Articles | Volume 22, issue 9
https://doi.org/10.5194/acp-22-6309-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-6309-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
| 
17 May 2022
Research article | Highlight paper |
| 17 May 2022
| 17 May 2022
Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere
Gordon A. Novak
Department of Chemistry, University of Wisconsin, Madison,
WI 53706, USA
now at: Cooperative Institute for Research in Environmental
Sciences, University of Colorado Boulder, Boulder, CO 80309, USA
now at: National Oceanic and Atmospheric Administration (NOAA), Chemical Sciences
Laboratory (CSL), Boulder, CO 80305, USA
Delaney B. Kilgour
Department of Chemistry, University of Wisconsin, Madison,
WI 53706, USA
Christopher M. Jernigan
Department of Chemistry, University of Wisconsin, Madison,
WI 53706, USA
Michael P. Vermeuel
Department of Chemistry, University of Wisconsin, Madison,
WI 53706, USA
now at: Department of Soil, Water, and Climate, University of
Minnesota, Twin Cities, St. Paul, MN 55108, USA
Timothy H. Bertram
CORRESPONDING AUTHOR
Department of Chemistry, University of Wisconsin, Madison,
WI 53706, USA
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Cited
26 citations as recorded by crossref.
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Theoretical Insights into the Gas-Phase Oxidation of 3-Methyl-2-butene-1-thiol by the OH Radical: Thermochemical and Kinetic Analysis P. Arathala & R. Musah 10.1021/acs.jpca.3c07775
- Volatile Organic Compounds Released by Oxyrrhis marina Grazing on Isochrysis galbana C. Wohl et al. 10.3390/oceans4020011
- Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater D. Kilgour et al. 10.5194/acp-24-3729-2024
- Assessing the Isomerization of a Primary Intermediate (CH3SCH2O2• Radical) in Dimethyl Sulfide Degradation in the Marine Boundary Layer M. Lily et al. 10.1021/acsearthspacechem.3c00209
- Microbially Driven Sulfur Cycling in the River–Wetland–Ocean Continuum X. Yu et al. 10.34133/olar.0027
- A review on air–sea exchange of reactive trace gases over the northern Indian Ocean M. Gupta et al. 10.1007/s12040-024-02268-5
- Reaction of Atmospherically Relevant Sulfur-Centered Radicals with RO2 and HO2 J. Chen et al. 10.1021/acs.jpca.3c00558
- Concentrations of dissolved dimethyl sulfide (DMS), methanethiol and other trace gases in context of microbial communities from the temperate Atlantic to the Arctic Ocean V. Gros et al. 10.5194/bg-20-851-2023
- Influence of open ocean biogeochemistry on aerosol and clouds: Recent findings and perspectives K. Sellegri et al. 10.1525/elementa.2023.00058
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean C. Wohl et al. 10.1126/sciadv.adq2465
- Global sensitivities of reactive N and S gas and particle concentrations and deposition to precursor emissions reductions Y. Ge et al. 10.5194/acp-23-6083-2023
- Polar oceans and sea ice in a changing climate M. Willis et al. 10.1525/elementa.2023.00056
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al. 10.5194/acp-25-1931-2025
- Contribution of Speciated Monoterpenes to Secondary Aerosol in the Eastern North Atlantic D. Kilgour et al. 10.1021/acsestair.3c00112
- Characteristics of atmospheric reduced-sulfur compounds at a suburban site of Shanghai K. Deng et al. 10.1016/j.jes.2024.06.030
- Highly Efficient Autoxidation of Triethylamine E. Kjærgaard et al. 10.1021/acs.jpca.3c04341
- Evaluation of air quality simulation with a coupled atmosphere-ocean model: A case study on natural marine and biogenic emissions S. Cho et al. 10.1016/j.scitotenv.2023.163021
- Carbonate clumped isotope values compromised by nitrate-derived NO2 interferent J. Fiebig et al. 10.1016/j.chemgeo.2024.122382
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
- Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea H. Hellén et al. 10.5194/acp-24-4717-2024
- Climate Change Impacts on the Marine Cycling of Biogenic Sulfur: A Review R. Jackson & A. Gabric 10.3390/microorganisms10081581
- Spectroscopic Characterization and Photochemistry of the Atmospherically Relevant Methanesulfenic Acid X. Shao et al. 10.1021/acs.jpclett.4c01750
- Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere G. Novak et al. 10.5194/acp-22-6309-2022
25 citations as recorded by crossref.
- Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K E. Assaf et al. 10.1021/acs.jpca.2c09095
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Theoretical Insights into the Gas-Phase Oxidation of 3-Methyl-2-butene-1-thiol by the OH Radical: Thermochemical and Kinetic Analysis P. Arathala & R. Musah 10.1021/acs.jpca.3c07775
- Volatile Organic Compounds Released by Oxyrrhis marina Grazing on Isochrysis galbana C. Wohl et al. 10.3390/oceans4020011
- Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater D. Kilgour et al. 10.5194/acp-24-3729-2024
- Assessing the Isomerization of a Primary Intermediate (CH3SCH2O2• Radical) in Dimethyl Sulfide Degradation in the Marine Boundary Layer M. Lily et al. 10.1021/acsearthspacechem.3c00209
- Microbially Driven Sulfur Cycling in the River–Wetland–Ocean Continuum X. Yu et al. 10.34133/olar.0027
- A review on air–sea exchange of reactive trace gases over the northern Indian Ocean M. Gupta et al. 10.1007/s12040-024-02268-5
- Reaction of Atmospherically Relevant Sulfur-Centered Radicals with RO2 and HO2 J. Chen et al. 10.1021/acs.jpca.3c00558
- Concentrations of dissolved dimethyl sulfide (DMS), methanethiol and other trace gases in context of microbial communities from the temperate Atlantic to the Arctic Ocean V. Gros et al. 10.5194/bg-20-851-2023
- Influence of open ocean biogeochemistry on aerosol and clouds: Recent findings and perspectives K. Sellegri et al. 10.1525/elementa.2023.00058
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean C. Wohl et al. 10.1126/sciadv.adq2465
- Global sensitivities of reactive N and S gas and particle concentrations and deposition to precursor emissions reductions Y. Ge et al. 10.5194/acp-23-6083-2023
- Polar oceans and sea ice in a changing climate M. Willis et al. 10.1525/elementa.2023.00056
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al. 10.5194/acp-25-1931-2025
- Contribution of Speciated Monoterpenes to Secondary Aerosol in the Eastern North Atlantic D. Kilgour et al. 10.1021/acsestair.3c00112
- Characteristics of atmospheric reduced-sulfur compounds at a suburban site of Shanghai K. Deng et al. 10.1016/j.jes.2024.06.030
- Highly Efficient Autoxidation of Triethylamine E. Kjærgaard et al. 10.1021/acs.jpca.3c04341
- Evaluation of air quality simulation with a coupled atmosphere-ocean model: A case study on natural marine and biogenic emissions S. Cho et al. 10.1016/j.scitotenv.2023.163021
- Carbonate clumped isotope values compromised by nitrate-derived NO2 interferent J. Fiebig et al. 10.1016/j.chemgeo.2024.122382
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
- Shipping and algae emissions have a major impact on ambient air mixing ratios of non-methane hydrocarbons (NMHCs) and methanethiol on Utö Island in the Baltic Sea H. Hellén et al. 10.5194/acp-24-4717-2024
- Climate Change Impacts on the Marine Cycling of Biogenic Sulfur: A Review R. Jackson & A. Gabric 10.3390/microorganisms10081581
- Spectroscopic Characterization and Photochemistry of the Atmospherically Relevant Methanesulfenic Acid X. Shao et al. 10.1021/acs.jpclett.4c01750
Latest update: 11 Mar 2025
Short summary
We describe field measurements of the mixing ratio and oceanic emission flux of dimethyl sulfide (DMS) and methanethiol (MeSH) from a coastal ocean site. DMS is known to impact aerosol formation and growth in the marine atmosphere, influencing cloud formation and climate. Measurements of MeSH, which is produced by the same oceanic source as DMS, are rare. We show that MeSH emissions are large and must be measured alongside DMS to understand marine sulfur chemistry and aerosol formation.
We describe field measurements of the mixing ratio and oceanic emission flux of dimethyl sulfide...
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