Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7297-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7297-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Jul 2023
Research article |
| 04 Jul 2023
| 04 Jul 2023
Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway
Hao Luo
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Hongru Shen
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland, 70210 Kuopio, Finland
Mattias Hallquist
Department of Chemistry and Molecular biology, University of
Gothenburg, 41258 Gothenburg, Sweden
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Fachgruppe Physik, Universität zu Köln, 50932 Cologne,
Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
deceased, 6 February 2023
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai 200438, China
National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, Fudan University, Shanghai 200438, China
Shanghai Frontiers Science Center of Atmosphere–Ocean Interaction,
Fudan University, Shanghai 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chongming, Shanghai 202162, China
CMA-FDU Joint Laboratory of Marine Meteorology, Fudan University,
Shanghai 200438, China
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Cited
7 citations as recorded by crossref.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al. 10.1016/j.atmosenv.2024.120747
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al. 10.1021/acs.chemrestox.4c00326
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al. 10.1016/j.jes.2024.08.007
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
6 citations as recorded by crossref.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al. 10.1016/j.atmosenv.2024.120747
- Chemical Composition of Aerosols from the E-Cigarette Vaping of Natural and Synthetic Cannabinoids N. Robertson et al. 10.1021/acs.chemrestox.4c00326
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al. 10.1016/j.jes.2024.08.007
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. 10.1039/D3EA00149K
Latest update: 13 Dec 2024
Short summary
Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime oxidant, forms many highly oxygenated organic molecules (HOMs), including C10-20 compounds. HOMs play an important role in new particle formation and growth. HOM formation can be explained by the chemistry of peroxy radicals. We found that a minor branching ratio initial pathway plays an unexpected, significant role. Considering this pathway enables accurate simulations of HOMs and other concentrations.
Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime...
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