Articles | Volume 20, issue 12
https://doi.org/10.5194/acp-20-7531-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-7531-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
30 Jun 2020
Research article |
| 30 Jun 2020
| 30 Jun 2020
Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing
Daniel J. Bryant
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
William J. Dixon
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
James R. Hopkins
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Rachel E. Dunmore
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
Kelly L. Pereira
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
Marvin Shaw
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Freya A. Squires
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
Thomas J. Bannan
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
Archit Mehra
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
Stephen D. Worrall
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
now at: Chemical Engineering and Applied Chemistry, School of
Engineering and Applied Science, Aston University, Birmingham, UK
Asan Bacak
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
now at: Turkish Accelerator and Radiation Laboratory, Ankara University
Institute of Accelerator Technologies, Ankara, Turkey
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
Carl J. Percival
School of Earth and Environmental Sciences, The University of
Manchester, Manchester, UK
now at: Jet Propulsion Laboratory, California Institute of
Technology, 4800 Oak Grove Drive, Pasadena, CA, USA
Lisa K. Whalley
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds,
UK
Dwayne E. Heard
School of Chemistry, University of Leeds, Leeds, UK
Eloise J. Slater
School of Chemistry, University of Leeds, Leeds, UK
Bin Ouyang
Lancaster Environment Centre, Lancaster University, Lancaster, UK
Department of Chemistry, University of Cambridge, Cambridge, UK
Tianqu Cui
Department of Environmental Sciences and Engineering, Gillings School
of Global Health, University of North Carolina, Chapel Hill, USA
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute,
5232 Villigen, Switzerland
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School
of Global Health, University of North Carolina, Chapel Hill, USA
Di Liu
School of Geography, Earth and Environmental Sciences, the University
of Birmingham, Birmingham, UK
now at: State Key Laboratory of Organic Geochemistry and Guangdong
Provincial Key Laboratory of Environmental Protection and Resources
Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of
Sciences, Guangzhou 510640, PR China
Zongbo Shi
School of Geography, Earth and Environmental Sciences, the University
of Birmingham, Birmingham, UK
Institute of Surface-Earth System Science, Tianjin University,
Tianjin, China
Roy Harrison
School of Geography, Earth and Environmental Sciences, the University
of Birmingham, Birmingham, UK
Yele Sun
Institute of Atmospheric Physics, Chinese Academy of Sciences,
Beijing, PR China
Weiqi Xu
Institute of Atmospheric Physics, Chinese Academy of Sciences,
Beijing, PR China
Alastair C. Lewis
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
James D. Lee
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Jacqueline F. Hamilton
CORRESPONDING AUTHOR
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
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Cited
38 citations as recorded by crossref.
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Effects of NO2 and SO2 on the secondary organic aerosol formation from β-pinene photooxidation X. Zang et al. 10.1016/j.jes.2022.10.040
- Emissions from ships’ activities in the anchorage zone: A potential source of sub-micron aerosols in port areas A. Loh et al. 10.1016/j.jhazmat.2023.131775
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Molecular characterization of organic aerosols in Taiyuan, China: Seasonal variation and source identification W. Wang et al. 10.1016/j.scitotenv.2021.149419
- Nontarget Screening Exhibits a Seasonal Cycle of PM2.5 Organic Aerosol Composition in Beijing J. Ma et al. 10.1021/acs.est.1c06905
- Characterisation of atmospheric organic aerosols with one- and multidimensional liquid chromatography and mass spectrometry: State of the art and future perspectives S. Hildmann & T. Hoffmann 10.1016/j.trac.2024.117698
- Estimating emissions of biogenic volatile organic compounds from urban green spaces and their contributions to secondary pollution J. Ma et al. 10.1039/D4EA00099D
- Recent developments and applications of selected ion flow tube mass spectrometry (SIFT‐MS) D. Smith et al. 10.1002/mas.21835
- Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021 G. Oomen et al. 10.5194/acp-24-449-2024
- Molecular Characterization of Organosulfur and Organonitrogen Compounds in Summer and Winter PM2.5 via UHPLC-Q-Orbitrap MS/MS H. Li et al. 10.1021/acs.est.4c02727
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Development and Assessment of a High-Resolution Biogenic Emission Inventory from Urban Green Spaces in China M. Ma et al. 10.1021/acs.est.1c06170
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
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- A Semi-Quantitative Approach to Nontarget Compositional Analysis of Complex Samples R. Evans et al. 10.1021/acs.analchem.4c00819
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- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Impacts of biogenic emissions from urban landscapes on summer ozone and secondary organic aerosol formation in megacities Y. Gao et al. 10.1016/j.scitotenv.2021.152654
- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
- Autoxidation Mechanism and Kinetics of Methacrolein in the Atmosphere Z. Zhang et al. 10.1021/acs.jpca.3c00128
- An Automated Methodology for Non-targeted Compositional Analysis of Small Molecules in High Complexity Environmental Matrices Using Coupled Ultra Performance Liquid Chromatography Orbitrap Mass Spectrometry K. Pereira et al. 10.1021/acs.est.0c08208
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Different Reactivity of Birnessite and Cryptomelane toward Isoprene: Effect of Structure, Morphology, and Exposed Faces P. Liu et al. 10.1021/acs.jpcc.2c03418
- Heterogeneous Oxidation Products of Fine Particulate Isoprene Epoxydiol-Derived Methyltetrol Sulfates Increase Oxidative Stress and Inflammatory Gene Responses in Human Lung Cells F. Khan et al. 10.1021/acs.chemrestox.3c00278
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- An evaluation of new particle formation events in Helsinki during a Baltic Sea cyanobacterial summer bloom R. Thakur et al. 10.5194/acp-22-6365-2022
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Quantification of solid fuel combustion and aqueous chemistry contributions to secondary organic aerosol during wintertime haze events in Beijing Y. Tong et al. 10.5194/acp-21-9859-2021
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
38 citations as recorded by crossref.
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Effects of NO2 and SO2 on the secondary organic aerosol formation from β-pinene photooxidation X. Zang et al. 10.1016/j.jes.2022.10.040
- Emissions from ships’ activities in the anchorage zone: A potential source of sub-micron aerosols in port areas A. Loh et al. 10.1016/j.jhazmat.2023.131775
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Molecular characterization of organic aerosols in Taiyuan, China: Seasonal variation and source identification W. Wang et al. 10.1016/j.scitotenv.2021.149419
- Nontarget Screening Exhibits a Seasonal Cycle of PM2.5 Organic Aerosol Composition in Beijing J. Ma et al. 10.1021/acs.est.1c06905
- Characterisation of atmospheric organic aerosols with one- and multidimensional liquid chromatography and mass spectrometry: State of the art and future perspectives S. Hildmann & T. Hoffmann 10.1016/j.trac.2024.117698
- Estimating emissions of biogenic volatile organic compounds from urban green spaces and their contributions to secondary pollution J. Ma et al. 10.1039/D4EA00099D
- Recent developments and applications of selected ion flow tube mass spectrometry (SIFT‐MS) D. Smith et al. 10.1002/mas.21835
- Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021 G. Oomen et al. 10.5194/acp-24-449-2024
- Molecular Characterization of Organosulfur and Organonitrogen Compounds in Summer and Winter PM2.5 via UHPLC-Q-Orbitrap MS/MS H. Li et al. 10.1021/acs.est.4c02727
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Development and Assessment of a High-Resolution Biogenic Emission Inventory from Urban Green Spaces in China M. Ma et al. 10.1021/acs.est.1c06170
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Preventing biogenic secondary organic aerosols formation in India S. Azmi & M. Sharma 10.1016/j.atmosenv.2022.119352
- Particulate Matter-Induced Cardiovascular Dysfunction: A Mechanistic Insight N. Ain & S. Qamar 10.1007/s12012-021-09652-3
- A Semi-Quantitative Approach to Nontarget Compositional Analysis of Complex Samples R. Evans et al. 10.1021/acs.analchem.4c00819
- NMVOC emissions and their formation into secondary organic aerosols over India using WRF-Chem model S. Azmi et al. 10.1016/j.atmosenv.2022.119254
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Impacts of biogenic emissions from urban landscapes on summer ozone and secondary organic aerosol formation in megacities Y. Gao et al. 10.1016/j.scitotenv.2021.152654
- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
- Autoxidation Mechanism and Kinetics of Methacrolein in the Atmosphere Z. Zhang et al. 10.1021/acs.jpca.3c00128
- An Automated Methodology for Non-targeted Compositional Analysis of Small Molecules in High Complexity Environmental Matrices Using Coupled Ultra Performance Liquid Chromatography Orbitrap Mass Spectrometry K. Pereira et al. 10.1021/acs.est.0c08208
- Coupling a gas chromatograph simultaneously to a flame ionization detector and chemical ionization mass spectrometer for isomer-resolved measurements of particle-phase organic compounds C. Bi et al. 10.5194/amt-14-3895-2021
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Different Reactivity of Birnessite and Cryptomelane toward Isoprene: Effect of Structure, Morphology, and Exposed Faces P. Liu et al. 10.1021/acs.jpcc.2c03418
- Heterogeneous Oxidation Products of Fine Particulate Isoprene Epoxydiol-Derived Methyltetrol Sulfates Increase Oxidative Stress and Inflammatory Gene Responses in Human Lung Cells F. Khan et al. 10.1021/acs.chemrestox.3c00278
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- An evaluation of new particle formation events in Helsinki during a Baltic Sea cyanobacterial summer bloom R. Thakur et al. 10.5194/acp-22-6365-2022
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Quantification of solid fuel combustion and aqueous chemistry contributions to secondary organic aerosol during wintertime haze events in Beijing Y. Tong et al. 10.5194/acp-21-9859-2021
- Quality assurance and quality control of atmospheric organosulfates measured using hydrophilic interaction liquid chromatography (HILIC) P. Liu et al. 10.5194/amt-17-3067-2024
Latest update: 25 Dec 2024
Short summary
Using the chemical composition of offline filter samples, we report that a large share of oxidized organic aerosol in Beijing during summer is due to isoprene secondary organic aerosol (iSOA). iSOA organosulfates showed a strong correlation with the product of ozone and particulate sulfate. This highlights the role of both photochemistry and the availability of particulate sulfate in heterogeneous reactions and further demonstrates that iSOA formation is controlled by anthropogenic emissions.
Using the chemical composition of offline filter samples, we report that a large share of...
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