Articles | Volume 21, issue 24
https://doi.org/10.5194/acp-21-18213-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-18213-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Dec 2021
Research article |
| 16 Dec 2021
| 16 Dec 2021
Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer?
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, United Kingdom
now at: Department of Chemistry, York University, Toronto, ON, Canada
Louisa J. Kramer
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, United Kingdom
now at: Ricardo Energy & Environment, Harwell, Oxfordshire, United Kingdom.
Francis D. Pope
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, United Kingdom
Chris Reed
Wolfson Atmospheric Chemistry Laboratory (WACL), Department of Chemistry, University of York, Heslington, York, United Kingdom
now at: FAAM Airborne Laboratory, Building 146, Cranfield University, Cranfield, United Kingdom
James D. Lee
Wolfson Atmospheric Chemistry Laboratory (WACL), Department of Chemistry, University of York, Heslington, York, United Kingdom
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratory (WACL), Department of Chemistry, University of York, Heslington, York, United Kingdom
Lloyd D. J. Hollis
School of Chemistry, University of Leicester, Leicester, United Kingdom
Stephen M. Ball
School of Chemistry, University of Leicester, Leicester, United Kingdom
William J. Bloss
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, United Kingdom
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Cited
21 citations as recorded by crossref.
- Spatiotemporal distribution of marine aerosols and gaseous species over the North Pacific Ocean S. Oh et al. 10.1016/j.scitotenv.2025.178642
- An investigation into the chemistry of HONO in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda Y. Zhu et al. 10.5194/acp-22-6327-2022
- Intensive photochemical oxidation in the marine atmosphere: evidence from direct radical measurements G. Zhang et al. 10.5194/acp-24-1825-2024
- HONO Measurement by Catalytic Conversion to NO on Nafion Surfaces Z. Payne et al. 10.1021/acs.est.2c05944
- A review of measurements and model simulations of atmospheric nitrous acid L. Wang et al. 10.1016/j.atmosenv.2025.121094
- Nitrous acid budgets in the coastal atmosphere: potential daytime marine sources X. Zhong et al. 10.5194/acp-23-14761-2023
- Coarse particles compensate for missing daytime sources of nitrous acid and enhance atmospheric oxidation capacity in a coastal atmosphere M. Tang et al. 10.1016/j.scitotenv.2024.170037
- Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis C. Xing et al. 10.5194/acp-24-10093-2024
- Role of Heterogeneous Reactions in the Atmospheric Oxidizing Capacity in Island Environments C. Xue et al. 10.1021/acs.est.4c11647
- Comparison of Simultaneous Measurements of Indoor Nitrous Acid: Implications for the Spatial Distribution of Indoor HONO Emissions B. Bottorff et al. 10.1021/acs.est.2c02196
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Insights Into NOx and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign Y. Jiang et al. 10.1029/2023JD038865
- Observation-Based Diagnostics of Reactive Nitrogen Recycling through HONO Heterogenous Production: Divergent Implications for Ozone Production and Emission Control K. Chong et al. 10.1021/acs.est.3c07967
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Dominant Processes of HONO Derived from Multiple Field Observations in Contrasting Environments Y. Jiang et al. 10.1021/acs.estlett.2c00004
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- Global Impact of Particulate Nitrate Photolysis on Fine Sulfate Aerosol L. Liu et al. 10.1021/acs.estlett.4c00416
- Origins of atmospheric nitrous acid and their contributions to OH radical from ship plumes, marine atmosphere, and continental air masses over South China Sea X. Ni et al. 10.1016/j.scitotenv.2024.175841
- Unveiling the underestimated direct emissions of nitrous acid (HONO) Q. Zhang et al. 10.1073/pnas.2302048120
- Observations of HONO and its precursors between urban and its surrounding agricultural fields: The vertical transports, sources and contribution to OH C. Xing et al. 10.1016/j.scitotenv.2023.169159
- Snowmelt Leads to Seasonal Nitrous Acid Formation Across Northwestern China X. Wang et al. 10.1029/2022GL098035
20 citations as recorded by crossref.
- Spatiotemporal distribution of marine aerosols and gaseous species over the North Pacific Ocean S. Oh et al. 10.1016/j.scitotenv.2025.178642
- An investigation into the chemistry of HONO in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda Y. Zhu et al. 10.5194/acp-22-6327-2022
- Intensive photochemical oxidation in the marine atmosphere: evidence from direct radical measurements G. Zhang et al. 10.5194/acp-24-1825-2024
- HONO Measurement by Catalytic Conversion to NO on Nafion Surfaces Z. Payne et al. 10.1021/acs.est.2c05944
- A review of measurements and model simulations of atmospheric nitrous acid L. Wang et al. 10.1016/j.atmosenv.2025.121094
- Nitrous acid budgets in the coastal atmosphere: potential daytime marine sources X. Zhong et al. 10.5194/acp-23-14761-2023
- Coarse particles compensate for missing daytime sources of nitrous acid and enhance atmospheric oxidation capacity in a coastal atmosphere M. Tang et al. 10.1016/j.scitotenv.2024.170037
- Observations of the vertical distributions of summertime atmospheric pollutants in Nam Co: OH production and source analysis C. Xing et al. 10.5194/acp-24-10093-2024
- Role of Heterogeneous Reactions in the Atmospheric Oxidizing Capacity in Island Environments C. Xue et al. 10.1021/acs.est.4c11647
- Comparison of Simultaneous Measurements of Indoor Nitrous Acid: Implications for the Spatial Distribution of Indoor HONO Emissions B. Bottorff et al. 10.1021/acs.est.2c02196
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Insights Into NOx and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign Y. Jiang et al. 10.1029/2023JD038865
- Observation-Based Diagnostics of Reactive Nitrogen Recycling through HONO Heterogenous Production: Divergent Implications for Ozone Production and Emission Control K. Chong et al. 10.1021/acs.est.3c07967
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Dominant Processes of HONO Derived from Multiple Field Observations in Contrasting Environments Y. Jiang et al. 10.1021/acs.estlett.2c00004
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- Global Impact of Particulate Nitrate Photolysis on Fine Sulfate Aerosol L. Liu et al. 10.1021/acs.estlett.4c00416
- Origins of atmospheric nitrous acid and their contributions to OH radical from ship plumes, marine atmosphere, and continental air masses over South China Sea X. Ni et al. 10.1016/j.scitotenv.2024.175841
- Unveiling the underestimated direct emissions of nitrous acid (HONO) Q. Zhang et al. 10.1073/pnas.2302048120
- Observations of HONO and its precursors between urban and its surrounding agricultural fields: The vertical transports, sources and contribution to OH C. Xing et al. 10.1016/j.scitotenv.2023.169159
1 citations as recorded by crossref.
Latest update: 21 Apr 2025
Short summary
Nitrous acid (HONO) is a key source of atmospheric oxidants. We evaluate if the ocean surface is a source of HONO for the marine boundary layer, using measurements from two contrasting coastal locations. We observed no evidence for a night-time ocean surface source, in contrast to previous work. This points to significant geographical variation in the predominant HONO formation mechanisms in marine environments, reflecting possible variability in the sea-surface microlayer composition.
Nitrous acid (HONO) is a key source of atmospheric oxidants. We evaluate if the ocean surface is...
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