Articles | Volume 23, issue 4
https://doi.org/10.5194/acp-23-2613-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-2613-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note
| 
24 Feb 2023
Technical note |
| 24 Feb 2023
| 24 Feb 2023
Technical note: Chemical composition and source identification of fluorescent components in atmospheric water-soluble brown carbon by excitation–emission matrix spectroscopy with parallel factor analysis – potential limitations and applications
Tao Cao
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
University of Chinese Academy of Sciences, Beijing 100049, China
Meiju Li
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
University of Chinese Academy of Sciences, Beijing 100049, China
Cuncun Xu
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
University of Chinese Academy of Sciences, Beijing 100049, China
Jianzhong Song
CORRESPONDING AUTHOR
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
Guangdong–Hong Kong–Macao Joint Laboratory for Environmental Pollution
and Control, Guangzhou 510640, China
Xingjun Fan
College of Resource and Environment, Anhui Science and Technology
University, Fengyang 233100, China
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
Guangdong–Hong Kong–Macao Joint Laboratory for Environmental Pollution
and Control, Guangzhou 510640, China
Wanglu Jia
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
Ping'an Peng
State Key Laboratory of Organic Geochemistry and Guangdong Provincial
Key Laboratory of Environmental Protection and Resources Utilization,
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou
510640, China
CAS Center for Excellence in Deep Earth Science, Guangzhou 510640,
China
University of Chinese Academy of Sciences, Beijing 100049, China
Guangdong–Hong Kong–Macao Joint Laboratory for Environmental Pollution
and Control, Guangzhou 510640, China
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12 citations as recorded by crossref.
- Soil acidity accelerates soil organic matter decomposition in Cryptomeria japonica stands and Chamaecyparis obtusa stands R. Hayashi et al. 10.1007/s11104-023-06308-9
- Molecular-level transformations of biomass burning-derived water-soluble organic carbon during dark aqueous OH oxidation: Insights from absorption, fluorescence, high-performance size exclusion chromatography and high-resolution mass spectrometry analysis X. Fan et al. 10.1016/j.scitotenv.2023.169290
- Variations in optical properties of water- and methanol-soluble organic carbon in PM2.5 in Tianjin and Handan over the Wintertime of 2018–2020 H. Chen et al. 10.1016/j.atmosres.2024.107332
- Distribution, chemical, and molecular composition of high and low molecular weight humic-like substances in ambient aerosols X. Fan et al. 10.5194/acp-24-3769-2024
- Molecular composition of Beijing PM2.5 Brown carbon associated with fluorescence revealed by gas chromatography time-of-flight mass spectrometry and parallel factor analysis J. Cao et al. 10.1016/j.atmosenv.2024.120670
- Compositions and sources of fluorescent water-soluble and water-insoluble organic aerosols H. Ma et al. 10.1016/j.scitotenv.2024.174627
- Molecular-level insights into the temperature-dependent formation dynamics and mechanism of water-soluble dissolved organic carbon derived from biomass pyrolysis smoke T. Li et al. 10.1016/j.watres.2024.121176
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- Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations Z. Dong et al. 10.5194/acp-24-5887-2024
- Separation and spectroscopic characterization of soil fulvic acid constituents by hydrophilic interaction chromatography and reversed-phase high-performance liquid chromatography with π–π interactions M. Aoyama 10.1080/00380768.2024.2398549
- Compositional and optical characteristics of aqueous brown carbon and HULIS in the eastern Indo-Gangetic Plain using a coupled EEM PARAFAC, FT-IR and 1H NMR approach S. Dey & S. Sarkar 10.1016/j.scitotenv.2024.171084
- Effects of aerosol water content and acidity on the light absorption of atmospheric humic-like substances in winter T. Tang et al. 10.1016/j.chemosphere.2023.140796
12 citations as recorded by crossref.
- Soil acidity accelerates soil organic matter decomposition in Cryptomeria japonica stands and Chamaecyparis obtusa stands R. Hayashi et al. 10.1007/s11104-023-06308-9
- Molecular-level transformations of biomass burning-derived water-soluble organic carbon during dark aqueous OH oxidation: Insights from absorption, fluorescence, high-performance size exclusion chromatography and high-resolution mass spectrometry analysis X. Fan et al. 10.1016/j.scitotenv.2023.169290
- Variations in optical properties of water- and methanol-soluble organic carbon in PM2.5 in Tianjin and Handan over the Wintertime of 2018–2020 H. Chen et al. 10.1016/j.atmosres.2024.107332
- Distribution, chemical, and molecular composition of high and low molecular weight humic-like substances in ambient aerosols X. Fan et al. 10.5194/acp-24-3769-2024
- Molecular composition of Beijing PM2.5 Brown carbon associated with fluorescence revealed by gas chromatography time-of-flight mass spectrometry and parallel factor analysis J. Cao et al. 10.1016/j.atmosenv.2024.120670
- Compositions and sources of fluorescent water-soluble and water-insoluble organic aerosols H. Ma et al. 10.1016/j.scitotenv.2024.174627
- Molecular-level insights into the temperature-dependent formation dynamics and mechanism of water-soluble dissolved organic carbon derived from biomass pyrolysis smoke T. Li et al. 10.1016/j.watres.2024.121176
- Atomically dispersed ternary FeCoNb active sites anchored on N-doped honeycomb-like mesoporous carbon for highly catalytic degradation of 4-nitrophenol Z. Jiang et al. 10.1016/j.jcis.2024.08.027
- Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations Z. Dong et al. 10.5194/acp-24-5887-2024
- Separation and spectroscopic characterization of soil fulvic acid constituents by hydrophilic interaction chromatography and reversed-phase high-performance liquid chromatography with π–π interactions M. Aoyama 10.1080/00380768.2024.2398549
- Compositional and optical characteristics of aqueous brown carbon and HULIS in the eastern Indo-Gangetic Plain using a coupled EEM PARAFAC, FT-IR and 1H NMR approach S. Dey & S. Sarkar 10.1016/j.scitotenv.2024.171084
- Effects of aerosol water content and acidity on the light absorption of atmospheric humic-like substances in winter T. Tang et al. 10.1016/j.chemosphere.2023.140796
Latest update: 02 Nov 2024
Short summary
This work comprehensively investigated the fluorescence data of light-absorbing organic compounds, water-soluble organic matter in different types of aerosol samples, soil dust, and fulvic and humic acids using an excitation–emission matrix (EEM) method and parallel factor modeling. The results revealed which light-absorbing species can be detected by EEM and also provided important information for identifying the chemical composition and possible sources of these species in atmospheric samples.
This work comprehensively investigated the fluorescence data of light-absorbing organic...
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