Articles | Volume 21, issue 13
https://doi.org/10.5194/acp-21-9955-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-9955-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Jul 2021
Research article |
| 02 Jul 2021
| 02 Jul 2021
Secondary aerosol formation from dimethyl sulfide – improved mechanistic understanding based on smog chamber experiments and modelling
Robin Wollesen de Jonge
CORRESPONDING AUTHOR
Division of Nuclear Physics, Lund University, P.O. Box 118, Lund, Sweden
Jonas Elm
Department of Chemistry, Aarhus University, Langelandsgade 140, Aarhus, Denmark
Bernadette Rosati
Department of Chemistry, Aarhus University, Langelandsgade 140, Aarhus, Denmark
Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria
Sigurd Christiansen
Department of Chemistry, Aarhus University, Langelandsgade 140, Aarhus, Denmark
Noora Hyttinen
Nano and Molecular Systems Research Unit, University of Oulu, P.O. Box 3000, 90014 Oulu, Finland
Department of Applied Physics, University of Eastern Finland, P.O. Box 1627, 70211 Kuopio, Finland
Dana Lüdemann
Division of Nuclear Physics, Lund University, P.O. Box 118, Lund, Sweden
Merete Bilde
Department of Chemistry, Aarhus University, Langelandsgade 140, Aarhus, Denmark
Pontus Roldin
Division of Nuclear Physics, Lund University, P.O. Box 118, Lund, Sweden
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Cited
37 citations as recorded by crossref.
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- Contribution of Methanesulfonic Acid to the Formation of Molecular Clusters in the Marine Atmosphere F. Rasmussen et al. 10.1021/acs.jpca.2c04468
- Direct sulfuric acid formation from the gas-phase oxidation of reduced-sulfur compounds T. Berndt et al. 10.1038/s41467-023-40586-2
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Spectroscopic characterization of two peroxyl radicals during the O2-oxidation of the methylthio radical Z. Wu et al. 10.1038/s42004-022-00637-z
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
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- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model B. Cala et al. 10.5194/acp-23-14735-2023
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
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- Towards automated inclusion of autoxidation chemistry in models: from precursors to atmospheric implications L. Pichelstorfer et al. 10.1039/D4EA00054D
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- Quantum chemical modeling of atmospheric molecular clusters involving inorganic acids and methanesulfonic acid M. Engsvang et al. 10.1063/5.0152517
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- Modification of the Conversion of Dimethylsulfide to Methanesulfonic Acid by Anthropogenic Pollution as Revealed by Long-Term Observations B. Jiang et al. 10.1021/acsearthspacechem.1c00222
- Role of gas–molecular cluster–aerosol dynamics in atmospheric new-particle formation T. Olenius & P. Roldin 10.1038/s41598-022-14525-y
- Developments at the AURA atmospheric simulation chamber to characterize chamber volume, air mixing, and charging E. Iversen et al. 10.1080/02786826.2024.2429658
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- Effects of natural and anthropogenic emissions on the composition and toxicity of aerosols in the marine atmosphere S. Song et al. 10.1016/j.scitotenv.2021.150928
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- Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations U. Jongebloed et al. 10.5194/acp-25-4083-2025
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36 citations as recorded by crossref.
- Equilibria and Kinetics Involving Aqueous BrCl·– D. Stanbury 10.1021/acsestwater.5c00071
- Contribution of Methanesulfonic Acid to the Formation of Molecular Clusters in the Marine Atmosphere F. Rasmussen et al. 10.1021/acs.jpca.2c04468
- Direct sulfuric acid formation from the gas-phase oxidation of reduced-sulfur compounds T. Berndt et al. 10.1038/s41467-023-40586-2
- Atmospheric Gas-Phase Formation of Methanesulfonic Acid J. Chen et al. 10.1021/acs.est.3c07120
- Spectroscopic characterization of two peroxyl radicals during the O2-oxidation of the methylthio radical Z. Wu et al. 10.1038/s42004-022-00637-z
- Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard K. Siegel et al. 10.5194/acp-23-7569-2023
- Effects of atmospheric oxidation processes on the latitudinal distribution differences in MSA and nss-SO42- in the Northwest Pacific B. Jiang et al. 10.1016/j.atmosenv.2023.119618
- Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism M. Goss & J. Kroll 10.5194/acp-24-1299-2024
- Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes Q. Ye et al. 10.5194/acp-22-16003-2022
- Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model B. Cala et al. 10.5194/acp-23-14735-2023
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Atmospherically Relevant Chemistry and Aerosol box model – ARCA box (version 1.2) P. Clusius et al. 10.5194/gmd-15-7257-2022
- Pan-Arctic methanesulfonic acid aerosol: source regions, atmospheric drivers, and future projections J. Pernov et al. 10.1038/s41612-024-00712-3
- Untangling the influence of Antarctic and Southern Ocean life on clouds M. Mallet et al. 10.1525/elementa.2022.00130
- Machine Learning for Predicting Chemical Potentials of Multifunctional Organic Compounds in Atmospherically Relevant Solutions N. Hyttinen et al. 10.1021/acs.jpclett.2c02612
- Facile preparation and efficient MnxCoy porous nanosheets for the sustainable catalytic process of soot M. Hu et al. 10.1016/j.gee.2022.08.006
- Interaction between marine and terrestrial biogenic volatile organic compounds: Non-linear effect on secondary organic aerosol formation X. Chen et al. 10.1016/j.atmosenv.2024.120868
- Oxidation mechanism and performance control of manganese-based catalysts in soot oxidation T. Zhao et al. 10.1016/j.gee.2024.12.004
- Towards automated inclusion of autoxidation chemistry in models: from precursors to atmospheric implications L. Pichelstorfer et al. 10.1039/D4EA00054D
- Cloud processing dominates the vertical profiles of aerosols in marine air masses over the Great Barrier Reef R. Braga et al. 10.1016/j.atmosres.2025.107928
- Role of Iodine-Assisted Aerosol Particle Formation in Antarctica C. Xavier et al. 10.1021/acs.est.3c09103
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Secondary aerosol formation in marine Arctic environments: a model measurement comparison at Ny-Ålesund C. Xavier et al. 10.5194/acp-22-10023-2022
- Hygroscopicity and CCN potential of DMS-derived aerosol particles B. Rosati et al. 10.5194/acp-22-13449-2022
- Quantum chemical modeling of atmospheric molecular clusters involving inorganic acids and methanesulfonic acid M. Engsvang et al. 10.1063/5.0152517
- Implications for new particle formation in air of the use of monoethanolamine in carbon capture and storage V. Perraud et al. 10.1039/D4CP00316K
- Modification of the Conversion of Dimethylsulfide to Methanesulfonic Acid by Anthropogenic Pollution as Revealed by Long-Term Observations B. Jiang et al. 10.1021/acsearthspacechem.1c00222
- Role of gas–molecular cluster–aerosol dynamics in atmospheric new-particle formation T. Olenius & P. Roldin 10.1038/s41598-022-14525-y
- Developments at the AURA atmospheric simulation chamber to characterize chamber volume, air mixing, and charging E. Iversen et al. 10.1080/02786826.2024.2429658
- Implementing detailed nucleation predictions in the Earth system model EC-Earth3.3.4: sulfuric acid–ammonia nucleation C. Svenhag et al. 10.5194/gmd-17-4923-2024
- Natural Marine Precursors Boost Continental New Particle Formation and Production of Cloud Condensation Nuclei R. de Jonge et al. 10.1021/acs.est.4c01891
- High Gas-Phase Methanesulfonic Acid Production in the OH-Initiated Oxidation of Dimethyl Sulfide at Low Temperatures J. Shen et al. 10.1021/acs.est.2c05154
- Effects of natural and anthropogenic emissions on the composition and toxicity of aerosols in the marine atmosphere S. Song et al. 10.1016/j.scitotenv.2021.150928
- Identification and Photochemistry of the Mercaptomethyl Radical X. Shao et al. 10.1021/acs.jpclett.3c02526
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. 10.1016/j.scitotenv.2024.175207
- Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations U. Jongebloed et al. 10.5194/acp-25-4083-2025
1 citations as recorded by crossref.
Latest update: 29 May 2025
Short summary
This study presents a detailed analysis of the OH-initiated oxidation of dimethyl sulfide (DMS) based on experiments performed in the Aarhus University Research on Aerosol (AURA) smog chamber and the gas- and particle-phase chemistry kinetic multilayer model (ADCHAM). We capture the formation, growth and chemical composition of aerosols in the chamber setup by an improved multiphase oxidation mechanism and utilize our results to reproduce the important role of DMS in the marine boundary layer.
This study presents a detailed analysis of the OH-initiated oxidation of dimethyl sulfide (DMS)...
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