Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2203-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-2203-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour
Claudiu Roman
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Cecilia Arsene
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Iustinian Gabriel Bejan
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Romeo Iulian Olariu
CORRESPONDING AUTHOR
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
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Latest update: 01 Aug 2025
Short summary
Gas-phase reaction rate coefficients of OH radicals with four nitrocatechols have been investigated for the first time by using ESC-Q-UAIC chamber facilities. The reactivity of all investigated nitrocatechols is influenced by the formation of the intramolecular H-bonds that are connected to the deactivating electromeric effect of the NO2 group. For the 3-nitrocatechol compounds, the electromeric effect of the
freeOH group is diminished by the deactivating E-effect of the NO2 group.
Gas-phase reaction rate coefficients of OH radicals with four nitrocatechols have been...
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