Articles | Volume 23, issue 9 
            
                
                    
            
            
            https://doi.org/10.5194/acp-23-5419-2023
                    © Author(s) 2023. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-5419-2023
                    © Author(s) 2023. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
Multiple pathways for the formation of secondary organic aerosol in the North China Plain in summer
Yifang Gu
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    
                                            University of Chinese Academy of Sciences, Beijing 100049, China
                                        
                                    Ru-Jin Huang
CORRESPONDING AUTHOR
                                            
                                    
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    
                                            Institute of Global Environmental Change, Xi'an Jiaotong University, Xi'an 710049, China
                                        
                                    
                                            University of Chinese Academy of Sciences, Beijing 100049, China
                                        
                                    Jing Duan
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    Chunshui Lin
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    Haobin Zhong
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    
                                            University of Chinese Academy of Sciences, Beijing 100049, China
                                        
                                    Ying Wang
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    Haiyan Ni
                                            SKLLQG, Center for Excellence in Quaternary Science and Global Change, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
                                        
                                    
                                            State Key Laboratory of Severe Weather & Key Laboratory of Atmospheric Chemistry of CMA,  Chinese Academy of Meteorological Sciences, Beijing 100081, China
                                        
                                    Ruiguang Xu
                                            Department of Environmental Engineering, School of Energy and Environmental Engineering,  Hebei University of Engineering, Handan 056038, China
                                        
                                    
                                            Hebei Key Laboratory of Air Pollution Cause and Impact, Handan 056038, China
                                        
                                    Litao Wang
                                            Department of Environmental Engineering, School of Energy and Environmental Engineering,  Hebei University of Engineering, Handan 056038, China
                                        
                                    
                                            Hebei Key Laboratory of Air Pollution Cause and Impact, Handan 056038, China
                                        
                                    Yong Jie Li
                                            Department of Civil and Environmental Engineering, Faculty of Science and Technology,  University of Macau, Taipa, Macau SAR 999078, China
                                        
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                            Cited
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- Aerosol and precipitation composition at a coastal New England site (Acadia National Park): implications for air quality and aerosol composition during cold air outbreaks A. Seckar-Martinez et al. 10.1039/D4EA00119B
- Mixing state and evolutionary mechanism of oxalic acid homologs in Liaocheng, East China: Insights from seasonal and hourly observations J. Ma et al. 10.1016/j.partic.2024.09.011
- Emission Characteristics, Environmental Impacts, and Health Risks of Volatile Organic Compounds from Asphalt Materials: A State-of-the-Art Review J. Li et al. 10.1021/acs.energyfuels.3c04438
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- Divergent changes in aerosol optical hygroscopicity and new particle formation during a heatwave of summer 2022 Y. Hao et al. 10.5194/acp-25-12811-2025
- Substantial contribution of transported emissions to organic aerosol in Beijing K. Daellenbach et al. 10.1038/s41561-024-01493-3
- Sources of PM2.5 exposure and health benefits of clean air actions in Shanghai Y. Gu et al. 10.1016/j.envint.2025.109259
- Unveiling the key drivers and formation pathways for secondary organic aerosols in an eastern China megacity F. Zhang et al. 10.1016/j.jhazmat.2025.139925
- Influence of ozone pollution on the mixing state and formation of oxygenated organics containing single particles S. Liu et al. 10.1016/j.scitotenv.2024.171880
- Influence of atmospheric ammonia on secondary inorganic aerosol formation in PM2.5 during spring 2024 in the Hongseong area, Republic of Korea J. Jang et al. 10.1016/j.atmosenv.2025.121363
- Variations in polycyclic aromatic hydrocarbons concentrations and their contribution to aerosol optical depth during the COVID-19 outbreak: A study in Yokohama using generalized additive model W. Jing et al. 10.1016/j.apr.2025.102547
16 citations as recorded by crossref.
- The semi-solid phase of atmospheric particles facilitates the formation of secondary brown carbon: Possible contribution of ionic strength to Maillard-like reactions J. Xie et al. 10.1016/j.atmosenv.2024.120991
- Characteristics of airborne bacteria over inland and coastal atmosphere influenced by systemic air mass in northern China Z. Wang et al. 10.1016/j.envpol.2025.126429
- Aerosol and precipitation composition at a coastal New England site (Acadia National Park): implications for air quality and aerosol composition during cold air outbreaks A. Seckar-Martinez et al. 10.1039/D4EA00119B
- Mixing state and evolutionary mechanism of oxalic acid homologs in Liaocheng, East China: Insights from seasonal and hourly observations J. Ma et al. 10.1016/j.partic.2024.09.011
- Emission Characteristics, Environmental Impacts, and Health Risks of Volatile Organic Compounds from Asphalt Materials: A State-of-the-Art Review J. Li et al. 10.1021/acs.energyfuels.3c04438
- Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze J. Duan et al. 10.5194/acp-24-7687-2024
- Wintertime fine aerosol particles composition and its evolution in two megacities of southern and northern China Y. Cheng et al. 10.1016/j.scitotenv.2023.169778
- Current challenges in the visibility improvement of urban Chongqing in Southwest China: From the perspective of PM2.5-bound water uptake property over 2015–2021 Y. Hao et al. 10.1016/j.atmosres.2023.107215
- Fossil-dominated secondary organic aerosol (SOA) formation in coastal China: size-divergent pathways of aqueous Fenton reactions versus gas-phase volatile organic compound (VOC) autoxidation J. Wang et al. 10.5194/acp-25-9831-2025
- Divergent changes in aerosol optical hygroscopicity and new particle formation during a heatwave of summer 2022 Y. Hao et al. 10.5194/acp-25-12811-2025
- Substantial contribution of transported emissions to organic aerosol in Beijing K. Daellenbach et al. 10.1038/s41561-024-01493-3
- Sources of PM2.5 exposure and health benefits of clean air actions in Shanghai Y. Gu et al. 10.1016/j.envint.2025.109259
- Unveiling the key drivers and formation pathways for secondary organic aerosols in an eastern China megacity F. Zhang et al. 10.1016/j.jhazmat.2025.139925
- Influence of ozone pollution on the mixing state and formation of oxygenated organics containing single particles S. Liu et al. 10.1016/j.scitotenv.2024.171880
- Influence of atmospheric ammonia on secondary inorganic aerosol formation in PM2.5 during spring 2024 in the Hongseong area, Republic of Korea J. Jang et al. 10.1016/j.atmosenv.2025.121363
- Variations in polycyclic aromatic hydrocarbons concentrations and their contribution to aerosol optical depth during the COVID-19 outbreak: A study in Yokohama using generalized additive model W. Jing et al. 10.1016/j.apr.2025.102547
Latest update: 30 Oct 2025
Short summary
                    Secondary organic aerosol (SOA) can be produced by various pathways, but its formation mechanisms are unclear. Observations were conducted in the North China Plain during a highly oxidizing atmosphere in summer. We found that fast photochemistry dominated SOA formation during daytime. Two types of aqueous-phase chemistry (nocturnal and daytime processing) take place at high relative humidity. The potential transformation from primary organic aerosol (POA) to SOA was also an important pathway.
                    Secondary organic aerosol (SOA) can be produced by various pathways, but its formation...
                    
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