Articles | Volume 24, issue 6
https://doi.org/10.5194/acp-24-3445-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-3445-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Mar 2024
Research article |
| 20 Mar 2024
| 20 Mar 2024
Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics
Daniel A. Knopf
CORRESPONDING AUTHOR
School of Marine and Atmospheric Sciences, Stony Brook University, Stony Brook, New York, USA
Department of Chemistry, Stony Brook University, Stony Brook, New York, USA
Markus Ammann
Laboratory of Environmental Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Department of Chemistry, University of California Irvine, Irvine, California, USA
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- Temperature–RH dependent viscosity of organic aerosols from 273 to 303 K: implications for global N2O5 uptake A. Ullah et al. https://doi.org/10.5194/acp-26-2319-2026
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Saved (final revised paper)
Latest update: 24 Jul 2026
Short summary
The initial step of interfacial and multiphase chemical processes involves adsorption and desorption of gas species. This study demonstrates the role of desorption energy governing the residence time of the gas species at the environmental interface. A parameterization is formulated that enables the prediction of desorption energy based on the molecular weight, polarizability, and oxygen-to-carbon ratio of the desorbing chemical species. Its application to gas–particle interactions is discussed.
The initial step of interfacial and multiphase chemical processes involves adsorption and...
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