Articles | Volume 24, issue 6
https://doi.org/10.5194/acp-24-3445-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-3445-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics
Daniel A. Knopf
CORRESPONDING AUTHOR
School of Marine and Atmospheric Sciences, Stony Brook University, Stony Brook, New York, USA
Department of Chemistry, Stony Brook University, Stony Brook, New York, USA
Markus Ammann
Laboratory of Environmental Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Department of Chemistry, University of California Irvine, Irvine, California, USA
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12 citations as recorded by crossref.
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- Elucidating gas–surface interactions relevant to atmospheric particle growth using combined temperature programmed desorption and temperature-dependent uptake K. Johnson et al. 10.1039/D4CP02528H
- Carbon Nanoparticle Oxidation by NO2 and O2: Chemical Kinetics and Reaction Pathways T. Berkemeier & U. Pöschl 10.1002/anie.202413325
- A compartmentalized model of multiphase chemical kinetics A. Prophet & K. Wilson 10.1063/5.0266383
- Surfaces, silica and semivolatile organics—limonene uptake and desorption indoors and outdoors R. Reynolds et al. 10.1039/D5EM00275C
- HOSO2 Released from Mineral Dust: A Novel Channel of Heterogeneous Oxidation of Sulfur Dioxide during Dust Storms K. Chen et al. 10.1021/acsearthspacechem.4c00189
- Oxidation von Kohlenstoff‐Nanopartikeln durch NO2 und O2: Chemische Kinetik und Reaktionspfade T. Berkemeier & U. Pöschl 10.1002/ange.202413325
- Accelerated Chlorination at the Air-Organic Interface Revealed by Molecular Simulations and Kinetic Modeling L. Cohen et al. 10.1021/acs.jpclett.5c01169
- Kinetics model for thermal selective etching of Si1−xGex in F2/Ar Y. Chen et al. 10.1116/6.0004634
- Geomechanical integrity and geochemical reactions of shale caprocks for hydrogen storage: A comprehensive review A. Fatah & A. Al-Yaseri 10.1016/j.fuel.2025.135728
- Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review H. Alkhaldi et al. 10.1039/D4RA05269B
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
11 citations as recorded by crossref.
- Photochemical Degradation of Iron Citrate in Anoxic Viscous Films Enhanced by Redox Cascades A. Mishra et al. 10.1021/acsearthspacechem.4c00364
- Elucidating gas–surface interactions relevant to atmospheric particle growth using combined temperature programmed desorption and temperature-dependent uptake K. Johnson et al. 10.1039/D4CP02528H
- Carbon Nanoparticle Oxidation by NO2 and O2: Chemical Kinetics and Reaction Pathways T. Berkemeier & U. Pöschl 10.1002/anie.202413325
- A compartmentalized model of multiphase chemical kinetics A. Prophet & K. Wilson 10.1063/5.0266383
- Surfaces, silica and semivolatile organics—limonene uptake and desorption indoors and outdoors R. Reynolds et al. 10.1039/D5EM00275C
- HOSO2 Released from Mineral Dust: A Novel Channel of Heterogeneous Oxidation of Sulfur Dioxide during Dust Storms K. Chen et al. 10.1021/acsearthspacechem.4c00189
- Oxidation von Kohlenstoff‐Nanopartikeln durch NO2 und O2: Chemische Kinetik und Reaktionspfade T. Berkemeier & U. Pöschl 10.1002/ange.202413325
- Accelerated Chlorination at the Air-Organic Interface Revealed by Molecular Simulations and Kinetic Modeling L. Cohen et al. 10.1021/acs.jpclett.5c01169
- Kinetics model for thermal selective etching of Si1−xGex in F2/Ar Y. Chen et al. 10.1116/6.0004634
- Geomechanical integrity and geochemical reactions of shale caprocks for hydrogen storage: A comprehensive review A. Fatah & A. Al-Yaseri 10.1016/j.fuel.2025.135728
- Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review H. Alkhaldi et al. 10.1039/D4RA05269B
Latest update: 01 Aug 2025
Short summary
The initial step of interfacial and multiphase chemical processes involves adsorption and desorption of gas species. This study demonstrates the role of desorption energy governing the residence time of the gas species at the environmental interface. A parameterization is formulated that enables the prediction of desorption energy based on the molecular weight, polarizability, and oxygen-to-carbon ratio of the desorbing chemical species. Its application to gas–particle interactions is discussed.
The initial step of interfacial and multiphase chemical processes involves adsorption and...
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