Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2203-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-2203-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
17 Feb 2022
Research article |
| 17 Feb 2022
| 17 Feb 2022
Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour
Claudiu Roman
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Cecilia Arsene
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Iustinian Gabriel Bejan
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
Romeo Iulian Olariu
CORRESPONDING AUTHOR
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi,
Iasi, 11th Carol I, 700506, Romania
Integrated Center of Environmental Science Studies in the North Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, Iasi, 11th Carol I, 700506, Romania
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- Characteristics and evolution of brown carbon in western United States wildfires L. Zeng et al. 10.5194/acp-22-8009-2022
- Nitrate-Photolysis Shortens the Lifetimes of Brown Carbon Tracers from Biomass Burning Y. Liu et al. 10.1021/acs.est.4c06123
- Gas-Phase Kinetics of a Series of cis-3-Hexenyl Esters with OH Radicals under Simulated Atmospheric Conditions C. Mairean et al. 10.1021/acs.jpca.4c03069
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- Perylene diimide functionalized nano-silica: green emissive material for selective probing and remediation of 4-nitrocatechol, Ru3+, and Cu2+ with biosensing applications S. Yadav et al. 10.1039/D4MA00862F
- The performance of a 100 m3 outdoor atmospheric simulation chamber in China Y. Ren et al. 10.1016/j.scitotenv.2024.177567
- Gas-Phase Ozone Reaction Kinetics of a Series of cis-3-Hexenyl Esters under Simulated Atmospheric Conditions C. Mairean et al. 10.1021/acs.jpca.5c01004
- Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals C. Mapelli et al. 10.5194/acp-22-14589-2022
- Co-photolysis of mixed chromophores affects atmospheric lifetimes of brown carbon Y. Wang et al. 10.1039/D3EA00073G
- Gas-Phase Ozone Reaction Kinetics of C5–C8Unsaturated Alcohols of Biogenic Interest A. Grira et al. 10.1021/acs.jpca.2c02805
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Gas-Phase Reaction Kinetic Study of a Series of Methyl-Butenols with Ozone under Atmospherically Relevant Conditions A. Rusu (Vasilache) et al. 10.1021/acs.jpca.4c03653
- Evaluation of the Environmental Fate of a Semivolatile Transformation Product of Ibuprofen Based on a Simple Two-Media Fate Model C. Arsene et al. 10.1021/acs.est.2c04867
- Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations Y. Ren et al. 10.5194/acp-25-6975-2025
- A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs) Y. Peng et al. 10.5194/acp-25-7037-2025
Latest update: 22 Aug 2025
Short summary
Gas-phase reaction rate coefficients of OH radicals with four nitrocatechols have been investigated for the first time by using ESC-Q-UAIC chamber facilities. The reactivity of all investigated nitrocatechols is influenced by the formation of the intramolecular H-bonds that are connected to the deactivating electromeric effect of the NO2 group. For the 3-nitrocatechol compounds, the electromeric effect of the
freeOH group is diminished by the deactivating E-effect of the NO2 group.
Gas-phase reaction rate coefficients of OH radicals with four nitrocatechols have been...
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