A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides
Junting Qiu,Xinlin Shen,Jiangyao Chen,Guiying Li,and Taicheng An
Junting Qiu
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Key Laboratory of City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa 277-8563, Japan
Xinlin Shen
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Key Laboratory of City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Jiangyao Chen
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Key Laboratory of City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Guiying Li
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Key Laboratory of City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Key Laboratory of City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China
Viewed
Total article views: 5,236 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
4,268
829
139
5,236
379
159
203
HTML: 4,268
PDF: 829
XML: 139
Total: 5,236
Supplement: 379
BibTeX: 159
EndNote: 203
Views and downloads (calculated since 20 Sep 2023)
Cumulative views and downloads
(calculated since 20 Sep 2023)
Total article views: 3,756 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
3,307
358
91
3,756
150
114
129
HTML: 3,307
PDF: 358
XML: 91
Total: 3,756
Supplement: 150
BibTeX: 114
EndNote: 129
Views and downloads (calculated since 05 Jan 2024)
Cumulative views and downloads
(calculated since 05 Jan 2024)
Total article views: 1,480 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
961
471
48
1,480
229
45
74
HTML: 961
PDF: 471
XML: 48
Total: 1,480
Supplement: 229
BibTeX: 45
EndNote: 74
Views and downloads (calculated since 20 Sep 2023)
Cumulative views and downloads
(calculated since 20 Sep 2023)
Viewed (geographical distribution)
Total article views: 5,236 (including HTML, PDF, and XML)
Thereof 5,173 with geography defined
and 63 with unknown origin.
Total article views: 3,756 (including HTML, PDF, and XML)
Thereof 3,710 with geography defined
and 46 with unknown origin.
Total article views: 1,480 (including HTML, PDF, and XML)
Thereof 1,463 with geography defined
and 17 with unknown origin.
We studied reactions of secondary ozonides (SOZs) with amines. SOZs formed from ozonolysis of β-caryophyllene and α-humulene are found to be reactive to ethylamine and methylamine. Products from SOZs with various conformations reacting with the same amine had different functional groups. Our findings indicate that interaction of SOZs with amines in the atmosphere is very complicated, which is potentially a hitherto unrecognized source of N-containing compound formation.
We studied reactions of secondary ozonides (SOZs) with amines. SOZs formed from ozonolysis of...
