Articles | Volume 22, issue 22
https://doi.org/10.5194/acp-22-14589-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-14589-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals
Caterina Mapelli
Department of Chemistry, University of York, York, YO10 5DD, UK
Juliette V. Schleicher
Department of Chemistry, University of York, York, YO10 5DD, UK
now at: École Polytechnique Fédérale de Lausanne, 1015 Lausanne,
Switzerland
Alex Hawtin
Department of Chemistry, University of York, York, YO10 5DD, UK
Conor D. Rankine
Department of Chemistry, University of York, York, YO10 5DD, UK
Department of Chemistry, Newcastle University, Newcastle upon Tyne,
NE1 7RU, UK
Fiona C. Whiting
Department of Chemistry, University of York, York, YO10 5DD, UK
Fergal Byrne
Department of Chemistry, University of York, York, YO10 5DD, UK
Department of Chemistry, Maynooth University, Maynooth, Co. Kildare,
W23 F2H6, Ireland
C. Rob McElroy
Department of Chemistry, University of York, York, YO10 5DD, UK
Claudiu Roman
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Integrated Center of Environmental Science Studies in the North
Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Cecilia Arsene
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Integrated Center of Environmental Science Studies in the North
Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Romeo I. Olariu
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Integrated Center of Environmental Science Studies in the North
Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Iustinian G. Bejan
Faculty of Chemistry, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Integrated Center of Environmental Science Studies in the North
Eastern Region – CERNESIM, “Alexandru Ioan Cuza” University of Iasi, 11th Carol I, 700506,
Iasi, Romania
Department of Chemistry, University of York, York, YO10 5DD, UK
Viewed
Total article views: 2,618 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 04 Jul 2022)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
1,916 | 648 | 54 | 2,618 | 166 | 51 | 80 |
- HTML: 1,916
- PDF: 648
- XML: 54
- Total: 2,618
- Supplement: 166
- BibTeX: 51
- EndNote: 80
Total article views: 1,978 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 17 Nov 2022)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
1,536 | 403 | 39 | 1,978 | 90 | 45 | 72 |
- HTML: 1,536
- PDF: 403
- XML: 39
- Total: 1,978
- Supplement: 90
- BibTeX: 45
- EndNote: 72
Total article views: 640 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 04 Jul 2022)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
380 | 245 | 15 | 640 | 76 | 6 | 8 |
- HTML: 380
- PDF: 245
- XML: 15
- Total: 640
- Supplement: 76
- BibTeX: 6
- EndNote: 8
Viewed (geographical distribution)
Total article views: 2,618 (including HTML, PDF, and XML)
Thereof 2,618 with geography defined
and 0 with unknown origin.
Total article views: 1,978 (including HTML, PDF, and XML)
Thereof 1,978 with geography defined
and 0 with unknown origin.
Total article views: 640 (including HTML, PDF, and XML)
Thereof 640 with geography defined
and 0 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
4 citations as recorded by crossref.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al. 10.5194/acp-25-9169-2025
- 2,2,5,5-Tetramethyloxolane (TMO) Replacing Toluene as an Azeotropic Solvent for the Synthesis of Polyester Resins T. Link et al. 10.1021/acs.iecr.4c00874
- Atmospheric oxidation of new “green” solvents – Part 2: methyl pivalate and pinacolone C. Mapelli et al. 10.5194/acp-23-7767-2023
- Solvent Solutions: Comparing Extraction Methods for Edible Oils and Proteins in a Changing Regulatory Landscape. Part 7: Overall comparison between solvent solutions P. Carré et al. 10.1051/ocl/2025013
3 citations as recorded by crossref.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al. 10.5194/acp-25-9169-2025
- 2,2,5,5-Tetramethyloxolane (TMO) Replacing Toluene as an Azeotropic Solvent for the Synthesis of Polyester Resins T. Link et al. 10.1021/acs.iecr.4c00874
- Atmospheric oxidation of new “green” solvents – Part 2: methyl pivalate and pinacolone C. Mapelli et al. 10.5194/acp-23-7767-2023
Latest update: 28 Aug 2025
Short summary
Solvents represent an important source of pollution from the chemical industry. New "green" solvents aim to replace toxic solvents with new molecules made from renewable sources and designed to be less harmful. Whilst these new molecules are selected according to toxicity and other characteristics, no consideration has yet been included on air quality. Studying the solvent breakdown in air, we found that TMO has a lower impact on air quality than traditional solvents with similar properties.
Solvents represent an important source of pollution from the chemical industry. New "green"...
Altmetrics
Final-revised paper
Preprint