Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7297-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7297-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Jul 2023
Research article |
| 04 Jul 2023
| 04 Jul 2023
Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway
Hao Luo
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Hongru Shen
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland, 70210 Kuopio, Finland
Mattias Hallquist
Department of Chemistry and Molecular biology, University of
Gothenburg, 41258 Gothenburg, Sweden
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Fachgruppe Physik, Universität zu Köln, 50932 Cologne,
Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
deceased, 6 February 2023
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Shanghai Frontiers Science Center of Atmosphere–Ocean Interaction,
Fudan University, Shanghai 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chongming, Shanghai 202162, China
CMA-FDU Joint Laboratory of Marine Meteorology, Fudan University,
Shanghai 200438, China
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Cited
16 citations as recorded by crossref.
- Key Role of Nitrogen-containing Oxygenated Organic Molecules (OOMs) in SOA Formation Evidenced by OH/NO3-induced Terpinolene Oxidation H. Wu et al.
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al.
- VaPOrS v1.0.1: an automated model for functional group detection and property prediction of organic compounds via SMILES notation M. Bezaatpour et al.
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al.
- Chemical Composition of Secondary Organic Aerosol Formed from the Oxidation of Semivolatile Isoprene Epoxydiol Isomerization Products M. Frauenheim et al.
- Chlorine-Initiated Oxidation of Limonene under Simulated Indoor and Outdoor Lighting Conditions P. Abue et al.
- Unveiling the formation of atmospheric oxygenated organic molecules under anthropogenic–biogenic interactions: insights from binned positive matrix factorization on multi-subrange mass spectra J. Yin et al.
- Formation of highly oxygenated organic molecules from α-pinene photooxidation: evidence for the importance of highly oxygenated alkoxy radicals S. Kang et al.
- Competing multiple oxidation pathways shape atmospheric limonene-derived organonitrates simulated with updated explicit chemical mechanisms Q. Guo et al.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al.
- OH-Initiated Photooxidation of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al.
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al.
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al.
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al.
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al.
16 citations as recorded by crossref.
- Key Role of Nitrogen-containing Oxygenated Organic Molecules (OOMs) in SOA Formation Evidenced by OH/NO3-induced Terpinolene Oxidation H. Wu et al.
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al.
- VaPOrS v1.0.1: an automated model for functional group detection and property prediction of organic compounds via SMILES notation M. Bezaatpour et al.
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al.
- Chemical Composition of Secondary Organic Aerosol Formed from the Oxidation of Semivolatile Isoprene Epoxydiol Isomerization Products M. Frauenheim et al.
- Chlorine-Initiated Oxidation of Limonene under Simulated Indoor and Outdoor Lighting Conditions P. Abue et al.
- Unveiling the formation of atmospheric oxygenated organic molecules under anthropogenic–biogenic interactions: insights from binned positive matrix factorization on multi-subrange mass spectra J. Yin et al.
- Formation of highly oxygenated organic molecules from α-pinene photooxidation: evidence for the importance of highly oxygenated alkoxy radicals S. Kang et al.
- Competing multiple oxidation pathways shape atmospheric limonene-derived organonitrates simulated with updated explicit chemical mechanisms Q. Guo et al.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al.
- OH-Initiated Photooxidation of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al.
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al.
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al.
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al.
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al.
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al.
Saved (final revised paper)
Latest update: 06 May 2026
Short summary
Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime oxidant, forms many highly oxygenated organic molecules (HOMs), including C10-20 compounds. HOMs play an important role in new particle formation and growth. HOM formation can be explained by the chemistry of peroxy radicals. We found that a minor branching ratio initial pathway plays an unexpected, significant role. Considering this pathway enables accurate simulations of HOMs and other concentrations.
Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime...
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