Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2203-2022
https://doi.org/10.5194/acp-22-2203-2022
Research article
 | 
17 Feb 2022
Research article |  | 17 Feb 2022

Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour

Claudiu Roman, Cecilia Arsene, Iustinian Gabriel Bejan, and Romeo Iulian Olariu

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Latest update: 02 Mar 2024
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Short summary
Gas-phase reaction rate coefficients of OH radicals with four nitrocatechols have been investigated for the first time by using ESC-Q-UAIC chamber facilities. The reactivity of all investigated nitrocatechols is influenced by the formation of the intramolecular H-bonds that are connected to the deactivating electromeric effect of the NO2 group. For the 3-nitrocatechol compounds, the electromeric effect of the free OH group is diminished by the deactivating E-effect of the NO2 group.
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