Articles | Volume 22, issue 9
https://doi.org/10.5194/acp-22-6103-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-6103-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
10 May 2022
Research article |
| 10 May 2022
| 10 May 2022
Molecular-level nucleation mechanism of iodic acid and methanesulfonic acid
Key Laboratory of Cluster Science, Ministry of Education of China,
School of Chemistry and Chemical Engineering, Beijing Institute of
Technology, Beijing 100081, China
Key Laboratory of Cluster Science, Ministry of Education of China,
School of Chemistry and Chemical Engineering, Beijing Institute of
Technology, Beijing 100081, China
Lin Ji
Department of Chemistry, Capital Normal University, Beijing 100048,
China
Key Laboratory of Cluster Science, Ministry of Education of China,
School of Chemistry and Chemical Engineering, Beijing Institute of
Technology, Beijing 100081, China
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Cited
15 citations as recorded by crossref.
- Enhancement of Atmospheric Nucleation Precursors on Iodic Acid-Induced Nucleation: Predictive Model and Mechanism F. Ma et al. 10.1021/acs.est.3c01034
- Role of Iodine-Assisted Aerosol Particle Formation in Antarctica C. Xavier et al. 10.1021/acs.est.3c09103
- Critical Role of Iodous Acid in Neutral Iodine Oxoacid Nucleation R. Zhang et al. 10.1021/acs.est.2c04328
- Overlooked significance of iodic acid in new particle formation in the continental atmosphere A. Ning et al. 10.1073/pnas.2404595121
- Cluster-dynamics-based parameterization for sulfuric acid–dimethylamine nucleation: comparison and selection through box and three-dimensional modeling J. Shen et al. 10.5194/acp-24-10261-2024
- Atmospheric Particle Number Concentrations and New Particle Formation over the Southern Ocean and Antarctica: A Critical Review J. Wang et al. 10.3390/atmos14020402
- Methanesulfonic acid and iodous acid nucleation: a novel mechanism for marine aerosols N. Wu et al. 10.1039/D3CP01198D
- Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion) R. Salignat et al. 10.5194/acp-24-3785-2024
- Molecular-level study on the role of methanesulfonic acid in iodine oxoacid nucleation J. Li et al. 10.5194/acp-24-3989-2024
- Atmospheric Bases-Enhanced Iodic Acid Nucleation: Altitude-Dependent Characteristics and Molecular Mechanisms J. Li et al. 10.1021/acs.est.4c06053
- Iodine Clusters in the Atmosphere I: Computational Benchmark and Dimer Formation of Oxyacids and Oxides M. Engsvang et al. 10.1021/acsomega.4c01235
- Quantum chemical modeling of atmospheric molecular clusters involving inorganic acids and methanesulfonic acid M. Engsvang et al. 10.1063/5.0152517
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- HIO3–HIO2-Driven Three-Component Nucleation: Screening Model and Cluster Formation Mechanism R. Zhang et al. 10.1021/acs.est.3c06098
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
15 citations as recorded by crossref.
- Enhancement of Atmospheric Nucleation Precursors on Iodic Acid-Induced Nucleation: Predictive Model and Mechanism F. Ma et al. 10.1021/acs.est.3c01034
- Role of Iodine-Assisted Aerosol Particle Formation in Antarctica C. Xavier et al. 10.1021/acs.est.3c09103
- Critical Role of Iodous Acid in Neutral Iodine Oxoacid Nucleation R. Zhang et al. 10.1021/acs.est.2c04328
- Overlooked significance of iodic acid in new particle formation in the continental atmosphere A. Ning et al. 10.1073/pnas.2404595121
- Cluster-dynamics-based parameterization for sulfuric acid–dimethylamine nucleation: comparison and selection through box and three-dimensional modeling J. Shen et al. 10.5194/acp-24-10261-2024
- Atmospheric Particle Number Concentrations and New Particle Formation over the Southern Ocean and Antarctica: A Critical Review J. Wang et al. 10.3390/atmos14020402
- Methanesulfonic acid and iodous acid nucleation: a novel mechanism for marine aerosols N. Wu et al. 10.1039/D3CP01198D
- Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion) R. Salignat et al. 10.5194/acp-24-3785-2024
- Molecular-level study on the role of methanesulfonic acid in iodine oxoacid nucleation J. Li et al. 10.5194/acp-24-3989-2024
- Atmospheric Bases-Enhanced Iodic Acid Nucleation: Altitude-Dependent Characteristics and Molecular Mechanisms J. Li et al. 10.1021/acs.est.4c06053
- Iodine Clusters in the Atmosphere I: Computational Benchmark and Dimer Formation of Oxyacids and Oxides M. Engsvang et al. 10.1021/acsomega.4c01235
- Quantum chemical modeling of atmospheric molecular clusters involving inorganic acids and methanesulfonic acid M. Engsvang et al. 10.1063/5.0152517
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- HIO3–HIO2-Driven Three-Component Nucleation: Screening Model and Cluster Formation Mechanism R. Zhang et al. 10.1021/acs.est.3c06098
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
Latest update: 20 Nov 2024
Short summary
Iodic acid (IA) and methanesulfonic acid (MSA) were previously proved to be significant nucleation precursors in marine areas. However, the nucleation process involved in IA and MSA remains unclear. We show the enhancement of MSA on IA cluster formation and reveal the IAM-SA nucleating mechanism using a theoretical approach. This study helps to understand the clustering process in which marine sulfur- and iodine-containing species are jointly involved and its impact on new particle formation.
Iodic acid (IA) and methanesulfonic acid (MSA) were previously proved to be significant...
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