Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-7693-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-7693-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Jul 2020
Research article |
| 02 Jul 2020
| 02 Jul 2020
Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Arttu Ylisirniö
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Wei Huang
Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Claudia Mohr
Department of Environmental Science and Analytical Chemistry,
Stockholm University, Stockholm, Sweden
Manjula Canagaratna
Aerodyne Research Inc., Billerica, MA 08121, USA
Douglas R. Worsnop
Aerodyne Research Inc., Billerica, MA 08121, USA
Siegfried Schobesberger
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Annele Virtanen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Viewed
Total article views: 3,994 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 20 Nov 2019)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,615 | 1,326 | 53 | 3,994 | 443 | 47 | 85 |
- HTML: 2,615
- PDF: 1,326
- XML: 53
- Total: 3,994
- Supplement: 443
- BibTeX: 47
- EndNote: 85
Total article views: 2,956 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 02 Jul 2020)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,014 | 893 | 49 | 2,956 | 300 | 42 | 73 |
- HTML: 2,014
- PDF: 893
- XML: 49
- Total: 2,956
- Supplement: 300
- BibTeX: 42
- EndNote: 73
Total article views: 1,038 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 20 Nov 2019)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 601 | 433 | 4 | 1,038 | 143 | 5 | 12 |
- HTML: 601
- PDF: 433
- XML: 4
- Total: 1,038
- Supplement: 143
- BibTeX: 5
- EndNote: 12
Viewed (geographical distribution)
Total article views: 3,994 (including HTML, PDF, and XML)
Thereof 3,861 with geography defined
and 133 with unknown origin.
Total article views: 2,956 (including HTML, PDF, and XML)
Thereof 2,847 with geography defined
and 109 with unknown origin.
Total article views: 1,038 (including HTML, PDF, and XML)
Thereof 1,014 with geography defined
and 24 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
27 citations as recorded by crossref.
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements O. Tikkanen et al. 10.5194/acp-20-10441-2020
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Molecular Insights into Gas–Particle Partitioning and Viscosity of Atmospheric Brown Carbon Q. Xie et al. 10.1021/acs.est.4c05650
- Advanced instrumental approaches for chemical characterization of indoor particulate matter R. Duarte et al. 10.1080/05704928.2021.2018596
- Uncovering global-scale risks from commercial chemicals in air Q. Liu et al. 10.1038/s41586-021-04134-6
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Insights into the formation of secondary organic aerosols from agricultural residue burning emissions: A review of chamber-based studies S. Joshi et al. 10.1016/j.scitotenv.2024.175932
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Influence of organic aerosol molecular composition on particle absorptive properties in autumn Beijing J. Cai et al. 10.5194/acp-22-1251-2022
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Advances on analytical strategies for targeted and untargeted profiling of organic aerosols: Lessons learned and future challenges R. Duarte et al. 10.1016/j.hazadv.2023.100375
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol P. Rund et al. 10.1021/acsearthspacechem.3c00034
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Modeling atmospheric aging of small-scale wood combustion emissions: distinguishing causal effects from non-causal associations V. Leinonen et al. 10.1039/D2EA00048B
- Volatility Measurements of Individual Components in Organic Aerosol Mixtures Using Temperature-Programmed Desorption–Direct Analysis in Real Time–High Resolution Mass Spectrometry C. West et al. 10.1021/acs.analchem.3c00923
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
27 citations as recorded by crossref.
- The characterization of ambient levoglucosan in Beijing during summertime: Dynamic variation and source contributions under strong cooking influences J. Wang et al. 10.1016/j.jes.2024.08.029
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements O. Tikkanen et al. 10.5194/acp-20-10441-2020
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Molecular Insights into Gas–Particle Partitioning and Viscosity of Atmospheric Brown Carbon Q. Xie et al. 10.1021/acs.est.4c05650
- Advanced instrumental approaches for chemical characterization of indoor particulate matter R. Duarte et al. 10.1080/05704928.2021.2018596
- Uncovering global-scale risks from commercial chemicals in air Q. Liu et al. 10.1038/s41586-021-04134-6
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Insights into the formation of secondary organic aerosols from agricultural residue burning emissions: A review of chamber-based studies S. Joshi et al. 10.1016/j.scitotenv.2024.175932
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- Evolution of volatility and composition in sesquiterpene-mixed and <i>α</i>-pinene secondary organic aerosol particles during isothermal evaporation Z. Li et al. 10.5194/acp-21-18283-2021
- Influence of organic aerosol molecular composition on particle absorptive properties in autumn Beijing J. Cai et al. 10.5194/acp-22-1251-2022
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Advances on analytical strategies for targeted and untargeted profiling of organic aerosols: Lessons learned and future challenges R. Duarte et al. 10.1016/j.hazadv.2023.100375
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol P. Rund et al. 10.1021/acsearthspacechem.3c00034
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Modeling atmospheric aging of small-scale wood combustion emissions: distinguishing causal effects from non-causal associations V. Leinonen et al. 10.1039/D2EA00048B
- Volatility Measurements of Individual Components in Organic Aerosol Mixtures Using Temperature-Programmed Desorption–Direct Analysis in Real Time–High Resolution Mass Spectrometry C. West et al. 10.1021/acs.analchem.3c00923
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
Latest update: 23 Nov 2024
Short summary
To understand the role of aerosol particles in the atmosphere, it is necessary to know their detailed chemical composition and physical properties, especially volatility. The thermal desorption data from FIGAERO–CIMS provides both but are difficult to analyse. With positive matrix factorisation, we can separate instrument background from the real signal. Compounds can be classified by their apparent volatility, and the contribution of thermal decomposition in the instrument can be identified.
To understand the role of aerosol particles in the atmosphere, it is necessary to know their...
Altmetrics
Final-revised paper
Preprint