Articles | Volume 24, issue 20
https://doi.org/10.5194/acp-24-11943-2024
https://doi.org/10.5194/acp-24-11943-2024
Research article
 | 
28 Oct 2024
Research article |  | 28 Oct 2024

Formation of reactive nitrogen species promoted by iron ions through the photochemistry of a neonicotinoid insecticide

Zhu Ran, Yanan Hu, Yuanzhe Li, Xiaoya Gao, Can Ye, Shuai Li, Xiao Lu, Yongming Luo, Sasho Gligorovski, and Jiangping Liu

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Short summary
We report enhanced formation of nitrous acid (HONO) and NOx (NO + NO2) triggered by iron ions during photolysis of neonicotinoid insecticides at the air–water interface. This novel previously overlooked source of atmospheric HONO and NOx may be an important contribution to the global nitrogen cycle and affects atmospheric oxidizing capacity and climate change.
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