Articles | Volume 23, issue 18
https://doi.org/10.5194/acp-23-10809-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-10809-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism
Shan Zhang
Environment Research Institute, Shandong University, Qingdao 266237, China
Environment Research Institute, Shandong University, Qingdao 266237, China
Zhaomin Yang
Environment Research Institute, Shandong University, Qingdao 266237, China
Narcisse Tsona Tchinda
Environment Research Institute, Shandong University, Qingdao 266237, China
Jianlong Li
Environment Research Institute, Shandong University, Qingdao 266237, China
Environment Research Institute, Shandong University, Qingdao 266237, China
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Cited
13 citations as recorded by crossref.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al. https://doi.org/10.5194/acp-26-6147-2026
- VOCs-driven ozone extremes during dry and wet heatwaves in the Jiangsu–Shandong–Henan–Anhui Boundary: Integrating meteorological forcings and SHAP interpretation C. Wang et al. https://doi.org/10.1016/j.atmosres.2025.108396
- Molecular composition of secondary brown carbon from styrene at low-to-high oxidation degrees S. Zhang et al. https://doi.org/10.1016/j.envpol.2025.125795
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al. https://doi.org/10.1039/D5EM00823A
- Assessing the NO and SO2 pollution impacts on the Δ3-carene photooxidation mechanisms Y. Zhao et al. https://doi.org/10.1016/j.envpol.2026.128185
- Chemical interactions within biomass-burning emissions significantly influence the composition and optical properties of nanoscale secondary organic aerosols S. Zhang et al. https://doi.org/10.1039/D5EN00770D
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała https://doi.org/10.1016/j.chemosphere.2023.140854
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. https://doi.org/10.1039/D3EA00149K
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al. https://doi.org/10.1016/j.jes.2025.04.020
- Oxidation Flow Reactor and Its Application in Secondary Organic Aerosol Formation in Laboratory Studies X. Ma et al. https://doi.org/10.1021/acsestair.5c00047
- Evaporation-Induced Transformations in Volatile Chemical Product-Derived Secondary Organic Aerosols: Browning Effects and Alterations in Oxidative Reactivity L. Zhou et al. https://doi.org/10.1021/acs.est.4c02316
- Elucidation of the myrcene ozonolysis mechanism from a Criegee Chemistry perspective M. Chen et al. https://doi.org/10.5194/acp-26-2103-2026
- Pollution Characterization and Environmental Impact Evaluation of Atmospheric Intermediate Volatile Organic Compounds: A Review Y. Yan et al. https://doi.org/10.3390/toxics13040318
13 citations as recorded by crossref.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al. https://doi.org/10.5194/acp-26-6147-2026
- VOCs-driven ozone extremes during dry and wet heatwaves in the Jiangsu–Shandong–Henan–Anhui Boundary: Integrating meteorological forcings and SHAP interpretation C. Wang et al. https://doi.org/10.1016/j.atmosres.2025.108396
- Molecular composition of secondary brown carbon from styrene at low-to-high oxidation degrees S. Zhang et al. https://doi.org/10.1016/j.envpol.2025.125795
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al. https://doi.org/10.1039/D5EM00823A
- Assessing the NO and SO2 pollution impacts on the Δ3-carene photooxidation mechanisms Y. Zhao et al. https://doi.org/10.1016/j.envpol.2026.128185
- Chemical interactions within biomass-burning emissions significantly influence the composition and optical properties of nanoscale secondary organic aerosols S. Zhang et al. https://doi.org/10.1039/D5EN00770D
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała https://doi.org/10.1016/j.chemosphere.2023.140854
- Effect of relative humidity on the molecular composition of secondary organic aerosols from α-pinene ozonolysis H. Luo et al. https://doi.org/10.1039/D3EA00149K
- Photooxidation and ozonolysis of α-pinene and limonene mixtures: Mechanisms of secondary organic aerosol formation and cross-dimerization Y. Zhao et al. https://doi.org/10.1016/j.jes.2025.04.020
- Oxidation Flow Reactor and Its Application in Secondary Organic Aerosol Formation in Laboratory Studies X. Ma et al. https://doi.org/10.1021/acsestair.5c00047
- Evaporation-Induced Transformations in Volatile Chemical Product-Derived Secondary Organic Aerosols: Browning Effects and Alterations in Oxidative Reactivity L. Zhou et al. https://doi.org/10.1021/acs.est.4c02316
- Elucidation of the myrcene ozonolysis mechanism from a Criegee Chemistry perspective M. Chen et al. https://doi.org/10.5194/acp-26-2103-2026
- Pollution Characterization and Environmental Impact Evaluation of Atmospheric Intermediate Volatile Organic Compounds: A Review Y. Yan et al. https://doi.org/10.3390/toxics13040318
Saved (final revised paper)
Latest update: 07 Jun 2026
Short summary
In this study, we have investigated the distinct impacts of humidity on the ozonolysis of two structurally different monoterpenes (limonene and Δ3-carene). We found that the molecular structure of precursors can largely influence the SOA formation under high RH by impacting the multi-generation reactions. Our results could advance knowledge on the roles of water content in aerosol formation and inform ongoing research on particle environmental effects and applications in models.
In this study, we have investigated the distinct impacts of humidity on the ozonolysis of two...
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