Articles | Volume 20, issue 18
https://doi.org/10.5194/acp-20-10865-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-10865-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Sep 2020
Research article |
| 18 Sep 2020
| 18 Sep 2020
Determination of the absorption cross sections of higher-order iodine oxides at 355 and 532 nm
Thomas R. Lewis
CORRESPONDING AUTHOR
Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, Madrid, Spain
School of Chemistry, University of Leeds, LS29JT, Leeds, UK
Juan Carlos Gómez Martín
Instituto de Astrofísica de Andalucía, CSIC, 18008, Granada,
Spain
Mark A. Blitz
School of Chemistry, University of Leeds, LS29JT, Leeds, UK
Carlos A. Cuevas
Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, Madrid, Spain
School of Chemistry, University of Leeds, LS29JT, Leeds, UK
Alfonso Saiz-Lopez
Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, Madrid, Spain
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Cited
17 citations as recorded by crossref.
- Chemical Implications of Rapid Reactive Absorption of I2O4 at the Air-Water Interface A. Ning et al. 10.1021/jacs.3c01862
- Global Bromine- and Iodine-Mediated Tropospheric Ozone Loss Estimated Using the CHASER Chemical Transport Model T. Sekiya et al. 10.2151/sola.2020-037
- Heterogenous Chemistry of I2O3 as a Critical Step in Iodine Cycling A. Ning et al. 10.1021/jacs.4c13060
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
- Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid J. Gómez Martín et al. 10.1021/jacs.1c12957
- Observations of iodine monoxide over three summers at the Indian Antarctic bases of Bharati and Maitri A. Mahajan et al. 10.5194/acp-21-11829-2021
- Low‐Volatility Vapors and New Particle Formation Over the Southern Ocean During the Antarctic Circumnavigation Expedition A. Baccarini et al. 10.1029/2021JD035126
- Sensitivity of Iodine-Mediated Stratospheric Ozone Loss Chemistry to Future Chemistry-Climate Scenarios J. Klobas et al. 10.3389/feart.2021.617586
- Noble classical and quantum approach to model the optical properties of metallic nanoparticles to enhance the sensitivity of optoplasmonic sensors A. Kumela et al. 10.1039/D2RA00824F
- Photochemical Mechanisms in Atmospherically Relevant Iodine Oxide Clusters N. Frederiks & C. Johnson 10.1021/acs.jpclett.4c01324
- Hydrogen sulfide measurement of combustion gaseous product using ultraviolet absorption spectroscopy B. Yang et al. 10.1016/j.measurement.2023.112766
- Probing the Potential Energy Profile of the I + (H2O)3 → HI + (H2O)2OH Forward and Reverse Reactions: High Level CCSD(T) Studies with Spin-Orbit Coupling Included X. Zhang et al. 10.3390/molecules28020904
- Iodine chemistry in the chemistry–climate model SOCOL-AERv2-I A. Karagodin-Doyennel et al. 10.5194/gmd-14-6623-2021
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- Mixing state and distribution of iodine-containing particles in Arctic Ocean during summertime L. Wang et al. 10.1016/j.scitotenv.2022.155030
- Laboratory mass spectrometry of intact atmospherically-relevant particles A. Hariharan & C. Johnson 10.1016/j.jaerosci.2024.106502
- A gas-to-particle conversion mechanism helps to explain atmospheric particle formation through clustering of iodine oxides J. Gómez Martín et al. 10.1038/s41467-020-18252-8
16 citations as recorded by crossref.
- Chemical Implications of Rapid Reactive Absorption of I2O4 at the Air-Water Interface A. Ning et al. 10.1021/jacs.3c01862
- Global Bromine- and Iodine-Mediated Tropospheric Ozone Loss Estimated Using the CHASER Chemical Transport Model T. Sekiya et al. 10.2151/sola.2020-037
- Heterogenous Chemistry of I2O3 as a Critical Step in Iodine Cycling A. Ning et al. 10.1021/jacs.4c13060
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
- Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid J. Gómez Martín et al. 10.1021/jacs.1c12957
- Observations of iodine monoxide over three summers at the Indian Antarctic bases of Bharati and Maitri A. Mahajan et al. 10.5194/acp-21-11829-2021
- Low‐Volatility Vapors and New Particle Formation Over the Southern Ocean During the Antarctic Circumnavigation Expedition A. Baccarini et al. 10.1029/2021JD035126
- Sensitivity of Iodine-Mediated Stratospheric Ozone Loss Chemistry to Future Chemistry-Climate Scenarios J. Klobas et al. 10.3389/feart.2021.617586
- Noble classical and quantum approach to model the optical properties of metallic nanoparticles to enhance the sensitivity of optoplasmonic sensors A. Kumela et al. 10.1039/D2RA00824F
- Photochemical Mechanisms in Atmospherically Relevant Iodine Oxide Clusters N. Frederiks & C. Johnson 10.1021/acs.jpclett.4c01324
- Hydrogen sulfide measurement of combustion gaseous product using ultraviolet absorption spectroscopy B. Yang et al. 10.1016/j.measurement.2023.112766
- Probing the Potential Energy Profile of the I + (H2O)3 → HI + (H2O)2OH Forward and Reverse Reactions: High Level CCSD(T) Studies with Spin-Orbit Coupling Included X. Zhang et al. 10.3390/molecules28020904
- Iodine chemistry in the chemistry–climate model SOCOL-AERv2-I A. Karagodin-Doyennel et al. 10.5194/gmd-14-6623-2021
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- Mixing state and distribution of iodine-containing particles in Arctic Ocean during summertime L. Wang et al. 10.1016/j.scitotenv.2022.155030
- Laboratory mass spectrometry of intact atmospherically-relevant particles A. Hariharan & C. Johnson 10.1016/j.jaerosci.2024.106502
Latest update: 29 May 2025
Short summary
Iodine-bearing gasses emitted from the sea surface are chemically processed in the atmosphere, leading to iodine accumulation in aerosol and transport to continental ecosystems. Such processing involves light-induced break-up of large, particle-forming iodine oxides into smaller, ozone-depleting molecules. We combine experiments and theory to report the photolysis efficiency of iodine oxides required to assess the impact of iodine on ozone depletion and particle formation.
Iodine-bearing gasses emitted from the sea surface are chemically processed in the atmosphere,...
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