596, https://doi.org/10.5194/amt-6-3577-2013, 2013.
Moreno, T., Querol, X., Alastuey, A., de la Rosa, J., Sánchez de la Campa, A. M., Minguillón, M., Pandolfi, M., González-Castanedo, Y., Monfort, E., and Gibbons, W.: Variations in vanadium, nickel and lanthanoid element concentrations in urban air, Sci. Total Environ., 408, 4569–4579, https://doi.org/10.1016/j.scitotenv.2010.06.016, 2010.
Murphy, D. M., Middlebrook, A. M., and Warshawsky, M.: Cluster Analysis of Data from the Particle Analysis by Laser Mass Spectrometry (PALMS) Instrument, Aerosol Sci. Tech., 37, 382–391, https://doi.org/10.1080/02786820300971, 2003.
Murphy, D. M., Cziczo, D. J., Hudson, P. K., Thomson, D. S., Wilson, J. C., Kojima, T., and Buseck, P. R.: Particle Generation and Resuspension in Aircraft Inlets when Flying in Clouds, Aerosol Sci. Tech., 38, 401–409, https://doi.org/10.1080/02786820490443094, 2004.
Murphy, D. M., Cziczo, D. J., Froyd, K. D., Hudson, P. K., Matthew, B. M., Middlebrook, A. M., Peltier, R. E., Sullivan, A., Thomson, D. S., and Weber, R. J.: Single-particle mass spectrometry of tropospheric aerosol particles, J. Geophys. Res.-Atmos., 111, D23S32, https://doi.org/10.1029/2006JD007340, 2006.
Murphy, S. M., Agrawal, H., Sorooshian, A., Padró, L. T., Gates, H., Hersey, S., Welch, W. A., Jung, H., Miller, J. W., Cocker, D. R. I., Nenes, A., Jonsson, H. H., Flagan, R. C., and Seinfeld, J. H.: Comprehensive Simultaneous Shipboard and Airborne Characterization of Exhaust from a Modern Container Ship at Sea, Environ. Sci. Technol., 43, 4626–4640, https://doi.org/10.1021/es802413j, 2009.
Ndour, M., D'Anna, B., George, C., Ka, O., Balkanski, Y., Kleffmann, J., Stemmler, K., and Ammann, M.: Photoenhanced uptake of NO2 on mineral dust: Laboratory experiments and model simulations, Geophys. Res. Lett., 35, L05812, https://doi.org/10.1029/2007GL032006, 2008.
Ndour, M., Conchon, P., D'Anna, B., Ka, O., and George, C.: Photochemistry of mineral dust surface as a potential atmospheric renoxification process, Geophys. Res. Lett., 36, L05816, https://doi.org/10.1029/2008GL036662, 2009.
Passig, J., Schade, J., Irsig, R., Li, L., Li, X., Zhou, Z., Adam, T., and Zimmermann, R.: Detection of ship plumes from residual fuel operation in emission control areas using single-particle mass spectrometry, Atmos. Meas. Tech., 14, 4171–4185, https://doi.org/10.5194/amt-14-4171-2021, 2021.
Qin, X., Chen, Z., Gong, Y., Dong, P., Cao, Z., Hu, J., and Xu, J.: Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry, Environ. Sci. Technol., 56, 9978–9987, https://doi.org/10.1021/acs.est.2c03630, 2022.
Schlesinger, W. H., Klein, E. M., and Vengosh, A.: Global biogeochemical cycle of vanadium, P. Natl. Acad. Sci. USA, 114, E11092–E11100, https://doi.org/10.1073/pnas.1715500114, 2017.
Shafer, M. M., Toner, B. M., Overdier, J. T., Schauer, J. J., Fakra, S. C., Hu, S., Herner, J. D., and Ayala, A.: Chemical Speciation of Vanadium in Particulate Matter Emitted from Diesel Vehicles and Urban Atmospheric Aerosols, Environ. Sci. Technol., 46, 189–195, https://doi.org/10.1021/es200463c, 2012.
Singh, H. B., Gregory, G. L., Anderson, B., Browell, E., Sachse, G. W., Davis, D. D., Crawford, J., Bradshaw, J. D., Talbot, R., Blake, D. R., Thornton, D., Newell, R., and Merrill, J.: Low ozone in the marine boundary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms, and entrainment, J. Geophys. Res.-Atmos., 101, 1907–1917, https://doi.org/10.1029/95JD01028, 1996.
Song, H., Chen, X., Lu, K., Zou, Q., Tan, Z., Fuchs, H., Wiedensohler, A., Moon, D. R., Heard, D. E., Baeza-Romero, M.-T., Zheng, M., Wahner, A., Kiendler-Scharr, A., and Zhang, Y.: Influence of aerosol copper on HO2 uptake: a novel parameterized equation, Atmos. Chem. Phys., 20, 15835–15850, https://doi.org/10.5194/acp-20-15835-2020, 2020.
Song, S.-K., Shon, Z.-H., Moon, S.-H., Lee, T.-H., Kim, H.-S., Kang, S.-H., Park, G.-H., and Yoo, E.-C.: Impact of international Maritime Organization 2020 sulfur content regulations on port air quality at international hub port, J. Clean. Prod., 347, 131298, https://doi.org/10.1016/j.jclepro.2022.131298, 2022.
Thomson, D. S., Schein, M. E., and Murphy, D. M.: Particle analysis by laser mass spectrometry WB-57F instrument overview, Aerosol Sci. Tech., 33, 153–169, 2000.
Thompson, C. R., Wofsy, S. C., Prather, M. J., Newman, P. A., Hanisco, T. F., Ryerson, T. B., Fahey, D. W., Apel, E. C., Brock, C. A., Brune, W. H., Froyd, K., Katich, J. M., Nicely, J. M., Peischl, J., Ray, E., Veres, P. R., Wang, S., Allen, H. M., Asher, E., Bian, H., Blake, D., Bourgeois, I., Budney, J., Bui, T. P., Butler, A., Campuzano-Jost, P., Chang, C., Chin, M., Commane, R., Correa, G., Crounse, J. D., Daube, B., Dibb, J. E., DiGangi, J. P., Diskin, G. S., Dollner, M., Elkins, J. W., Fiore, A. M., Flynn, C. M., Guo, H., Hall, S. R., Hannun, R. A., Hills, A., Hintsa, E. J., Hodzic, A., Hornbrook, R. S., Huey, L. G., Jimenez, J. L., Keeling, R. F., Kim, M. J., Kupc, A., Lacey, F., Lait, L. R., Lamarque, J.-F., Liu, J., McKain, K., Meinardi, S., Miller, D. O., Montzka, S. A., Moore, F. L., Morgan, E. J., Murphy, D. M., Murray, L. T., Nault, B. A., Neuman, J. A., Nguyen, L., Gonzalez, Y., Rollins, A., Rosenlof, K., Sargent, M., Schill, G., Schwarz, J. P., Clair, J. M. S., Steenrod, S. D., Stephens, B. B., Strahan, S. E., Strode, S. A., Sweeney, C., Thames, A. B., Ullmann, K., Wagner, N., Weber, R., Weinzierl, B., Wennberg, P. O., Williamson, C. J., Wolfe, G. M., and Zeng, L.: The NASA Atmospheric Tomography (ATom) Mission: Imaging the Chemistry of the Global Atmosphere, B. Am. Meteorol. Soc., 103, E761–E790, https://doi.org/10.1175/BAMS-D-20-0315.1, 2022.
Tsamalis, C., Chédin, A., Pelon, J., and Capelle, V.: The seasonal vertical distribution of the Saharan Air Layer and its modulation by the wind, Atmos. Chem. Phys., 13, 11235–11257, https://doi.org/10.5194/acp-13-11235-2013, 2013.
Uhler, A. D., Stout, S. A., Douglas, G. S., Healey, E. M., and Emsbo-Mattingly, S. D.: 13 – Chemical character of marine heavy fuel oils and lubricants, in: Standard Handbook Oil Spill Environmental Forensics, 2nd. edn., edited by: Stout, S. A. and Wang, Z., Academic Press, Boston, 641–683, https://doi.org/10.1016/B978-0-12-803832-1.00013-1, 2016.
United Nations Conference on Trade and Development (UNCTAD): Review of Maritime Transport 2018, ISBN 978-92-1-112928-1, 2018.
United Nations Conference on Trade and Development (UNCTAD): Review of Maritime Transport 2022, ISBN 978-92-1-113073-7, 2022.
Underwood, G. M., Miller, T. M., and Grassian, V. H.: Transmission FT-IR and Knudsen Cell Study of the Heterogeneous Reactivity of Gaseous Nitrogen Dioxide on Mineral Oxide Particles, J. Phys. Chem. A, 103, 6184–6190, https://doi.org/10.1021/jp991586i, 1999.
Viana, M., Amato, F., Alastuey, A., Querol, X., Moreno, T., García Dos Santos, S., Herce, M. D., and Fernández-Patier, R.: Chemical Tracers of Particulate Emissions from Commercial Shipping, Environ. Sci. Technol., 43, 7472–7477, https://doi.org/10.1021/es901558t, 2009.
Wang, X., Shen, Y., Lin, Y., Pan, J., Zhang, Y., Louie, P. K. K., Li, M., and Fu, Q.: Atmospheric pollution from ships and its impact on local air quality at a port site in Shanghai, Atmos. Chem. Phys., 19, 6315–6330, https://doi.org/10.5194/acp-19-6315-2019, 2019.
Wofsy, S. C., Afshar, S., Allen, H. M., Apel, E. C. Asher, E. C., Barletta, B., Bent, J., Bian, H., Biggs, B. C., Blake, D. R., Blake, N., Bourgeois, I., Brock, C. A., Brune, W. H., Budney, J. W., Bui, T. P., Butler, A., Campuzano-Jost, P., Chang, C. S., Chin, M., Commane, R., Correa, G., Crounse, J. D., Cullis, P. D., Daube, B. C., Day, D. A., Dean-Day, J. M., Dibb, J. E., DiGangi, J. P., Diskin, G. S., Dollner, M., Elkins, J. W., Erdesz, F., Fiore, A. M., Flynn, C. M., Froyd, K. D., Gesler, D. W., Hall, S. R., Hanisco, T. F., Hannun, R. A., Hills, A. J., Hintsa, E. J., Hoffman, A., Hornbrook, R. S., Huey, L. G., Hughes, S., Jimenez, J. L., Johnson, B. J., Ka3ch, J. M., Keeling, R. F., Kim, M. J., Kupc, A., Lait, L. R., McKain, K., Mclaughlin, R. J., Meinardi, S., Miller, D. O., Montzka, S. A., Moore, F. L., Morgan, E. J., Murphy, D. M., Murray, L. T., Nault, B. A., Neuman, J. A., Newman, P. A., Nicely, J. M., Pan, X., Paplawsky, W., Peischl, J., Prather, M. J., Price, D. J., Ray, E. A., Reeves, J. M., Richardson, M., Rollins, A. W., Rosenlof, K. H., Ryerson, T. B., Scheuer, E., Schill, G. P., Schroder, J. C., Schwarz, J. P., St. Clair, J. M., Steenrod, S. D., Stephens, B. B., Strode, S. A., Sweeney, C., Tanner, D., Teng, A. P., Thames, A. B., Thompson, C. R., Ullmann, K., Veres, P. R., Wagner, N. L., WaB, A., Weber, R., Weinzierl, B. B., Wennberg, P. O, Williamson, C. J., Wilson, J. C., Wolfe, G. M., Woods, C. T., Zeng, L. H., and Vieznor, N.: ATom: Merged Atmospheric Chemistry, Trace Gases, and Aerosols, Version 2, ORNL DAAC [data set], Oak Ridge, Tennessee, USA, https://doi.org/10.3334/ORNLDAAC/1925, 2021.
Wu, D., Li, Q., Ding, X., Sun, J., Li, D., Fu, H., Teich, M., Ye, X., and Chen, J.: Primary Particulate Matter Emitted from Heavy Fuel and Diesel Oil Combustion in a Typical Container Ship: Characteristics and Toxicity, Environ. Sci. Technol., 52, 12943–12951, https://doi.org/10.1021/acs.est.8b04471, 2018.
Wu, L., Xu, Y., Wang, Q., Wang, F., and Xu, Z.: Mapping Global Shipping Density from AIS Data, J. Navigation, 70, 67–81, https://doi.org/10.1017/S0373463316000345, 2017.
Xiong, X., Wang, Z., Cheng, C., Li, M., Yun, L., Liu, S., Mao, L., and Zhou, Z.: Long-Term Observation of Mixing States and Sources of Vanadium-Containing Single Particles from 2020 to 2021 in Guangzhou, China, Toxics, 11, 339, https://doi.org/10.3390/toxics11040339, 2023.
Ye, D., Klein, M., Mulholland, J. A., Russell, A. G., Weber, R., Edgerton, E. S., Chang, H. H., Sarnat, J. A., Tolbert, P. E., and Ebelt, S. S.: Estimating Acute Cardiovascular Effects of Ambient PM2.5 Metals, Environ. Health Persp., 126, 027007, https://doi.org/10.1289/EHP2182, 2018.
Yu, G., Zhang, Y., Yang, F., He, B., Zhang, C., Zou, Z., Yang, X., Li, N., and Chen, J.: Dynamic
Yuan, T., Song, H., Wood, R., Wang, C., Oreopoulos, L., Platnick, S. E., von Hippel, S., Meyer, K., Light, S., and Wilcox, E.: Global reduction in ship-tracks from sulfur regulations for shipping fuel, Sci. Adv., 8, eabn7988, https://doi.org/10.1126/sciadv.abn7988, 2022.
Zhang, F., Chen, Y., Tian, C., Wang, X., Huang, G., Fang, Y., and Zong, Z.: Identification and quantification of shipping emissions in Bohai Rim, China, Sci. Total Environ., 497–498, 570–577, https://doi.org/10.1016/j.scitotenv.2014.08.016, 2014.
Zhou, S., Zhou, J., and Zhu, Y.: Chemical composition and size distribution of particulate matters from marine diesel engines with different fuel oils, Fuel, 235, 972–983, https://doi.org/10.1016/j.fuel.2018.08.080, 2019.
Zhou, Y., Wang, Z., Pei, C., Li, L., Wu, M., Wu, M., Huang, B., Cheng, C., Li, M., Wang, X., and Zhou, Z.: Source-oriented characterization of single particles from in-port ship emissions in Guangzhou, China, Sci. Total Environ., 724, 138179, https://doi.org/10.1016/j.scitotenv.2020.138179, 2020.
Short summary
Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust...
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