Articles | Volume 23, issue 20
https://doi.org/10.5194/acp-23-13485-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-13485-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Oct 2023
Research article |
| 25 Oct 2023
| 25 Oct 2023
Intra-event evolution of elemental and ionic concentrations in wet deposition in an urban environment
Université Paris Cité and Université Paris-Est Créteil , CNRS, LISA, 75013, Paris, France
Benoit Laurent
CORRESPONDING AUTHOR
Université Paris Cité and Université Paris-Est Créteil , CNRS, LISA, 75013, Paris, France
Karine Desboeufs
Université Paris Cité and Université Paris-Est Créteil , CNRS, LISA, 75013, Paris, France
Gael Noyalet
Université Paris Cité and Université Paris-Est Créteil , CNRS, LISA, 75013, Paris, France
Franck Maisonneuve
Université Paris-Est Créteil and Université Paris Cité, CNRS, LISA, 94010, Créteil, France
Olivier Lauret
Université Paris-Est Créteil and Université Paris Cité, CNRS, LISA, 94010, Créteil, France
Université Paris-Est Créteil , CNRS, ENPC, Université Paris Cité, OSU-EFLUVE, 94010, Créteil, France
Servanne Chevaillier
Université Paris-Est Créteil and Université Paris Cité, CNRS, LISA, 94010, Créteil, France
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Atmos. Chem. Phys., 25, 16107–16125, https://doi.org/10.5194/acp-25-16107-2025, https://doi.org/10.5194/acp-25-16107-2025, 2025
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We present a comparison between concentrations of dissolved trace metals in pairs of total suspended particulate (TSP) and fog samples collected in Henties Bay, Namibia, during the AErosols, Radiation and CLOuds in southern Africa (AEROCLO-sA) field campaign. We found enhanced concentrations of dissolved metals in fog samples, which we attributed to metal–ligand complex formation in the early stages of particle activation into droplets that can then remain in a kinetically stable form in fog or lead to the formation of colloidal nanoparticles.
Paola Formenti, Chiara Giorio, Karine Desboeufs, Alexander Zherebker, Marco Gaetani, Clarissa Baldo, Gautier Landrot, Simona Montebello, Servanne Chevaillier, Sylvain Triquet, Guillaume Siour, Claudia Di Biagio, Francesco Battaglia, Jean-François Doussin, Anais Feron, Andreas Namwoonde, and Stuart John Piketh
Atmos. Chem. Phys., 25, 16127–16145, https://doi.org/10.5194/acp-25-16127-2025, https://doi.org/10.5194/acp-25-16127-2025, 2025
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The elemental composition and solubility of several metals, including iron, at a coastal site in Namibia in August–September 2017, indicate that natural and anthropogenic dust had different solubility depending on mineralogy but mostly on the processing by fluoride ions from marine emissions, pointing to the complexity of atmospheric--oceanic interactions in this region of the world influenced by the Benguela current and significant aerosol load.
Francesco Battaglia, Paola Formenti, Chiara Giorio, Mathieu Cazaunau, Edouard Pangui, Antonin Bergé, Aline Gratien, Diana L. Pereira, Thomas Bertin, Joel F. de Brito, Manolis N. Romanias, Vincent Michoud, Clarissa Baldo, Servanne Chevaillier, Gael Noyalet, Philippe Decorse, Bénédicte Picquet-Varrault, and Jean-François Doussin
Atmos. Chem. Phys., 25, 12409–12431, https://doi.org/10.5194/acp-25-12409-2025, https://doi.org/10.5194/acp-25-12409-2025, 2025
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EGUsphere, https://doi.org/10.5194/egusphere-2025-3512, https://doi.org/10.5194/egusphere-2025-3512, 2025
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Johannes Heuser, Claudia Di Biagio, Jérôme Yon, Mathieu Cazaunau, Antonin Bergé, Edouard Pangui, Marco Zanatta, Laura Renzi, Angela Marinoni, Satoshi Inomata, Chenjie Yu, Vera Bernardoni, Servanne Chevaillier, Daniel Ferry, Paolo Laj, Michel Maillé, Dario Massabò, Federico Mazzei, Gael Noyalet, Hiroshi Tanimoto, Brice Temime-Roussel, Roberta Vecchi, Virginia Vernocchi, Paola Formenti, Bénédicte Picquet-Varrault, and Jean-François Doussin
Atmos. Chem. Phys., 25, 6407–6428, https://doi.org/10.5194/acp-25-6407-2025, https://doi.org/10.5194/acp-25-6407-2025, 2025
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Ludovico Di Antonio, Matthias Beekmann, Guillaume Siour, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Joel F. de Brito, Paola Formenti, Cecile Gaimoz, Olivier Garret, Aline Gratien, Valérie Gros, Martial Haeffelin, Lelia N. Hawkins, Simone Kotthaus, Gael Noyalet, Diana L. Pereira, Jean-Eudes Petit, Eva Drew Pronovost, Véronique Riffault, Chenjie Yu, Gilles Foret, Jean-François Doussin, and Claudia Di Biagio
Atmos. Chem. Phys., 25, 4803–4831, https://doi.org/10.5194/acp-25-4803-2025, https://doi.org/10.5194/acp-25-4803-2025, 2025
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The summer of 2022 has been considered a proxy for future climate scenarios due to its hot and dry conditions. In this paper, we use the measurements from the Atmospheric Chemistry of the Suburban Forest (ACROSS) campaign, conducted in the Paris area in June–July 2022, along with observations from existing networks, to evaluate a 3D chemistry transport model (WRF–CHIMERE) simulation. Results are shown to be satisfactory, allowing us to explain the gas and aerosol variability at the campaign sites.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 25, 4885–4905, https://doi.org/10.5194/acp-25-4885-2025, https://doi.org/10.5194/acp-25-4885-2025, 2025
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Ludovico Di Antonio, Claudia Di Biagio, Paola Formenti, Aline Gratien, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Patrice Coll, Barbara D'Anna, Joel F. de Brito, David O. De Haan, Juliette R. Dignum, Shravan Deshmukh, Olivier Favez, Pierre-Marie Flaud, Cecile Gaimoz, Lelia N. Hawkins, Julien Kammer, Brigitte Language, Franck Maisonneuve, Griša Močnik, Emilie Perraudin, Jean-Eudes Petit, Prodip Acharja, Laurent Poulain, Pauline Pouyes, Eva Drew Pronovost, Véronique Riffault, Kanuri I. Roundtree, Marwa Shahin, Guillaume Siour, Eric Villenave, Pascal Zapf, Gilles Foret, Jean-François Doussin, and Matthias Beekmann
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Karine Desboeufs, Franck Fu, Matthieu Bressac, Antonio Tovar-Sánchez, Sylvain Triquet, Jean-François Doussin, Chiara Giorio, Patrick Chazette, Julie Disnaquet, Anaïs Feron, Paola Formenti, Franck Maisonneuve, Araceli Rodríguez-Romero, Pascal Zapf, François Dulac, and Cécile Guieu
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Elvira Pulido-Villena, Karine Desboeufs, Kahina Djaoudi, France Van Wambeke, Stéphanie Barrillon, Andrea Doglioli, Anne Petrenko, Vincent Taillandier, Franck Fu, Tiphanie Gaillard, Sophie Guasco, Sandra Nunige, Sylvain Triquet, and Cécile Guieu
Biogeosciences, 18, 5871–5889, https://doi.org/10.5194/bg-18-5871-2021, https://doi.org/10.5194/bg-18-5871-2021, 2021
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We report on phosphorus dynamics in the surface layer of the Mediterranean Sea. Highly sensitive phosphate measurements revealed vertical gradients above the phosphacline. The relative contribution of diapycnal fluxes to total external supply of phosphate to the mixed layer decreased towards the east, where atmospheric deposition dominated. Taken together, external sources of phosphate contributed little to total supply, which was mainly sustained by enzymatic hydrolysis of organic phosphorus.
France Van Wambeke, Vincent Taillandier, Karine Desboeufs, Elvira Pulido-Villena, Julie Dinasquet, Anja Engel, Emilio Marañón, Céline Ridame, and Cécile Guieu
Biogeosciences, 18, 5699–5717, https://doi.org/10.5194/bg-18-5699-2021, https://doi.org/10.5194/bg-18-5699-2021, 2021
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Simultaneous in situ measurements of (dry and wet) atmospheric deposition and biogeochemical stocks and fluxes in the sunlit waters of the open Mediterranean Sea revealed complex physical and biological processes occurring within the mixed layer. Nitrogen (N) budgets were computed to compare the sources and sinks of N in the mixed layer. The transitory effect observed after a wet dust deposition impacted the microbial food web down to the deep chlorophyll maximum.
Evelyn Freney, Karine Sellegri, Alessia Nicosia, Leah R. Williams, Matteo Rinaldi, Jonathan T. Trueblood, André S. H. Prévôt, Melilotus Thyssen, Gérald Grégori, Nils Haëntjens, Julie Dinasquet, Ingrid Obernosterer, France Van Wambeke, Anja Engel, Birthe Zäncker, Karine Desboeufs, Eija Asmi, Hilkka Timonen, and Cécile Guieu
Atmos. Chem. Phys., 21, 10625–10641, https://doi.org/10.5194/acp-21-10625-2021, https://doi.org/10.5194/acp-21-10625-2021, 2021
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In this work, we present observations of the organic aerosol content in primary sea spray aerosols (SSAs) continuously generated along a 5-week cruise in the Mediterranean. This information is combined with seawater biogeochemical properties also measured continuously along the ship track to develop a number of parametrizations that can be used in models to determine SSA organic content in oligotrophic waters that represent 60 % of the oceans from commonly measured seawater variables.
Matthieu Roy-Barman, Lorna Foliot, Eric Douville, Nathalie Leblond, Fréderic Gazeau, Matthieu Bressac, Thibaut Wagener, Céline Ridame, Karine Desboeufs, and Cécile Guieu
Biogeosciences, 18, 2663–2678, https://doi.org/10.5194/bg-18-2663-2021, https://doi.org/10.5194/bg-18-2663-2021, 2021
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The release of insoluble elements such as aluminum (Al), iron (Fe), rare earth elements (REEs), thorium (Th) and protactinium (Pa) when Saharan dust falls over the Mediterranean Sea was studied during tank experiments under present and future climate conditions. Each element exhibited different dissolution kinetics and dissolution fractions (always lower than a few percent). Changes in temperature and/or pH under greenhouse conditions lead to a lower Th release and a higher light REE release.
Kahina Djaoudi, France Van Wambeke, Aude Barani, Nagib Bhairy, Servanne Chevaillier, Karine Desboeufs, Sandra Nunige, Mohamed Labiadh, Thierry Henry des Tureaux, Dominique Lefèvre, Amel Nouara, Christos Panagiotopoulos, Marc Tedetti, and Elvira Pulido-Villena
Biogeosciences, 17, 6271–6285, https://doi.org/10.5194/bg-17-6271-2020, https://doi.org/10.5194/bg-17-6271-2020, 2020
Cited articles
Aikawa, M. and Hiraki, T.: Washout/rainout contribution in wet deposition estimated by 0.5 mm precipitation sampling/analysis, Atmos. Environ., 43, 4935–4939, https://doi.org/10.1016/j.atmosenv.2009.07.057, 2009.
Aikawa, M., Kajino, M., Hiraki, T., and Mukai, H.: The contribution of site to washout and rainout: Precipitation chemistry based on sample analysis from 0.5 mm precipitation increments and numerical simulation, Atmos. Environ., 95, 165–174, https://doi.org/10.1016/j.atmosenv.2014.06.015, 2014.
Airparif: Synthèse des connaissances sur les particules en Île-de-France, https://www.airparif.asso.fr/sites/default/files/documents/2021-04/Note_particules_042021.pdf (last access: 2 March 2022), 2021.
Andronache, C.: Estimates of sulfate aerosol wet scavenging coefficient for locations in the Eastern United States, Atmos. Environ., 38, 795–804, https://doi.org/10.1016/j.atmosenv.2003.10.035, 2004.
Anil, I., Alagha, O., and Karaca, F.: Effects of transport patterns on chemical composition of sequential rain samples: trajectory clustering and principal component analysis approach, Air Qual. Atmos. Hlth., 10, 1193–1206, https://doi.org/10.1007/s11869-017-0504-x, 2017.
Asman, W. A. H., Jonker, P. J., Slanina, J., and Baard, J. H.: Neutralization of Acid in Precipitation and Some Results of Sequential Rain Sampling, in: Deposition of Atmospheric Pollutants: Proceedings of a Colloquium held at Oberursel/Taunus, West Germany, 9–11 November 1981, edited by: Georgii, H.-W. and Pankrath, J., Springer Netherlands, Dordrecht, 115–123, https://doi.org/10.1007/978-94-009-7864-5_12, 1982.
Audoux, T., Laurent, B., Chevaillier, S., Féron, A., Pangui, E., Maisonneuve, F., Desboeufs, K., Triquet, S., Noyalet, G., Lauret, O., and Huet, F.: Automatic sequential rain sampling to study atmospheric particulate and dissolved wet deposition, Atmos. Environ., 295, 119561, https://doi.org/10.1016/j.atmosenv.2022.119561, 2023.
Baechmann, K., Ebert, P., Haag, I., and Prokop, T.: The chemical content of raindrops as a function of drop radius – I. Field measurements at the cloud base and below the cloud, Atmos. Environ., 30, 1019–1025, https://doi.org/10.1016/1352-2310(95)00409-2, 1996a.
Baechmann, K., Ebert, P., Haag, I., Prokop, T., and Steigerwald, K.: The chemical content of raindrops as a function of drop radius – II. Field experimental study on the scavenging of marked aerosol particles by raindrops sampled as a function of drop size, Atmos. Environ., 30, 1027–1033, https://doi.org/10.1016/1352-2310(95)00325-8, 1996b.
Basart, S., Nickovic, S., Terradellas, E., Cuevas, E., García-Pando, C. P., García-Castrillo, G., Werner, E., and Benincasa, F.: The WMO SDS-WAS Regional Center for Northern Africa, Middle East and Europe, E3S Web Conf., 99, 04008, https://doi.org/10.1051/e3sconf/20199904008, 2019.
Berberler, E., Gemici, B. T., Ucun Özel, H., Demir, T., and Karakaş, D.: Source identification of water-insoluble single particulate matters in rain sequences, Atmos. Pollut. Res., 13, 101499, https://doi.org/10.1016/j.apr.2022.101499, 2022.
Bertrand, G., Celle-Jeanton, H., Laj, P., Rangognio, J., and Chazot, G.: Rainfall chemistry: long range transport versus below cloud scavenging. A two-year study at an inland station (Opme, France), J. Atmos. Chem., 60, 253–271, https://doi.org/10.1007/s10874-009-9120-y, 2008.
Bukowiecki, N., Lienemann, P., Hill, M., Figi, R., Richard, A., Furger, M., Rickers, K., Falkenberg, G., Zhao, Y., and Cliff, S. S.: Real-world emission factors for antimony and other brake wear related trace elements: size-segregated values for light and heavy duty vehicles, Environ. Sci. Technol., 43, 8072–8078, 2009.
Calvo, A. I., Pont, V., Olmo, F. J., Castro, A., Alados-Arboledas, L., Vicente, A. M., Fernández-Raga, M., and Fraile, R.: Air Masses and Weather Types: A Useful Tool for Characterizing Precipitation Chemistry and Wet Deposition, Aerosol Air Qual. Res., 12, 856–878, https://doi.org/10.4209/aaqr.2012.03.0068, 2012.
Celle-Jeanton, H., Travi, Y., Loÿe-Pilot, M.-D., Huneau, F., and Bertrand, G.: Rainwater chemistry at a Mediterranean inland station (Avignon, France): Local contribution versus long-range supply, Atmos. Res., 91, 118–126, https://doi.org/10.1016/j.atmosres.2008.06.003, 2009.
Cerqueira, M., Pio, C., Legrand, M., Puxbaum, H., Kasper-Giebl, A., Afonso, J., Preunkert, S., Gelencsér, A., and Fialho, P.: Particulate carbon in precipitation at European background sites, J. Aerosol Sci., 41, 51–61, https://doi.org/10.1016/j.jaerosci.2009.08.002, 2010.
Chamberlain, A. C.: Aspects of the deposition of radioactive and other gases and particles, Int. J. Air Pollut., 3, 63–88, 1960.
Chatterjee, A., Jayaraman, A., Rao, T. N., and Raha, S.: In-cloud and below-cloud scavenging of aerosol ionic species over a tropical rural atmosphere in India, J. Atmos. Chem., 66, 27–40, https://doi.org/10.1007/s10874-011-9190-5, 2010.
Cheng, I. and Zhang, L.: Long-term air concentrations, wet deposition, and scavenging ratios of inorganic ions, HNO3, and SO2 and assessment of aerosol and precipitation acidity at Canadian rural locations, Atmos. Chem. Phys., 17, 4711–4730, https://doi.org/10.5194/acp-17-4711-2017, 2017.
Cheng, I., Al Mamun, A., and Zhang, L.: A synthesis review on atmospheric wet deposition of particulate elements: scavenging ratios, solubility, and flux measurements, Environ. Rev., 29, 340–353, https://doi.org/10.1139/er-2020-0118, 2021.
Colette, A., Andersson, C., Manders, A., Mar, K., Mircea, M., Pay, M.-T., Raffort, V., Tsyro, S., Cuvelier, C., Adani, M., Bessagnet, B., Bergström, R., Briganti, G., Butler, T., Cappelletti, A., Couvidat, F., D'Isidoro, M., Doumbia, T., Fagerli, H., Granier, C., Heyes, C., Klimont, Z., Ojha, N., Otero, N., Schaap, M., Sindelarova, K., Stegehuis, A. I., Roustan, Y., Vautard, R., van Meijgaard, E., Vivanco, M. G., and Wind, P.: EURODELTA-Trends, a multi-model experiment of air quality hindcast in Europe over 1990–2010, Geosci. Model Dev., 10, 3255–3276, https://doi.org/10.5194/gmd-10-3255-2017, 2017.
Croft, B., Lohmann, U., Martin, R. V., Stier, P., Wurzler, S., Feichter, J., Hoose, C., Heikkilä, U., van Donkelaar, A., and Ferrachat, S.: Influences of in-cloud aerosol scavenging parameterizations on aerosol concentrations and wet deposition in ECHAM5-HAM, Atmos. Chem. Phys., 10, 1511–1543, https://doi.org/10.5194/acp-10-1511-2010, 2010.
Dépée, A., Lemaitre, P., Gelain, T., Monier, M., and Flossmann, A.: Laboratory study of the collection efficiency of submicron aerosol particles by cloud droplets – Part I: Influence of relative humidity, Atmos. Chem. Phys., 21, 6945–6962, https://doi.org/10.5194/acp-21-6945-2021, 2021.
Desboeufs, K., Journet, E., Rajot, J.-L., Chevaillier, S., Triquet, S., Formenti, P., and Zakou, A.: Chemistry of rain events in West Africa: evidence of dust and biogenic influence in convective systems, Atmos. Chem. Phys., 10, 9283–9293, https://doi.org/10.5194/acp-10-9283-2010, 2010.
Draxler, R. R. and Rolph, G. D.: HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website, http://ready.arl.noaa.gov/HYSPLIT.php (last access: 30 August 2022), 2012.
Duce, R. A., Liss, P. S., Merrill, J. T., Atlas, E. L., Buat-Menard, P., Hicks, B. B., Miller, J. M., Prospero, J. M., Arimoto, R., Church, T. M., Ellis, W., Galloway, J. N., Hansen, L., Jickells, T. D., Knap, A. H., Reinhardt, K. H., Schneider, B., Soudine, A., Tokos, J. J., Tsunogai, S., Wollast, R., and Zhou, M.: The atmospheric input of trace species to the world ocean, Global Biogeochem. Cy., 5, 193–259, https://doi.org/10.1029/91GB01778, 1991.
Favez, O., Weber, S., Petit, J.-E., Alleman, L. Y., Albinet, A., Riffault, V., Chazeau, B., Amodeo, T., Salameh, D., Zhang, Y., Srivastava, D., Samaké, A., Aujay-Plouzeau, R., Papin, A., Bonnaire, N., Boullanger, C., Chatain, M., Chevrier, F., Detournay, A., Dominik-Sègue, M., Falhun, R., Garbin, C., Ghersi, V., Grignion, G., Levigoureux, G., Pontet, S., Rangognio, J., Zhang, S., Besombes, J.-L., Conil, S., Uzu, G., Savarino, J., Marchand, N., Gros, V., Marchand, C., Jaffrezo, J.-L., and Leoz-Garziandia, E.: Overview of the French Operational Network for In Situ Observation of PM Chemical Composition and Sources in Urban Environments (CARA Program), Atmosphere, 12, 207, https://doi.org/10.3390/atmos12020207, 2021.
Ge, B., Wang, Z., Gbaguidi, A. E., and Zhang, Q.: Source Identification of Acid Rain Arising over Northeast China: Observed Evidence and Model Simulation, Aerosol Air Qual. Res., 16, 1366–1377, https://doi.org/10.4209/aaqr.2015.05.0294, 2016.
Ge, B., Xu, D., Wild, O., Yao, X., Wang, J., Chen, X., Tan, Q., Pan, X., and Wang, Z.: Inter-annual variations of wet deposition in Beijing from 2014–2017: implications of below-cloud scavenging of inorganic aerosols, Atmos. Chem. Phys., 21, 9441–9454, https://doi.org/10.5194/acp-21-9441-2021, 2021a.
Ge, Y., Heal, M. R., Stevenson, D. S., Wind, P., and Vieno, M.: Evaluation of global EMEP MSC-W (rv4.34) WRF (v3.9.1.1) model surface concentrations and wet deposition of reactive N and S with measurements, Geosci. Model Dev., 14, 7021–7046, https://doi.org/10.5194/gmd-14-7021-2021, 2021b.
Germer, S., Neill, C., Krusche, A. V., Neto, S. C. G., and Elsenbeer, H.: Seasonal and within-event dynamics of rainfall and throughfall chemistry in an open tropical rainforest in Rondônia, Brazil, Biogeochemistry, 86, 155–174, https://doi.org/10.1007/s10533-007-9152-9, 2007.
Gong, W., Stroud, C., and Zhang, L.: Cloud Processing of Gases and Aerosols in Air Quality Modeling, Atmosphere, 2, 567–616, https://doi.org/10.3390/atmos2040567, 2011.
González, C. M. and Aristizábal, B. H.: Acid rain and particulate matter dynamics in a mid-sized Andean city: The effect of rain intensity on ion scavenging, Atmos. Environ., 60, 164–171, https://doi.org/10.1016/j.atmosenv.2012.05.054, 2012.
Grythe, H., Kristiansen, N. I., Groot Zwaaftink, C. D., Eckhardt, S., Ström, J., Tunved, P., Krejci, R., and Stohl, A.: A new aerosol wet removal scheme for the Lagrangian particle model FLEXPART v10, Geosci. Model Dev., 10, 1447–1466, https://doi.org/10.5194/gmd-10-1447-2017, 2017.
Haeffelin, M., Barthès, L., Bock, O., Boitel, C., Bony, S., Bouniol, D., Chepfer, H., Chiriaco, M., Cuesta, J., Delanoë, J., Drobinski, P., Dufresne, J.-L., Flamant, C., Grall, M., Hodzic, A., Hourdin, F., Lapouge, F., Lemaître, Y., Mathieu, A., Morille, Y., Naud, C., Noël, V., O'Hirok, W., Pelon, J., Pietras, C., Protat, A., Romand, B., Scialom, G., and Vautard, R.: SIRTA, a ground-based atmospheric observatory for cloud and aerosol research, Ann. Geophys., 23, 253–275, https://doi.org/10.5194/angeo-23-253-2005, 2005.
Huff, F. A. and Stout, G. E.: Distribution of Radioactive Rainout in Convective Rainfall, J. Appl. Meteorol., 3, 707–717, 1964.
Jaffrezo, J.-L. and Colin, J.-L.: Rain-aerosol coupling in urban area: Scavenging ratio measurement and identification of some transfer processes, Atmos. Environ., 22, 929–935, https://doi.org/10.1016/0004-6981(88)90270-3, 1988.
Jaffrezo, J.-L., Colin, J.-L., and Gros, J.-M.: Some physical factors influencing scavenging ratios, Atmos. Environ. A.-Gen., 24, 3073–3083, https://doi.org/10.1016/0960-1686(90)90486-7, 1990.
Jones, A. C., Hill, A., Hemmings, J., Lemaitre, P., Quérel, A., Ryder, C. L., and Woodward, S.: Below-cloud scavenging of aerosol by rain: a review of numerical modelling approaches and sensitivity simulations with mineral dust in the Met Office's Unified Model, Atmos. Chem. Phys., 22, 11381–11407, https://doi.org/10.5194/acp-22-11381-2022, 2022.
Karşı, M. B. B., Yenísoy-Karakaş, S., and Karakaş, D.: Investigation of washout and rainout processes in sequential rain samples, Atmos. Environ., 190, 53–64, https://doi.org/10.1016/j.atmosenv.2018.07.018, 2018.
Kasahara, M., Ogiwara, H., and Yamamoto, K.: Soluble and insoluble components of air pollutants scavenged by rain water, Nucl. Instrum. Meth. B, 118, 400–402, https://doi.org/10.1016/0168-583X(95)01087-4, 1996.
Kasper-Giebl, A., Kalina, M. F., and Puxbaum, H.: Scavenging ratios for sulfate, ammonium and nitrate determined at Mt. Sonnblick (3106 m a.s.l.), Atmos. Environ., 33, 895–906, https://doi.org/10.1016/S1352-2310(98)00279-9, 1999.
Kim, K. D., Lee, S., Kim, J.-J., Lee, S.-H., Lee, D., Lee, J.-B., Choi, J.-Y., and Kim, M. J.: Effect of Wet Deposition on Secondary Inorganic Aerosols Using an Urban-Scale Air Quality Model, Atmosphere, 12, 168, https://doi.org/10.3390/atmos12020168, 2021.
Laakso, L., Grönholm, T., Rannik, Ü., Kosmale, M., Fiedler, V., Vehkamäki, H., and Kulmala, M.: Ultrafine particle scavenging coefficients calculated from 6 years field measurements, Atmos. Environ., 37, 3605–3613, https://doi.org/10.1016/S1352-2310(03)00326-1, 2003.
Laboratoire Interuniversitaire des Systèmes Atmosphériques: Data linked to the article `Intra-event evolution of elemental and ionic concentrations in wet deposition in an urban environment', Audoux et al., ACP, 2023, http://www.lisa.u-pec.fr/fr/donnees, last access: 23 October 2023.
Laquer, F. C.: Sequential precipitation samplers: A literature review, Atmos. Environ. A.-Gen., 24, 2289–2297, https://doi.org/10.1016/0960-1686(90)90322-E, 1990.
LCSQA: Conformité technique des appareils de mesure, Laboratoire Central de Surveillance de la Qualité de l'Air, https://www.lcsqa.org/fr/conformite-technique-appareils-mesure (last access: 2 February 2023), 2021.
Lim, B., Jickells, T. D., and Davies, T. D.: Sequential sampling of particles, major ions and total trace metals in wet deposition, Atmos. Environ. A.-Gen., 25, 745–762, https://doi.org/10.1016/0960-1686(91)90073-G, 1991.
Ma, C.-J.: Chemical composition of a yellowish rainfall by the application of PIXE and micro-PIXE technique, Nuclear Instrum. Meth. B, 251, 501–506, https://doi.org/10.1016/j.nimb.2006.07.025, 2006.
Mamun, A. A., Cheng, I., Zhang, L., Celo, V., Dabek-Zlotorzynska, E., and Charland, J.-P.: Estimation of Atmospheric Dry and Wet Deposition of Particulate Elements at Four Monitoring Sites in the Canadian Athabasca Oil Sands Region, J. Geophys. Res.-Atmos., 127, e2021JD035787, https://doi.org/10.1029/2021JD035787, 2022.
Marticorena, B., Chatenet, B., Rajot, J. L., Bergametti, G., Deroubaix, A., Vincent, J., Kouoi, A., Schmechtig, C., Coulibaly, M., Diallo, A., Koné, I., Maman, A., NDiaye, T., and Zakou, A.: Mineral dust over west and central Sahel: Seasonal patterns of dry and wet deposition fluxes from a pluriannual sampling (2006–2012), J. Geophys. Res.-Atmos., 122, 1338–1364, https://doi.org/10.1002/2016JD025995, 2017.
Migliavacca, D. M., Teixeira, E. C., Raya Rodriguez, M. T., Wiegand, F., and Pereira, F. N.: Analysis of the sulfate aerosol scavenging processes in the metropolitan area of Porto Alegre (MAPA), RS, Brazil, Atmos. Pollut. Res., 1, 82–93, https://doi.org/10.5094/APR.2010.011, 2010.
Monteiro, L. R., Terzer-Wassmuth, S., Matiatos, I., Douence, C., and Wassenaar, L. I.: Distinguishing in-cloud and below-cloud short and distal N-sources from high-temporal resolution seasonal nitrate and ammonium deposition in Vienna, Austria, Atmos. Environ., 266, 118740, https://doi.org/10.1016/j.atmosenv.2021.118740, 2021.
Oduber, F., Calvo, A. I., Castro, A., Blanco-Alegre, C., Alves, C., Barata, J., Nunes, T., Lucarelli, F., Nava, S., Calzolai, G., Cerqueira, M., Martín-Villacorta, J., Esteves, V., and Fraile, R.: Chemical composition of rainwater under two events of aerosol transport: A Saharan dust outbreak and wildfires, Sci. Total Environ., 734, 139202, https://doi.org/10.1016/j.scitotenv.2020.139202, 2020.
Okita, T., Hara, H., and Fukuzaki, N.: Measurements of atmospheric SO2 and SO
Pant, P. and Harrison, R. M.: Estimation of the contribution of road traffic emissions to particulate matter concentrations from field measurements: A review, Atmos. Environ., 77, 78–97, https://doi.org/10.1016/j.atmosenv.2013.04.028, 2013.
Ryu, Y.-H. and Min, S.-K.: Improving Wet and Dry Deposition of Aerosols in WRF-Chem: Updates to Below-Cloud Scavenging and Coarse-Particle Dry Deposition, J. Adv. Model. Earth Sy., 14, e2021MS002792, https://doi.org/10.1029/2021MS002792, 2022.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, John Wiley & Sons, 1146 pp., ISBN 978-1-118-94740-1, 2016.
Seymour, M. D. and Stout, T.: Observations on the chemical composition of rain using short sampling times during a single event, Atmos. Environ., 17, 1483–1487, https://doi.org/10.1016/0004-6981(83)90301-3, 1983.
Slinn, W. G. N.: Some approximations for the wet and dry removal of particles and gases from the atmosphere, Water, Air Soil Pollut., 7, 513–543, https://doi.org/10.1007/BF00285550, 1977.
Sparmacher, H., Fülber, K., and Bonka, H.: Below-cloud scavenging of aerosol particles: Particle-bound radionuclides–Experimental, Atmos. Environ. A-Gen., 27, 605–618, https://doi.org/10.1016/0960-1686(93)90218-N, 1993.
Tanner, P. A., Tam, C. W. F., Tanner, P. A., and Tam, C. W. F.: In-Cloud Concentrations and Below-Cloud Scavenging Processes in Hong Kong, China, Environ. Chem., 3, 142–148, https://doi.org/10.1071/EN05084, 2006.
Tapiador, F. J., Checa, R., and de Castro, M.: An experiment to measure the spatial variability of rain drop size distribution using sixteen laser disdrometers, Geophys. Res. Lett., 37, L16803, https://doi.org/10.1029/2010GL044120, 2010.
Taylor, S. R. and McLennan, S. M.: The continental crust: Its composition and evolution, ISBN 0632011483, 1985.
Thorpe, A. and Harrison, R. M.: Sources and properties of non-exhaust particulate matter from road traffic: A review, Sci. Total Environ., 400, 270–282, https://doi.org/10.1016/j.scitotenv.2008.06.007, 2008.
Vincent, J., Laurent, B., Losno, R., Bon Nguyen, E., Roullet, P., Sauvage, S., Chevaillier, S., Coddeville, P., Ouboulmane, N., di Sarra, A. G., Tovar-Sánchez, A., Sferlazzo, D., Massanet, A., Triquet, S., Morales Baquero, R., Fornier, M., Coursier, C., Desboeufs, K., Dulac, F., and Bergametti, G.: Variability of mineral dust deposition in the western Mediterranean basin and south-east of France, Atmos. Chem. Phys., 16, 8749–8766, https://doi.org/10.5194/acp-16-8749-2016, 2016.
Wang, X., Zhang, L., and Moran, M. D.: Uncertainty assessment of current size-resolved parameterizations for below-cloud particle scavenging by rain, Atmos. Chem. Phys., 10, 5685–5705, https://doi.org/10.5194/acp-10-5685-2010, 2010.
Wang, X., Zhang, L., and Moran, M. D.: On the discrepancies between theoretical and measured below-cloud particle scavenging coefficients for rain – a numerical investigation using a detailed one-dimensional cloud microphysics model, Atmos. Chem. Phys., 11, 11859–11866, https://doi.org/10.5194/acp-11-11859-2011, 2011.
Wang, X., Zhang, L., and Moran, M. D.: Development of a new semi-empirical parameterization for below-cloud scavenging of size-resolved aerosol particles by both rain and snow, Geosci. Model Dev., 7, 799–819, https://doi.org/10.5194/gmd-7-799-2014, 2014.
Wiegand, F., Pereira, F. N., and Teixeira, E. C.: Study on wet scavenging of atmospheric pollutants in south Brazil, Atmos. Environ., 45, 4770–4776, https://doi.org/10.1016/j.atmosenv.2010.02.020, 2011.
Xu, D., Ge, B., Wang, Z., Sun, Y., Chen, Y., Ji, D., Yang, T., Ma, Z., Cheng, N., Hao, J., and Yao, X.: Below-cloud wet scavenging of soluble inorganic ions by rain in Beijing during the summer of 2014, Environ. Pollut., 230, 963–973, https://doi.org/10.1016/j.envpol.2017.07.033, 2017.
Xu, D., Ge, B., Chen, X., Sun, Y., Cheng, N., Li, M., Pan, X., Ma, Z., Pan, Y., and Wang, Z.: Multi-method determination of the below-cloud wet scavenging coefficients of aerosols in Beijing, China, Atmos. Chem. Phys., 19, 15569–15581, https://doi.org/10.5194/acp-19-15569-2019, 2019.
Yamagata, S., Kobayashi, D., Ohta, S., Murao, N., Shiobara, M., Wada, M., Yabuki, M., Konishi, H., and Yamanouchi, T.: Properties of aerosols and their wet deposition in the arctic spring during ASTAR2004 at Ny-Alesund, Svalbard, Atmos. Chem. Phys., 9, 261–270, https://doi.org/10.5194/acp-9-261-2009, 2009.
Yang, Q., Easter, R. C., Campuzano-Jost, P., Jimenez, J. L., Fast, J. D., Ghan, S. J., Wang, H., Berg, L. K., Barth, M. C., Liu, Y., Shrivastava, M. B., Singh, B., Morrison, H., Fan, J., Ziegler, C. L., Bela, M., Apel, E., Diskin, G. S., Mikoviny, T., and Wisthaler, A.: Aerosol transport and wet scavenging in deep convective clouds: A case study and model evaluation using a multiple passive tracer analysis approach, J. Geophys. Res.-Atmos., 120, 8448–8468, https://doi.org/10.1002/2015JD023647, 2015.
Zou, C., Yang, X., Zhang, Y., and Huang, H.: Characteristics and distribution of inorganic ions in segmented precipitation and contribution of below-cloud/in-cloud scavenging in Nanchang, Air Qual. Atmos. Hlth., 15, 903–916, https://doi.org/10.1007/s11869-022-01166-3, 2022.
Short summary
In the Paris region, a campaign was conducted to study wet deposition of aerosol particles during rainfall events. Simultaneous measurements of aerosol and wet deposition allowed us to discuss their transfer from the atmosphere to rain. Chemical evolution within events revealed meteorology, atmospheric conditions and local vs. long range sources as key factors. This study highlights the variability of wet deposition and the need to consider event-specific factors to understand its mechanisms.
In the Paris region, a campaign was conducted to study wet deposition of aerosol particles...
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