Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7741-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7741-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A thermodynamic framework for bulk–surface partitioning in finite-volume mixed organic–inorganic aerosol particles and cloud droplets
Ryan Schmedding
Department of Atmospheric and Oceanic Sciences, McGill University, Montréal, Quebec, Canada
Department of Atmospheric and Oceanic Sciences, McGill University, Montréal, Quebec, Canada
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Total article views: 1,349 (including HTML, PDF, and XML)
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Cited
13 citations as recorded by crossref.
- Model-Measurement Comparisons for Surfactant-Containing Aerosol Droplets A. Bain et al. 10.1021/acsearthspacechem.4c00199
- Quantifying surface tension of metastable aerosols via electrodeformation V. Shahabadi et al. 10.1038/s41467-024-54106-3
- Properties of Surface-Active Organics in Aerosol Particles Produced from Combustion of Biomass Fuels under Simulated Prescribed-Fire and Wildfire Conditions A. Deegan et al. 10.1021/acsestair.4c00243
- Water activity and surface tension of aqueous ammonium sulfate and D-glucose aerosol nanoparticles E. Mikhailov et al. 10.5194/acp-24-2971-2024
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Cloud drop activation of insoluble aerosols aided by film-forming surfactants A. Laaksonen 10.5194/ar-2-343-2024
- Surface tension predictions during hygroscopic growth and cloud droplet activation using a simple kinetic surfactant partitioning model E. Werner et al. 10.1080/02786826.2025.2465705
- Predicting Liquid–Liquid Phase Separation of Submicrometer Proxies for Atmospheric Secondary Aerosol Q. Huang et al. 10.1021/acsestair.4c00254
- Recent advances in experimental techniques for investigating aerosol surface tension A. Bain 10.1080/02786826.2024.2373907
- Surface-Area-to-Volume Ratio Determines Surface Tensions in Microscopic, Surfactant-Containing Droplets A. Bain et al. 10.1021/acscentsci.3c00998
- Exploring How the Surface-Area-to-Volume Ratio Influences the Partitioning of Surfactants to the Air–Water Interface in Levitated Microdroplets M. Jacobs et al. 10.1021/acs.jpca.4c06210
- The role of interfacial tension in the size-dependent phase separation of atmospheric aerosol particles R. Schmedding & A. Zuend 10.5194/acp-25-327-2025
- Surfactant Partitioning Dynamics in Freshly Generated Aerosol Droplets A. Bain et al. 10.1021/jacs.4c03041
13 citations as recorded by crossref.
- Model-Measurement Comparisons for Surfactant-Containing Aerosol Droplets A. Bain et al. 10.1021/acsearthspacechem.4c00199
- Quantifying surface tension of metastable aerosols via electrodeformation V. Shahabadi et al. 10.1038/s41467-024-54106-3
- Properties of Surface-Active Organics in Aerosol Particles Produced from Combustion of Biomass Fuels under Simulated Prescribed-Fire and Wildfire Conditions A. Deegan et al. 10.1021/acsestair.4c00243
- Water activity and surface tension of aqueous ammonium sulfate and D-glucose aerosol nanoparticles E. Mikhailov et al. 10.5194/acp-24-2971-2024
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Cloud drop activation of insoluble aerosols aided by film-forming surfactants A. Laaksonen 10.5194/ar-2-343-2024
- Surface tension predictions during hygroscopic growth and cloud droplet activation using a simple kinetic surfactant partitioning model E. Werner et al. 10.1080/02786826.2025.2465705
- Predicting Liquid–Liquid Phase Separation of Submicrometer Proxies for Atmospheric Secondary Aerosol Q. Huang et al. 10.1021/acsestair.4c00254
- Recent advances in experimental techniques for investigating aerosol surface tension A. Bain 10.1080/02786826.2024.2373907
- Surface-Area-to-Volume Ratio Determines Surface Tensions in Microscopic, Surfactant-Containing Droplets A. Bain et al. 10.1021/acscentsci.3c00998
- Exploring How the Surface-Area-to-Volume Ratio Influences the Partitioning of Surfactants to the Air–Water Interface in Levitated Microdroplets M. Jacobs et al. 10.1021/acs.jpca.4c06210
- The role of interfacial tension in the size-dependent phase separation of atmospheric aerosol particles R. Schmedding & A. Zuend 10.5194/acp-25-327-2025
- Surfactant Partitioning Dynamics in Freshly Generated Aerosol Droplets A. Bain et al. 10.1021/jacs.4c03041
Latest update: 06 Apr 2025
Short summary
Aerosol particles below 100 nm in diameter have high surface-area-to-volume ratios. The enrichment of compounds in the surface of an aerosol particle may lead to depletion of that species in the interior bulk of the particle. We present a framework for modeling the equilibrium bulk–surface partitioning of mixed organic–inorganic particles, including cases of co-condensation of semivolatile organic compounds and species with extremely limited solubility in the bulk or surface of a particle.
Aerosol particles below 100 nm in diameter have high surface-area-to-volume ratios. The...
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