Articles | Volume 21, issue 19
https://doi.org/10.5194/acp-21-14789-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-14789-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Oct 2021
Research article |
| 06 Oct 2021
| 06 Oct 2021
Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NOx in eastern China
Yuliang Liu
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Wei Nie
CORRESPONDING AUTHOR
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Yuanyuan Li
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Dafeng Ge
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Chong Liu
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Zhengning Xu
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
College of Environmental and Resource Sciences, Zhejiang University, Zhejiang, China
Liangduo Chen
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Tianyi Wang
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Meteorological Service Center of Hubei Province, Wuhan, China
Lei Wang
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Ximeng Qi
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Jiaping Wang
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Zheng Xu
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Jian Yuan
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Yanjun Zhang
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, Villeurbanne, France
Dandan Huang
State Environmental Protection Key Laboratory of Formation and Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental Sciences, Shanghai, China
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hong Kong SAR, China
Neil M. Donahue
Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA, USA
Douglas Worsnop
Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica, MA, USA
Xuguang Chi
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
Mikael Ehn
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Aijun Ding
Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing, China
Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing, China
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- Response of organic aerosol characteristics to emission reduction in Yangtze River Delta region J. Wang et al. 10.1007/s11783-023-1714-0
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
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- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al. 10.1016/j.envpol.2022.120684
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- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
25 citations as recorded by crossref.
- Size-dependent chemical composition of atmospheric nanoparticles in urban Beijing during springtime Y. Chen et al. 10.1016/j.atmosenv.2023.119970
- NO at low concentration can enhance the formation of highly oxygenated biogenic molecules in the atmosphere W. Nie et al. 10.1038/s41467-023-39066-4
- Modeling the Formation of Organic Compounds across Full Volatility Ranges and Their Contribution to Nanoparticle Growth in a Polluted Atmosphere Z. Li et al. 10.1021/acs.est.3c06708
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Underestimated Contribution of Heavy Aromatics to Secondary Organic Aerosol Revealed by Comparative Assessments Using New and Traditional Methods L. Tian et al. 10.1021/acsearthspacechem.2c00252
- Characterization, Sources, and Chemical Processes of Submicron Aerosols at a Mountain Site in Central China H. Ou et al. 10.1029/2022JD038258
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- An overlooked oxidation mechanism of toluene: computational predictions and experimental validations Z. Fu et al. 10.1039/D3SC03638C
- One-year observation of the mixing states of oxygenated organics-containing single particles in Guangzhou, China L. Mao et al. 10.1007/s11783-024-1824-3
- Iodine oxoacids and their roles in sub-3 nm particle growth in polluted urban environments Y. Zhang et al. 10.5194/acp-24-1873-2024
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- Insufficient Condensable Organic Vapors Lead to Slow Growth of New Particles in an Urban Environment X. Li et al. 10.1021/acs.est.2c01566
- Diverse mixing states of amine-containing single particles in Nanjing, China Q. Zhong et al. 10.5194/acp-21-17953-2021
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Secondary organic aerosol formed by condensing anthropogenic vapours over China’s megacities W. Nie et al. 10.1038/s41561-022-00922-5
- Response of organic aerosol characteristics to emission reduction in Yangtze River Delta region J. Wang et al. 10.1007/s11783-023-1714-0
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Recent Progress in Atmospheric Chemistry Research in China: Establishing a Theoretical Framework for the “Air Pollution Complex” T. Zhu et al. 10.1007/s00376-023-2379-0
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Precursor apportionment of atmospheric oxygenated organic molecules using a machine learning method X. Qiao et al. 10.1039/D2EA00128D
- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al. 10.1016/j.envpol.2022.120684
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
Latest update: 26 Apr 2024
Short summary
Oxygenated organic molecules (OOMs) are crucial intermediates linking volatile organic compounds to secondary organic aerosols. Using nitrate time-of-flight chemical ionization mass spectrometry in eastern China, we performed positive matrix factorization (PMF) on binned OOM mass spectra. We reconstructed over 1000 molecules from 14 derived PMF factors and identified about 72 % of the observed OOMs as organic nitrates, highlighting the decisive role of NOx in OOM formation in populated areas.
Oxygenated organic molecules (OOMs) are crucial intermediates linking volatile organic compounds...
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