Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 22, issue 22
Articles | Volume 22, issue 22
https://doi.org/10.5194/acp-22-14529-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-14529-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 22, issue 22
Research article
 | 
16 Nov 2022
Research article |  | 16 Nov 2022

Oligomer formation from the gas-phase reactions of Criegee intermediates with hydroperoxide esters: mechanism and kinetics

Long Chen, Yu Huang, Yonggang Xue, Zhihui Jia, and Wenliang Wang

Viewed

Total article views: 2,546 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
2,023 477 46 2,546 154 31 38
  • HTML: 2,023
  • PDF: 477
  • XML: 46
  • Total: 2,546
  • Supplement: 154
  • BibTeX: 31
  • EndNote: 38
Views and downloads (calculated since 08 Jun 2022)
Cumulative views and downloads (calculated since 08 Jun 2022)

Viewed (geographical distribution)

Total article views: 2,546 (including HTML, PDF, and XML) Thereof 2,651 with geography defined and -105 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 

Cited

Latest update: 22 Nov 2024
Download
Short summary
Quantum chemical methods are applied to gain insight into the oligomerization reaction mechanisms and kinetics of distinct stabilized Criegee intermediate (SCI) reactions with hydroperoxide esters, where calculations show that SCI addition reactions with hydroperoxide esters proceed through the successive insertion of SCIs to form oligomers that involve SCIs as the repeating unit. The saturated vapor pressure of the formed oligomers decreases monotonically with the increasing number of SCIs.
Read more
Altmetrics
Final-revised paper
Preprint